• Proceedings of the KIPE Conference
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• 2010.07a
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• pp.188-189
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• 2010

기존의 에너지 저장장치를 갖는 계통연계형 태양광 발전 시스템은 태양광 모듈의 높은 개방전압으로 인하여 별도의 양방향 컨버터를 이용하여 배터리에 에너지를 충방전 해왔다. 이러한 시스템은 구조상 다수의 반도체 소자의 사용으로 인한 제작단가 상승 및 전기적 절연의 문제가 발생한다. 이러한 문제점을 개선하기 위하여 본 논문에서는 새로운 구조의 에너지 저장장치를 갖는 고주파 링크 방식의 계통연계형 태양광 발전 시스템을 제안하며, 제안된 시스템의 이론적 분석을 수행하고, PSIM 시뮬레이션 툴을 이용한 모의 실험을 통해 그 우수성을 검증한다.

• Proceedings of the KIPE Conference
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• 2020.08a
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• pp.46-48
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• 2020

본 논문에서는 전기자동차용 배터리의 충방전 시 단자전압이 배터리의 상하한 전압에 도달하지 않는 최대 가용 출력 전류 추정 알고리즘을 제안한다. 제안하는 알고리즘은 SOC에 따라 변화하는 내부 파라미터를 고려하여 일정 시간동안 배터리가 출력 가능한 최대의 전류를 추정함으로써 해당 시간 동안 배터리의 출력을 보장하고 배터리의 가용 에너지를 극대화한다. 알고리즘을 검증하기 위하여 전기자동차용 배터리를 이용한 실험 및 시뮬레이션을 진행한다.

• Korean Journal of Materials Research
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• v.11 no.4
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• pp.294-299
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• 2001

Effects of the surface fluorination on the electrochemical charge-discharge properties of $Mg_2$Ni electrode in Ni-MH batteries fabricated by mechanical alloying were investigated. After 20h ball milling, Mg and Ni powder formed nanocrystalline $Mg_2$Ni. Discharge capacity of this alloy increased greatly at first one cycle, but due to the formation of Mg(OH)$_2$ passive layer, it showed a rapid degradation in alkaline solution within 10cyc1es. In case of 6N KOH +xN KF electrolyte (x = 0.5, 1, 2), a continuous and stable fluorinated layer formed by adding excess F$^{[-10]}$ ion, increased durability of $Mg_2$Ni electrode greatly and high rate discharge capability(90-100mAh/g). 2N KF addition led to the highest durability of all tested here. The reason of the improvement is due to thin MgF$_2$, which can prevent the $Mg_2$Ni electrode from forming Mg(OH)$_2$layer that is the main cause of degradation.

• Journal of the Korean Electrochemical Society
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• v.11 no.4
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• pp.289-296
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• 2008

Electrochemical studies were performed by a half-cell test for the nickel hydroxide (cathode) and hydrogen storage alloy(anode) electrodes for the sealed Ni-MH batteries applicable to industrial use. The electrodes were fabricated and checked a charge efficiency and an internal pressure of the battery during charge-discharge cycling. In order to reduce the internal pressure of the sealed Ni-MH battery, cyclic voltammetry (CV) were performed on the electrodes of nickel hydroxide(cathode) and hydrogen storage alloy(anode), respectively. The results of the test showed clearly the oxidation/reduction and oxygen evolution reaction in a nickel hydroxide electrode and the hydrogenation behavior of a hydrogen storage electrode. The sealed Ni-MH battery of 130Ah was fabricated by using nickel hydroxide of a high over-voltage for an oxygen gas evolution and hydrogen storage alloy of a good performance for activation The battery showed a good characteristics such as a high charge efficiency of 98% at 1 C charge current, a low level internal pressure of 4 atm on a continuous over-charging and a large preservation capacity of 95% at 400 cycle.

• Journal of IKEEE
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• v.24 no.1
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• pp.333-338
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• 2020

This paper proposes a method of estimating the SOC(State of Charge) of a battery cell using a neural network algorithm. To this, we implement a battery SOC estimation simulator and derive input and output data for neural network learning through charge and discharge experiments at various temperatures. Finally, the performance of the battery SOC estimation is analyzed by comparing with the experimental value by Ah-counting using Matlab/Simulink program and confirmed that the error rate can be reduced to less than 3%.

• Journal of the Korean Electrochemical Society
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• v.5 no.2
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• pp.52-56
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• 2002

Tin oxide was coated on graphite particle by sol-gel method and an electrode with this material having microcrystalline structure for lithium ion battery was obtained by heat treatment in the range $400-600^{\circ}C$. The content of tin oxide was controlled within the range of $2.25wt\%\~11.1wt\%$. The discharge capacity increased with the content of tin oxide and also initial irreversible capacity increased. The discharge capacity of tin oxide electrode showed more than 350 mAh/g at the initial cycle and 300 mAh/g after the 30th cycle in propylene carbonate(PC) based electrolyte whereas graphite electrode without surface modification showed 140 mAh/g. When the charge and discharge rate was changed from C/5 to C/2, The discharge capacity of tin oxide and graphite electrode showed $92\%\;and\;77\%$ of initial capacity, respectively. It has been considered that such an enhancement of electrode characteristics was caused because lithium $oxide(Li_2O)$ passive film formed from the reaction between tin oxide and lithium ion prevented the exfoliation of graphite electrode and also reduced tin enhanced the electrical conduction between graphite particles to improve the current distribution of electrode.

