• Title/Summary/Keyword: 침투도랑

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Organic-inorganic Nanocomposite Adhesive with Improved Barrier Property to Water Vapor for Backsheets of Photovoltaic Modules (태양광모듈용 저가형 백시트 제조를 위한 고수분차단성 유무기 나노복합형 접착제)

  • Hwang, Jin Pyo;Lee, Chang Hyun
    • Membrane Journal
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    • v.25 no.6
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    • pp.530-537
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    • 2015
  • Photovoltaic (PV) modules are environmentally energy conversion devices to generate electricity via photovoltaic effect of semiconductors from solar energy. One of key elements in PV modules is "Backsheet," a multilayered barrier film, which determines their lifetime and energy conversion efficiency. The representative Backsheet is composed of chemically resistant poly(vinyl fluoride) (PVF) and cheap poly(ethylene terephthalate) (PET) films used as core and skin materials, respectively. PVF film is too expensive to satisfy the market requirements to Backsheet materials with production cost as low as possible. The promising alternatives to PVF-based Backsheet are hydrocarbon Backsheets employing semi-crystalline PET films instead of PVF film. It is, however, necessary to provide improved barrier property to water vapor to the PET films, since PET films are suffering from hydrolytic decomposition. In this study, a polyurethane adhesive with reduced water vapor permeation behavior is developed via a homogeneous distribution of hydrophobic silica nanoparticles. The modified adhesive is expected to retard the hydrolysis of PET films located in the core and inner skin. To clarify the efficacy of the proposed concept, the mechanical properties and electrochemical PV performances of the Backsheet are compared with those of a Backsheet employing the polyurethane adhesive without the silica nanoparticles, after the exposure under standard temperature and humidity conditions.

Characterization of Water Absorption by CFRP Using Air-Coupled Ultrasonic Testing (공기결합 초음파탐상에 의한 CFRP 복합재의 흡습 특성 평가)

  • Lee, Joo-Min;Lee, Joo-Sung;Kim, Yong-Kwon;Park, Ik-Keun
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.2
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    • pp.155-164
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    • 2014
  • Carbon-fiber-reinforced plastic (CFRP) composites are increasingly being used in a variety of industry applications, such as aircraft, automobiles, and ships because of their high specific stiffness and high specific strength. Aircraft are exposed to high temperatures and high humidity for a long duration during flights. CFRP materials of the aircraft can absorb water, which could decrease the adhesion strength of these materials and cause their volumes to change with variation in internal stress. Therefore, it is necessary to estimate the characteristics of CFRP composites under actual conditions from the viewpoint of aircraft safety. In this study air-coupled ultrasonic testing (ACUT) was applied to the evaluation of water absorption properties of CFRP composites. CFRP specimens were fabricated and immersed in distilled water at $75^{\circ}C$ for 30, 60, and 120 days, after which their ultrasonic images were obtained by ACUT. The water absorption properties were determined by quantitatively analyzing the changes in ultrasonic signals. Further, shear strength was applied to the specimens to verify the changes in their mechanical properties for water absorption.

Application of Analysis Models on Soil Water Retention Characteristics in Anthropogenic Soil (인위적으로 변경된 토양에서의 수분보유특성 해석 모형의 적용)

  • Hur, Seung-Oh;Jeon, Sang-Ho;Han, Kyung-Hwa;Jo, Hee-Rae;Sonn, Yeon-Kyu;Ha, Sang-Keun;Kim, Jeong-Gyu;Kim, Nam-Won
    • Korean Journal of Soil Science and Fertilizer
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    • v.43 no.6
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    • pp.823-827
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    • 2010
  • This study was conducted to assess the propriety of models for soil water characteristics estimation in anthropogenic soil through the measurement of soil water content and soil water matric potential. Soil profile was characterized with four different soil layers. Soil texture was loamy sand for the first soil layer (from soil surface to 30 cm soil depth), sand for the second (30~70 cm soil depth) and the third soil layers (70~120 cm soil depth), and sandy loam for the fourth soil layer (120 cm < soil depth). Soil water retention curve (SWRC), the relation between soil water content and soil water matric potential, took a similar trend between different layers except the layer of below 120 cm soil depth. The estimation of SWRC and air entry value was better in van Genuchten model by analytical method than in Brooks-Corey model with power function. Therefore, it could be concluded that van Genuchten model is more desirable than Brook-Corey model for estimating soil water characteristics of anthropogenic soil accumulated with saprolite.

