• Title/Summary/Keyword: 지화학 자료

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탄산수와 탄산침전물 및 침전잔류물에서의 희토류원소(REEs)의 분배 및 거동 특성

  • 최현수;고용권;윤성택;배대석
    • Proceedings of the Korean Society of Soil and Groundwater Environment Conference
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    • 2004.04a
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    • pp.384-387
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    • 2004
  • 강원도 지역 탄산수에 대해 혼합에 의한 용존 희유원소의 거동특성 및 탄산염 침전물 형성에 따른 REE 분별작용을 살펴보았다. 탄산수들은 화학적으로 $Na-HCO_3형,\; Ca-Na-HCO_3형\; 및\; Ca-HCO_3$형으로 구분되며, 동위원소조성도 유형에 따라 명확히 구분되는 특징을 보인다. 지화학 및 동위원소 자료의 해석 결과, $Na-HCO_$형 탄산수는 지하심부에서 심부 기원 $CO_2$의 공급에 의해 형성된 반면, 다른 두 유형의 탄산수들은 $Na-HCO_$ 형 탄산수와 천부지하수 간의 혼합에 의해 생성되었음을 지시하였다. 탄산수 내 용존 REE 함량은 물 유형에 따라 변화하지만, ∑REE 함량은 TDS, pH, alkalinity, $\delta^{18}O$$\delta^{18}O$ 및 tritium 함량과 좋은 상관성을 보여주어, 천부 지하수와의 혼합된 특징을 나타내었다. Na-HCO$_3$형 탄산수의 용존 REE 패턴은 강한 HREE 부화를 보여주어 이른바 'S-shape'을 나타내는 반면, $Na-HCO_$ 형은 분산되어 있으며 LREE 부화를 보여주었다. $Ca-Na-HCO_3$형은 약한 HREE 분화 패턴을 보여주었다. 탄산수로부터 침전된 침전물과 침전물을 제거한 잔류물의 REE 패턴은 원 탄산수와 거의 유사한 형태를 보여주어, 탄산염 침전물과 잔류물 간의 REE 분별작용은 일어나지 않았음을 나타낸다.지 않았음을 나타낸다.

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Some Aspects of Tungsten Mineralogy and Geochemistry (중석의 광물학적, 지화학적 고찰)

  • Kim, Sahng Yup
    • Economic and Environmental Geology
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    • v.12 no.3
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    • pp.127-146
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    • 1979
  • Though tungsten minerals have been mined for over fifty years in Korea, which has become one of the worlds largest tungsten producers since 1951, knowledge of their mineralogy and geochemistry is somewhat limited to the school of tungsten students. There is a considerable amount of literature throughout the world on the tungsten mineralogy, the geochemical behaviour of tungsten, the nature of tungsten deposits and geological environments for tungsten mineralisation. Commonly known tungsten minerals such as scheelite and wolframite belong to one of two series, the scheelite or the wolframite series, as the primary tungsten minerals. Secondary tungsten minerals are known rather rare, however, some of them plays an important role-of exploration guide in search for tungsten deposits. The geochemistry of tungsten is imperfectly known, and apparently the behaviour of tungsten in geological processes has been the subject of few studies. Recently, some aspects of the fundamental geochemistry of tungsten has been worked out and compiled the data in broad the up to date by many authors. In order to facilitate the better understanding and future exploration of tungsten deposits, an attempt has been made to summarise the existing knowledge of the fundamental geochemistry of tungsten, together with its common geochemical association with various types of tungsten deposits.

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Survey of Chemistry Teachers' Perceptions and Teaching Style on Chemistry I Course (화학 I 교과에 대한 화학 교사들의 인식과 학습 지도 방식에 대한 조사)

