• Journal of the Korean Chemical Society
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• v.47 no.4
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• pp.315-324
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• 2003

In this study, a new method is presented to produce stable hydrophobic metal alloy nanocluster in chloroform solution including surfactant NaAOT(sodium bis(2-ethylhexyl)-sulfosuccinate) via the chemical reduction of metal salt $(HAuCl_4,\AgNO_3,\Cu(NO_3)_2)$ by sodium borohydride. For the alloy nanocluster, several samples were prepared by changing the molar ratio of Au/Cu, Au/Ag alloy nanocluster, 3:1, 1:1, 1:3. The alloy nanoclusters were characterized by UV-Visible spectrophotometer, TEM(Transmission Electron Microscope), and XPS(X-ray Photoelectron Spectrometer). With the change of the mole ratio of the alloy component, the wavelengths of the surface plasmon absorption shift linearly from 520 nm of the pure Au nanocluster to 570 nm of the pure Cu nanocluster for Au/Cu alloy nanoclusters and from 405 nm to 520 nm for Au/Ag alloy nanoclusters. The chemical shifts of the Au4f, Ag3d, Cu2p XPS peaks were observed with changing the molar ratio of the alloy element. The alloy nanoclusters in chloroform solution were made uniformly in size and colloidally stable for long periods of time. These results indicate that the method here is a very effective method for synthesizing hydrophobic alloy nanoclusters with uniform or nearly uniform particle size distribution.

• Journal of the Korean Chemical Society
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• v.55 no.2
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• pp.208-217
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• 2011

The effects of pH and temperature on the removal of two dyes (neutral red; NR and malachite green oxalates; MG) from aqueous effluents using Maghnia montmorillonite clay in a batch adsorption process were investigated. The results showed the stability of the optical properties of MG in aqueous solution and adsorbed onto clay under wide range of pH 3-9. However, the interaction of NR dye with clay is accompanied by a red shift of the main absorption bands of monomer cations under pH range of 3-5, whereas, those of neutral form remains nearly constant over the pH range of 8-12. The optimal pH for favorable adsorption of the dyes, i.e. ${\geq}$90% has been achieved in aqueous solutions at 6 and 7 for NR and VM respectively. The most suitable adsorption temperatures were 298 and 318 K with maximum adsorption capacities of 465.13mg/g for NR and 459.89 mg/g for MG. The adsorption equilibrium results for both dyes follow Langmuir, Freundlich isotherms. The numerical values of the mean free energy $E_a$ of 4.472-5.559 kj/mol and 2.000-2.886 kj/mol for NR and MG respectively indicated physical adsorption. Various thermodynamic parameters, such as ${\Delta}H^{\circ}$, ${\Delta}S^{\circ}$, ${\Delta}G^{\circ}$ and Ea have been calculated. The data showed that the adsorption process is spontaneous and endothermic. The sticking probability model was further used to assess the potential feasibility of the clay mineral as an alternative adsorbent for organic ion pollutants in aqueous solution.

• Journal of Korean Society of Steel Construction
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• v.17 no.4 s.77
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• pp.395-405
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• 2005

This paper summarizes the test results of the flexible-stiff mixed system for the effective use of high-strength steel. Steel with a high degree of strength and performance is being increasingly required as buildings get larger and taller. High-strength steels cannot be used for many applications, though, because they have a number of defects. For instance, they have a high yield ratio, a small strain in maximum stress, and equal Young's modulus compared to mild steels. A new structural system is needed to effectively use high-strength steels with some defects. This paper proposes the flexible-stiff mixed system for the effective use of high-strength steels with high yield ratios. The possibility of using the system is discussed through the test of flexible-stiff mixed columns with high-strength steels. The main variable of the specimens is the yield displacement ratio, including both the force ratio and the stiffness ratio. The proper yield displacement ratio is proposed by adopting the flexible-stiff mixed system. The test results showed that the proposed flexible-stiff mixed system has a high capacity for energy absorption and the highest capacity for energy absorption when the yield displacement ratio of the flexible element to the stiff element ranges from 2.7 to 3.3.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.22 no.1
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• pp.116-122
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• 2021

