• Title/Summary/Keyword: 질소처리

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Nitrogen Removal from Municipal Waste Water Treatment Plants (하수처리장으로 부터의 질소제거)

  • Choe, Ui-So
    • 수도
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    • s.69
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    • pp.23-46
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    • 1994
  • 하수처리장으로부터의 질소제거는 과거 3차 처리의 개념을 토대로 시설비가 고가로 소요되었으나 현재는 2차 처리시에 탄소제거와 함께 질소를 제거하는 개념으로 바뀌어지고 있다. 또한 질소제거는 탄소제거만에 의한 수질보호 차원에서 암모니아 독성을 제거하며 질소산화에 의한 추가 산소소모를 감소시키는 효과를 기대할 수 있다. 2차 처리시설에 의한 질소제거는 약 6%의 시설비와 연간 유지관리비의 증가에 불과하다. 질소제거는 하천이나 호소수의 수질개선뿐만 아니라 독성제거와 산소공급 내지 산소결핍 가능성을 저하시키며 하수처리장의 수질을 향상시킨다. 따라서 앞으로 질소제거는 모든 하수처리장의 2차 처리시설에 적용이 되리라는 것이 국제적인 추세이다. 하수처리장이 계속해서 신설되고 있는 우리나라로서는 이러한 개념을 되도록 빨리 받아들여 뒤늦게 질소제거를 수행함에 따르는 추가 비용의 낭비를 최소화 시키는 것이 현명하리라 생각된다.

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Comparison of Water, Nitrogen Uptake and Use Efficiency Treated with Silica and N Application Forms (규산과 질소형태별 처리에 따른 벼의 수분 및 질소흡수와 이용효율 비교)

  • Choi, Kyung-Jin;Lee, Jung-Il;Chung, Nam-Jin;Yang, Won-Ha;Lee, Chung-Keun;Oh, Se-Kwan;Kim, Je-Kyu
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.58 no.3
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    • pp.220-225
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    • 2013
  • This experiment was carried out to elucidate the effects of silicate and different application forms of N on the uptake of water and N by rice plants. Three rice cultivars, Ilpum, Anda and M202, were grown under the hydroponics in a phytotron. One-hundred ppm silica was applied for silicate treatment. For nitrogen application forms were 100% $NH_4$ and $NH_4+NO_3$ in 2:1 ratio were applied. Silica treatment, compared to silica free, was very effective on the nitrogen uptake and dry weight increase of rice plants. Although silica application demonstrated no significant effect on the amount of water uptake, it improved increased water and nitrogen use efficiency. Therefore, sufficient application of silicate in paddy field will be useful for the growth of rice plants and water saving.

Reducing Nitrogen Fertilization Level of Rice (Oryza sativa L.) by Silicate Application in Korean Paddy Soil (논토양에서 규산질 비료 시용에 의한 질소 시비 저감수준 평가)

  • Lee, Chang-Hoon;Yang, Min-Suk;Chang, Ki-Woon;Lee, Yong-Bok;Chung, Ki-Yeol;Kim, Pil-Joo
    • Korean Journal of Soil Science and Fertilizer
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    • v.38 no.4
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    • pp.194-201
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    • 2005
  • Silicate (Si) fertilizers are well-known for soil amendment and to improve rice productivity as well as nitrogen efficiency. In this study, we investigated the possible reduction level of nitrogen fertilization for rice cultivation by amending Si fertilizer application. Field experiments were carried out to evaluate the productivity of rice (Oryza sativa L.) on a silt loam soil, where three levels of nitrogen (0, 110 and $165kg\;ha^{-1}$) were selected and Si fertilizer as a slag type was applied at 0, 1 and 2 times of the recommendation level (available $SiO_2\;130mg\;kg^{-1}$). Application of Si fertilizer increased significantly the rice yield and nitrogen efficiency. With increasing N uptake of rice, 1 and 2 times of recommended levels of Si fertilization could decrease nitrogen application level to about 76 and $102kg\;N\;ha^{-1}$ to produce the target yield, the maximum yield in the non-Si amended treatment. Silicate fertilizer improved soil pH and significantly increased available phosphate and Si contents. Conclusively, the Si fertilizer could be a good alternative source for soil amendment, restoring the soil nutrient balance and to reduce the nitrogen application level in rice cultivation.

