• Journal of the Mineralogical Society of Korea
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• v.31 no.1
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• pp.47-55
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• 2018

Talc, hydrous magnesium phyllosilicate, is one of the most popular industrial minerals due to their chemical stability and adsorptivity. While micro-sized talc has long been used as a filler and coating, nano-sized talc recently is attracting attention as additives for improving the stability of nanocomposites. In this study, we produced the nano-sized talc powder by mechanical method using high energy ball mill and investigated the changes in particle size and crystallinity with increasing milling time up to 720 minutes. X-ray diffraction results show that the peak width of talc gradually as the milling proceeded, and after 720 minutes of pulverization, the talc showed an amorphous-like X-ray diffraction pattern. Lase diffraction particle size analysis presents that particle size of talc which was ${\sim}12{\mu}m$ decreased to ${\sim}0.45{\mu}m$ as the milling progressed, but no significant reduction of particle size was observed even after grinding for 120 minutes or more. BET specific surface area, however, steadily increases up to the milling time of 720 minutes, indicating that the particle size and morphology change steadily as the milling progressed. Scanning electron microscope and transmission electron microscope images shows that layered particles of about 100 to 300 nm was aggregated as micro-sized particles after pulverization for 720 minutes. As the grinding time increases, the particle size and morphology of talc continuously change, but the nano-sized talc particles form micro sized agglomerates. These results suggest that there is a critical size along the a, b axes in which the size of plates is reduced even though the grinding proceeds, and the reduction of plate thickness along the c axis leads the increase in specific surface area with further grinding. This study could enhance the understanding of the mechanism of the formation of nano-sized talc by mechanical grinding.

• Korean Journal of Heritage: History & Science
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• v.47 no.2
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• pp.46-67
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• 2014

The Dinosaur track-bearing deposits recently found at Bangudae Petroglyph site in Ulju (National Treasure No. 285) have been studied in the aspects of sedimentology, paleoenvironments, and significance in natural history. The dinosaur tracks occur in the Daegu Formation (late Early Cretaceous), and over 80 footprints including 43 ornithopod footprints, 36 sauropod footprints, and 2 theropod footprints are preserved in this tracksite. The track-bearing deposits consist of irregularly interlaminated siltstone and mudstone, calcareous sandy to silty mudstone, thin-bedded tuffaceous sandstone, planar- to cross-laminated sandstone, and thin- to medium-bedded graded sandstone, and they are interpreted to be sheetflood deposits on an alluvial plain. Diverse types of ripples and mudcracks, rainprints, and invertebrate trace fossils are observed in these deposits, and the crest-lines of wave ripples do not show preferred orientation. Dinosaur footprints occur as true prints, underprints, overtracks, and casts on the bedding surfaces, and the orientation of trackways are scattered. It is interpreted that paleoclimatic condition of the track-bearing deposits were semiarid with alternation of wetting and drying periods, and that dinosaurs frequented small and shallow ponds during wetting periods and recorded their tracks on an alluvial plain. The frequent occurrence of dinosaur tracks in study area indicates that the Cretaceous deposits around Daegokcheon Stream are very useful sedimentological and paleontological records to understand the paleoecology and paleoenvironments during the dinosaur age in Korean Peninsula. Consequently the dinosaur track-bearing deposits around Daegokcheon Stream should be further studied in sedimentary geology and paleontology in order to enhance cultural heritage value of the Petroglyphs of Bangudae Terrace as the World Heritage.

• Economic and Environmental Geology
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• v.49 no.2
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• pp.77-88
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• 2016

Chrysotile is a 1:1 sheet silicate mineral belonging to serpentine group. It has been highlighted studies because of uses, shapes and structural characteristics of the fibrous chrysotile. However, it was designated as Class 1 carcinogen, so high attentions were being placed on detoxification studies of chrysotile. The objectives of this study were to investigate changes of mineralogical characteristics of chrysotile and to suggest detoxification mechanism of chrysotile by thermal decomposition. Samples for this study were obtained from LAB Chrysotile mine in Canada. The samples were heated in air in the range of 600 to $1,300^{\circ}C$. Changes of mineralogical characteristics such as crystal structure, shape, and chemical composition of the chrysotile fibers were examined by TG-DTA, XRD, FT-IR, TEM-EDS and SEM-EDS analyses. As a result of thermal decomposition, the fibrous chrysotile having hollow tube structure was dehydroxylated at $600-650^{\circ}C$ and transformed to disordered chrysotile by removal of OH at the octahedral sheet (MgOH) (Dehydroxylation 1). Upon increasing temperature, it was transformed to forsterite ($Mg_2SiO_4$) at $820^{\circ}C$ by rearrangement of Mg, Si and O (Dehydroxylation 2). In addition, crystal structure of forsterite had begun to transform at $800^{\circ}C$, and gradually grown 3-dimensionally to enstatite ($MgSiO_3$) by recrystallization after the heating above $1,100^{\circ}C$. And then finally transformed to spherical minerals. This study showed chrysotile structure was collapsed about $600-700^{\circ}C$ by dehydroxylation. And then the fibrous chrysotile was transformed to forsterite and enstatite, as non-hazardous minerals. Therefore, this study indicates heat treatment can be used to detoxification of chrysotile.

