• Journal of the Korean Chemical Society
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• v.47 no.6
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• pp.547-552
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• 2003

Separation and determinations of Co(II) and Ni(II) ions as their 4-(2-pyridylazo)resorcinol(PAR) chelates by reversed-phase capillary high-performance liquid chromatography(RP-CpHPLC) were performed. Among many capillary columns, Vydac C4 column was selected and acetonitrile solution was used as mobile phase. The effect of pH and MeCN concentration(%) on the retention factor, k and peak intensity was examined and discussed. As a results, it was found that 22.5% MeCN and pH 5.60 was adequate as mobile phase for the separation of the two metal ions and determination of Co(II) ion, but the mobile phase condition for Ni(II) ion determination was 22.5% MeCN of pH 7.20. Detection limit(D.L., S/N=3) of Co(II) and Ni(II) ions were $2.0{\times}10{-7}$ M(14.9 ppb) and $1.0{\times}10{-6}$ M(59.2 ppb), respectively.

• Journal of radiological science and technology
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• v.8 no.2
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• pp.71-72
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• 1985

This study was performed on the dose distribution of various field size and the effect of penumbra shield in the telecobalt unit. The results obtained are as follows. 1. Errors of the light and ${\gamma}-ray$ field size was below the regulation as 0.52 percentage. 2. The coefficient of field area was increased with the larger field area, and this coefficient was showed the more difference in larger SSD. 3. The rectangular field areas, which were described by level of the same percentage depth does, were decreased with the more elongation factor. At the same elongation factor, the compensating factor was decreased with the larger field size. 4. The lead block or extension collimator was able to shield r-ray exposure of outside field size from 50 to 80 percentage. 5. On the matching adjacent fields, while the gap between beam edges are contacted, that overlapped beam edges indicated up to 140 percentage, and while the gap was 1 cm, it could be reduced to 90 Percentage. The lead-libocking on the overlapped area was more effective to lower dose, as 80 percentage in this case. 6. Percentage depth dose of various trimming field sizes were increased linearlly according to area 1 perimeter size, but the center split field size did not maintain linearlly.

• Nuclear Engineering and Technology
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• v.22 no.4
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• pp.315-325
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• 1990

The analytical repository source term (REPS) computer code is developed for the safety assessment of radioactive waste geologic repository. For reliable prediction of the leach rates for various radionuclides, degradation of concrete structures, corrosion rate of waste container, degree of corrosion on the container surface, and the characteristics of radionuclides are considered in this REPS code. For the validation of the radionuclide leach rates predicted by the REPS model, the calculated leach rates of Cs-137, Sr-85, and Co-60 are compared with two reported leaching test results. Cesium and strontium leach congruently, and the leaching test results of these species can be reproduced by the congruent leaching model included in the REPS model. In case of cobalt, the solid diffusion model is in good agreement with the leaching test results.

• Cement
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• s.34
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• pp.34-49
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• 1970

Pneumatic coveying arrangements usually employed in the Cement Industry are one of big trouble makers. The troubles is, most of them are metal wears, on account of the high pressure and speed of the fluids inside of the conveying pipe and pressure vessel.

• The Science & Technology
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• v.8 no.11 s.78
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• pp.6-7
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• 1975

원자력의 산업적 이용에 대한 기틀이 될 대단위 방사선 가공 처리 시범 시설이 칙공 1년만인 10월 15일 한국 원자력 연구소 구내에 준공되었다. 국제 연합 개발계획(UNDP) 기금 49만 불의 지원과 내자 3억4천만 원을 들여 완공한 이 시설에는 코발트-60을 조사원으로 하는 방사선 조사 장치와 30만 전자 볼트의 전자 가속 장치가 설치되었다. 이날 최형섭 과학기술처장관, UNDP 주한 대표 "찬드"씨, 윤용구 한국원자력 연구소장을 비롯 2백여병의 내외 귀빈이 참석한 가운데 이 시설은 시운전 기간을 걸쳐 76년 말 국제원자력기구(IAEA)로부터 운영권이 한국원자력연구소로 이관되어 방사선의 산업적 이용을 극대화하게 된다. 이 시범 시설의 운영 목적은 국내의 여러 산업 기관으로 하여금 방사선 가공 기술의 응용 범위와 생산성이 높다는 것을 실제로 깨닫게 하여 제품을 개량하므로서 수출 증대를 도모하는데 있다.

