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$SrSnO3:RE^{3+}$(RE=Eu, Tb) 형광체 분말의 제조와 발광 특성

  • Kim, Jeong-Dae;Jo, Sin-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2013.08a
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    • pp.171-171
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    • 2013
  • 최근에 희토류 이온이 도핑된 형광체를 램프, 플라즈마, 디스플레이 패널, 음극선관, 광전 소자에 응용하기 위한 연구에 많은 노력이 경주되고 있다. 특히 희토류 이온은 4f-껍질에 존재하는 전자의 독특한 성질 때문에 좁은 밴드폭과 강한 발광 특성을 나타내므로 발광 다이오드, 자석, 촉매, 디스플레이 패널용 형광체로 개발되고 있다, 본 연구에서는 고효율의 녹색과 적색 형광체를 개발하기 위하여 모체 결정은 SrSnO3, 활성제 이온은 Eu (유로퓸) 와 Tb (테르븀)을 선택하여 도핑하였다. 합성된 형광체 분말의 회절상을 XRD로 측정한 결과에 의하면, Eu3+와 Tb3+의 함량비에 관계없이 모든 세라믹 분말은 JCPDS #74-1298에 제시된 회절상과 일치하였으며, 주 피크는 $31.3^{\circ}$, $44.9^{\circ}$, $55.8^{\circ}$에서 최대값을 갖는 (110), (200), (211)면에서 발생한 회절 신호이며, 이밖에도 $22.04^{\circ}$, $65.4^{\circ}$, $74.3^{\circ}$에서 약한 회절 피크를 갖는 (100), (220), (013)면의 신호들이 관측되었다. Eu3+ 이온의 함량비가 0.05 mol 인 경우에 (110)과 (211) 피크의 세기가 최대값을 나타내었고, Eu3+의 함량비가 증가함에 따라 두 피크의 세기는 점점 감소하였다. XRD의 데이터를 Scherrer의 식에 대입하여 계산한 결정 입자의 크기는 Eu3+ 이온이 도핑된 경우에는 0 mol에서 최소의 크기를 나타내었고, Tb3+ 이온이 도핑된 경우에 입자의 크기는 0.05 mol에서 최소이었고 0 mol에서 최대값을 보였다. SEM으로 촬영한 표면 형상의 변화를 관측한 결과, Eu3+의 함량비가 0.15 mol인 경우에, 결정 입자의 평균 크기는 400~450nm이며, Tb3+의 함량비가 0.05 mol인 경우에, 결정 입자의 평균 크기는 270~290nm 이었으며, 입자의 형상은 균일하게 분포하는 구형 형태을 보였다. Eu3+와 Tb3+ 이온의 함량비가 점점 증가함에 따라 미립자들이 서로 뭉쳐져서 각각 약 720 nm와 580 nm의 크기를 갖는 큰 입자를 형성하였고, 불규칙적인 분포를 나타내었다. 여기 파장 293 nm에서 Tb3+가 도핑된 SrSnO3:Tb3+ 형광체 분말의 발광 스펙트럼을 측정한 결과에 의하면, Tb3+의 함량비에 관계없이 모든 시료는 주 피크인 550 nm (녹색)와 상대적으로 세기가 약한 500, 590, 630 nm에서 발광 스펙트럼을 나타내었다. 주 피크의 발광 세기는 0.01 mol~0.15 mol에서는 증가 하였고, 더욱 함량비를 증가함에 따라 급격하게 감소하였다. 이 현상은 활성제 이온의 mol 비가 증가함에 따라 이온 사이의 거리가 가까워져서 서로 뭉치는 현상이 주도적으로 작용하여 발광의 세기가 현저히 감소하는 것으로 판단된다. 0.10 mol 일 때 세기가 가장 강한 녹색 형광 신호를 얻었다. 여기 파장 400nm에서 Eu3+가 도핑된 SrSnO3:Eu3+ 형광체 분말의 형광 스펙트럼은 Eu3+의 함량비에 관계없이 590, 619, 696 nm에서 관측되었다. Eu3+의 몰 비가 0.01~0.05 mol 영역에서 619 nm가 주 피크이나, 몰 비가 더욱 증가함에 다라 주 피크의 파장은 590 nm로 이동하였다. 한편, 696 nm의 발광세기는 몰 비가 증가함에 따라 더욱 증가하였다.

