• Title/Summary/Keyword: 차로 속도

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Solvent Effects on the Nucleophilc Addition (I) Effect of Solvent Polarity on the Nucleophilic Addition of Amine to Phenylvinylketone (친핵성 첨가반응에 대한 용매효과 (I) Phenylvinylketone에 대한 아민의 첨가반응속도에 미치는 용매의 극성효과)

  • Gap-Cheol Shin;Tae-Rin Kim
    • Journal of the Korean Chemical Society
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    • v.36 no.2
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    • pp.287-292
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    • 1992
  • The rate constants of the nucleophilic addition reaction of amines (piperidine and diethylamine) to phenylvinylketone in various solvents have been determined by UV spectrophotometry at $25^{\circ}C$. On the basis of the high sensitivity of the rate to the polarity of the medium, it may be concluded that the reaction intermediate has zwitterionic character. The effect of the solvents on the rate of the bimolecular nucleophilic addition reaction is described well by the Kirkwood equation: The transition state of the reaction has a cyclic structure formed through an intramolecular hydrogen bond. The addition reaction of primary and secondary amines to phenylvinylketone in all solvents take place considerably faster than that of tertiary amine and this results also can be explained by the intermediate products in the reaction have a cyclic structure formed through an intramolecular hydrogen bond for the primary and secondary amines but not for the tertiary amine.

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Effectiveness Analysis of Lane Balancing in Urban Areas (도시부 주행 차로수 일치에 따른 효과 분석 - 국도32호선 대전광역시 통과구간 대상 -)

  • Chang, Iljoon
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.2D
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    • pp.203-208
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    • 2011
  • Traffic demand is continuously increasing due to the development of urban areas in Korea. To cope with this, many efforts have been done including constructions of new roadways and increasing the number of lanes of the existing roadways. Those efforts, however, have been performed for only a short segment of target links having similar traffic characteristics. As a result, most urban cities experience bottle-neck phenomena which lead decreasing flow speed and increasing possibilities of accidents. Thus, this study aims to analyze problems of bottle-neck phenomena and effects of balancing number of lanes along the same corridor having similar traffic characteristics. For this, Route 32 passing the city of Daejeon in Korea has been selected as a case study, and a micro-simulation tool, VISSIM, has been adopted for the analysis. The results show that balanced number of lanes along the same corridor with similar traffic characteristics can increase flow speeds and enhance safety.

Some convergence properties of godard's quartic algorithm: 1. The rate of convergence (4차 고다드 알고리즘의 몇 가지 수렴 성질:1. 수렴속도)

  • 최진호;배진수;송익호;박래홍;박정순
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.21 no.9
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    • pp.2349-2354
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    • 1996
  • Convergence analysis on Godard's quartic (GQ) algorithm used forblind equalization is accomplished in this paper. The first main result is an explanation of the lacal behavior of the GQ algorithm around the global minimum point of the average performance functio, from which we can determine the adaptation gain. It is show that the normalized adaptation gain of the GQ algorithm should be smaller than that of the decision directed (DD) algorithm. In addition, it is observed that the GQ algorithm converges faster than the DD equalization algorithm.

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Taxonomic Review of the Genus Eupithecia (Lepidoptera : Geometridae : Larentiinae) from Korea (II) (한국산 애기물결자나방속의 분류학적 정리(II))

  • 오성환
    • Korean journal of applied entomology
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    • v.32 no.4
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    • pp.440-449
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    • 1993
  • Six species of the genus Eupithecia: E. okadai Inoue, E. scribai Prout, E. perpaupera Inoue, E. kobayashii Inoue, E. tripunctaria Herrich-Sch ffer, and E. virgaureata Doubleday are newly reported from Korea, with illustration of genitalia of both sexes. Further 5 previously known species are also included.

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Analysis of Lane-Changing Distribution within Merging and Weaving Sections of Freeways (고속도로 합류 및 엇갈림구간에서의 차로변경 분포 분석에 관한 연구)

