• Title/Summary/Keyword: 충진

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Wet-end Monitoring Experience in Liner Paper Mill (라이너지 제지공장의 습부공정 모니터링 경험)

  • 신종호;류정용;김용환;송봉근
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.11a
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    • pp.57-58
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    • 2001
  • 용수 다소비 산업으로 분류되는 제지공업의 특성 상, 용수사용의 억제 및 용수의 무방류화에 대한 압력이 증가되고 있는 반면, 초지환경은 날로 열악해지고 있는 실정이다. 한 예로써, 용지의 재활용율 및 재사용 비율이 증가함에 따라 원료의 저급화가 심 각한 수준에 이르고 있으며, 이러한 초지환경의 변화는 각질화되고 극도로 미세화된 다량의 미세섬유 발생 및 잡고지로부터 유입되는 점착성 이물질과 무기 충진제의 도입 등을 유발함으로서 제품의 물리적 성질 저하, 탈수부하 증가로 인한 생산성 저하, 약품사용량 증가 등을 초래하여, 결과적으로는 폐수처리장의 부하를 증대시킴과 동시에 청수사용량 및 폐수방류량을 증가시키는 악순환을 되풀이하게 된다. 국내 제지산업이 국제적 경쟁력을 갖추기 위해서는 제품의 증대가 필수적이나, 원료와 설비의존도를 감안할 때, 제품특성과 공정 분을 결정하는 습부공정을 정확히 파악하여 최적 운전조건을 확립하는 것이 가장 경제적이고 용이한 방법일 뿐만 아니라 전체 제지공정의 정정화에도 기여할 수 있을 것으로 판단된다. 일정규모이상의 종이를 생산하는 제지공장은 거의 대부분 컴퓨터로 처리되는 온라인 공정조절 시스템(On-line process control system)을 구비하고 료의 도입에서부터 설비운전 및 제품의 기본적인 품질관리까지 실시간의 자동화되고 안정적인 운전과 관리시스템을 유지하고 있다. 그러나 전체 제지공정 중, 제품 물성과 운전조건의 대부분을 결정하는 습부공정만큼은 아직도 주기적인 분석이 행해지고 있지 않을 뿐만 아니라, 슬러리의 농도나 보류도 정도를 제이하면 분석항목 조차도 변변히 확립되어 있지 않을 실정이다. 이는 다량의 물 속에 존재하게 되는 용전물질(Dissolved solids, DS), 부유물질(Suspended solids, SS), 섬 유(Fibers), 무기 미 세분(Inorganic f fines), 그리고 투입되는 약품간에 발생하는 계면동전현상 및 이러한 현상과 최종 지제 품의 물성간의 상관관계에 대한 이해 정도나 경험 부족에서 기인하는 것으로 생각된다. 1 1983년 미국제지기술연합회(T APpI)의 제지용 첨가제 분과위원회(Papermaking A Additive Committee)에서는 습부공정의 적절한 조절을 위해 어떤 항목들이 필요하며 그 중요도는 어떠한가를 조사하였으며, 그 결과로 전하밀도, 제타전위, 보류도 및 여수 도, 무기 미세분 함량 등이 중요하다고 보고하였다. 그러나 지료의 전기적 특성을 실시 간으로 측정하는 기자재류가 최근에 이르러서야 도입되고 있는 실정이기 때문에 충분 한 현장적용 사례가 보고되지 못하고 있으며, 결과적으로 얻어진 정보와 최종 지제품의 물성 및 초지기 운전조건과의 상관관계를 확립하는 작업결과는 더욱 찾아보기 어렵다. 따라서, 본 연구에서는, 라이너지 제조공장의 습부공정에 투입되는 약품이 지료 의 전기적 성질, 즉 전하밀도와 제타전위에 미치는 영향을 모니터링함으로서 지료의 전기적 성질들과 습부 공정상태와의 상관관계를 살펴보고자 하였다. 본 연구는 다음과 같은 순서로 진행하였다.