Evaluation on Mechanical Performance and Chloride Ion Penetration Resistance of On-Site Shotcrete Made with Slurry-Type Accelerator (슬러리형 급결제를 활용한 현장적용 숏크리트의 역학적 성능 및 염해저항성 평가)

  • Kim, Hyun-Wook;Yoo, Yong-Sun;Han, Jin-Kyu;Chung, Chul-Woo
    • Journal of the Korea Institute of Building Construction
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    • v.18 no.6
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    • pp.507-515
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    • 2018
  • The purpose of this research is to develop a slurry-type accelerator that contains various beneficial properties such as reduction of dust generation, lower alkalinity, early age strength development, etc., and uses such slurry type accelerator to produce high performance shotcrete that present excellent resistant against chloride ion penetration. In this work, shotcrete mixtures of 0.44 and 0.338 water-to-binder ratio (w/b) were produced at construction site using slurry-type accelerator. The mechanical properties and chloride ion penetration resistance of such shotcrete (including base concrete) were evaluated. According to the experimental results, the slurry-type accelerator was successfully used to produce both w/b 0.44 and 0.338 shotcretes. The 1 day and 28 day compressive strength of shotcrete were found to be closer to or higher than 10MPa and 40MPa, respectively. The w/b 0.338 shotcrete that used 40% replacement of blast furnace slag showed lower compressive strength than w/b 0.44 shotcrete without any mineral admixture at 1 day. However, the compressive strength with 40% blast furnace slag increased significantly at 28 day. Moreover, there was more than 50% increase in chloride ion penetration resistance with blast furnace slag, showing its strong potential for higher performance shotcrete application.

Synthesis of Pt-Bi/Carbon Electrodes by Reduction Method for Direct Methanol Fuel Cell (환원법에 의한 직접 메탄올 연료전지(DMFC)용 Pt-Bi/Carbon 전극제조)

  • Kim, Kwan Sung;Kim, Min Kyung;Noh, Dong Kyun;Tak, Yongsug;Baeck, Sung-Hyeon
    • Applied Chemistry for Engineering
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    • v.22 no.5
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    • pp.479-485
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    • 2011
  • Pt-Bi/C catalysts supported on carbon black with various Pt/Bi ratios were synthesized by a reduction method. Chloroplatinic acid hydrate ($H_2PtCl_6{\cdot}xH_2O$) and bismuth (III) nitrate pentahydrate ($Bi(NO_3)_3{\cdot}5H_2O$) were used as precursors for Pt and Bi, respectively. Before loading metal on carbon, heat treatment and pretreatment of carbon black in an acidic solution was conducted to enhance the degree of dispersion. The physical property of the synthesized catalysts was investigated by X-ray diffraction and X-ray photoelectron spectroscopy. The XRD pattern of untreated Pt-Bi/C catalyst showed BiPt and $Bi_2Pt$ peaks in addition to Pt peaks. These results imply that Bi atoms were incorporated into the Pt crystal lattice by Pt-Bi alloy formation. The catalytic activity for methanol oxidation was measured using cyclic voltammetry in a mixture of 0.5 M $H_2SO_4$ and 0.5 M $CH_3OH$ aqueous solution. The addition of proper amount of Bi was found to significantly improve catalytic activity for methanol oxidation. The catalytic activity for methanol oxidation was closely related to the stability between electrode and electrolyte. In order to investigate the stability of catalysts, chronoamperometry analysis was carried out in the same solution at 0.6 V.

