• Title/Summary/Keyword: 촉매점화

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Study on Auto Ignition of Hybrid Rocket Using $N_2O$ Catalytic Decomposition ($N_2O$ 촉매 분해를 이용한 하이브리드 로켓 자연 점화 연구)

  • Yong, Sung-Ju;Kim, Tae-Gyu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2010.05a
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    • pp.202-205
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    • 2010
  • Auto ignition of hybrid rocket using $N_2O$ catalytic decomposition was studied in the present study. The hybrid rocket consists of catalytic igniter, solid fuel, combustor, and nozzle. The Ru/$Al_2O_3$ catalyst for $N_2O$ decomposition was synthesized by an impregnation method, and $N_2O$ conversion as reaction temperatures was measured. The temperature change of the catalytic ignitor was measured at the operating condition, and the possibility for the auto ignition of hybrid rocket was validated.

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Ignition Studies Of Igniter using Hydrogen Peroxide And Kerosene (Catalyst Ignition) (과산화수소/케로신(촉매점화) 점화기의 점화특성에 관한 연구)

  • Kim, Ki-Woo;Kim, Tae-Wan;Lee, Yang-Suk;Kim, Yoo;Ko, Young-Sung;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.57-60
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    • 2009
  • Exothermic and ignition characteristic of igniter is very important factor in engine performance. Since the igniter performance is effected by Hydrogen Peroxide decomposition rate, we have to test the preliminary catalyst performance test. In this report, after making igniter using hydrogen peroxide/kerosene, a thermal characteristic were examined by comparing hydrogen peroxide mass and catalyst mass. And then we study ignition characteristic of the affects of O/F ratio using the previous data.

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A Study on Multi-Stage Catalytic Ignitor for Hybrid Rocket Auto Ignition (하이브리드 로켓 자동점화를 위한 다단촉매점화기에 관한 연구)

  • Choi, Woojoo;Kim, Jincheol;Kwon, Minchan;Yoo, Yeongjun;Kim, Taegyu
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.117-119
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    • 2017
  • The multi-stage catalytic igniter for hybrid rocket auto ignition is described in this paper. After charging the catalyst and pre-heating the first stage, the $N_2O$ was supplied at the first stage with the low mass flow rate, and then the $N_2O$ with the high flow rate was supplied into the second stage. Even though the $N_2O$ flow rate was high, it was decomposed by supplying the high temperature gas which was evolved from the $N_2O$ decomposition in the first stage. This multi-stage ignitor resulted in the decrease of the ignition time in comparison with the previous ignitor, and confirmed the possibility of $N_2O$ decomposition with the high flow rate using the multi-stage catalytic-ignition system.

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Design of Hydrogen Peroxide/Kerosene Ignitor and Ignition Characteristic according to Operation Condition (친환경 추진제를 사용하는 액체로켓엔진 점화기의 설계 및 운용 조건이 점화 특성에 미치는 영향)

  • Hwang, Oh-Sik;Kim, Tae-Woan;Jeon, Jun-Su;Ko, Young-Sung;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.74-77
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    • 2009
  • Ignition performance tests were performed to develop a catalytic ignitor which used hydrogen peroxide and kerosene. Ignition characteristics were investigated by exit area of the catalytic bed, shape of kerosene injector and lead time of purge gas. The results showed that exit area of catalytic bed must be enough for non chocking condition and kerosene must be sprayed with swirl in the middle of catalytic bed. Also in case without preheating of catalytic bed, hydrogen peroxide must be leaded by 3sec, and purge gas must be supplied simultaneously or lately with kerosene.

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A Study on Design of a Catalytic Ignitor for Liquid Rocket Engine using Hydrogen Peroxide and Kerosene (과산화수소/케로신을 사용하는 액체로켓엔진의 촉매 점화기 설계에 관한 연구)

  • Chae, Byoung-Chan;Lee, Yang-Suk;Jun, Jun-Su;Ko, Young-Sung
    • Journal of the Korean Society of Propulsion Engineers
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    • v.15 no.6
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    • pp.56-62
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    • 2011
  • An experimental study on design of a catalytic ignitor was performed to use an ignition source for a small bi-propellant liquid rocket engine which use hydrogen peroxide and kerosene as propellants. In the catalytic ignitor, hot gas of hydrogen peroxide which was decomposed by a catalyst induced autoignition of kerosene. Mass flow rate and O/F ratio for the ignitor were calculated by CEA code. A combustion chamber which had a quartz window and thermocouples was manufactured to determine whether the ignition is successful. Ignition performance was investigated according to exit area of fixed rings and mixture ratio. Results showed that reliable ignition performance was achieved at non-choking exit area of fixed ring and O/F ratio of 6~8.

