• Title/Summary/Keyword: 치환거동

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Oxidation Behavior and Magnetic Properties of Nd-Fe-B Based Melt-Spun Ribbons (Nd-Fe-B계 급냉리본의 산화거동과 자기적 특성)

  • Jo, Beom-Rae;Kim, Jin-Gu;Song, Jin-Tae;Gang, Gi-Won
    • Korean Journal of Materials Research
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    • v.5 no.4
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    • pp.483-489
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    • 1995
  • Nd-(Fe, Co)-B합금에 Ni, Al, Ti등을 복합치환하여 그에 따른 산화거동과 자기적 성질의 변화를 조사하였다. 이들 리본의 산호거동은 parabolic한 거동을 나타내고 있으며, Ni 첨가시 매우 낮은 산화량을 나타내었다. 또한 산화된 리본은 Nd-rich상의 우선적 산화에 의해 표면에 요철이 관찰되었으며 Ni 첨가시 그러한 요철은 많이 줄어들었다. 표면의 산화층은 Nd산화물이었고, 이는 입계에 있는 Nd-rich상이 산화되고 이것이 확산 통로로 작용하였다고 생각된다. 산화가 진행됨에 따라 입계상에 의한 domain wall pinning이 약해져 자기특성이 저하하였다. 그러나 Ni 첨가시 이러한 산화거동이 크게 억제되었으며 Ni의 첨가는 Nd-rich상의 산화저항성을 증가시킴으로써 리본의 산화를 억제해 자기특성의 저하를 억제하였다.

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Behaviour Characteristics of Sand Compaction Pile with varying Area Replacement Ratio (모래다집말뚝(SCP)의 치환율 변화에 따른 거동 특성 연구)

  • 박용원;김병일;윤길림;이상익;문대중;권오순
    • Journal of the Korean Geotechnical Society
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    • v.16 no.4
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    • pp.117-128
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    • 2000
  • Sand compaction pile(SCP) is one of the ground improvement techniques which is being used for not only accelerating consolidation but also increasing bearing capacity of loose sands or soft clay grounds. In this study, laboratory model test and large-scale direct shear test were performed to investigate the effects of area replacement ratio of composite ground in order to find out the optimum value of area replacement ratio for the ground improvement purpose. Area replacement ratios of 20%, 30%, 40%, 50%, 60% were chosen respectively in the model tests to study the effects of area replacement ratio on variations of stress concentration ratio, settlement and shear strength characteristics of composite ground. In large-scale direct she4ar tests, area replacement ratios of 20%, 30%, 46% were applied to study their effects on shear strength characteristics of composite ground.

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Evaluation of Structural Performance of RC Beams Retrofitted Steel Fiber consequential Replacement of Recycled Coarse Aggregate and Ground Granulated Blast Furnace Slag (순환골재와 고로슬래그 미분말을 치환한 강섬유 보강 RC보의 구조성능 평가)

  • Ha, Gee-Joo;Yi, Dong-Ryul;Ha, Jae-Hoon
    • Journal of the Korea Concrete Institute
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    • v.25 no.5
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    • pp.477-484
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    • 2013
  • In this study, eleven reinforced concrete beams, ground granulated blast furnace slag, replacing recycled coarse aggregate (BRS series) and recycled coarse aggregate with steel fiber (BSRS series), and standard specimen (BSS) were constructed and tested under monotonic loading. Experimental programs were carried out to improve and evaluate the shear performance of such test specimens, such as the load-displacement, the failure mode and the maximum load carrying capacity. All the specimens were modeled in 1/2 scale-down size. Test results showed that test specimens (BSRS Series) was increased the compressive strength by 9%, the maximum load carrying capacity by 1~6% and the ductility capacity by 1.02~1.13 times in comparison with the standard specimen (BSS). And the specimens (BSRS Series) showed enough ductile behavior and stable flexural failure.

