• Title/Summary/Keyword: 치환방법

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Contributions of Ionic Strength, pH, and Replacing Cations to the Cation Exchange Capacities of Soils (치환양(置換陽) ion의 종류(種類) 및 pH 가 토양(土壤)의 양(陽) ion 치환용량(置換容量)에 미치는 영향(影響))

  • Lim, Hyung-Sik;Kwag, Pan-Ju;Kim, Hee-Joong
    • Korean Journal of Soil Science and Fertilizer
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    • v.17 no.2
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    • pp.114-124
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    • 1984
  • Various methods for measuring cation exchange capacity (CEC) of soil were compared and the contributions of ionic strength, pH and replacing cations to the CEC were investigated on Kangweon soils (Pyeongchang soils derived from lime stone : Chuncheon, Weonseong soils from alluvium : Cheolweon soils from basalt). The results were as follows : 1. The CEC measuring method using shaker and centrifuge at saturating, washing and replacing precesses, which are common in determining CEC of soils, appeared to be superior to the other methods using column, filter, or Brown method. 2. For all soil samples, the higher the ionic strength, the higher CEC value was obtained with the fewer saturating processes. However, using monovalent saturating ion on Anmi series soil derived from lime stone, the CEC value decreased when the ionic strength and the number of saturating process increased. 3. The CEC value generally increased with increasing pH. But, Chuncheon soil (Gyuam series from alluvium) having higher Al content showed the abrupt increases of CEC from pH 5.5 to pH 7.5. 4. About 70% of CEC of Kangweon soils were attributed to organic matter. 5. In determining CEC of soils, saturating with 0.5M divalent cation solution 2 to 3 times for Pyeongchang and Weonseong soil, 3 to 4 times for Cheolweon soil, and replacing with 0.25M divalent cation solution about 3 times are thought to be recommendable.

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Partial Resection of Osteosarcoma in Proximal Tibia - A Case Report - (근위 경골 골육종의 부분 절제술 - 증례 보고 -)

  • Song, Won-Seok;Lee, Seung-Jun;Won, Ho-Hyun;Jeon, Dae-Geun
    • The Journal of the Korean bone and joint tumor society
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    • v.14 no.2
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    • pp.140-145
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    • 2008
  • After limb salvage operation becomes popular, reconstruction method of epi-metaphyseal osteosarcoma is relatively standardized though it may be operator's matter of preference. Most limb salvage techniques presently used are prosthesis reconstruction and osteoarticular allograft. In the case of prosthesis, it is very stable and shows good postoperative functional score, however, finally, it has a weak point of requirement for removal procedure due to failure. In the long run, allograft reconstruction has a good merit. But, it has a weak point of difficulties in securing the demanded size and shape. Allograft reconstruction should be performed only in the case of safe margin and established indication. In limb salvage operation, intercalary reconstruction is useful method in diaphyseal osteosarcoma, however, in metaphyseal osteosarcoma, the indication is not confirmed. We treated 17 year old osteosarcoma patient with localized in the tibial medial condyle with proximal medial condylectomy and pasteurized bone reconstruction in the conviction of safe surgical margin. We report this case because we guess if this procedure may be applied to premature patients, despite failure hemiarthroplasty can be tried successfully.

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Prediction of Setting Time of Concrete Using Fly Ash and Super Retarding Agent (초지연제 및 플라이애쉬를 사용한 콘크리트의 응결시간 예측)

  • Han, Min-Cheol
    • Journal of the Korea Concrete Institute
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    • v.18 no.6 s.96
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    • pp.759-767
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    • 2006
  • This paper presents a method to estimate the setting time of concrete using super retarding agent(SRA) and fly ash(FA) under various curing temperature conditions by applying maturity based on equivalent age. To estimate setting time, the equivalent age using apparent activation energy($E_a$) was applied. Increasing SRA content and decreasing curing temperature leads to retard initial and final set markedly. $E_a$ at the initial set and final set obtained by Arrhenius function showed differences in response to mixture type. It is estimated to be from $24{\sim}35KJ/mol$ in all mixtures, which is smaller than that of conventional mixture ranging from $30{\sim}50KJ/mol$. Based on the application of $E_a$ to Freisleben-Hansen and Pederson's equivalent age function, equivalent age is nearly constant, regardless of curing temperature and SRA contents. This implies that the concept of maturity is applicable in estimating the setting time of concrete containing SRA. A high correlation between estimated setting time and measured setting time is observed. Multi-regression model to determine appropriate dosage of SRA reflecting FA contents and equivalent age was provided. Thus, the setting time estimation method studied herein can be applicable to the concrete containing SRA and FA in construction fields.