This study quantitatively evaluated the performance improvement of a circular reinforced concrete pier under dynamic load with strengthening using a steel plate. Various three-dimensional elements were applied using the finite element program ABAQUS. The analytical parameters included the ratios of the steel cover length to the pier's total height and the ratios of the steel cover thickness to the pier diameter for inelastic-nonlinear analysis. The lower part of the pier had fixed boundary conditions, and lateral repetitive loads were applied at the top of the pier. The pier was investigated to evaluate the dynamic performance based on the load-displacement curve, stress-strain curve, ductility, energy absorption capability, and energy ratio. The yield and ultimate loads of piers with steel covers increased by 3.76 times, and the energy absorption capability increased by 4 times due to the confinement effects caused by the steel plate. A plastic hinge part of the column with a steel plate improved the ductility, and the thicker the steel plate was, the greater the energy absorption capacity. This study shows that the reinforced pier should be improved in terms of the seismic performance.

• Journal of the Korean Society of Radiology
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• v.11 no.3
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• pp.161-169
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• 2017

The cone beam computed tomography(CBCT) which can acquire 3-dimensions images is widely used for confirmation of patient position before radiation therapy. In this study, through the simulation using the Monte Carlo technique, we will analyze the exposure dose by cone beam computed tomography and present the standardized data. For the experiment, MCNPX(ver. 2.5.0) was used and the photon beam spectrum was analyzed after Cone beam was simulated. As a result of analyzing the photon beam spectrum, the average energy ranged from 25.7 to 37.6 keV at the tube voltage of 80 ~ 120 kVp and the characteristic X-ray energy was 9, 60, 68 and 70 keV. As a result of using the water phantom, the percentage depth dose was measured, and the maximum dose appeared on the surface and decreased with depth. The absorbed dose also decreased as the depth increased. The absorbed dose of the whole phantom was 9.7 ~ 18.7 mGy. This is a dose which accounts for 0.2% of about 10 Gy, which is generally used for radiation therapy per week, which is not expected to have a significant effect on the treatment effect. However, it should not be overlooked even if it is small compared with prescription dose.

• Journal of the Korean Chemical Society
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• v.50 no.1
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• pp.32-36
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• 2006

films of gold nanoparticles were formed on indium tin oxide (ITO) by an electrodeposition method from an aminosilicate stabilized gold colloid solution. The thin films were examined by cyclic voltammetry (CV), scanning electron microscopy (SEM), UV-visible, and energy dispersive X-ray spectroscopy (EDXS). The surface coverage of gold nanoparticles on the thin film was estimated to 1.2 nanomole/cm2. An anthraquinone-2, 6-disulfonic acid, disodium salt (AQDS) self-assembled layer was generated by immersing gold thin film into 1mM of AQDS in 0.1M HClO4 solution for over 20 hours. As a result, a new absorbance peak from the multi-layers (AQDS/thin film of gold /ITO) was obtained about at 690 nm. Also, the surface plasmon absorption of multi-layers was measured by UV-Visible spectrometer along with chronoamperometry by applying the various potentials from +0.5V to -0.5V. The maximum surface plasmon absorption band at 550 nm was decreased by applying negative potentials. The change of absorbance was correlated with the surface coverage of the AQDS indicating the pseudo-capacity surface state of the AQDS layer was coupled to the energy level of the plasmonband by applied negative potentials.