Effect of Nitrogen Fertilizer level on the Yield and Quality of watermelon(Citrullus vulgaris S.). (질소시비수준이 소과종 수박의 수량 및 품질에 미치는 영향)

  • 이상규;김광용;정주호;이용범
    • Proceedings of the Korean Society for Bio-Environment Control Conference
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    • 1997.05a
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    • pp.46-52
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    • 1997
  • 소과종 수박의 고밀도 지주재배시 질소시비량을 260kg/㏊, 200, 140, 0, 무비구로 하여 생육, 수양, 품질 및 무기양분 흡수에 미치는 영향을 조사한 결과는 다음과 같다. 가. 생육특성은 질소시용구가 0kg시용구와 무비구보다 초장, 엽면적, 생체중 및 건물중이 좋았고, 질소시용구간에는 차이가 없었으며 엽수는 모든 처리구에서 차이가 없었다. 나. 수량특성은 140kg/ha시용구가 32,010kg/ha로 가장 높았고, 착과율도 79%로 가장 높았다. 다. 품질특성은 140kg 시용구가 식미지수 3.9, 당도 12.5 $^{\circ}$Bx로 다른 처리구보다 좋았고, 무비구가 12.0 $^{\circ}$Bx로 처리구 중에서 가장 낮았다. 과피두께는 질소 시비량이 증가할수록 두꺼웠다. 라. 식물체(잎)내 T-N의 함량은 질소시비량이 많았던 처리구일수록 증가폭이 컸으며, 모든 처리구에서 생육중기에 가장 많이 흡수되었다. 인산함량은 질소시비량에 따라서 큰 차이가 없었으며 칼슘함량은 질소시비량이 많을수록 증가하는 경향을 보였고, 마그네슘 함량은 칼슘과는 달리 질소시비량이 많을수록 생육후기에 낮았다. 마. 이상의 결과를 종합해 보면 소과종 수박을 밀식하여 지주재배를 실시할 때 토양 염류집적을 줄여주고, 품질 및 수량을 향상시키기 위해서는 질소시비량을 대과종 수박재배시의 70% 수준으로 줄여서 시비하는 것이 바람직하다고 사료된다.

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A Study on the Reduction of COD, Total Phosphorus and Nitrogen in Wastewater by Electrolysis and HClO Treatment (전기화학처리와 HClO 처리를 통한 폐수중 COD, 총인, 총질소의 저감에 대한 연구)

  • Kim, Tae Kyeong;Song, Ju Yeong
    • Journal of the Korean Applied Science and Technology
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    • v.34 no.3
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    • pp.436-442
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    • 2017
  • This study was conducted to develop a wastewater treatment system to remove organic matter, nitrate nitrogen, and phosphate ion in synthetic wastewater. COD was removed almost 100% by the oxidation reaction of HClO and nitrate nitrogen was reduced to ammonia by electrolysis treatment, but ammonia was reoxidized into nitrate nitrogen by HClO treatment. Ammonia was removed almost 100% by heating evaporation and no ammonia was reoxidized into nitrate by HClO treatment. Phosphate ion could be removed by precipitation treatment by forming metal complex according to pH. Through electrolysis treatment and HClO treatment, removal efficiencies of COD 99.5%, nitrogen 97.3% and phosphorus 91.5% were obtained.

The Effect of Compound Fertilizer Contained Slow Release Nitrogen on Turfgrass Growth in Creeping Bentgrasss and on Change in Soil Nitrogen (완효성 질소 비료의 시비가 크리핑 벤트그래스 생장과 토양 중 질소변화에 미치는 영향)

  • Kim, Young-Sun;Kim, Tack-Soo;Ham, Suon-Kyu;Ban, Su-Won;Lee, Chang-Eun
    • Asian Journal of Turfgrass Science
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    • v.23 no.1
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    • pp.111-122
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    • 2009
  • Compound fertilizer contained slow release nitrogen was used at golf course management because of promoting turfgrass growth and decreasing fertilizing labor. But, it was hardly published about turf grass growth by its effect and form like isobutylidene diurea(IBDU) and methylene urea(MU) in golf course management of Korea. This study was conducted to investigate the effect of compound fertilizer contained slow release nitrogen such as IBDU and MU on creeping bentgrasss and the change in nitrogen in the root zone after application of fertilizers at AM turfgrass research institute with soil analysis, chlorophyll content index, leaf area index and dry weight during 5 months from July to december in 2007 year. Fertilizer treatments were designed as following; non-fertilizer(NF), straight fertilizer(CF), treatment 1(MU), treatment 2(IBDU 1), and treatment 3(IBDU 2). The every treatments were arranged a randomized complete block design with three replications. Results obtained were summarized as follows: As relative to time after N fertilizers application, ammonium and nitrate in soil were increased, but T-N was decrease. $NO_3$-N and T-N content of slow release fertilizer(SRF), the treatment MU, IBDU 1 and IBDU 2, in soil was higher than that of CF, and the change of ratio of available N and T-N by elapsed time after fertilizing SRFs and CF was higher about 5% in root zone of SF to l5days, but in root zone of SRF from 30days about $5{\sim}10%$. Compared with NF, the turf color index was increased 6.5%, 6.7%, 5.9% and 5.5%, respectively, the chlorophyll content 33.2%, 38.4%, 35.1% and 37.1%, the dry weight 76.2%, 77.7%, 69.5 and 72.3% and shoot number 28%, 52%, 56% and 51%. The chlorophyll content index of MD, IBDU 1 and IBDU 2 was increased $2.6{\sim}5.2%$ than that of CF, shoot number $18{\sim}22%$ but turf color index and dry weight was analogous to that of CF. These results showed that the SRF application was supplied nitrogen for a long time in root zone by increasing an available nitrogen, and so bring turf growth such as chlorophyll content and shoot number in creeping bentgrass.