Microbiological Safety of Minimally Processed White Radish in Modified Atmosphere Packaging Combined with Irradiation Treatment (가스치환포장과 감마선조사 병용 처리한 최소가공 무의 미생물학적 안전성)

  • Kim, Jae-Kyung;Jo, Cheo-Run;Kim, Hyun-Ju;Lee, Ju-Woon;Hwang, Han-Joon;Byun, Myung-Woo
    • Korean Journal of Food Science and Technology
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    • v.37 no.1
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    • pp.11-14
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    • 2005
  • White radish was minimally processed, packed with air, $CO_{2}$ (100%), and $CO_{2}/N_{2}$ (25/75%), and irradiated at 0, 1, and 2 kGy, and its microbiological quality and pH were investigated during storage for 2 weeks at $4^{\circ}C$. Irradiation significantly reduced total aerobic, coli-form, and lactic acid bacteria counts. Modified atmosphere packaging (MAP) enhanced microorganism control during storage. Acidity decreased by MAP but was restored during storage, Irradiation did not affect sample pH. Results show irradiation at 2 kGy combined with MAP can enhance microbiological safety and quality of minimally processed radish.

Development of Cellulosic Fiber Filter Using Replacement Liquid in Water-Swollen Fiber with Non-Polar Solvent (Non-Polar 물질 수분치환에 의한 종이필터 개발)

  • Kim, Kwang Soo;Ahn, Kwang Ho;Park, Jae Ro;Kim, Hyun Jung
    • Journal of Korean Society of Environmental Engineers
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    • v.35 no.10
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    • pp.743-748
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    • 2013
  • The purposes of this study are to prepare Hanji fiber-filter sheets using replacement liquid in water-swollen fiber with non-polar solvent such as ethanol, methanol and pentane. The experiments were studied on the selection of optimal non-polar solvent and the optimal drying method for wetted fiber and then were to know physicochemical characteristics of prepared Hanji fiber-filter sheet. The Ethanol as liquid changer in water-swollen fiber was excellent solvent and the optimal drying method for them was freeze drying served with vacuum pump. The bulk density and porosity of prepared fiber sheet from freeze dryer were 0.11-0.13 g/mL, half of natural dried fiber sheet, and 90%, respectively. The results of SEM observation for the fiber sheet prepared with natural drying or heating drying were shown very close structure of fiber wall in dry state. However, the freeze drying sheet were shown the open structure. So, the head loss of freeze drying sheet was very lower than natural drying and heating drying sheets. From the results of BTEX removal experiments, the sheets dried at water wetted condition was shown more higher efficiency than the fiber sheets dried at solvent wetted condition.

Homograft Aortic Root Replacement (동종이식편을 이용한 대동맥 근부 치환술)

  • Kim Jae Hyun;Oh Sam Sae;Lee Chang-Ha;Baek Man Jong;Kim Chong Whan;Na Chan-Young
    • Journal of Chest Surgery
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    • v.38 no.3 s.248
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    • pp.197-203
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    • 2005
  • Homograft aortic valve replacement (AVR) has many advantages such as excellent hemodynamic performance, faster left ventricular hypertrophy regression, resistance to infection and excellent freedom of thromboembolism. To find out the results of homograft AVR, we reviewed our surgical experiences. Material and Method: Eighteen patients (male female=16 : 2, mean age=39.3$\pm$16.2 years, range: 14$\~$68 years) who underwent homo-graft aortic valve replacement between May 1995 and May 2004 were reviewed. The number of homografts was 20 (17 aortic and 3 pulmonic homografts) including two re-operations. Ten patients had a history of previous aortic valve surgery. Indications for the use of a homograft were native valve endocarditis (n=7), prosthetic valve endocarditis (n=5), or Behcet's disease (n=8). The homograft had been implanted predominantly as a full root except in one patient in the subcoronary position. Result: Mean follow-up was 41.3 $\pm$ 26.2 months. There was one operative mortality. Postoperative complications included postoperative bleeding in 3 patients, and wound infection in 1. There was no late death. Three patients underwent redo-AVR. The etiology of the three reoperated patients was Behcet's disease (p=0.025). Freedom from reoperation was $87.5\pm8.3\%$, $78.8\pm11.2\%$ at 1, 5 years respectively, In patients with infective endocarditis, there was no recurrence of endocarditis. There was no thromboembolic complication. Conclusion: Although longer term follow-up with larger numbers of patients is necessary, the operative and mid-term results for homograft AVR was good when we took into account the operative risks of Behcet's disease or infective endocarditis. Behest's disease was a risk factor for reoperation after the homograft AVR. We think homograft AVR is the procedure of choice, particularly in patients with infective endocarditis.

