• JOURNAL OF ELECTRICAL WORLD
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• s.272
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• pp.81-85
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• 1999

코제너레이션이란 Co(공동의)와 Generation(발생한다)의 복합어로 이것을 시스템업한 것을 코제너레이션 시스템이라한다. 코제너레이션 시스템은 전기와 열을 동시에 생산하는데서 열(熱)병합 발전시스템이라고도 하며, 종래 대기 가운데 방출되고 있던 엔진배열(排熱)을 회수하여 발전함과 동시에 이것을 활용하여 종합에너지효율을 75$\%$전후로까지 높이는 시스템이다. 배열 이용으로 보일러 운전시간을 단축시켜 연료소비량을 줄일 수 있게 되어 이산화탄소($CO_2$)를 삭감할 수 있는 외에, 연료를 연소시킴으로써 발생하는 질소산화물($NO_x$)에 대해서도 그 저감기술이 여러 가지 개발되고 있어 국가에서 정한 기준치 이하로 억제할 수 있게 되었다. $CO_2$에 대해서는 지구 온난화방지 교토회의에서 1990년 대비 6$\%$삭감에 합의가 이루어졌으며, 이것을 해결할 수 있는 에너지효율화 환경기기로서 코제너레이션 시스템은 이제부터 보급이 가속화될 것으로 생각된다.

• Transactions of the Korean Society of Automotive Engineers
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• v.20 no.4
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• pp.150-155
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• 2012

Lean NOx Trap (LNT) catalysts are capable of reducing exhaust NOx emissions from diesel engines. LNT stores NOx in lean condition and exhausts N2 by reducing NOx in rich condition. NOx reduction characteristic of LNT catalysts using throttle position sensor and fuel injection timing control for light-duty diesel engine was investigated. In contrast to SCR system, LNT catalyst uses diesel fuel in resuctant. Also if the concentration of reductant is exceeded, excessive amount of reductant will slip throughout LNT and cause another emission problem. Thus LNT regeneration with precise engine control established that can make higher NOx conversion efficiency and lower fuel penalty, prevent another emission problem. NOx and reductant concentration were measured by the NOx sensor and Mexa7100D equipped inlet and outlet of catalyst. As a result of engine test, regeneration strategy has reached high of 77.8% NOx conversion efficiency according to engine operation condition. Moreover, we have proved that it is possible to use regeneration strategy of LNT within 5% fuel penalty.

• Applied Chemistry for Engineering
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• v.22 no.3
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• pp.308-311
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• 2011

The reaction mechanism of selective catalytic reduction of NOx over sewage sludge char impregnated with MnOx using $NH_3$ as the reducing agent was investigated. The active Mn phase was shown to be $Mn_3O_4$ from the XRD analysis. Adsorption was the dominant NOx removal mechanism at low temperatures below $150^{\circ}C$ although reduction reaction also contributed partly to the NOx removal at $100{\sim}150^{\circ}C$. The reaction rate constants of NOx removal over non-impregnated and MnOx-impregnated active chars were compared based on experimental results. The MnOx-impregnated char was shown to have a higher reaction rate constant and a higher NOx removal efficiency due to a higher collision coefficient and a lower activation energy. The activation energy for both chars was shown to be relatively low (10~12 kJ/mol) under the experimental conditions of this study.

• Applied Chemistry for Engineering
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• v.22 no.6
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• pp.658-663
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• 2011

The SNCR-SCR (selective non-catalytic reduction-selective catalytic reduction) hybrid system is an economical NOx removal system. In this study, the effect of the operating parameters of the SNCR-SCR hybrid system on NOx removal efficiency was investigated. When the SNCR reactor was operated at a temperature lower than the optimum temperature ($900{\sim}950^{\circ}C$), an additional NO removal is obtained basesd on the utilization of $NH_3$ slip. On the other hand, the SNCR reactor operated above the temperature resulted in no additional NO removal of SCR due to decomposition of $NH_3$. Therefore, the SNCR process should be operated at optimum temperature to obtain high NO removal efficiency and low $NH_3$ slip. Thus, it is important to adjust NSR (normalized stoichiometric ratio) so that $SR_{RES}$ can be maintained at an appropriate level.

• Journal of the Korea Academia-Industrial cooperation Society
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• v.18 no.10
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• pp.663-668
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• 2017

Dye waste water generated in the dye industry is categorized as hazardous waste water that requires appropriate treatment. The pilot scale experimental trials were carried out using dye waste water as an effective additive for the selective non-catalytic reduction (SNCR) of NOx in combustion flue gases. The additives were waste liquor obtained from the dye industry and several purification steps were taken to make a standardized reagents. The dye waste water was shown to possess valuable SNCR qualities (at least 87% NOx reduction efficiency) considering its availability as a waste product, which has to be strictly treated, and have little effects on CO removal. The results indicated that the NO removal efficiency increased first and then decreased with increasing temperature within $750-1150^{\circ}C$. The maximum NO reduction efficiency was approximately 87% at the optimal reaction temperature. A more than 10% increase in NO reduction was achieved in the presence of 1000 ppm Na-additives (dye waste water) compared to that without additives. The Na-based additives have also a significant promoting effect on $N_2O$ reduction and within the SNCR temperature window.