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Effects of Draw Ratio and Additive CaCO3 Content on Properties of High-Performance PE Monofilament (연신비와 첨가제 CaCO3가 PE 모노필라멘트의 물성에 미치는 영향)

  • Park, Eun-Jeong;Kim, Il-Jin;Lee, Dong-Jin;Kim, Jung-Soo;Lee, Young-Hee
    • Fashion & Textile Research Journal
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    • v.23 no.2
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    • pp.290-296
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    • 2021
  • The effect of draw ratio (8, 10, 12, 14 times) and additive CaCO3 content (0, 0.5, 1.0, 1.5, 2.0, and 3.0 wt%) on the properties of high-performance PE monofilament was investigated in this study. As the draw ratio increased (8-14 times), the melting enthalpy (ΔHf), crystallinity, specific gravity, and tensile strength increased significantly. However, the draw ratio had little effect on the melting temperature (Tm) and crystallization temperature (Tc). The seawater fastness (stain and fade) of the hydrophobic PE monofilament prepared in this study showed an excellent grade of 4-5 in all draw ratios. To investigate the effect of the additive CaCO3 content on the properties of high-performance PE monofilament, the draw ratio was fixed at 14 times. It was found that the tensile strength of the PE monofilament sample containing 0.5 wt% of CaCO3 was much greater compared to the sample without CaCO3, but the elongation of the sample containing 0.5 wt% of CaCO3 was much less than the sample with 0 wt% CaCO3. However, in the case of the sample containing more than 0.5 wt% CaCO3, the tensile strength slightly decreased and the elongation slightly increased as the CaCO3 content increased. The seawater fastness (stain and fade) of the hydrophobic PE monofilament showed excellent grades of 4-5, regardless of the amount of additives. From the above results, it was found that the maximum draw ratio of 14 times with an additive of 0.5 wt% CaCO3 are the optimal conditions for manufacturing high-performance marine fusion materials with various fineness (denier) with high strength and low elongation.

Effect of Additives on Paper Aging (종이 첨가제가 종이의 노화에 미치는 영향)

  • 윤병호;이명구;최경화
    • Journal of Korea Foresty Energy
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    • v.21 no.2
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    • pp.25-33
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    • 2002
  • One of the critical problems to preserve books and documents in libraries and archives is the deterioration. Some of previous results showed that the major cause of paper deterioration was the acid-catalyzed hydrolysis of the cellulose in paper fibres and aging rate of acidic paper was faster than that of alkaline paper. Therefore, It is necessary to remove the acid in the paper for reducing the rate of paper deterioration. It has been reported to extend the useful life of acidic paper by three to five times. Recently, It has been recognized the need for an effective method of deacidifying large quantities of books and document. However, in the previous many reports little attention was paid to the effect of paper additives. In this paper, We carried out experiment about the effect of additives on paper aging and the effect of deacidification by the gaseous ethanolamines (monoehtanolamine, diethanolamine, triehtanolamine). In result, it was found that the strength of aging was in the order of the alum+rosin>alum >AKD> control and the rate of deacidification was in the order of the monoethanolamine>diethanolamine>triethanolamine. The treatment with the gaseous ethanolamines caused decreasing of brightness and dropping of fold endurances. However, deacidification by combination treatment of the various gaseous ehtnaolamines prevented from decreasing of brightness and dropping of folding endurances.

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Biogeochemical Remediation of Cr(VI)-Contaminated Groundwater using MMPH-0 (Enterobacter aerogenes) (MMPH-0 (Enterobacter aerogenes)에 의한 6가 크롬 오염 지하수의 생지화학적 정화)

