• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.04a
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• pp.155-158
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• 2002

질산성질소 및 탁도로 오염된 지하수공에 대하여 환경성 복원을 위한 오염방지 시설을 시범 설치하였다. 지하수공에 대한 오염 정도를 조사한 결과 PS-1, CW-1, 그리고 CW-2 공이 질산성질소로 오염되어 먹는물 수질기준을 초과하였고, CW-3 공은 탁도가 먹는물 수질기준을 초과하였다. 오염원은 지하수공 개발시 수량 확보를 위하여 그라우팅을 제대로 하지 않은 불량시공으로 인한 오염된 지표수의 유입으로 기인되었다. 금번 연구는 오염된 지하수의 환경성 복원을 위한 것으로, 오염원과 지하수를 격리시켜 오염물질의 지하수 내 유입을 방지할 수 있도록 패커 그라우팅을 완벽하게 다시 실시하였으며, 오염방지시설을 설치하였다. 이 연구를 위하여 먼저 대수층의 분포 및 특성팍악, 지하수공내 지표수의 유입구간 규명, 지하수 오염원, 오염실태, 오염경로 등을 파악하였다 오염방지시설을 설치한 후, 설치 전,후의 질산성질소와 탁도의 함량을 비교하기 위하여 수질 분석을 실시하였다. PS-1의 경우, 오염방지시설 설치전의 질산성질소 함량은 16.1 mg/L 이었으나, 설치후에는 8.1 mg/L, 7.9 mg/L로써 설치전에 비하여 51% 감소되었으며, CW-1은 10.3 mg/L에서 6.3mg/L으로 39%, 그리고 CW-2는 14.9 mg/L에서 9.0 mg/L 으로 40% 감소되었다. CW-3 공의 탁도는 157 NTU에서 0.97 NTU로 완벽하게 복원되었다.

• Journal of Soil and Groundwater Environment
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• v.10 no.2
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• pp.20-27
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• 2005

The seasonal variation of water quality was studied in the Hwabongcheon. It runs though a small catchment where shallow groundwater was contaminated with $NO_3-N$ by intensive livestock facilities. A direct inflow of animal waste and incoming of contaminated groundwater affected its water quality. In the dry season, an important factor of water quality in the Hwabongcheon was direct inflow of animal waste. In the wet season, concentrations of $NO_3-N$ in the Hwabongcheon were elevated in spite of being diluted by precipitation. It could be explained by the effect of increased incoming of contaminated groundwater and showed by oxygen and hydrogen isotope values. $NO_3-N$ concentration in the Cheongmicheon was lower than that in the Hwabongcheon, so it increased next a junction. This effect was intense in wet season because $NO_3-N$ concentration in the Hwabongcheon was high.

• Economic and Environmental Geology
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• v.37 no.6 s.169
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• pp.647-655
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• 2004

To identify the influential factors and their relative significance on spatial distribution of $NO_3-N$ in urban ground water, spatial analysis was conducted using GIS and statistical approaches in the Seongnae-Koduk watersheds, where rapid urbanization has been proceeded. Several factors were considered including land-use type, distance to sewage lines, the ratio of impervious surface, and the ratio of green area. The spatial distribution of $NO_3-N$ in the land-use types shows differences between urban and crop field possibly due to the sewage networks in urban areas and the agrochemical uses in crop field. Nitrate concentrations in ground water were decreased with the distance to sewage lines to approximately 60-75 m. Concentrations of nitrate and distances to sewage lines showed negative correlation, indicating that the nitrate contamination was induced from the sewage system and specially significant in urban areas. The negative correlation of the ratio of impervious surface to the nitrate concentration in urban areas also suggested that the source materials of nitrate are introduced from the surface. Consequently, in areas of urbanization processes, systematic management of past-and-present land-use types and sewage systems are the most significant factors in preventing ground water from nitrate contamination.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.459-462
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• 2003

충청북도 증평에 위치한 문화마을 인근의 19개 지하수 관측정에서 시료를 채취하여 질산성질소 농도와 $\delta$$^{15}$ N 값, 암모니아성질소 농도와 $\delta$$^{15}$ N 값을 정량하였다. 그 결과 질산성질소에 의한 심각한 오염은 관찰되지 않으며, 질산성질소내 $\delta$$^{15}$ N이 +9.4~+36.8%0의 범위를 갖는 것으로 보아 계분이나 생활하수 혹은 두 가지 이상의 오염원이 동시에 작용함을 나타낸다. 연구지역의 $^{15}$ N 부화지수($\varepsilon$)은 -6.697%0로 탈질에 의한 범위를 만족한다. 암모늄의 질산화가 주요한 반응기작일 경우에 나타나는 암모늄 농도 감소에 따른 $^{15}$ N의 부화는 관찰할 수 없다.

• The Journal of Engineering Geology
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• v.20 no.1
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• pp.25-33
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• 2010

Most of contaminated groundwater in the study area was contaminated by $NO_3-N$ due to inflow of contaminated shallow surface groundwater inflow into groundwater well. Poor grouting and teared screen have increased contaminated shallow surface groundwater inflow into groundwater well. Contaminated shallow surface groundwater was inflowed into groundwater well throughout faults, joints and fracture zone of ESE-WNW, NNW, NW-SE and NS direction. The objective of this paper is to evaluate an improvement of water quality for contaminated groundwater by $NO_3-N$ using compression packer. For this study groundwater samples collected from 46 groundwater wells were analyzed to clarify $NO_3-N$ contents. Groundwater wells over 10 mg/L in $NO_3-N$ content is 9 wells showing 20% among total samples. $NO_3-N$ contents after compression packer installation showed 26~81% low value compared with before compression packer.

