• Title/Summary/Keyword: 차단막

Search Result 329, Processing Time 0.035 seconds

The Performance Degradation of PEMFCs Fabricated with Different GDLs During Exposure to Simultaneous Sulfur Impurity Poisoning Condition (서로 다른 GDL을 이용한 고분자전해질 막 연료전지의 황불순물 복합피독에 의한 성능 저하)

  • Lee, Soo;Kim, Jae-Hyun;Jin, Seok-Hwan
    • Journal of the Korean Applied Science and Technology
    • /
    • v.30 no.1
    • /
    • pp.146-151
    • /
    • 2013
  • This paper reveals the performance decrease and recovery of PEMFC when the contaminated fuel gas and air source with sulfur impurities such as hydrogen sulfide and sulfur dioxide were simultaneously introduced to anode and cathode, respectively. Three different GDLs were fabricated with different carbon black and activated carbon to prevent an introduction of sulfur compound impurities into MEA. components. The severity of $SO_2$ and $H_2S$ poisoning was depended on concentrations(3 ppm - 10 ppm) of sulfur impurities. Especially, cell performance degradation rate was rapid when MEA fabricated with CN-2 GDL because it had little porosity on GDL surface. Moreover, the cell performance can be recovered up to 90%-95% only with neat hydrogen and fresh air feeding.. Conclusively, MEA fabricated with porous CN-1 GDL showed the best cell performance and recovery efficiency during exposure to poisoning condition by simultaneous sulfur impurities.

FTS (Facing Target Sputtering)장비를 이용한 알루미늄 무기산화막 박막에 관한 연구

  • Bang, Seung-Gyu;Lee, Dong-Uk;Bae, Gang;Kim, Hwa-Min;Son, Seon-Yeong;Jeong, Sang-Gwon
    • Proceedings of the Korean Vacuum Society Conference
    • /
    • 2012.02a
    • /
    • pp.169-169
    • /
    • 2012
  • 현재 디스플레이 시장은 LCD (Liquid Crystal Display), PDP (Plasma Display Panel) 등과 같이 평판 디스플레이가 주류를 이루고 있으며 현재에는 기존의 디스플레이와는 달리 잘 휘어지고 높은 투과성을 가지는 플렉시블 디스플레이에 대한 연구가 활발히 진행 중이다. 하지만 이러한 플렉시블 디스플레이에 사용되는 플라스틱 기판의 경우 용제에 대한 화학적 저항성 및 기계적인 안정성이 취약한 점과 대기중의 수분이나 산소가 플라스틱 기판을 통하여 소자내로 침투하게 되어 금속전극을 산화시키거나 기포 또는 흑점 등과 같은 비 발광 영역이 확산되어 소자의 수명을 단축시키는 치명적인 단점을 가진다. 이에 본 실험에서는 고밀도 플라즈마 형성이 가능하고 저온공정이 가능한 FTS (Facing Target Sputtering) 장비를 이용하여 Polyethylene terephthalate (PET) 기판위에 낮은 수분 투과율 또는 산소 투과율을 갖는 양질의 무기 산화막을 적층하기 위해 저 투습도 및 기계적인 경도 향상을 위한 비 반응성 박막으로 $Al_20_3$층을 Ar분위기에서 증착하였고 그 위에 박막의 stress 감소, 유연성 향상을 위한 반응성 박막으로 Al을 Ar과 $O_2$를 비율별로 증착하여 비교 실험하였다. 이와 같이 제작된 무기산화막들을 Uv- spectrophotometer를 이용하여 광학적 특성을 조사한 결과 가시광 영역에서 모두 80% 이상의 높은 투과율을 나타내었으며, 그 외 XRD (X-ray Diffraction)를 사용하여 결정성을 확인, SEM (Scanning Electron Microscope), AFM (Atomic Force Microscope)을 이용하여 박막의 구조와 표면향상 및 표면조도를 측정한 결과 모든 박막에서 밀집도가 좋으며 거칠기가 작은 것으로 확인되었다. 마지막으로 수분 투과율(WVTR)을 알아보기 위해 Mocon (Permatran W3/31)장비를 이용하여 측정한 결과 $1.0{\sim}3.0{\times}10^{-3}g/m{\cdot}day$의 낮은 수분 투과율을 볼 수 있었다. 이러한 측정 결과로 볼 때 향후 FTS 장비를 이용하여 양질의 플라즈마를 형성하여 알루미늄 무기산화막을 이용한 고밀도 다층막을 형성하면 더욱 낮은 수분투과율을 갖는 가스차단막을 제작할 수 있을 것으로 보여지며 반도체 소자 및 디바이스의 Pachaging으로도 사용가능 할 것이라 사료된다. 본 연구는 한국산업기술진흥원에서 지원하는 2011년도 지역산업기술개발사업의 연구수행으로 인한 결과물임을 밝힙니다.