• Applied Chemistry for Engineering
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• v.32 no.6
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• pp.659-663
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• 2021

10 m³/min (CMM) multi-pollutants abatement system was successfully developed by effectively integrating ozone oxidation, wet scrubbing, and wet electrostatic precipitation for the simultaneous removal of particulate matters (PMs) and NOx in a semiconductor fabrication process. The sophisticated control and optimization of operating parameters were conducted to maximize the destruction and removal efficiency of NOx. In particular, the stability test of a wet electrostatic precipitator was carried out in parallel for 30 days to validate the reliability of core parts including a power supply. An O₃/NO ratio, which is the most important operating parameter, was optimized to be about 1.5 and the optimization of wet scrubbing with a reducing agent made it possible to analyze the contribution of neutralization reaction.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.41 no.4
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• pp.269-275
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• 2017

$NO_X$ reducing technique such as LNT, LNC, and selective catalytic reduction (SCR) have been developed and applied, especially on heavy-duty vehicles. However, it is expected that $NO_X$ reduction techniques will also be applied to diesel passenger vehicles. The urea-SCR system is receiving attention as the most effective $NO_X$ reduction technology without a fuel penalty. Thus, many advanced countries are developing this technology. The urea-SCR system sprays an aqueous urea solution that separates $NO_X$ into $N_2$ and $H_2O$, which are harmless and emitted into the atmosphere. The urea injected in front of the SCR catalyst should be changed to 100％ $NH_3$, which is required for $NO_X$ reduction in the SCR system to maximize the reduction efficiency. The purpose of this study was to determine the basic data for the urea-SCR system to maximize the $NO_X$ reduction efficiency by understanding the $NO_X$ reduction characteristics in a real passenger vehicle to comply with the post EURO-6 emission regulation.

• Journal of Advanced Marine Engineering and Technology
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• v.41 no.3
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• pp.216-221
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• 2017

Diesel engines have the highest brake thermal efficiency among internal combustion engines. Therefore, they are utilized in medium and large transportation vehicles requiring large amounts of power such as heavy trucks, ships, power generation systems, etc. However, diesel engines have a disadvantage of generating large quantities of nitrogen oxides during the combustion process. Therefore, the authors tried to reduce the amount of nitrogen oxides in marine diesel engines using a wet-type exhaust gas cleaning system utilizing the undivided electrolyzed seawater method. In this method, electrolyzed seawater in injected into the harmful gas discharge from the diesel engine using real seawater. The authors investigated the reduction of NO and NOx from the pH value, available chlorine concentration, and the temperature of electrolyzed seawater. The results of this experiment indicated that when the electrolyzed seawater is acidic, the NO oxidation rate in the oxidation tower is higher than that when the electrolyzed seawater has a neutral pH. Likewise, the NO oxidation rate increased with the increase in concentration of chlorine. Further, it was confirmed that the electrolyzed seawater temperature had no effect on the NO oxidation rate. Thus, the NOx exhaust emission value produced by the diesel engine was reduced by means of electrolyzed seawater treatment.

• Proceedings of the Korean Society of Marine Engineers Conference
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• 2011.10a
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• pp.41-41
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• 2011

국제해사기구(IMO)에서2016년에 건조되는 선박부터 Tier III 규제를 예고하고 있다. 이 규 제를 만족하기 위하여 엔진 전처리 기술 및 후처리 기술 개발과 실증 연구가 활발히 진행되고 있다. 이중 SCR(Selective Catalytic Reduction) 반응을 이용한 질소산화물 저감기술이 80% 이상의 Tier III NOx 규제치를 만족할 수 있는 유일한 기술이다. 육상 플랜트에서 실증과 검증이 확보된 SCR 기술의 선박 엔진에 대한 적용을 위해서는 선박의 급격한 운전조건 변화와 엔진에 의한 저주파 진동에 대한 촉매 내구성 확보가 중요하다. 본 연구에서 기공 분포면에서 마이크로 기공보다는 메죠 및 매크로 기공쪽으로 구조를 개선함으로써 촉매 사용시 우려되는 배기가스중의 Soot 또는 2차 합성물질에 의한 촉매기공 막힘을 최대한 방지한 상용 SCR 촉매를 개발하였다. 또한 촉매에 대한 내구성 실증을 위하여 현재 운항 선박(한진피츠버그호)에 장착하여 실증 실험을 수행하였다. 기존 corrugate 타입의 촉매보다 40% 정도의 부피 감소와 차압 감소를 달성하였고 이로 인하여 선박내 제한된 공간에 효율적으로 SCR 시스템 설치가 가능할 것으로 생각된다. 그리고 본 연구에서는 가이드 베인 설치 없이 유동 균일화를 달성하여 반응기 전체의 크기 축소가 가능하다. 이는 추가적인 비용 및 압력 손실 저감, 유지 보수 공간 확보 등의 장점이 있다.

• Transactions of the Korean Society of Mechanical Engineers B
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• v.40 no.3
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• pp.127-138
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• 2016

Diesel vehicles should be equipped with urea-selective catalytic reduction(SCR) system as a high-performance catalyst, in order to reduce harmful nitrogen oxide emissions. In this study, a three-dimensional Eulerian-Lagrangian CFD analysis was used to numerically predict the multiphase flow characteristics of the urea-SCR system, coupled with the chemical reactions of the system's transport phenomena. Then, the numerical spray structure was modified by comparing the results with the measured values from spray visualization, such as the injection velocity, penentration length, spray radius, and sauter mean diameter. In addition, the analysis results were verified by comparison with the removal efficiency of the nitrogen oxide emissions during engine and chassis tests, resulting in accuracy of the relative error of less than 5%. Finally, a verified CFD analysis was used to calculate the interanl flow of the urea-SCR system, thereby analyzing the characteristics of pressure drop and velocity increase, and predicting the uniformity index and overdistribution positions of ammonia.