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Synthesis of CaZrO3 : Eu3+ phosphor by skull melting method (스컬용융법에 의한 CaZrO3 : Eu3+ 형광체 합성)

  • Choi, Hyunmin;Kim, Youngchool;Seok, Jeongwon
    • Journal of the Korean Crystal Growth and Crystal Technology
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    • v.30 no.4
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    • pp.131-135
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    • 2020
  • Single crystal phased CaZrO3 : Eu3+ phosphor have been synthesized by skull melting method. The crystal structure, morphology and optical properties of synthesized phosphor were investigated XRD (X-ray diffraction), SEM (scanning electron microscopy), UV (ultraviolet) fluorescence reaction and PL (photo luminescence). The starting materials having chemical composition of CaO: ZrO2 : Eu2O3= 0.962 : 1.013 : 0.025 mol% were charged into a cold crucible. The cold crucible was 120 mm in inner diameter and 150 mm in inner height, and 3 kg of mixed powder (CaO, ZrO2 and Eu2O3) was completely melted within 1 hour at an oscillation frequency of 3.4 MHz, maintained in the molten state for 2 hours, and finally air-cooled. The XRD results show that synthesized phosphor is stabilized in orthorhombic perovskite structure without any impurity phases. The synthesized phosphor could be excited by UV light (254 or 365 nm) and the emission spectra results indicated that bright red luminescence of CaZrO3 : Eu3+ due to magnetic dipole transition 5D07F2 at 615 nm was dominant.

Design Considerations and Pull-Out Behavior of Mechanical Anchor of Reinforcement (철근 기계적 정착장치의 설계 고려사항과 인발특성)

  • 천성철;김대영
    • Journal of the Korea Concrete Institute
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    • v.13 no.6
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    • pp.593-601
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    • 2001
  • In RC structure, sufficient anchorage of reinforcement is necessary for the member to produce the full strength. Generally, conventional standard hook is used for the reinforcement's anchorage. However, the use of standard hook results in steel congestion, making fabrication and construction difficult. Mechanical anchor offers a potential solution to these problems and may also ease fabrication, construction and concrete placement. In this paper, the required characteristics and the design considerations of mechanical anchor were studied. Also, the mechanical anchor was designed according to the requirements. To investigate the pull-out behavior and properness of mechanical anchorage, pull-out tests were performed. The parameters of tests were embedment length, diameter of reinforcement, concrete compressive strength, and spacing of reinforcements. The strengths of mechanical anchor were consistent with the predictions by CCD method. The slip between mechanical anchor and concrete could be controlled under 0.2mm. Therefore, the mechanical anchor with adequate embedment could be used for reinforcement's anchorage. However, it was observed that the strength of mechanical anchors with short spacing of reinforcements was greatly reduced. To apply the mechanical anchor in practice (e.g. anchorage of the beams reinforcements in beam-column joint), other effects that affect the mechanical anchor mechanism, such as confinement effect of adjacent member from frame action or effects of shear reinforcement, should be considered.

Removal Characteristics of Heavy Metals in Acid Mine Drainage (AMD) Using Porous Starfish Ceramics (II) - Treatment of AMD in a Column Reactor System (불가사리 소재 다공성 세라믹을 이용한 산성광산배수 내 중금속의 제거특성(II) - 컬럼연속 실험을 통한 산성광산배수의 처리특성)

  • Lee, Yonghwan;Yim, Soobin
    • Journal of the Korean GEO-environmental Society
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    • v.15 no.12
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    • pp.25-34
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    • 2014
  • The objective of this study was to investigate the removal characteristics and the elimination mechanism of heavy metals in Acid Mine Drainage (AMD) using spherical-type porous Zeolite-StarFish ceramics (porous ZSF ceramics) packed in a continuous column reactor system. The average removal efficiencies of heavy metals in AMD were Al 98.7, As 98.7, Cd 96.0, Cu 89.1, Fe 99.5, Mn 94.4, Pb 96.3 and Zn 80.8 % during 110 days of operation time. The average removal capacity of porous ZSF ceramics for heavy metals were measured to be Al 21.76, As 1.52, Cd 1.27, Cu 3.41, Fe 44.83, Mn 3.48, Pb 2.36 and Zn $3.76mg/kg{\cdot}day$. The analysis results of mechanism using SEM, EDS and XRD exhibited that the porous ZSF ceramics could act as a multi-functional ceramics for the removal of heavy metals in AMD through the reactions of precipitation, adsorption and ion-exchange. The experimental results of column reactor system displayed that the porous ZSF ceramics would be a consistently efficient agent for the removal of heavy metals in AMD for a long term.