A Case Study of Investigating Appropriate Replacement Area for the Stability of Reinforced Retaining Walls on Soft Ground (연약지반에서 보강옹벽의 안정성을 위한 적정 치환영역의 사례 연구)

  • Song, Young-Sun;Lee, Byung-Sik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.11 no.6
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    • pp.113-120
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    • 2007
  • For the cases of constructing reinforced earth and gabion walls on the soft ground, an appropriate replacement area of soft ground required to maintain the stability of walls was investigated by FEM analyses. Incremental analyses were performed in FEM, in which construction sequences including consolidation of soft soil layer were simulated. As a first step to suggest the appropriate replacement area, a series of analyses for cases varying the replacement depth were conducted to examine the behaviors of wall and adjacent ground according to the construction sequence. The analysis results were, then, evaluated with the proper limiting values of displacements of wall, settlements and shear strains of ground to guarantee the stability of walls, which were specified based on the literature review. Consequently, the typical construction drawings could be suggested, in which appropriate replacement areas for varying wall heights for the ground condition investigated in this study were represented in terms of the ratio of replacement depth to the height of wall.

Effect of Recycled Coarse Aggregate (RCA) Replacement Level on the Bond Behaviour between RCA Concrete and Deformed Rebars (순환 굵은골재의 혼입률에 따른 콘크리트와 이형철근의 부착 거동)

  • Jang, Yong-Heon;Choi, Ki-Sun;You, Young-Chan;Kim, Keung-Hwan;Yun, Hyun-Do
    • Journal of the Korea Concrete Institute
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    • v.22 no.1
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    • pp.123-130
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    • 2010
  • In this study, mixed recycled coarse aggregate (RCA) was produced by mixing RCA from waste concrete in order to evaluate a new method of RCA production. Bond strength between reinforcing bars and RCA concrete was qualitatively evaluated as a part of continuous studies to establish design code of reinforced concrete structural members using recycled aggregate. For practical application, specimens were manufactured with the ready mix RCA concrete. Parameters investigated include: concrete compressive strength (i.e 21, 27 and 40 MPa), replacement levels (i.e 0, 30, 60 and 100%), bar position (i.e vertical and horizontal) and bar location (75 and 225 mm). For the pull-out test, each specimen was in the form of a cube, with each side of 150 mm in length and a deformed bar, 16 mm in diameter, was embedded in the center of each specimen. From the test results, the most of HT type specimen with compressive strength of 21 and 27 MPa showed lower bond strength than the ones provided in CEB-FIP and considered in reinforcement location factor ($\alpha\;=\;1.3$). It was reasoned that bonded area of top bar specimen was reduced at the soffit of reinforcement because of bleed water of fresh concrete. Therefore the reinforcement location factor in current KCI design code should be reviewed and modified.

The Predicting Environmental Fate of Cd, Cu, and Pb by Sequential Fractionation in Mine Tailings and Agricultural Soils

  • Lee, Do-Kyoung;Chung, Doug-Young;Park, Mi-Sun;Lee, Seung-Kil
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 1998.11a
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    • pp.195-200
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    • 1998
  • 토양내에 있어 중금속의 총량 분석만으로는 오염 토양에 대한 환경 평가를 위한 충분한 자료가 되지 못한다. 또한 중금속의 토양내 위해성은 중금속과 토양과의 화학적 상호작용에 의해 결정되기 때문에 중금속의 화학적 형태를 규명하는 것은 토양 환경에 있어서 그들의 이동성과 거동 특성을 평가하는데 중요한 자료가 된다. 연속 추출법은 구봉 광산의 광미로 부터 Cd, Cu, Pb을 화학적 형태에 따라 분리하고, 인위적으로 중금속을 포화시킨 광미와 두밭토양에 있어 중금속의 토양내 거동 특성을 예측하기 위하여 이용되었다. 광미중 Pb의 대부분은 Fe-Mn oxide, carbonate의 결합 형태로 존재하였으며, Cu와 Cd은 각각 71.8%와 42.9%가 유기물, carbonate의 결합형태로 존재하였다. 상당량의 Cd(94.9%), Cu(95.1%), 그리고 Pb(85.8%)은 토양내 잠재적으로 이동 가능한 형태로 존재하였다. 유성과 논산의 밭토양 에 가해진 Cd는 대부분 이동성이 가장 높은 치환태로 존재하였으며, 유성과 논산 토양에서 각각 67.9%와 93.2%가 치환태로 존재하였다. 토양에 가해진 Cd, Cu, Pb은 대부분 이동이 용이한 형태로 존재하였으며, 토양과의 결합세기는 Pb > Cu > Cd 순으로 감소하였다.