  • Seo, Hyun-Hee;Rhee, Sung-Keun;Kim, Kang-Joo;Park, Eun-Gyu;Kim, Yeong-Kyoo;Chon, Chul-Min;Moon, Ji-Won;Roh, Yul
    • Economic and Environmental Geology
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    • v.45 no.2
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    • pp.105-119
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    • 2012
  • Indigenous bacteria isolated from contaminated sites play important roles to remediate contaminated groundwater. Chromium has the most stable oxidation states. Cr(VI) is toxic, carcinogenic, and mobile, but Cr(III) is less toxic and immobile. In this study, indigenous microorganism (MMPH-0) was enriched from Cr(VI) contaminated groundwater, and identified by 16S rRNA gene analysis. Using MMPH-0, the effect of stimulating with e-donors (glucose, lactate, acetate, and no e-donor control), respiration conditions, biomass, tolerance, and geochemical changes on Cr(VI) reduction were investigated in batch experiments for 4 weeks. The changes of Cr(VI) concentration and geochemical conditions were monitored using UV-vis-spectrophotometer and Eh-pH meter. And the morphological and chemical characteristics of MMPH-0 and precipitates in the effluents were characterized by TEM-EDS and SEM-EDS analyses. MMPH-0 (Enterobacter aerogenes) was able to tolerate up to 2000 mg/L Cr(VI) and reduce Cr(VI) under aerobic and anaerobic conditions. MMPH-0 performed faster and higher efficiency of Cr(VI) reduction with electron donors (over 70% after 1 week with e-donor, 10-20% after 4 weeks without e-donor). The changes of Eh-pH in effluents showing the tendency from oxidizing to reducing condition and a bit of acidic change in pH due to microbial oxidation of organic matters donating electrons and protons suggested the roles of MMPH-0 on Cr(VI) in the contaminated water catalyzing to transit geochemical stable zone for more stable $Cr(OH)_3$ or Cr(III) precipitates. TEM/SEM-EDS analyses of MMPH-0 and precipitates indicate direct and indirect Cr(VI) reduction: extracellular polymers capturing Cr component outside cells. These results suggested diverse indigenous bacteria and their biogeochemical reactions might enhance more effective and feasible remediation technology of redox sensitive heavy metals in metal-contaminated in groundwater.

A Study on The Introduction Method of Industrial Design for Small Business (중소기업의 산업디자인 도입방법에 관한 연구)

  • 이수봉
    • Archives of design research
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    • v.11 no.2
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    • pp.129-140
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    • 1998
  • This study aimed to grqJe for and present guideline roodel when the qJerator of domestic small manufacturing industry try to introch1ce the first industrial design by easier and more effective method. As the method of study, first of aiL examined the necessary of introducing industrial design throogh coosidering about the role and importance of small business. And next, analysed and examined the result of researching by enquete that is for qJerators of cbnestic small business. As a result, preconditioos for effective introducing industrial design were found. And, based 00 the preconditioos that were found through researching by enquete, examined the approachable introducing methods. Finally, set up the effectivable introducing methods of industrial design for doo1estic small manufacturing industry as a graphical model. As a result of study, First, the operator of small business who try to introduce industrial design needs to be well aware of these six cooditions as a prenise of effective awroach.1) coosciousness of role and versus a nation and a people of own industry Cereative 2) managing coosideratim and examinatim of a necessity of introducing industrial design as a cata1yst 3) A certain understanding aIntt essence and value of industrial design 4) Study and examinatim about a case of sucessful introducing industrial design arxl common introducing method of small business.5) Befarehand examinatim of introducing method making use of professional design organization and consultatim wicket 6) Prodent examination about the appointlrent puprpose, method of designer and infonmtion about designer. Second, as the position of small bnsiness that introduce industrial design fur the first time, it is confirmed that the aroroach going with introducing types - preliminary introducing, partitial introducing, regular introducing, whole industry level introducing - considered necessity rate of introducing industrial design and introducing range at the same time. This method is able to approach step by step, but it is confinmed that there is a characteristic in being able to select the method freely, and understanding easily for being coostructed visual form.

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Research on Improvement of CH4 Reduction Performance of NGOC for CNG Bus (CNG 버스용 NGOC의 CH4 저감 성능 향상을 위한 연구)

  • Seo, Choong-Kil
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.18 no.5
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    • pp.708-715
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    • 2017
  • Recently, in order to meet the stricter emission regulations, the proportion of after-treatments for vehicles and vessels has been increasing gradually. The objective of this study is to investigate the improvement of $CH_4$ reduction ability of natural gas oxidation catalyst (NGOC), which reduces toxic gases emitted from CNG buses. Thirteen NGOCs were prepared, and the conversion performance of noxious gases according to the type of supports, the loading amount of noble metal, and surfactant and aging were determined. Support Zeolite supported on No. 3 $NGOC(1Pt-1Pd-3MgO-3CeO_2/(46TiO_2+23Al_2O_3+23Zeolite)$ is an anionic alkali metal/earth metal component that improved the oxidation reactivity between CO and NO and noble metal dispersion, and thus enhanced the $CH_4$ reduction ability. As the loading amount of Pd, a noble metal with a high selectivity to $CH_4$, was increased, the number of reaction sites was increased and the ability to reduce $CH_4$ was improved. No. 11 $NGOC(1Pt-1Pd-3MgO-3CeO_2/(Z20+Al80)$(pH=8.5), to which nitrate surfactant had been added, exhibited well dispersed catalyst particles with no agglomeration and improved the $CH_4$ reduction ability by 5-15%. The $NGOC(2Pt-2Pd-3Cr-3MgO/90Al_2O_3)$(48h aging), which was mildly thermal aged for 48h, increased the $CH_4$ reduction ability to about 10% or less as compared with No. 12 NGOC(Fresh).