The Short Term Clinical Follow-up Study for Hemiarthroplasty in Proximal Humeral Fracture (상완골 근위부 분쇄 골절에서의 상완골 두 치환술의 단기 추시 결과)

  • Sung, Chang-Meen;Cho, Se-Hyun;Jung, Soon-Taek;Hwang, Sun-Chul;Park, Hyung-Bin
    • Clinics in Shoulder and Elbow
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    • v.10 no.1
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    • pp.92-98
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    • 2007
  • Introduction: The treatment of proximal humeral fracture is traditionally determined by Neer's classification system. The severely displaced three-part or four-part fracture is an indication for primary hemiarthroplasty. The current authors report the clinical results of 10 patients who received hemiarthroplasty for proximal comminuted fractures. The minimum follow-up period was 12 months. Materials and Methods: The current authors studied 10 patients who, between July 1999 and March 2005, each received hemiarthroplasty for a proximal humeral fracture of one shoulder. According to Neer's classification system, 5 of the patients had three-part fractures, and 5 of the patients had 4-part fractures. The mean interval between trauma and hemiarthroplasty was 6.1 days. The mean age of the 6 female and 4 male patients was 67.4 years(range: 56 to 76). Shoulder function was evaluated using the Constant score, the Simple Shoulder Test, and the modified UCLA score. Results: The mean Constant score was 51.4(range: 34 to 60). The mean modified SST score was 7.8 out of 12 tasks. Excluding the one patient who had also sustained an axillary artery rupture and a brachial plexus injury after the initial trauma, the mean Constant score for the remaining 9 patients was 53.5(range: 44 to 60), and the mean SST score was 7.2 tasks. The modified UCLA score averages for pain, function, and active forward flexion and strength were, respectively, 8.2($6{\sim}10$), 6.6($2{\sim}8$), and 6.9($4{\sim}8$). The total UCLA score was an average of 21.7($12{\sim}26$). Patients' the modified UCLA ratings were as follows: Excellent: 3, Good: 6, and Poor: 1. The patient with the poor outcome was the one who had also sustained the neurovascular injury. Patient's subjective satisfaction rating were as follows: Excellent: 2, Good: 7, and Poor: 1. Conclusion: Based on short term follow-up results, this study indicates that hemiarthroplasty is the treatment of choice for proximal humeral fractures on which it would be difficult to perform open reduction and internal fixation. Hemiarthroplasty is a useful treatment modality to prevent shoulder stiffness and to allow daily living tasks in elderly patients. However, restoration of muscle power and range of joint motion were not recovered satisfactorily.

Clinical Result of Aortic Arch Replacement using Antegrade Brain Perfusion Via Right Axillary Artery (우액와동맥을 통한 순행성 뇌관류법을 이용한 대동맥궁 치환의 임상성적)