• Journal of the Korean Electrochemical Society
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• v.6 no.3
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• pp.196-202
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• 2003

We investigated the effect of both 4 types additives and $0.5wt\%\;Pb_3O_4$ which have been reported to show an improvement on the performance of Zinc anode. And Experimental methods such as corrosion potential measurement, potentiodynamic polorization test and charging-discharging cycle life test were carried out in $40 wt\%$ KOH with $Pb_3O_4(0.5, \;10\;&\;2.0wt\%)$ and 4 types additives $(0.4wt\%\;of\;Ca(OH)_2$, 0.025M of Citrate, Tartrate and Gluconate). Corrosion potential was shifted to high direction and also changed to high and low direction repeatedly with increasing of $Pb_3O_4$ quantity. However by adding $0.5wt\%\;Pb_3O_4$, corrosion potential shifted to low direction and showed stable condition. Furthermore it was well known that corrosion resistance was predominantly increased compared to no addition and improved charging-discharging property with adding additives. By SEM analysis, it was concluded that the morphology of surface in case of only $0.5wt\%\;Pb_3O_4$ addition was nearly the same as that of Tartrate additive and in the other additives such as $Ca(OH)_2$, Citrate, Tartrate and Gluconate, their morphologies showed dendrite growth. Eventually it was thought that the additive of Tartrate indicated comparatively good corrosion resistance effect as well as charging-discharging property improvement among those four types additives.

• Journal of the Korean Electrochemical Society
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• v.14 no.1
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• pp.16-21
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• 2011

$Li_4Sn_xTi_{5-x}O_{12}$ was manufactured by high energy ball milling (HEBM) and used as an anode material for lithium ion battery. Various amount of $SnO_2$was added to $Li_4Ti_5O_{12}$ and heated at different temperatures. The purpose of this research was to see the effect of $SnO_2$ addition into $Li_4Ti_5O_{12}$. Manufactured samples were analyzed by TGA, XRD, SEM, PSA. Battery cycler was used to test the charge/discharge properties of active materials. Heat treatment temperature of $800^{\circ}C$ was needed to make a stable structure of $Li_4Sn_xTi_{5-x}O_{12}$ and the particle size distribution was $0.2{\sim}0.6\;{\mu}m$. Charge/discharge process was repeated for 50 cycles at room temperature. The initial capacity was 168mAh/g and the voltage plateau was observed at 1.55V(Li/$Li^+$).

• Journal of Platform Technology
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• v.11 no.2
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• pp.54-65
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• 2023

Due to the nature of electric vehicles, the batteries used for electric vehicles have a very large rated capacity. If an electric vehicle runs for a long time or an electric vehicle is abandoned due to a traffic accident, the electric vehicle battery becomes a waste battery. Even in vehicles that are being abandoned, the remaining capacity of waste batteries for electric vehicles is sufficient for other purposes. Waste batteries for automobiles are very expensive, so they need to be recycled and reused, but there was a problem that the standards for measuring the performance grade of waste batteries for recycling and reuse were insufficient. As a method for measuring the remaining capacity of waste battery, the most stable and reliable method is to measure the remaining capacity of battery using full charge and discharge. However, the inspection method by the full charging and discharging method varies depending on the capacity of the battery, but it takes more than a day to inspect, and many people are making great efforts to solve this problem. In this paper, an electric vehicle battery residual capacity analysis technique using voltage deviation between cells was studied and analyzed as a method to reduce inspection time for electric vehicle batteries. To this end, a full charging and discharging-based capacity measurement system was constructed, experimental data were collected using a nose or waste battery, and the correlation between the voltage deviation and the remaining capacity of the battery pack was analyzed to verify whether it can be used for battery inspection.

• Proceedings of the KIPE Conference
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• 2013.11a
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• pp.220-221
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• 2013

본 논문은 OCV 추정기법을 이용한 전류적산법의 SOC Reset 알고리즘을 제안한다. 제안한 알고리즘은 배터리 상황에 따라 OCV 추정을 위한 휴지시간을 달리 설정한다. 이에 따라 짧은 휴지 시에도 SOC Reset Point를 늘려 전류적산법의 오차를 Reset함으로써 SOC 추정 능력을 향상한다. Li-ion 27 Ah/99.9 Wh 배터리의 충 방전 실험을 통해서 OCV 판별 시간을 도출하여 알고리즘을 구현한다. 전기자동차의 주행 패턴을 모사하여 기존의 전류적산법과 비교 실험을 통해 제안한 알고리즘을 검증한다.