Effect of Reduced Nitrogen Fertigation Rates on Growth and Yield of Tomato (질소 관비량 절감이 토마토 생육 및 수량에 미치는 효과)

  • Lee, In-Bog;Lim, Jae-Hyun;Park, Jin-Myeon
    • Korean Journal of Environmental Agriculture
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    • v.26 no.4
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    • pp.306-312
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    • 2007
  • To investigate the effect of N fertigation on the growth, yield, and water and nitrogen use efficiencies during tomato cultivation, seedlings were transplanted in a sandy loam soil under plastic film house condition. 0, 88, 132, 176, $220\;kg\;ha^{-1}$ N rates, which correspond to 0 (NF0), 40 (NF40), 60 (NF60), 80 (NF80), 100% (NF100) N level of soil test-based N fertilization, were injected weekly through drip irrigation system for 15 weeks in N fertigation system, and the control (conventional N treatment) was installed for comparison. Herein, nitrogen was applied by top-dressing with 60% as a basal and 40% as additional fertilizer. There was little different in stem diameter growth among N fertigation treatments, but plant height and dry matter increased with increasing N fertigation rates as well as in N conventional treatment. Tomato yield was increased with increasing the number of marketable fruits in N fertigation treatments, and the fruit yield was maximized in NF 80 treatment ($176\;kg\;ha^{-1}$ N supply or $96.6\;mg\;L^{-1}$ N injection). Dry matter productivity and nitrogen uptake amount were significantly increased with increasing N fertigation rates. The ratio of fruits to the dry weight of whole plant was decreased with increasing N fertigation rates, but this ratio was $2.6{\sim}5.3%$ higher in N fertigation treatments than in the control. In addition, the ratios of nitrogen distributed toward fruits in N fertigation treatments were $3.7{\sim}21.7%$ higher than that of control. The apparent N recovery percentages showed significantly higher values as $71.8{\sim}102.3%$ in N fertigation treatments, compared to 45% in N conventional treatment. Water use efficiency was significantly increased by fertigation system with the maximum $361\;kg/ha\;cm^{-1}$ in NF 80, which is comparable to $324\;kg/ha\;cm^{-1}$ of the conventional treatment. Conclusively, N fertigation system was effective on increasing tomato productivity and nutrient efficiency as well as 20% reduction of N fertilization level.

Removal of Ammonia-Nitrogen Contained in Landfill Leachate by Ammonia Stripping(I) (암모니아 탈기공정을 이용한 침출수의 암모니아성 질소제거(I))

  • Lee, Byung-Jin;Cho, Soon-Haing
    • Journal of Korean Society of Environmental Engineers
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    • v.22 no.10
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    • pp.1893-1904
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    • 2000
  • Nitrogen compounds are one of the major pollutants which cause eutrophication problems of the river or lake and red tides problems of the ocean. Currently available technologies for the removal of nitrogen compounds are mostly biological treatment. However, biological treatment is only effective for the wastewater which contains low concentration of nitrogen compounds. Leachate from solid waste landfill or industrial wastewater which contains high concentration of nitrogen can not be effectively treated by most of the currently available biological treatment technologies. With this connection. the objective of this study is to examine the applicability of ammonia stripping technology for the removal of high concentration of ammonia nitrogen compounds of the leachate from solid waste landfill. It can be concluded that ammonia stripping technology which was placed before the biological treatment process was very effective for the removal of high concentration of ammonium compounds. The chemical cost for the ammonia stripping was 16 percent higher than MLE process, so other methods like sludge recycling are needed for the reduction of operation cost. Further details are discussed in this paper.