  • PDF

Case History of Sea Dyke Filter Construction Using Geotextile Tube Mattress (튜브형 매트리스를 활용한 방조제 필터공 축조사례연구)

  • Oh, Young-In;Yoo, Jeon-Yong;Kim, Hyun-Tae
    • Journal of the Korean Geosynthetics Society
    • /
    • v.6 no.1
    • /
    • pp.9-16
    • /
    • 2007
  • Geotextile is one of the most useful and effective polymer material in civil construction works and the main function of geotextile is separation, reinforcement, filtering and drainage. Recently, because of the shortage of natural rock, traditional forms of river and coastal structures have become very expensive to build and maintain. Therefore, the materials used in hydraulic and coastal structures are changing from the traditional rubble and concrete systems to the cheaper materials and systems. One of these alternatives employs geotextile tube technology in the construction of coastal and shore protection structures, such as embankment, see dyke, groins, jetties, detached breakwaters and so on. Geotextile tube technology has changed from being an alternative construction technique and, in fact, has advanced to become the most effective solution of choice. This paper presents case history of sea dyke filter construction using geotextile tube mattress and also, various issues related to the tube mattress design and construction technology.

  • PDF

Intraoperative Neurophysiological Monitoring and Neuromuscular Anesthesia Depth Monitoring (수술 중 신경계 추적 감시 검사와 근 이완 마취 심도의 측정)

  • Kim, Sang-Hun;Park, Soon-Bu;Kang, Hyo-Chan;Park, Sang-Ku
    • Korean Journal of Clinical Laboratory Science
    • /
    • v.52 no.4
    • /
    • pp.317-326
    • /
    • 2020
  • Deep blocking of consciousness alone does not prevent a reaction to severe stimuli, and copious amounts of pain medication do not guarantee unconsciousness. Therefore, anesthesia must satisfy both: the loss of consciousness as well as muscle relaxation. Muscle relaxants improve the intra-bronchial intubation, surgical field of vision, and operating conditions, while simultaneously reducing the dose of inhalation or intravenous anesthesia. Muscle relaxants are also very important for breathing management during controlled mechanical ventilation during surgery. Excessive dosage of such muscle relaxants may therefore affect neurological examinations during surgery, but an insufficient dosage will result in movement of the patient during the procedure. Hence, muscle relaxation anesthesia depth and neurophysiological monitoring during surgery are closely related. Using excessive muscle relaxants is disadvantageous, since neurophysiological examinations during surgery could be hindered, and eliminating the effects of complete muscle relaxation after surgery is challenging. In the operation of neurophysiological monitoring during the operation, the anesthesiologist administers muscle relaxant based on what standard, it is hoped that the examination will be performed more smoothly by examining the trends in the world as well as domestic and global trends in maintaining muscle relaxant.

A Study on Risk Factors for Early Major Morbidity and Mortality in Multiple-valve Operations (중복판막수술후 조기성적에 영향을 미치는 인자에 관한 연구)