• Magazine of the Korea Concrete Institute
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• v.10 no.2
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• pp.119-126
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• 1998

본 연구는 철근비와 보강판비를 조정한 보강철근비를 변수로 탄소섬유쉬트 접착된 철근콘크리트 보에 대하여 그 변형특성과 강도특성 및 파괴모드를 실험적으로 고찰한 것이다. 철근비와 보강판비가 증가할수록 최대내력은 증가하는 경향을 보이지만 탄소섬유쉬트의 겹수가 증가할수록 철근비 증가의 경우와는 달리 에너지흡수능력이 저하된다. 철근비와 보강판비에 따른 파괴모드를 구분하고 시험결과와 비교, 고찰하였던 바 파괴모드와 연성의 측면에서 보강철근비 е의 한계값을 0.87 max으로 제안하였다．탄소섬유쉬트와 철근콘크리트 보의 합성작용이 철근항복이후까지 유지되어 비선형적인 거동을 보임으로써 구조적거동이 양호하게 나타나는 것으로 입증되었다.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2000.04a
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• pp.20-25
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• 2000

In order to study the impact fracture behavior of brittle materials, a steel-ball-impact experiment was Performed. Five kinds of materials were used in this study : soda-lime glass plates, glass/epoxy prepreg-one layer-bonded and unbonded glass plates, glass/epoxy prepreg-three layers-bonded and unbonded glass plates. Fracture patterns, the maximum stress and absorbed fracture energy were observed according to various impact velocities 40-120m/s. With increasing impact velocity, ring crack, cone crack, radial crack and lateral crack took place in the interior of glass plates. The generation of such cracks was largely reduced with glass/epoxy prepreg coating. Consequently, it is thought that the characteristics of the dynamic Impact fracture behavior could be evaluated using the absorbed fracture energy and the maximum stress measured at the back surface of glass plates.

• Proceedings of the Korean Nuclear Society Conference
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• 1996.05c
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• pp.182-187
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• 1996

원자로 압력용기강의 품질 열처리인 ？칭과 템퍼링 중간에 페라이트와 오스테나이트가 공존하는 2상영역에서 열처리를 행함으로써 인성을 향상시키는 제조공정을 개발하였다. 710~74$0^{\circ}C$에서 4~8시간 동안 2상영역 열처리를 추가하면 기존 열처리 과정에 비하여 상온 충격인성이 크게 증가하였다. 상온 충격인성과 두께를 고려하여 결정한 최적 조건안 7$25^{\circ}C$에서 6시간 동안 2상영역 열처리를 하면 최대 흡수 에너지가 30~50% 증가하고, 천이 온도가 약 l$0^{\circ}C$ 감소하였다. 2상영역에서 형성된 침상 오스테나이트는 냉각 중에 하부 베이나이트 또는 마르텐사이트로 변태하여 템퍼드 베이나이트와 복합조직을 이루므로 균열진전을 억제하여 충격인성이 향상되었다. 2상영역 열처리 온도가 높거나 시간이 길면 오스테나이트의 체적 분율이 증가하거나 조대화가 일어나 균열진전억제 효과는 저하되었다.

• Proceedings of the Korean Society of Applied Pharmacology
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• 1995.04a
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• pp.68-68
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• 1995

청주 근처 토양에서 분리한 에너지 대사 저해제인 2,4-dinitrophenol (DNP)에 내성을 보이는 Streptomyces CM 001 균주가 생산하는 항진균성 물질(CUA)을 순수하게 분리 정제하고 화학분석을 통한 구조의 규명, 항진균활성 연구 및 유전적 변이원성(mutagenicity)등을 살펴보았다. CM 001 균주를 베네트 배지와 같이 영양성이 좋은 배지에서 배양시 항진균 활성이 동반 생성되는 색소와 비례적으로 증가했다. 배양 상등액 속의 항진균성 물질들을 염산처리, 유기용매처리 후 Amberlite XAD-4 column chromatography, silica gel adsorption-Sephadex LH-20 chromatography 과정을 통해 색소가 제거된 부분 정제 백색분말로 얻었다 이로부터 Prep. HPLC과정을 통하여 8종의 화합물을 각기 분리하였는데 이 화합물들은 동일한 UV spectrum과 216, 260nm에서 최대 흡수파장을 보였다.