• Economic and Environmental Geology
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• v.34 no.1
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• pp.1-12
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• 2001

The crystal structure of biotite-1M from Bancroft, Ontario, was determined by Rietveld refinement method using high-resolution neutron powder diffraction data at -26.3$^{\circ}C$, 2$0^{\circ}C$, 30$0^{\circ}C$, $600^{\circ}C$, 90$0^{\circ}C$. The crystal structure has been refined to a R sub(B) of 5.06%-11.9% and S (Goodness of fitness) of 2.97-3.94. The expansion rate of a, b, c unit cell dimensions with elevated temperature linearly increase to $600^{\circ}C$. The expansivity of the c dimension is $1.61{\times}10^{40}C^{-1}$, while $2.73{\times}10^{50}C^{-1}$ and $5.71{\times}10^{-50}C^{-1}$ for the a and b dimensions, respectively. Thus, the volume increase of the unit cell is dominated by expansion of the c axis as increasing temperature. In contrast to the trend, the expansivity of the dimensions is decreased at 90$0^{\circ}C$. It may be attributed to a change in cation size caused by dehydroxylation-oxidation of $Fe^{2+}$ to $Fe^{3+}$ in vacuum condition at such high temperature. The position of H-proton was determined by the refinement of diffraction pattern at low temperature (-2.63$^{\circ}C$). The position is 0.9103${\AA}$ from the O sub(4) location and located at atomic coordinates (x/a=0.138, y/b=0.5, z/c=0.305) with the OH vector almost normal to plane (001). According to the increase of the temperature, $\alpha$* (tetrahedral rotation angle), $t_{oct}$ (octahedral sheet thickness), mean distance increase except 90$0^{\circ}C$ data. But the trend is less clearly relative to unit cell dimension expansion because the expansion is dominant to the interlayer. Also, ${\Psi}$ (octahedral flattening angle) shows no trends as increasing temperature and it may be because the octahedron (M1, M2) is substituted by Mg and Fe.

• Journal of the Korean Geotechnical Society
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• v.38 no.7
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• pp.49-62
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• 2022

The hollow modular concrete block reinforced foundation method is one of the ground reinforcement foundation methods that uses hexagonal honeycomb-shaped concrete blocks with mixed crushed rock to reinforce soft grounds. It then forms an artificial layered ground that increases bearing capacity and reduces settlement. The hollow modular honeycomb-shaped concrete block is a geometrically economical, stable structure that distributes forces in a balanced way. However, the behavioral characteristics of hollow modular concrete block reinforced foundations are not yet fully understood. In this study, a bearing capacity test is performed to analyze the reinforcement effectiveness of the hollow modular concrete block through the laboratory model tests. From the load-settlement curve, punching shear failure occurs under the unfilled sand condition (A-1-N). However, the filled sand condition (A-1-F) shows a linear curve without yielding, confirming the reinforcement effect is three times higher than that of unreinforced ground. The bearing capacity equation is proposed for the parts that have contact pressure under concrete, vertical stress of hollow blocks, and the inner skin friction force from horizontal stress by confining effect based on the schematic diagram of confining effect inside a hollow modular concrete block. As a result of calculating the bearing capacity, the percentage of load distribution for contact force on the area of concrete is about 65%, vertical force on the area of hollow is 16.5% and inner skin friction force of area of the inner wall is about 18.5%. When the surcharge load is applied to the concrete part, the vertical stress occurs on the area of the hollow part by confining effect first. Then, in the filled sand in the hollow where the horizontal direction is constrained, the inner skin friction force occurs by the horizontal stress on the inner wall of the hollow modular concrete block. The inner skin friction force suppresses the punching of the concrete part and reduces contact pressure.