• Journal of radiological science and technology
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• v.11 no.2
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• pp.65-71
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• 1988

Radiation dose outside the radiotherapy treatment field can be significant and therefore is of clinical interest estimating organ dose. We have made measurements of dose at distances up to 70 cm from the central axis of $5{\times}5$, $10{\times}10$, $15{\times}15$, and $25{\times}25$ cm radiation fields of Co-60 ${\gamma}-ray$, at 5 cm depth in water. Contributions to the total secondary radiation dose from water scatter, machine (collimator) scatter and leakage radiation have been seperated. We have found that the component of dose from water scatter can be described by simple exponential function of distance from the central axis of the radiation field for all field sizes. Machine scatter contributes 20 to 60% of the total secondary dose depending on field size and distance from the field. Leakage radiation contributes very little dose, but becomes the dominant componant at distance beyond 40 cm from the central axis. Then, wedges can cause a factor 2 to 3 increase in dose at any point outside the field compared with the dose when no wedge is used. Adding blocks to a treatment field can cause an increase in dose at points outside the field, but the effect is much smaller than the effect of a wedge. From the results of these measurements, doses to selected organs outside the field for specified treatment geometries were estimated, and the potential for reducing these organ doses by additional shielding was assessed.

• Journal of the Korean Electrochemical Society
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• v.23 no.3
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• pp.57-65
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• 2020

It is crucial to investigate the thermal degradation of lithium-ion batteries (LIBs) to understand the possible malfunction at high temperature. Herein, we investigated the effects of surface film formation on the thermal degradation of lithium cobalt oxide (LiCoO₂, LCO) cathode that is one of representative cathode materials. Cycling test at 60℃ exhibited poorer cycleability compared with the cycling at 25℃. Cathodes after the initial 5 cycles at 60℃ (60-LCO) exhibited higher impedance compared to the cathode after initial 5 cycles at 25℃ (25-LCO), resulting in the lower rate capability upon subsequent cycling at 25℃, although the capacity values were similar at the lowest C-rate of 0.1C. In order to understand degradation of the LCO cathode at the high temperature, we analyzed the cathodes surface using X-ray photoelectron spectroscopy (XPS). Among various peaks, intensity of lithium hydroxide (LiOH) increased substantially after the operation at 60℃, and the C-C signal that represents the conductive agent was distinctly lower on 60-LCO compared to 25-LCO. These results pointed to an excessive formation of cathode-electrolyte interphase including LiOH at 60℃, leading to the increase in the resistance and the resultant degradation in the electrochemical performances.

• Applied Chemistry for Engineering
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• v.30 no.3
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• pp.365-370
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• 2019

In this study, effects of the ultrasonic irradiation during the reaction process were investigated for the enantioselective kinetic resolution (EKR) reaction of racemic epoxides in the presence of chiral cobalt salen catalysts, as compared to that of using the conventional mechanical stirring. In order to compare catalytic activities, the chiral cobalt salen complexes having $AlCl_3-$, $BF_3-$ and nitrobenzenesulfonic acid (NBSA) were synthesized and used as catalysts, and then three kinds of the racemic epoxides such as ephichlorohydrine (ECH), epoxy phenoxypropane (EPP) and propylene oxide (PO) were used as reactants. In addition, EKR reactions have been performed using the water and methanol as nucleophiles, respectively. The unique contribution of ultrasonic irradiation as a powerful mixing medium was evaluated in this study to improve the kinetics in comparison to the conventional mechanical agitation during EKR reactions. The reaction time to obtain the highest 99 ee% became shorten more than that of above 60%, when the ultrasonic irradiation was used. This result may be interpreted by the cavitation effect of ultrasound in the solution, generating a powerful shear force for the very violent mixing.

• Journal of the Korean Society for Aeronautical & Space Sciences
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• v.41 no.1
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• pp.79-84
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• 2013

DC/DC switching power converters are commonly used to generate a regulated DC output voltage with high efficiency. The DC/DC converter is composed of a PWM-IC (pulse width modulation-integrated circuit) controller, a MOSFET (metal-oxide semiconductor field effect transistor), inductor, capacitor, etc. It is shown that the variation of threshold voltage and the offset voltage in the electrical characteristics of PWM-IC increase by radiation effects in TID (Total Ionizing Dose) testing at the low energy ${\gamma}$ rays using $^{60}Co$, and 4 heavy ions applied for SEL (Single Event Latch-up) make the PWM pulse unstable. Also, the output waveform for the given input in the DC/DC converter is observed by the simulation program with integrated circuit emphasis (SPICE). TID testing on PWM-IC is accomplished up to the total dose of 30 krad, and the cross section($cm^2$) versus LET($MeV/mg/cm^2$) in the PWM operation is studied at SEL testing after implementation of the controller board.

• Progress in Medical Physics
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• v.11 no.2
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• pp.131-139
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• 2000

We designed high dose rate Ir-192 source which was prepared for substitute the Co-60 source in Ralstron unit (Simatsu, Japan) which is supplied for cervical cancer treatment. The source dimension is 1.5 mm in a diameter and 1.5mm thickness of cylinder and encapsulated with 3 mm diameter of stainless steel(SUS316L) to substituted for the Co-60 source size. The Ir-192 source was prepared the dose model for tissue dose computation through the experimental determination of apparent activity and applied the empirical tissue correction factors extended to 20cm distance. The tissue dose model was applied the 4.69 R/cm-mCi-hr gamma constant and the ratio of energy absorption coefficient of water to that of air showed 1.112 include filteration of the self-absorptions. In this experiments, we prepared the dose computation software to clinical usefulness.