  • Kim, Yeong-Chun;Kim, Sang-Gu
    • Journal of Korean Society of Transportation
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    • v.27 no.4
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    • pp.115-126
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    • 2009
  • The lane-change behavior usually consists of discretionary lane-change and mandatory lane-change types. For the first type, drivers change lanes selectively to maintain their own driving condition and the second type is the case that the drivers must change the current lane, which can occur in recurrent congestion sections like merging and weaving sections. The mandatory lane-change behavior have a great effect on the operation condition of freeway. In this paper, we first generate data such as traffic volumes, speeds, densities, and the number of lane-change within the merging and weaving sections using the data of individual vehicle collected from time-lapse aerial photography. And then, the data is divided into the stable and congested flow by analyzing the speed variation pattern of individual vehicles. In addition, the number of lane-changing from ramp to mainline within every 30-meter interval is investigated before and after traffic congestion at study sites and the distribution of lane-changing at each 30-meter point is analyzed to identify the variation of lane-changing ratio depending on the stable and congested flows. To recognize the effect of mainline flow influenced by ramp flow, this study also analyzes the characteristics of the lane-changing distributions within the lanes of mainline. The purpose of this paper is to present the basic theory to be used in developing a lane-changing model at the merging and weaving sections on freeways.

Development of a Vehicle Operating Speed Model and its Application for Designing Consistent Horizontal Alignment (차량 주행속도를 반영한 도로 평면선형설계 기법 연구)

  • Choi, Jai-Sung;Kim, Sang-Youp;Lee, Jeom-Ho;Hwang, Kyung-Sung
    • International Journal of Highway Engineering
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    • v.10 no.2
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    • pp.57-67
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    • 2008
  • At present engineers use the highway design speed concept to develop the horizontal alignment. This concept has a strength of attaining consistent horizontal alignments because of its use of a single speed value. Yet it shows a critical weakness that when opened the operating speed for the vehicles on the road can be a lot different than the design speed. To resolve this, many countries already develop the horizontal alignment by adopting procedures that weigh vehicle operating speeds, and this research joins them by developing an operating speed based horizontal alignment design. We have collected vehicle speed samples over the nation, selected some speed influential design elements by doing a statistical analysis, provided a set of models for two-lane roads and four lane roads, and showed a stepwise feedback procedure by doing a case study. It is underscored that in the case study the proposed procedure has scaled down the speed inconsistency problem, and we are of opinion that our procedure would coin both investment efficiency and speed consistency in future highway projects.

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현황 및 향후 계획

  • 소종석
    • Proceedings of the KSR Conference
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    • 2002.05a
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    • pp.47.2-60
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    • 2002
  • 전기철도(Electric Railway) 실용화 - 1879년 베를린(Berlin) 산업박람회에서 시멘스 할스케 (Siemens Halske) 회사가 소형 전기기관차로 객차 3량을 속도 12[Km/h]로 견인 운전 전기철도(Electric Railway) 상업운전 - 시멘스 할스케 회사가 1881년에 베를린시 부근의 리히테르펠데(Lichterfelde)에 전기철도를 건설하여 전기차에 의한 일반여객 수송(중략)

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A Design of an SARPE System considering the moving speed and direction of a vehicle (차량의 이동속도와 이동방향을 고려한 SARPE 시스템 설계)

  • Lee, ByungKwan;Jeong, Eun Hee;Jung, INa
    • Journal of Korea Society of Industrial Information Systems
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    • v.18 no.6
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    • pp.61-70
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    • 2013
  • This paper proposes a design of SARPE(Speed and Azimuth based Routing Protocol for Emergency) system which transfers an emergency message rapidly and accurately by minimizing path disconnection with a vehicle's speed and azimuth in case of accidents. The SARPE system accomplishes the path search based on an azimuth in order to minimize unnecessary messages and workload. It also selects the paths with the lowest probability that the path disconnection will happen by using the difference between the speed(maximum, minimum) of intermediate nodes and the average speed of a source node and destination node. Therefore, this paper minimizes the path resetting work happening due to path disconnection and transfers an emergency message rapidly and accurately.

적응적 고차상관 처리를 이용한 차량의 주행궤적 검출계

  • 장경영;오재응
    • Proceedings of the Korean Society of Precision Engineering Conference
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    • 2001.10a
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    • pp.169-173
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    • 2001
  • 무인 운반차 등의 주행괘적을 검출하기 위해서는, 일반적으로 순간적인 주행속도와 진행방향을 축차적으로 검출하여 이로부터 궤적을 측정하는 방법이 이용되어져 왔으며, 이를 위하여 종래에는 타코미터, 2차 상관법, 공간 필터법 등과 같은 속도 계측 수단과 스티어링 각도 검출기, 자이로등의 회전각 검출 수단을 병용하여야 했다. 본 논문에서는 복수개의 광 선 검출기 군과 이에 대응하는 고차의 상관처리를 이용한 단일계로서 차량의 임의의 궤적을 원호로 근사하여 검출함으로써 곡선 궤적인 경우에도 고정도의 궤적추정이 가능한 새로운 계측법을 제안한다.