Auto-ignition Characteristics of Paraffin and PE Hybrid Rocket with $H_2O_2$ Catalytic Decomposition (과산화수소 촉매 분해를 이용한 파라핀 및 PE 하이브리드 로켓의 자연 점화 특성)

  • An, Sung-Yong;Jin, Jung-Kun;Jung, Eun-Sang;Kwon, Se-Jin
    • Journal of the Korean Society of Propulsion Engineers
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    • v.13 no.5
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    • pp.48-56
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    • 2009
  • The auto-ignition tests of hybrid rockets with the concentrated hydrogen peroxide as an oxidizer were presented. Auto-ignition was successfully demonstrated by injecting decomposed gases from $H_2O_2$ into paraffin or polyethylene fuels. In addition, restart and instant ignition were realized with this rocket. For stable combustion, a higher $L^*$ value was required for the paraffin combustion compared with PE. On the other hand, much faster response time was demonstrated in case of a paraffin, which was 13 and 30 ms at ignition delay and rise time respectively.

Auto-ignition Characteristics of Paraffin and PE Hybrid Rocket with $H_2O_2$ Catalytic Decomposition (과산화수소 촉매 분해를 이용한 하이브리드 로켓 자연 점화)

  • An, Sung-Yong;Jin, Jung-Kun;Jung, Eun-Sang;Kwon, Se-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.11a
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    • pp.499-502
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    • 2009
  • The auto-ignition tests of hybrid rockets with the concentrated hydrogen peroxide as an oxidizer were presented. Auto-ignition, restartability, and instant ignition were successfully demonstrated by injecting decomposed gases from $H_2O_2$ into paraffin or polyethylene fuels. In addition, much faster response time was demonstrated in case of a paraffin, which was 13 and 30 ms at ignition delay and rise time respectively.

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Development of Hydrogen Peroxide Thruster adopted Silver Catalyst (은을 촉매로 사용하는 과산화수소 추력기 개발)

  • Lee, Su-Lim;Lee, Choong-Won
    • Journal of the Korean Society of Propulsion Engineers
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    • v.11 no.4
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    • pp.67-73
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    • 2007
  • In recent years hydrogen peroxide has become considerably more attractive as a green rocket propellant so a laboratory model of hydrogen peroxide thruster adopted silver catalyst and a test facility has been developed to research a hydrogen peroxide propulsion. The design scheme of thruster and the test data are presented including ignition delay, efficiency of characteristic exhaust velocity. As a result, 95% of efficiency of characteristic exhaust velocity was obtained at steady state operation condition.

A Study of Design of $H_2O_2$/Kerosene Ignition Injector and Spray Characteristics (과산화수소/케로신 점화용 분사기 설계 및 분무특성에 관한 연구)

  • Kim, Bo-Yeon;Hwang, Oh-Sik;Lee, Yang-Suk;Ko, Young-Seong;Kim, Yoo;Kim, Sun-Jin
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2009.05a
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    • pp.37-40
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    • 2009
  • This study was performed to design of $H_2O_2$/Kerosene catalyst ignition injector and cold flow test to measure the mass flow rate and spray angle. Mass flow rate and spray angle were measured by designed injector through cold flow test. Result of test kerosene mass flow rate was measured 12.88 g/s and 40 deg of spray angle at pressure drop 3 bar as same as design point. And hydrogen peroxide was measured 94.39 g/s at pressure drop 1 bar smaller than design point.

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Thermoelectric Property of Fe-Si Based Materials Prepared By Self-Propagating High Temperature Synthesis (비기체연소합성법으로 제조한 Fe-Si계 재료의 열전특성)

  • Song, Tae-Ho;Lee, Hyeong-Min;Lee, Hong-Rim;Bae, Cheol-Hun
    • Korean Journal of Materials Research
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    • v.7 no.4
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    • pp.295-302
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    • 1997
  • 금속분말 Fe와 Si에 KNO$_{3}$(Fe+Si)무게비=0.2로 점화촉매 KNO$_{3}$를 혼합하고 50MPa로 성형한 후 점화시키는 비기체연소합성(SHS; Self propagating High temperature Synthesis)법으로 출발 분말을 얻었다. 점화분위기를 공기 및 Ar으로 한 경우 XRD결과에서 특별한 차이가 없었고 두 경우 모두 SiO$_{2}$피크가 검출되었다. 합성된 분말을 성형한 후 119$0^{\circ}C$환원분위기에서 소결하고 포석온도이하에서 열처리하여 반도성 FeSi$_{2}$가 주상인 Fe-Si계 열전재료를 제조하였다. Fe/Si무게비=46/54,44/56 및 42/58시편의 제벡계수는 Si함량이 증가할수록 증가하였다. 점화후의 세척처리를 2단계로 하는 경우 제벡계수의 부호가 변화하여 p-type에서 n-type으로 변화하며 소결밀도가 크게 상승하였다. 조성에 관계없이 공통적으로 발견되는 SiO$_{2}$는 점화시의 분위기보다는 점화촉매에 포함된 K성분이 소결 및 열처리시 산화제로 작용하여 형성되는 것이 확인되었다.

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