  • Kim, Dong-Jin;Na, Yong-Jun;Jeong, Dong-Seop;Kim, Kyung-Hwan
    • Journal of Chest Surgery
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    • v.40 no.1 s.270
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    • pp.25-31
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    • 2007
  • Background: Cerebral protection is one of the most important procedures during aortic arch surgery. We can minimize neurological complications through short period of total circulatory arrest and resuming of brain perfusion. We evaluated 11 patients who underwent arch replacement using antegrade brain perfusion via right axillary artery. Material and Method: Between July 2004 and July 2006, 11 patients (male 9, female 2) underwent aortic arch replacement with antegrade brain perfusion via right axillary artery. Preoperative diagnosis was listed; 5 type A aortic dissections (5/11, 45.5%), 5 aortic aneurysms (5/11, 45,5%) and 1 type A IMH (intramural hematoma, 1/11, 9%). The mean age at the time of operation was $60.3{\pm}12.8$ years. For antegrade brain perfusion, we performed right axillary artery cannulation in all patients. Retrograde brain perfusion was used briefly during total circulatory arrest. Result: The mean total circulatory arrest time was $31.1{\pm}16.9$ minutes and the mean retrograde brain perfusion time was $21{\pm}17.8$ minutes. Mean antegrade brain perfusion time was $77.9{\pm}17.5\;(43{\sim}101)$ minutes. We had neither operative mortality nor permanent neurological complications. Conclusion: By means of antegrade brain perfusion via right axillary artery, that could lead to decrease circulatory arrest time and minimize damages to severely atheromatous arch vessels, we can expect to reduce neurological complications after aortic arch replacement. Further investigation with iarge patient populations will be required.

A Study on the Shape Analysis of Membrane Structures Using Line Elements (선재 요소를 이용한 막 구조물의 형상해석에 관한 연구)

  • Kim, Seung-Deog;Lee, Shin-Woo
    • Journal of Korean Association for Spatial Structures
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    • v.10 no.2
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    • pp.45-60
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    • 2010
  • Nonlinear problems for membrane structures are very sensitive in convergence procedure in nonlinear iterations. Therefore many researchers have suggested a lot of ideas in published papers. In this study, authors are trying to get easier solution for taking membrane shape by initial stresses from substitution of the membrane to line elements. To obtain nonlinear stiffness, the nonlinear finite element method is used for both membrane and cable elements, and only geometric nonlinear terms are taken for shape analysis. By some examined models, we can find that the substituted models show better results to get, initial shape in which the concentrating phenomenon is removed at edge parts.

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Immobilization of Lum,brokinase on the Surface of Polyurethane by using the Photoreactive Poly(acrylic acid) (광반응성 poly(acrylic acid)를 이용한 Lumbrokinase 의 polyurethane 표면 고정화 방법에 관한 연구)

  • 김현정;류은숙;김종원;민병구
    • Journal of Biomedical Engineering Research
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    • v.20 no.6
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    • pp.547-553
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    • 1999
  • 생체재료로 사용되는 polyurethane(PU) 표면에 항혈전성 lumbrokinase(LK)를 고정함으로써 생체적합성을 향상시키고자하였다. 먼저 LK를 PU 표면에 고정하기 위한 가교제로서 4-azidoaniline hydrochloride와 poly(acrylic acid)를 이용하여 4-azidophenyl 작용기가 amido 결합으로 치환된 수용성, 광반응성 poly(acrylic acid)(PPa-II)를 합성하였다. H-nuclear magnetic reasonance spectrum(500MHz H-NMR)의 6-7 peak와 infrared spectrum (FT-IR) 의 2125.48 cm peak으로부터 PPA-II의 합성을 지원하였다. EH한 4-azidophenyl 작용기가 poly(acrylid acid) 잔기에 치환된 정도는 UV/VIS adpectrophotometric spectrum을 확인한 결과 11~14%임을 알 수있었다. 0.5 1및 5% PPA-II를 각각 광반응하여 얻은 PU는 39.5, 161.8 및 181.5 nmole/$\textrm{cm}^2$의 농도로 표면에 carvoxyl 작용기가 유도되었음을 알 수있었다. 0.05M KH2PO4 (pH 4.5) 용액에서 1-ethyl-3-(3-(dimethylamino)propyl)carbodiimide(EDC)를 촉매로 사용하여 LK를 PU표면에 amido 공유결합으로 고정하였으며, 이것은 지속적인 fibrinolytic 활성도를 보였다. PPA-II를 이용한 표면 개질 방법은 수용성 반응조건에서 이루어진다는 점과 광반응을 이용함으로써 특정부위에서의 표면개질이 가능하다는 점에서 그 응용가치가 크며 아울러 PU의 생체적합성을 향상시킬 수 있는 방법으로서 판단된다.

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