• Journal of Environmental Impact Assessment
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• v.30 no.1
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• pp.35-48
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• 2021

In this study, the assessment of field applicability of in-situ remediation of nitrate-contaminated groundwater located in Yesan-gun was performed. Zero-valent iron/bio composite media injected PRB (Permeable Reactive Barrier) and monitoring well were installed in the contaminated groundwater site and monitored main remediation indicators during the PRB operation. Nitrate, nitrite, ammonia, Fe ion, TOC, and turbidity were analyzed and the diversity and population of microorganism in the PRB installed site were investigated for the verification of effect of injected PRB. In the study site where is an agricultural area, a river flows from west to east that forms a river boundary and the southern area has an impermeable sector. It was found that nitrate flows into the river, which is similar as groundwater flow. Simulation result for the fate of nitrate in groundwater showed steady state of nitrate arrived after 3~5 years passed. However, it is just to consider current conditions with no additional input of contaminant source, if additional input of contaminant source occurs contamination dispersion and time for steady state are expected to be increased. The monitoring results showed that Fe ion, TOC and turbidity in groundwater were not clearly changed in concentration after PRB installation, which indicates adaptability of the injected PRB for remediation of groundwater with no additional harmful effect to water quality. The concentration of nitrate maintained less than 5mg/L until 42 days after PRB installation and recovered its initial concentration after 84 days passed and showed termination of reactivity of injected zero-valent iron/bio composite media for removal nitrate. Nitrite and ammonia ions found after installation of PRB indicates reductive removal of nitrate. And the outstanding increase of microorganism diversity and population of Betaproteobacteria Class which includes denitrification microorganism explains biologically reductive removal of nitrate in injected PRB.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2002.09a
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• pp.215-218
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• 2002

The purposes of this research are to identify the source and the extent of contamination of nitrate in groundwater in a typical agricultural area. The study area has many livestock raising facilities, rice paddies and grape farms. In order to identify the hydrogeological character, we sampled groundwater and surface water in 27 locations and performed chemical analyses. Nitrate-nitrogen is the major contaminant in this area. Approximately 32 ~ 42% of groundwater samples are over the drinking water limit(10 mg/L) and 77% estimated to be entered from artificial sources. The nitrogen isotope analysis indicates animal waste being the major source of nitrate in water samples. Not only presently operating livestock facilities but also abandoned ones influence groundwater quality for a long time.

• KSCE Journal of Civil and Environmental Engineering Research
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• v.32 no.1B
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• pp.79-84
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• 2012

Nitrate is a common contaminant in groundwater aquifer. The present study investigates the performance of the bipolar zero valent iron (ZVI, $Fe^0$) packed bed electrolytic cell in removing nitrate in different operating conditions. The packing mixture consists of ZVI as electronically conducting material and silica sand as non-conducting material between main cathode and anode electrodes. In the continuous experiments for the simulated wastewater (contaminated groundwater, initial nitrate about 30 mg/L as N and electrical conductivity about 300 ${\mu}S/cm$), over 99% removal of nitrate was achieved in the applied voltage 600 V and at the flow rate of 20 mL/min. The optimum packing ratio (v/v) and flow rate were determined to be 1:1~2:1 (silica sand to ZVI), 30 mL/ min respectively. Effluent pH was proportional to nitrate influx concentration, and ammonia which is the final product of nitrate reduction was about 60% of nitrate influx. Magnetite was observed on the surface of the used ZVI as major oxidation product.

• Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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• 2003.04a
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• pp.246-249
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• 2003

충북 괴산군-보은군 일대를 따라 발달된 중부 옥천대의 구룡산층과 운교리층 분포지역에서, 기반암에 따른 지하수의 수질특성의 차이를 규명하고자 하였다. 2002년 11월에 18개 지점에서 지하수 시료를 채취하였고, 이를 분석하여 기반암에 따른 지하수의 수질을 분류하였다. 구룡산층 시료와 운교리층 시료 모두 Ca-(HCO$_3$+ CO$_3$) 유형의 수질특성을 보였다. 군집분석의 결과 기반암의 종류에 따라 수질특성이 나됨을 알 수 있었다. 수질 분석결과를 국내 먹는물 수질기준와 비교 하였을때, 질산성 질소 항목만 기준치를 초과하였다. 질산성 질소의 경우, 국내 먹는물 수질기준인 10 mg/L를 초과한 시료는 한 지점이었지만, 인간 활동에 의해 오염된 것으로 여겨지는 2 mg/L이상의 시료는 전체 18개 시료 중 61%인 11개 지점으로 나타나, 이 연구지역에서 인간활동에 의한 질산성 질소의 오염이 진행되고 있음을 추정할 수 있었다.

• Journal of Soil and Groundwater Environment
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• v.8 no.1
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• pp.57-67
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• 2003

Nitrate contamination by human activities is a serious problem to water-supply in agricultural area. Shallow groundwater is the main source of water-supply, but it is very sensitive to contamination. Study area for nitrate contamination is a region of Iljuk, Kyunggi where is an agricultural area having many livestock facilities in various scales. As a result, the points having availability of incoming of external contaminant are 77%, and the ones over the Drinking Water Limit (DWL) are 32～42%. For a nitrogen isotope analysis, all the points having availability of incoming of external contaminant have $\delta$$^{15}$ N-NO$_3$ values over 5$\textperthousand$, and the points of 59% are strongly affected by nitrogen originated from animal wastes. The major source of nitrate in this area is intensive livestock facilities. Even though a livestock facility had enclosed, it affects groundwater quality for a long time. The chemical property of contaminant source is various according to animal species in surface water, but not in groundwater since some solutes are removed by reactions during an inflow to subsurface.