Anti-wrinkle Effect of Cambodian Phellinus linteus Extracts (캄보디안 상황버섯 추출물의 주름개선 효과 연구)

  • Cheon, Soon-Ju;Jang, Min-Jung;Jang, Young-Ah;Choi, Eun-Young;Jun, Dong-Ha;Kim, Young-Hun;Cho, Woo-A;Jeong, Yeon-Sook;Kwon, Hyeork-Bum;Kim, Tae-Hoon;Choi, Kyung-Im;Do, Jeong-Ryong;Lee, Chang-Eon;Lee, Jin-Tae
    • Journal of Life Science
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    • v.18 no.12
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    • pp.1718-1721
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    • 2008
  • The skin of human is constantly being exposed to environmental irritants such as ultraviolet, smoke and chemicals. These irritants cause free radicals and reactive oxygen species which leave serious damages on the cells of skin. The water and ethanol extracts of Cambodian Phellinus linteus were investigated for the activities of anti-lipid peroxidation and anti-wrinkle effects to apply as a functional ingredient for cosmetic products. As the result of evaluation of liquid oxidation rate by add $Fe^{2+}$ and $Cu^{2+}$ to Cambodian Phellinus linteus extracts, Cambodian Phellinus linteus ethanol extracts were higher than Cambodian Phellinus linteus water extracts in the chealting ability of $Fe^{2+}$ and $Cu^{2+}$. The Cambodian Phellinus linteus ethanol extracts exhibited that anti-lipid peroxidation higher than butylated hydroxytoluene (BHT) at the concentration of 0.1 mg/ml, 0.5 mg/ml and 1 mg/ml. Cambodian Phellinus linteus water and ethanol extracts showed a higher inhibitory effect on $Fe^{2+}$-induced lipid peroxidation compared to $Cu^{2+}$-induced lipid peroxidation. In the case of anti-wrinkle effect, the elastase inhibition activity of Cambodian Phellinus linteus ethanol extracts was 50.7%, and it is higher than urosolic acid at the concentration of 0.01 mg/ml. Also, in collagenase inhibition activity, Cambodian Phellinus linteus water extract showed low effect, but Cambodian Phellinus linteus ethanol extract was about 50% at a 0.1 mg/ml. concentration. These results proved that Cambodian Phellinus linteus had anti-lipid peroxidation and anti-wrinkle effect. Therefore, Cambodian Phellinus linteus could be useful as an anti-wrinkle cosmetic ingredient.

Monitoring of Activated Coagulation Time with Kaolin vs. Celite Activator in Cardiac Surgical Patients with Aprotinin (Aprotinin을 투여한 개심술 환자에서 Kaolin과 Celite Activator를 이용한 Activated Coagulation Time(ACT) 측정의 비교)

  • Kim, Joung-Taek;Sun, Kyung;Lee, Choon-Soo;Baik, Wan-Ki;Cho, Sang-Rock;Kim, Hyun-Tae;Kim, Hea-Sook;Park, Hyun-Hee;Kim, Kwang-Ho
    • Journal of Chest Surgery
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    • v.31 no.9
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    • pp.873-876
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    • 1998
  • Background: High-dose aprotinin has been reported to enhance the anticoagulant effects of heparin during cardiopulmonary bypass ; hence, som authors have advocated reducing the dose of heparin in patients treated with aprotinin. Material and Method: The ACT was measured before, during and after cardiopulmonary bypass, with Hemochron 801 system using two activators of celite(C-ACT) and kaolin(K- ACT) as surface activator. From June, 1996 to February, 1997, 22 adult patients who were scheduled for elective operation were enrolled in this study. Result: The ACT without heparin did not differ between C-ACT and K-ACT. At 30 minutes after anticoagulation with heparin and cardiopulmonary bypass, the average C-ACT was 928${\pm}$400 s; K-ACT was 572${\pm}$159s(p<0.05). After administration of protamine, C-ACT was 137${\pm}$26 s; K-ACT was 139${\pm}$28s, which were not statistically significant. Conclusion: Our results showed that the significant increase in the ACT during heparin- induced anticoagulation in the presence of aprotinin was due to the use of celite as surface activator, rather than due to enhanced anticoagulation of heparin by aprotinin. We conclude that the ACT measured with kaolin provides better monitoring of cardiac surgical patients treated with high dose aprotinin than does the ACT measured with celite. The patients treated with aprotinin should receive the usual doses of heparin.