Gold and Silver Mineralization of the Soowang Ore Deposits in Muju, Korea (무주 수왕광상의 금-은 광화작용)

  • Park, Hee-In;Youn, Seok-Tai
    • Journal of the Korean earth science society
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    • v.25 no.6
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    • pp.484-494
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    • 2004
  • The Soowang Au-Ag deposits occur as quartz veins which filled fissures in middle Cretaceous porphyritic granite an/or gneiss of the Precambrian Sobaegsan gneiss complex. The paragenetic studies suggest that vein filling can be divided into four identifiable stages (I to IV). Stage I is the main sulfide stage, characterized by the deposition of base-metal sulfide and minor electrum. Stage II is the electrum stage, whereas stage III represents a period of the deposition of silver-bearing sulfosalts and minor electrum. Stage IV is the post ore stage. Mineralogical and fluid inclusion evidences suggest that mineralization of the Soowang deposits were deposited by the cooling of the fluids from initial high temperatures 300$^{\circ}C$ to later low temperatures 150$^{\circ}C$. The salinity of the fluids were moderate, ranging from 10.4wt.% equivalent NaCl in sphalerite to 3.1wt.% equivalent NaCl in barite. The gold-silver mineralization of the Soowang mine occurred at temperatures between 140 and 250$^{\circ}C$ from fluids with log $fs_2$ from -12 to -18 atm. A consideration of the pressure regime during ore deposition, based on the fluid inclusion evidence of boiling, suggests lithostatic pressure of less than 210 bars. This pressure condition indicates that vein system of the Soowang deposit formed at depth around 800 m below the surface at the time of gold-silver mineralization.

A Preliminary Study of Rodent Burrows at Lake Hovsgol, Mongolia: Comparison with the Late Pleistocene Rodent Burrows of Korea (몽골 흡수굴 호수 지역의 설치류 서관 구조에 대한 예비 연구: 한국 플라이스토세 말기 서관 구조와의 비교 연구)

  • Lim, Hyoun Soo;Lee, Jae Il;Park, Sujeong;Jeong, Hoon Young;Hwang, Jinyeon;Kim, Jin-Seop;Son, Moon;Yoon, Ho Il
    • Journal of the Korean earth science society
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    • v.35 no.4
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    • pp.290-294
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    • 2014
  • In this study, we investigated the characteristics of rodent (mainly ground squirrel) burrows found near the Lake Hovsgol, Mongolia. Those burrows are straight to slightly curved and gently inclined in lateral view. Cross-sectional shapes are either circular or elliptical with diameters ranging from mostly 8-10 cm. Most abandoned burrows are passively filled with soils and/or pebbles. The size and architecture of these Mongolian burrows are remarkably similar to those of the previously reported Late Pleistocene burrows from Korea. Therefore, the rodent burrows found at Korean Palaeolithic sites are thought to have been formed by ground squirrels. However, the difference in burrow-fills suggests that the mean annual precipitation of the Korean Peninsula during the Late Pleistocene is much higher than that of Mongolia.

Treatment of Giant Cell Tumor Around Knee - by Intralesional Excision Using High Speed Burr and Methylmethacrylate - (슬관절 주변에 발생한 거대세포종의 치료 - 고속 바(High-Speed Burr)와 골 시멘트를 이용한 병소 내 절제술 -)

  • Park, Jong-Hoon;Lee, Soo-Yong;Jeon, Dae-Geun;Cho, Wan-Hyung;Song, Won-Seok;Kim, Jin-Wook;Koh, Han-Sang
    • The Journal of the Korean bone and joint tumor society
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    • v.11 no.2
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    • pp.160-167
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    • 2005
  • Purpose : Distal femur and proximal tibia are the common sites affected by giant cell tumor of bone. There are a variety of treatment modality including wide excision and intralesional curettage. We evaluated the local recurrence rates and the post-operative functional scores of giant cell tumors around knee joint and investigated the identification of possible prognostic factors for recurrence. Materials and Methods: We reviewed 41 patients pathologically confirmed as giant cell tumors around knee joint that have undergone intralesional curettage using high-speed burr and methylmethacrylate. We evaluated the recurrence rate and post-surgical functional score and possible prognostic factors for recurrence, such as, gender, age, tumor location, size, subchondral invasion, intra-articular invasion and the Campanacci Grades. Mean follow up period was 50 (12-122) months. Results: The recurrence rate was 17% and mean recurrence onset was 10 months postoperatively. According to Musculoskeletal Tumor Society (MSTS) functional evaluation system, the average score was 27.8(93%) and 78% had excellent function. According to our study, suspected prognostic factors revealed not significant for recurrence. Conclusion: We found no significant recurrence related factors. Intralesional excision with high-sped burring and PMMA provides a low recurrence rate, similar to others in the literature, and good functional scores.