  • 한일용;조용길;황윤호;조광현
    • Journal of Chest Surgery
    • /
    • v.31 no.3
    • /
    • pp.233-241
    • /
    • 1998
  • To define the risk factors affecting the early major morbidity and mortality after multiple- valve operations, the preoperative, intraoperative and postoperative informations were retrospectively collected on 124 consecutive patients undergoing a multiple-valve operation between October 1985 and July 1996 at the department of Thoracic and Cardiovascular Surgery of Pusan Paik Hospital. The study population consists of 53 men and 71 women whose mean age was 37.9$\pm$11.5(mean$\pm$SD) years. Using the New York Heart Association(NYHA) classification, 41 patients(33.1%) were in functional class II, 60(48.4%) in class III, and 20(16.1%) in class IV preoperatively. Seven patients(5.6%) had undergone previous cardiac operations. Atrial fibrillations were present in 76 patients(61.3%), a history of cerebral embolism in 5(4.0%), and left atrial thrombus in 13(10.5%). The overall early mortality rate and postoperative morbidity was 8.1% and 21.8% respectively. Among the 124 cases of multiple-valve operation, there were 57(46.0%) of combined mitral valve replacement(MVR) and aortic valve replacement(AVR), 48(38.7%) of combined MVR and tricuspid annuloplasty(TVA), 12(9.7%) of combined MVR, AVR and TVA, 3(2.4%) of combined MVR and aortic valvuloplasty, 2(1.6%) of combined MVR and tricuspid valve replacement, and others. The patients were classified according to the postoperative outcomes; Group A(27 cases) included the patients who had early death or major morbidity such as low cardiac output syndrome, mediastinitis, cardiac rupture, ventricular arrhythmia, sepsis, and others; Group B(97 cases) included the patients who had the good postoperative outcomes. The patients were also classified into group of early death and survivor. In comparison of group A and group B, there were significant differences in aortic cross-clamping time(ACT, group A:153.4$\pm$42.4 minutes, group B:134.0$\pm$43.7 minutes, p=0.042), total bypass time(TBT, group A:187.4$\pm$65.5 minutes, group B:158.1$\pm$50.6 minutes, p=0.038), and NYHA functional class(I:33.3%, II:9.7%, III:20%, IV:50%, p=0.004). In comparison of early death(n=10) and survivor(n=114), there were significant differences in age(early death:45.2$\pm$8.7 years, survivor:37.2$\pm$11.6 years, p=0.036), sex(female:12.7%, male:1.9%, p=0.043), ACT(early death:167.1$\pm$38.4 minutes, survivor:135.7$\pm$43.7 minutes, p=0.030), and NYHA functional class(I:0%, II:4.9%, III:1.7%, IV:35%, p=0.001). In conclusion, the early major morbidity and mortality were influenced by the preoperative clinical status and therefore the earlier surgical intervention should be recommended whenever possible. Also, improved methods of myocardial protection and operative techniques may reduce the risk in patients with multiple-valve operation.

  • PDF

Preparation of Alumina Sol Coated BOPP Composites and Their Gas Permeation Characteristics (Alumina Sol을 코팅한 BOPP 복합체의 제조 및 기체 투과 특성)

  • Hong, Seong-Uk;Oh, Jae-Won;Ko, Young-Deok;Song, Ki-Chang
    • Membrane Journal
    • /
    • v.19 no.1
    • /
    • pp.19-24
    • /
    • 2009
  • Sol-gel process is relatively simple, easy to use, cheap to install, and results in thin coating layers with superior physical and gas barrier properties. Films coated by the sol-gel process can be used as insulating films or packaging films for foods, chemicals, drugs, and beverages, etc. In this study, alumina sol was synthesized from aluminum isopropoxide and silane coupling agent was added to make coating solutions. In addition, biaxially oriented polypropylene (BOPP) was coated using several alumina sol solutions and their oxygen permeabilities were measured. The experimental results indicate that in the best case, the oxygen permeability of coated film was reduced by 85% compared to that of pure BOPP.

Failure of Urination and Defecation after Intrathecal Phenol-glycerin Block for Management of Chronic Perineal Pain -A case report- (만성회음부 통증 치료를 위한 지주막하 페놀글리세린 차단 후 발생한 배변 및 배뇨장애 -증례 보고-)

  • Ahn, Hyun-Jung;Kim, Jong-Il;Lee, Sang-Gon;Ban, Jong-Seouk;Min, Byung-Woo
    • The Korean Journal of Pain
    • /
    • v.12 no.2
    • /
    • pp.268-271
    • /
    • 1999
  • Intrathecal phenol-glycerin block is a potent tool in stepwise approach to intractable perineal pain. At outpatient clinic, intrathecal phenol-glycerin block have been frequently used to control the cancer pain, as this procedure does not require special equipment. However, undesirable effects may occur with any given intrathecal injection. Although most side effects do not last long, they deserve well to prevent. Recently, we have been controlled the perineal and perianal cancer pain with intrathecal phenol-glycerin block without any specific complications. However, one patient we managed experienced that one patient, with this procedure for chronic non-malignant perineal pain control experience gait disturbance and one-week of voiding and defication difficulties. This research reports these practices, including the review of literature.