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Effect of Nitrogen level under low Temperature Condition on Growth Characters, Nitrogen Concentration and Ethylene Evolution of Rice Varieties (저온하에서 질소시비량이 수도품종의 생육형질, 질소함량 및 ethylene 생성량에 미치는 영향)

  • Lee, Jong-Hoon;Lee, Moon-Hee
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.32 no.2
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    • pp.215-223
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    • 1987
  • This experiment was carried out to determine the effect of nitrogen application on the cold tolerance of rice plant, with treatment of three levels of nitrogen and three times of application under the low temperature at tillering and panicle initiation stages. The higher cold tolerance variety was increased in plant height and number of tillers on high nitrogen level during the low temperature treatment. Nitrogen content of leaf blade was increased, but carbohydrate content was decreased during the low temperature treatment at tillering stage. Ethylene evolution from leaf was remark-ably increased just after low temperature treatment. Highly significant negative correlation was observed bet-ween the nitrogen content of leaf blade and percentage of filled grain under low temperature condition at reproductive growth stage.

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Ocean Outfall과 폐수처리 공정의 비용분석을 이용한 수영만의 수질관리

  • Park, Hae-Sik;Park, Cheong-Gil;Lee, Seok-Mo
    • Proceedings of the Korean Environmental Sciences Society Conference
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    • 1997.10a
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    • pp.52-53
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    • 1997
  • 수역의 유기오염 개선을 위하여 생활하수, 산업폐수 등의 저하시키는데 주안점을 두어왔으나 공공수역에서의 제거되지 않은 질소와 인의 유입으로 부영양화가 진행되어 하천에는 남조류가 대량발생하고 해역에는 적조가 광역에서 발생하여 큰 사회문제가 되고 있고, 질소와 인의 유입으로 인한 자생 COD가 전체COD의 약 절반을 차지하고 있는 실정이다. 따라서 앞으로의 수질을 개선하기 위해서는 조류증식의 제한인자인 질소와 인의 규제가 필요할 뿐만아니라 하수처리장에 고차처리를 적용하거나, 해양의 회석자용을 이용한 Ocean을 적용하여 연안해역 수질을 관리해야 할 것이다. 따라서 본 연구는 수영만을 대상으로 Ocean Outfall과 폐수처리시절을 적절하게 조합하기 위해서 3차원 생태계모델을 적용하여 유기물질 뿐만 아니라 영양염류인 질소와 인의 농도를 예측하여 환경기준을 만족시키고 비용을 최소화 할 수 있는 폐수처리공법과 해중방류관의 위치를 선정하고자 하였다. 본 연구결과 수영만의 1994년 COD는 II등급, DIN과 DIP는 III등급이었다. 현재의 활성슬러지공법으로 질소와 인을 제거하지 않고 방류할 경우 2001년에 는 하수처리량의 증가로 인해 COD의 경우 1994년 보다 조금 감소하지만 DIN 과 DIP는 1994년과 같은 III등급을 유지하였다. 고도처리공법을 도입할 경우 COD의 농도는 광안리와 해운대해수욕장에서 I등급을 보이고, DIP의 농도도 수영만 전체에서 강등급을 보이지만, DM의 농도는 광안리해수욕장에서 II등급, 해운대해수욕장에서 IH등급을 보였다 하수처리장 유출수를 Ocean Outfall을 이용하여 하수처리장으로부터 4km에 서 방류할 경우의 COD농도는 I등급을 보이고, DE 농도도 광안리와 해운대해 수욕장에서는 I등급을 보이고, DU의 농도는 ll등급을 보여 수질이 개선된 것 을 볼 수 있다. 이상에서와 같이 광안리와 해운대해수욕장의 해역환경기준 ll등급을 만족 하는 하수처리방법은 Ocean Outfall이었다. 수영하수처리장에 인을 처리하기 위한 화학적 침전법의 경우 956억원이 소요되고, 질소를 제거하기 위한 질소제거공정을 추가 건설 할 경우는 2181억원이 전요된다. 그리고 두공정을 같이 건설할 경우에는 3137억원의 비용이 소요된다 수영하수처리장에서 4km 거리와 관경을 2m의 Ocean Outfall 건설비용은 325 억원 정도가 소요되는 것으로 산출되었다. 고차처리시 증가되는 비용으로 건설할 수 있는 Ocean Outfall의 길이는 인 제거공정을 첨가하는 경우에는 18km을 건설할 수 있고, 질소제거공정을 첨가 하는 경우에는 46km를 건설할 수 있는 것으로 산출되었다.

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