Field Applicability Evaluation of Control Low Strength Materials as Utilizing Various Industrial by-Products (공동충전재로써 각종 산업부산물을 활용한 CLSM의 현장적용 가능성 평가)

  • Liao, Xiao-kai;Kim, Dong-Hun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.8 no.4
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    • pp.387-394
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    • 2020
  • In this research, a physical property test of CLSM, which can safely and effectively utilize a great number of industrial byproducts and waste types, was used to review the applicability of GBFS, FNS, and FGB, as well as their field applicabilities as cavity fillers, and the following conclusions have been reached. first, For CLSM utilizing GBFS, FNS, and FGB, it was revealed that a proper mixing of over 30% of GBFS and FNS or within 5% of FGB is effective in improving the fluidity for field application. second, It was revealed that GF15B5 can suppress bleeding at a similar level as the base, whereas GF30B5 can do so at about 0.17% compared to the base. It was also verified that GF15, GF30, and GF45 can suppress bleeding at about 0.2%, 0.26%, and 0.3%, respectively, compared to the base. third, Both GF15B5 and GF30B5 exceeded 0.4MPa in 7day strength tests to satisfy the field application and, also, the rates of increase of their initial strengths were found to be 323% and 233% higher than the base, respectively. Meanwhile, the 7day strength test of GF, which utilizes GBFS and FNS, also reached over 0.2MPa for field application, and it was revealed that GF15, GF30, and GF45 show 160%, 237%, and 185% higher strength increase rates, respectively, compared to the base.

A Study of the Transdermal Permeation of Lotion Formulations Containing Angelica gigas Nakai Extracts in Franz Diffusion Cells (Franz diffusion cell을 이용한 참당귀 추출물 함유한 로션제형의 피부 투과 연구)

  • Kim, Kang Min
    • Journal of Life Science
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    • v.31 no.11
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    • pp.1004-1009
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    • 2021
  • Angelica gigas Nakai (AGN) has been used in Korean herbal medicine for various pharmacological activities, such as to create antioxidant and skin whitening effects. Decursin and decursinol angelate of AGN extracts can be used as potential active drugs and cosmetic ingredients. This study investigated the possibility of topical delivery of AGN extracts using a manufactured emulsion system. Lotion was formulated by using Tefose® and paraffin for the oil phase, Kolliphor RH 40 for the surfactant and solubilizing agent-which showed high solubility in water (0.82 mg/ml)-and a water phase with a carbomer. In vitro skin permeation of decursin and decursinol angelate was determined using a Strat-M® membrane in Franz diffusion cells. Lotion samples as the experimental group (248.08±19.72 ug/cm2) significantly increased the permeation of decursin and decursinol angelate for up to 24 hr compared to the control group (119.18±19.23 ug/cm2). The permeability was also characterized by the flux (penetration rates) and Kp (permeability coefficient) values. The experimental group (17.20±1.23 ug/h/cm2 and 5.73±1.39 cm/h*10-3) had higher flux and Kp than the control group (8.22±1.24 ug/h/cm2 and 2.74±0.51 cm/h*10-3). Lotion with decursin and decursinol angelate of AGN extracts could be used for the topical application of drug and cosmetic products.

COVID-19 in a 16-Year-Old Adolescent With Mucopolysaccharidosis Type II: Case Report and Review of Literature

  • Park, So Yun;Kim, Heung Sik;Chu, Mi Ae;Chung, Myeong-Hee;Kang, Seokjin
    • Pediatric Infection and Vaccine
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    • v.29 no.2
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    • pp.70-76
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    • 2022
  • Coronavirus disease 2019 (COVID-19) in patients with underlying diseases, is associated with high infection and mortality rates, which may result in acute respiratory distress syndrome and death. Mucopolysaccharidosis (MPS) type II is a progressive metabolic disorder that stems from cellular accumulation of the glycosaminoglycans, heparan, and dermatan sulfate. Upper and lower airway obstruction and restrictive pulmonary diseases are common complaints of patients with MPS, and respiratory infections of bacterial or viral origin could result in fatal outcomes. We report a case of COVID-19 in a 16-year-old adolescent with MPS type II, who had been treated with idursulfase since 5 years of age. Prior to infection, the patient's clinical history included developmental delays, abdominal distension, snoring, and facial dysmorphism. His primary complaints at the time of admission included rhinorrhea, cough, and sputum without fever or increased oxygen demand. His heart rate, respiratory rate, and oxygen saturation were within the normal biological reference intervals, and chest radiography revealed no signs of pneumonia. Consequently, supportive therapy and quarantine were recommended. The patient experienced an uneventful course of COVID-19 despite underlying MPS type II, which may be the result of an unfavorable host cell environment and changes in expression patterns of proteins involved in interactions with viral proteins. Moreover, elevated serum heparan sulfate in patients with MPS may compete with cell surface heparan sulfate, which is essential for successful interaction between the severe acute respiratory syndrome coronavirus 2 (SARS-CoV-2) spike protein and the host cell surface, thereby protecting against intracellular penetration by SARS-CoV-2.