  • PDF

기술현황분석 - 에코융합형 신개념 절삭 공구의 관련 기술 현황과 개발 사례

  • Gang, Jae-Hun
    • 기계와재료
    • /
    • v.24 no.1
    • /
    • pp.82-91
    • /
    • 2012
  • 이제 더 이상 지구 온난화는 나만 혹은 우리를 제외한 남의 일이 아닌 것이다. 거의 매일 우리는 지구 온난화로 인한 난처한 현상들을 보고 듣거나 직접 느끼고 있는 중이다. 지구 온난화의 주 원인인 이산화탄소 가스의 배출은 비록 다양한 배출 요인들로부터 비롯되고 있다지만 무엇보다도 과다한 생산 제조 활동 때문이라는 것을 모르는 사람은 거의 없을 것이다. 과다한 생산 제조 활동의 증가 추세가 둔화되지 않는 것을 지속적인 신규 생산 제조 활동으로부터 비롯되는 것이라 생각할 수 있다. 이를 막을 수 있는 방안은 말이 쉽긴 하나 재활용 더 나아가 재사용하는 길 뿐이다. 사실상 재활용 역시 상대적으로나 적은 범위의 국한된 생산 제조 활동일 뿐이지 이산화탄소 가스의 배출은 역시 원천적으로 차단하기가 거의 곤란하다. 결국은 재사용의 선택만이 효과적으로 이를 최대한 억제할 수 있는 바른 길이 될 수 있을 것이다. 한편, 최근에 들어서 이른 바 눈에 보이지 않는 자원 전쟁의 분위기가 전세계적으로 고조되고 있는 실정이다. 희귀 금속 자원을 보유하고 있지 않는 국내의 경우는 전반적으로 산업 분야에 걸친 생산 제조 활동에서 요구되고 있는 부품 소재용 원천 금속 자원을 매년 막대한 외화를 지불하며 종속적으로 중국 등의 국가들로부터 수입에 의존하고 있다. 이 또한 매년 일정한 수입 량이 보장되지도 않을 뿐만 아니라 해마다 관세가 높아져 여간 골치 아픈 일이 아니다. 따라서 생산 제조 활동을 주로 하여 수출에 많은 기대를 하고 있는 OECD 국가의 일원인 구내의 경우에는 환경적인 측면과 경제적인 측면을 동시에 고려한 이른바 에코지향형 생산 제조 활동을 더욱 심도있게 추구할 당위성이 제기된다. 이 중의 하나가 바로 생산 제조 활동의 주역을 이루는 매개체 중의 일원인 에코융합형 신개념의 절삭 공구라고 할 수 있다.

  • PDF

Studies on the deposition of ${Si_3}{N_4}$ for the passivation of PHEMT's (PHEMT Passivation을 위한 ${Si_3}{N_4}$)

  • Sin, Jae-Wan;Park, Hyeon-Chang;Park, Hyeong-Mu;Lee, Jin-Gu
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.39 no.1
    • /
    • pp.25-30
    • /
    • 2002
  • In this paper, high quality silicon nitride film is achieved using Plasma Enhanced Chemical Deposition(PECVD) system, and applied in passivating PHEMT's. Passivated PHEMT's(60 ${\mu}{\textrm}{m}$$\times$2 fingers) showed an increase of 2.7 % and 3 % in the drain saturation current and the maximum transconductance, respectively. The current gain cut-off frequency of 53 ㎓ and maximum oscillation frequency of 105 ㎓ were obtained from the fabricated PHEMT's.

Analysis and Optimization of a Depletion-Mode NEMFET Using a Double-Gate MOSFET (Double-Gate MOSFET을 이용한 공핍형 NEMFET의 특성 분석 및 최적화)

  • Kim, Ji-Hyun;Jeong, Na-Rae;Kim, Yu-Jin;Shin, Hyung-Soon
    • Journal of the Institute of Electronics Engineers of Korea SD
    • /
    • v.46 no.12
    • /
    • pp.10-17
    • /
    • 2009
  • Nano-Electro-Mechanical MOSFET (NEMFET) using Double-Gate MOSFET (DGMOS) structure can efficiently control the short channel effect. Espatially, subthreshold current of depletion-mode Double-Gate NEMFET (Dep-DGNEMFET) decreases in the off-state due to the thin equivalent-oxide thickness. Analytical $t_gap$ vs. $V_g$ equation for Dep-DGNEMFET is derived and characteristics for different device structures are analyzed. Dep-DGNEMFET structure is optimized to satisfy ITRS criteria.