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Characteristics of Sulfur oxidation and the Removal of Hydrogen sulfide by Burkholdera[Pseudomonas] cepacia (Burkholderia[Pseudomonas] cepacia의 황 산화 특성 및 황화 수소 제거)

  • 정성제;이은관;전억한;윤인길;박창호
    • KSBB Journal
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    • v.16 no.5
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    • pp.466-473
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    • 2001
  • A bacterium was isolated from soils in Suwon, Korea for the purpose of H$_2$S removal using a biofilter system. The isolate was gram-negative, rod-shaped, catalase-positive, motile, and the isolated bacterium showed a positve in utilizing energy sources including citrate, mannitol, sucrose, fructors, and trehalsoe. Based on its biochemical characteristics it was identified as Burkholderia(Pseudomonas) cepacia. The growth rate of the bacterium in thiosulfate medium with yeast extract was 0.15 hr$\^$-1/ and generation time was 4.6 hr. The cell productivity was 8.05 mg/L$.$h and the isolate grew logarithmically up to 12 hr. The maximum rate of sulfur oxidation was 0.18 g-S/L$.$h. The optimum pH and temperature for the growth of the bacterium were 7.0 and 30$\^{C}$, respectively. The pH range for the growth of B. cepacia was 5.0-8.0. The oxidation rate of thiosulfate was lowered by a substrate thiosulfate when the concentration was higher than 0.12 M. both growth rate and sulfur oxidation rate of Burkholderia(Pseudomonas) cepacia was enhanced about 1.5 times with the addition of 0.2% yeast extract. The removal of hydrogen sulfide was investigated by immobilized B. cepacia with Ca-alginate. The maximum rate removal for H$_2$S was 6.25 g$.$$.$h$\^$-1/ when 12 L/h of flow rate was supplied. From this study suggest the immobilized B. cepacia could have a potential for H$_2$S removal.

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Relationship between NVOCs Concentration and Korean Red Pine (Pinus densiflora S. et Z.) Forest Environment in Spring Season (봄철 소나무숲의 NVOC 농도와 숲환경과의 상관관계)

  • Kim, GeonWoo;Kwon, ChiWon;Yeom, DongGeol;Joung, Dawou;Choi, Yoon Ho;Park, Bum-Jin
    • Journal of Korean Society of Forest Science
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    • v.103 no.3
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    • pp.483-489
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    • 2014
  • This study aimed at a scientific examination of the relationship between NVOCs concentration and the physical environment of red pine forest in spring season. Atmospheric NVOC samples in red pine forest was collected through five trials conducted from March to May 2013, using Tanax-Ta-charged disposable tubes and mini-pumps. At each trial, measurements were taken at three different points in daytime (sunrise, southing and sunset). For maximum accuracy, two tubes were used for each measurement at the same location, and the mean value was used for analysis. Compound analysis on the NVOC samples was done using the HS-SPME method and GC-MS. Analysis of the relationship between NVOC and the physical forest environment found higher concentrations of most substances, including ${\alpha}$-pinene and ${\beta}$-pinene, with higher temperature, dew point, and lower concentrations with higher wind velocity. The findings of this study offer scientific evidence which can inform the creation of 'healing forests' and 'recreational forests' as well as forest environment in general, helping to promote public health and recreational activities.

Heavy matal removal in leaching water from the region buried tungsten tailing (중석광 폐재광미의 매립지에서 나오는 침출수 중의 중금속 제거)

  • Lee, Dong-Hoon;Oh, Sae-Gang;Choi, Choong-Lyeal;Park, Man;Choi, Jyung
    • Korean Journal of Environmental Agriculture
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    • v.19 no.3
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    • pp.218-222
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    • 2000
  • Wasted${\cdot}$rested mine areas give lots of effect on around-environmental changes after mining development. Leaching water at reclaimed land has been eluted from the solid components through physical, chemical, biological procedures by waters percolated through reclaimed site. The element analysis of waste tungsten ore tailing, leaching water analysis and removal of heavy metal by zeolite were performed to investigate the influent of acid rain on the released contents of H. M. The heavy metal contents in leaching water were determined to be As $1.21\;{\sim}\;1.54\;ppm$, Pb $0.11\;{\sim}\;0.15\;ppm$ and $SO_4\;^{2-}$ was $302\;{\sim}\;378ppm$. As deionized water and simulated acid rain (pH 3,4) were percolated through columns packed tungsten ore tailing, the amount of Mn, Na, Ca which were dissolved by pH4 solution was higher than those by distilled water. However, W and Mo were eluted easily by high pH solution. The change of heavy metal concentration by column experiment packed zeolite was effective a little because heavy metals were adsorved much more by zeolite.

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