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A Study on the Directions of Sewol Ferry Tragedy Memorial Park Based on the Analysis on Social Discourse and Recognition Evaluation (도심형 메모리얼파크의 사회적 담론 및 인식분석을 통한 4·16 세월호 참사 추모공원 방향성 제안 연구)

  • Kim, Do-Hun
    • Journal of the Korean Institute of Landscape Architecture
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    • v.48 no.6
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    • pp.25-38
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    • 2020
  • The objective of this study is to propose a direction for creating a memorial park for the 250 students victims of the Sewol ferry disaster. To this end, this study first attempted to understand the matters discussed at various levels to create a memorial park and find a way that the park can be built by gathering opinions from the bereaved families and the victims themselves, as well as local residents, and experts. Workshops, competitions, special lectures, and websites, etc, were analyzed. A social discourse analysis methodology was used for systematic analysis, and the analyzed discourse was categorized into 4 types for assessment, and the functions and roles were subdivided into 15 types. To assess the priorities and the adequacy of the discourse, an analytic hierarchy process (AHP) was used among 30 activists, public servants, and experts. Then, a survey was conducted to analyze the perception of the residents (467 participants including the bereaved families) about the memorial park. Based on the results of the analysis, two directions were set for the memorial park. First, is a memorial park to remember the victims in everyday life. It must be a park with various cultural contents instead of a conventional memorial park that is solemn and grave sharing anguish and sorrow. The memorial park for the Sewol ferry disaster must become a space where visitors can naturally encounter and remember the victims. Second, is a park that serves as a catalyst that brings change and innovation to the community. It must be able to bring change to the community with direct and indirect influence. It must serve as an impetus to bring change and innovation to the community in the mid-to-long-term. Having many visitors may also lead to an economic effect. These visitors may not just stay in the park, but even contribute to revitalizing the local businesses. The purpose of this study is to apply the research findings to guide the International Design Competition scheduled for 2020 and serve to establish guidelines for a continuous park management system.

The Korean Girl Group Kara's Differentiation Strategy Which Overcome the Trilemma and Led to the Great Reversal Success (삼중고 탈피 후 대역전의 성공을 이끈 걸 그룹'카라'의 차별화 전략)

  • Kim, Jeong-Seob
    • Journal of Korea Entertainment Industry Association
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    • v.15 no.2
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    • pp.169-178
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    • 2021
  • The Korean girl group "Kara" has suffered the trilemma of its de facto failure to debut, the crisis of team breakup, and the CEO crisis of the agency. But the group has made an outstanding achievement in the history of Korean pop music after overcoming all odds. Their success strategy has never been disclosed by insiders involved in Kara's total music projects. This study has been carried out in the analysis of the strategy to provide academic implications and to honor the contribution of the late CEO Ho-yeon Lee and Kara's key member Ha-ra Gu. Therefore, between Nov. and Dec. 2020, we conducted in-depth interviews with managers, composers, stylists and Ha-ra Gu(Only in 2019, before her death) who took part in the project. The research model is set up by combining Porter's Competitive Advantage Strategy and the music value chain model into categories of "Product Innovation Differentiation (PD)" (producing, album production, performance activities) and "Marketing Differentiation (MD)" (market targeting, image specialization, promotion and communication). The analysis showed that the PD focused on complete rediscovered harmonization and revalued members' personality and sincerity with peppy songs and dainty dances as well as emission of "bright energy" which caused healing effects instead of mimicking other star singers recklessly. In terms of MD, they selected Japan's 10-20s as their main market, increasing intimacy with fans and media with the image of cute+pretty+classy+sexy. The result suggests that Poter's differentiation can function as a meaningful strategy frame in the fostering, hit, and revival of idol groups. In addition, it reaffirmed that spontaneous and passionate activities of early-stage or celebrity fan may serve as a valid catalyst for realizing differentiation, as Kara's caller of Japanese actor Gekidan Hitori caused a strong "priming effect" that drove Kara's unexpected wonderful success in Japan.