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A study on the synthesis and formation behavior of nanostructrued TiN films by metal doping (금속원소 도핑에 따른 초고경도 나노구조 TiN 박막의 합성 및 형성 거동에 관한 연구)

  • 명현식;한전건
    • Journal of the Korean Vacuum Society
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    • v.12 no.3
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    • pp.193-199
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    • 2003
  • Ti-Cu-N and Ti-Ag-N nanocomposite films with various copper and silver contents were synthesized by arc ion plating and magnetron sputtering hybrid system. The structure and mechanical properties of these films were found to be dependant on the copper and silver concentration. The maximum hardness of Ti-Cu-N and Ti-Ag-N films showed approximately 40 ㎬ below 2 at%Me. The role of soft metallic phase in Ti-Me-N nanosturctured films containing one hard and one soft phase is also discussed.

Uniaxial Behavior of Reinforced Concrete Column with Recycled Fine Aggregate (순환잔골재를 치환한 철근콘크리트 기둥의 압축거동 특성)

  • Jang, Gwang-Soo;Kim, Yun-Su;Yun, Hyun-Do;Choi, Ki-Sun;You, Young-Chan;Kim, Keung-Hwan
    • Proceedings of the Korea Concrete Institute Conference
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    • 2008.04a
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    • pp.5-8
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    • 2008
  • The use of recycled aggregates is increasing due to problems of lack of natural aggregates. But there are no appropriate design recommendations and basic data for structural members using recycled fine aggregate concrete. This paper is to evaluate compression behavior of reinforced concrete column with displacement level of recycled fine aggregate. For these purpose, four recycled fine aggregate replacement levels (0%, 30%, 60%, 100%) were considered in this paper. Four columns with 400mm${\times}$400mm in cross section are tested under axial load. Experimental results were compared using current code(KCI2007). Compressive strength of reinforced concrete columns with recycled fine aggregate showed higher than that provided in KCI 2007. The KCI provision were conservative and subsequently can be used for design of reinforced recycled fine aggregate concrete column.

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The Properties of OPC-Slag Cement Mixed with Nano-Silica Solution by Mixing Water Weight Replacement Method (나노실리카 졸을 배합수 중량치환 방법으로 혼합한 OPC-slag cement의 특성)

  • Seo, Ki-Young;Kim, Taewan;Kim, Seong-Do
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.24 no.1
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    • pp.24-34
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    • 2020
  • This research is a study on the characteristics of OPC-slag cement using nano-silica solution (NSS) with water-weight substitution method. The new replacement method is a fundamental step to study the behavior of cement with higher NSS replacement rates than previous studies. NSS was replaced by 10%, 20%, 30%, 40%, and 50% of the mixing water weight. As a result, the mechanical and microstructural characteristics were improved. This can be summarized in two ways. First, when the NSS is replaced with mixing water, the homogeneous dispersion action of the nano-silica particles is improved. This promotes initial hydration. Second, substitution of NSS with higher density than mixing water reduces w / b. This forms a dense hydration reaction material. The new substitution method did not show any degradation of mechanical and microstructural properties as compared with the results using the powdered nano-silica particles revealed in the previous study. Therefore, it is considered that the method of weight substitution of NSS used in this study can be applied to the formulation of OPC-slag cement.

Structural Behaviors of Precast Concrete Box Structures Using Recycled Aggregate (순환골재 콘크리트 박스 구조의 거동)

  • Byun, Keun-Joo;Song, Ha-Won;Kim, Ho-Jin;Nam, Jin-Won;Kim, Ki-Hwan
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.2 no.1
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    • pp.93-102
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    • 2006
  • In order to use a recycled aggregate concrete for precast concrete box structures, the structural behaviors should be analytically and experimentally evaluated. In this study, full-scale precast concrete box structures are manufactured using the recycled aggregate (30% replacement) and natural aggregate. Then, the flexural failure test and shear failure test as well as water leakage lest for the structures arc carried out. First of all, test results of compressive strength show that recycled aggregate concrete is only 4% lower than normal concrete. In the flexural and shear failure test, the structural performances of precast box using the recycled aggregate concrete are 95% of the capacities of normal precast concrete box or more. Especially, the water leakage test shows that leakage pressure of recycled concrete box is more than the critical value, 60kPa, as well as 9% higher than normal precast concrete box. These test results are analyzed and compared with results of finite clement analysis. The comparison shows that test results are more excellent than analytical results. Also, the comparison confirms the applicability of recycled aggregate concrete for the use as practical precast concrete box structure.

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