Frequency Stability Enhancement of Power System using BESS (BESS를 활용한 전력계통 주파수 안정도 향상)

  • Yoo, Seong-Soo;Kwak, Eun-Sup;Moon, Chae-Joo
    • The Journal of the Korea institute of electronic communication sciences
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    • v.17 no.4
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    • pp.595-606
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    • 2022
  • Korea has the characteristics of traditional power system such as large-scale power generation and large-scale power transmission systems, including 20 GW large-scale power generation complexes in several regions with unit generator capacity exceeding 1.4 GW, 2-3 ultra-high-voltage transmission lines that transport power from large-scale power generation complexes, and 6 ultra-high-voltage transmission lines that transport power from non-metropolitan areas to the metropolitan area. Due to the characteristics of the power system, the penetration level for renewable energy is low, but due to frequency stability issue, some generators are reducing the output of generators. In the future, the issue of maintaining the stability of the power system is expected to emerge as the most important issue in accordance with the policy of expanding renewable energy. When non-inertial inverter-based renewable energy, such as solar and wind power, surges rapidly, the means to improve the power system stability in an independent system is to install a natural inertial resource synchronous condenser (SC) and a virtual inertial resource BESS in the system. In this study, we analyzed the effect of renewable energy on power system stability and the BESS effect to maintain the minimum frequency through a power system simulation. It was confirmed that the BESS effect according to the power generation constraint capacity reached a maximum of 122.81 %.

Numerical Study of Heat Flux and BOG in C-Type Liquefied Hydrogen Tank under Sloshing Excitation at the Saturated State (포화상태에 놓인 C-Type 액체수소 탱크의 슬로싱이 열 유속과 BOG에 미치는 변화의 수치적 분석)

  • Lee, Jin-Ho;Hwang, Se-Yun;Lee, Sung-Je;Lee, Jang Hyun
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.35 no.5
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    • pp.299-308
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    • 2022
  • This study was conducted to predict the tendency for heat exchange and boil-off gas (BOG) in a liquefied hydrogen tank under sloshing excitation. First, athe fluid domain excited by sloshing was modeled using a multiphase-thermal flow domain in which liquid hydrogen and hydrogen gas are in the saturated state. Both the the volume of fluid (VOF) and Eulerian-based multi-phase flow methods were applied to validate the accuracy of the pressure prediction. Second, it was indirectly shown that the fluid velocity prediction could be accurate by comparing the free surface and impact pressure from the computational fluid dynamics with those from the experimental results. Thereafter, the heat ingress from the external convective heat flux was reflected on the outer surfaces of the hydrogen tank. Eulerian-based multiphase-heat flow analysis was performed for a two-dimensional Type-C cylindrical hydrogen tank under rotational sloshing motion, and an inflation technique was applied to transform the fluid domain into a computational grid model. The heat exchange and heat flux in the hydrogen liquid-gas mixture were calculated throughout the analysis,, whereas the mass transfer and vaporization models were excluded to account for the pure heat exchange between the liquid and gas in the saturated state. In addition, forced convective heat transfer by sloshing on the inner wall of the tank was not reflected so that the heat exchange in the multiphase flow of liquid and gas could only be considered. Finally, the effect of sloshing on the amount of heat exchange between liquid and gas hydrogen was discussed. Considering the heat ingress into liquid hydrogen according to the presence/absence of a sloshing excitation, the amount of heat flux and BOG were discussed for each filling ratio.