• Journal of the Korean Geosynthetics Society
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• v.18 no.4
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• pp.299-306
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• 2019

In this study, a model experiment that simulates the behaviour of the ground composed of several compacted layer was intended to measure the loosened area in the event of a ground cavity through a LAD (Loosened area detector). It was confirmed that the size of the cone diameter was affected by the ground composed of fine grain + granulated soil layered through the model soil. In order to select the appropriate cone type, a scale effect experiment was conducted. From the test results, a micro-cone was chosen for the most suitable indoor model experiment. In the case of applying LAD in this study, the loosening condition of the ground was determined by the rapid change in penetration resistance caused by the difference in the boundary surface and relative density due to the compaction of the ground for indoor model testing. The range of loosened area occurring in the cavity was estimated through the penetration resistance characteristics on the ground, and the failure area was identified through the reduction rate of penetration resistance in the loosening area.

• The Korean Journal of Ecology
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• v.26 no.5
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• pp.223-236
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• 2003

The vegetation in this study area was divided into 10 plant communities: Pinus thunbergii, P. densiflora, Quercus acutissima, Q. mongolica, Q. serratea, Q. variabilis, Q. aliena, Q. dentata, Carpinus coreana, Betula davurica and 3 afforestations; Pinus rigida, Robinia pseudo-acacia, Castanea crenata. The dominant species in each stratum as determined by R-NCD appeared to be Q. acutissima, P. densiflora, Platycarya strobilacea, Sorbus alnifolia and Q. aliena in the tree-2 layer, Rhododendron mucronulatum, P. strobilacea, Q. serrata, Q. aliena and Q. acutissima in the shrub layer, and Carex lanceolata, C. humilis, R. mucronulatum, Mischanthus sinensis var. purpurascens and Oplismenus undulatifolius in the herb layer. The distribution of diameter at breast height(DBH) showed the highest percentage (56%) in the range of 2∼10㎝ in the study area and it was investigated as being in the restoration phase after disturbance. The average of the age of trees was under 40-years-od. The pH of soil collected at each site appeared to be within the range between 4.53 and 5.10(the average of 4.73) in each community, organic matters appeared higher than the value in Q. mongolica, P. rigida, C. crenata communities compared to P. thunbergii, P. densiflora communities. And soil organic matters and total nitrogen were highly correlated with their contents.

• Journal of the Korean Vacuum Society
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• v.15 no.1
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• pp.37-44
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• 2006

The homoepitaxy of Si(5 5 12) at $495^{\circ}C$ has been studied by Scanning Tunneling Microscopy under ultrahigh vacuum. A Si-dimer is the basic building-block and preferentially adsorbs on a unique site, that is, the Si-dimer/adatom site at the (337) and the (225) subsections within the Si(5 5 12) unit cell. The Si(5 5 12) unit cell is faceted to $3\times(337)$ subsections filled with Si-addimers and $1\times(113)$ subsection. In this step the tetramer at the other (337) section within the unit cell is transformed to a dimer/adatom site which can accept Si-dimers. Each (337) section is faceted to $1\times(112)\;and\;1\times(113)$, and then finally the unit cell of Si(5 5 12) is faceted to $3\tiems(112)\;and\;4\times(113)$ and forms the facet of effective height, $2.34{\AA}$. In this step, mutual transformation between the honeycomb chain and the dimer/adatom occurs. Finally, the valley between (112) and (113) facets is filled. If once the last step is completed, the uniform and planar Si(5 5 12) terrace is recovered. From the present study, therefore, it can be concluded that the homoepitaxy on Si(5 5 12) is periodically achieved and such growth mode is quite unique since faceting of the substrate-unit-cell plays a critical role for controlling uniformity of the overlayer.

• Journal of the Mineralogical Society of Korea
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• v.15 no.3
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• pp.147-159
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• 2002

Weathered bentonites occcur as surficial alterations of some domestic bentonite deposits in the Tertiary formations, with the thickness of less than about 50 cm, along naturally-formed weathering surface with slopping in gentle. 7 $\AA$-halloysite was found together with montmorillonite in the weathered bentonite. Compared to normal bentonite, the weathered one is generally more clay-rich and contains little amounts of original rock-forming minerals and residues. In the electron microscopy, fine-scale occurrence of the clay minerals tends to be somewhat discrete and segregated rather than closely associated. h curled margin of montmorillonite lamella is deformed to become obtuse in the weathered bentonite. Halloysite occurs as acicular to tubular crystals with the length of less than 2 $\mu$m and the width of about 0.3 $\mu$m, which commonly forms bundle-shaped aggregates. Electron microscopic observations on the fine-scale occurrence and texture of the wtathered bentonites indicate that the clay mineral transition from montmorillonite to halloysite has undergone without accompanying any intermediate phases of both clay minerals such as a mixed-layered type (M/H). The alteration reaction between these two clay minerals probably took place in the form of dissolution and precipitation mechanism in oxidation condition. An intense chemical leaching of SiO$_2$, Na, K and Ca might occur during the alteration reaction, forming a lot of dissolution cavity and residual concentration of A1$_2$O$_3$ and Fe, relatively. As the result of the chemical change, a fsvorable condition for halloysite formation seemed to be provided.

• Magazine of the Korean Society of Agricultural Engineers
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• v.18 no.1
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• pp.4011-4020
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• 1976

본논문은 북해도대학심사학위논문으로 총면수 143면인 영문으로 되어 있고 도 48, 표 7, 문묵 66부도, 부표 20면이있음. Plow는 옛부터 발달한 농구이기 때문에 많은 연구가 행하여졌지만 복잡한 물리성을 가준 토양을 대상으로 하는 기계이기 때문에 미해결의 문제도 적지않다. 이견인저항에 대하여 토양의 종류 및 조건을 변경하면서 실제의 포장에서 조직적으로 행한 실험은 극히 적고, 하물며 우리나라의 쟁기에 관한 연구는 거의없다. 본논문은 쟁기의 특징을 구명하고, 그의 개량, 발달에 기여하기 위한 기기자료를 획득코저 실시한 것이다. 1. 쟁기와 플라우의 구조 및 그의 차이 특징을 명백히하고 이체에 걸리는 각종의 저항의 내용 또는 그 비율등에 대하여 과거의 연구성과를 소개하였다. 2. 발달사 ; 플라우는 B.C. 2000년경에 녹각, 목지의 인력용의 경운용구에서 발달하고, 동양이도 기원은 대체로 같고 발달과정이 다를 뿐이다. 쟁기는 양자강연안에 기원을 가진 지나이가 신라와 백제에 도입되여 차차 발달하고, 지역적인 특징을 가지게 되었다. 3. 본장은 쟁기의 견인력에 관한 이론적해석을하고, 쟁기의 진행에 의해 층상으로 전단되는 전단저항을 구하고 쟁기의 표면 및 지측판과 토양과의 마찰력, 그리고 토양의 이동의 관성력을 쟁기의 견인저항에 관련되는 주요한 "힘"으로 생각하고 진행방면, 수직방면의 힘의 성분의 평형을 고려하여 식 10. 12를 유도 하였다. 4. 본장에서는 실험계획, 방법 공시기, 공시포장등을 기록하고, 축력용의 쟁기와 플라우를 사용하여 전지 4종 답 2종의 포장에서 실험하는데 견인력계와 자동경심측정기를 사용하였다. 5. 실험결과 및 고찰; 경심과 견인저항 Dp와의 관계는 식 10. 12와 갈이 표시되고, 실제의 제치를 대입하여 이론식을 유도하였으니 직선에 가까운 관계가 있고, 실험결과는 조금 곡선에 가까워졌다. 그리고, 토양의 물리성이 견인력Dp에의 영향을 세밀히 검토하였다. 쟁기의 견인비저항에 있어서도 식 12에서 {{{{K=AT+ { B} over {T } +C}}}}로 표시할수 있기 때문에 최소치를 표시하는 경심이 존재하고 이값은 쟁기나 플라우폭의{{{{ { 1} over {2 } }}}} 즉 10m정도이고 쟁기는 비저항이 0.llkg/$\textrm{cm}^2$에서 0.39kg/$\textrm{cm}^2$이였다. 그러나 이 비저항도 토양의 물리성이 많은 영향을 미치고 있다. 6. 요약 및 결론 ; 이상의 장에서 검토 고찰한 결과만을 기재하고 플라우는 쟁기에 비해 견인저항 및 비저항이 논에서나 밭에서 대로 나타난 것이 특이하다. 이상의 내용을 지면관계로 3회에 거쳐 요약 발표합니다.