  • Lee, Eun-Ju;Cho, Young-Ja;Kim, Eun-Suk;Ryu, Ran-Yeong;Kim, Dong-Jin;Park, Kuk-Tae
    • Journal of the Korean Chemical Society
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    • v.51 no.1
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    • pp.73-81
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    • 2007
  • The purpose of this study was to find out chemistry teachers' perceptions on the aims and characteristics of the chemistry I course from the 7th national curriculum by means of investigating how frequently particular learning contents were selected and what the teachers' teaching styles were in order to find out how effectively teachers were working with the 7th national curriculum in teaching. For this study, data was collected by means of questionnaires, which was answered by 44 chemistry teachers in 40 different high schools. Results from this study are as follows: As for the perception on the aim and characteristics of chemistry I course, many chemistry teachers have already perceived that the aim of the course was to promote democratic citizens with the knowledge of chemistry. And the most appropriate way of teaching chemistry I course was inquiry-centered teaching such as experiment-practice and inquiry-discussion. However, these perceptions were not reflected when they actually taught students in the classroom. Instead, most of the class was concepts learning and there were a lot of differences in selecting learning contents among chemistry teachers. Furthermore, although chemistry I course was considered a good subject to make students have interest and curiosity in chemistry, it was not appropriate to make students understand the concepts of chemistry. Therefore, learning contents in chemistry I course need to improve. In conclusion, as the goal of 7th national curriculum of chemistry I course was to emphasize inquiry teaching, inquiry based teaching should be practiced in the class. Moreover, sufficient teacher training should be accompanied and alternative additional teaching contents should be developed. Finally teachers' experiences should be reflected in the national curriculum when it is revised.

A Study on Improvement of Damage Impact Range Assessment for Field-Based Response Against Chemical Terrorism and Accidents (현장 중심의 화학테러·사고 대응을 위한 피해 영향 범위 평가 개선 방안 연구)

  • Lee, Deok-Jae;Song, Chang Geun
    • Journal of Convergence for Information Technology
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    • v.10 no.8
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    • pp.127-136
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    • 2020
  • Chemical terrorism and accidents using chemicals are continuously occurring and attempted in and out of the country. In Korea, the National Institute of Chemical Safety affiliated with Ministry of Environment employs the CARIS(Ver. 2018) to assess the damage impact range for field-based response against chemical terrorism and accidents. However, the current version of CARIS can not consider the effects of closed space such as indoor and underground, so it is difficult to provide accurate evaluation results for damage impact range required for field response, on top of the limited information available. The limitations and directions for improvement were studied by comparing and reviewing the evaluation results of the damage impact range obtained by driving CARIS (Ver. 2018) and the domestic and foreign literature. Proposed improvements also included the direction of information provided to residents, including the need to build modeling for special points, such as underground, indoor, etc., and on-site response personnel. It is expected that through the continuous supplementation and correction of CARIS, chemical terrorism and accident response capability system will be advanced further.

Ecological Health Assessment of Dongjin River Based on Chemical Measurement and Fish Assemblage Analysis. (동진강의 이.화학적 수질 및 서식지 분석을 통한 어류 생태영향 평가)

  • Kim, Yu-Pyo;Lee, Eui-Haeng;An, Kwang-Guk
    • Korean Journal of Ecology and Environment
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    • v.42 no.2
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    • pp.183-191
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    • 2009
  • This study was to evaluate ecological health of Dongjin River in October 2007. The ecological health assessments was based on the Index of Biological Integrity (IBI), Qualitative Habitat Evaluation Index (QHEI), and water chemistry. For the study, the models of IBI and QHEI were modified as 8 and 11 metric attributes, respectively. We also analyzed spatial patterns of chemical water quality over the period of 2005${\sim}$2008, using the water chemistry dataset, obtained from the Ministry of Environment, Korea. In Dongjin River, values of IBI averaged 19 (n=3), which is judged as a "Fair" condition after the criteria of Barbour et al. (1999). There was a distinct spatial variation. IBI score at Site 1 was estimated as 28, indicating a "Good" condition whereas, IBI at Site 2 and Site 3 were as 18 and 12, indicating "Fair" and "Poor" condition, respectively. Habitat analysis showed that QHEI values in the river averaged 117 (n=3), indicating a "Fair${\sim}$Good" condition after the criteria of Barbour et al. (1999). Values of BOD and COD averaged 2.3 mg $L^{-1}$ (scope: 0.1${\sim}$8.9 mg $L^{-1}$) and 5.5 mg $L^{-1}$ (scope: 1.8${\sim}$12.6 mg $L^{-1}$), respectively during the study. Total nitrogen (TN) and total phosphorus (TP) averaged 2.7mg $L^{-1}$ and 0.127mg $L^{-1}$, respectively, and the nutrients showed large longitudinal gradients between the upper and lower reach. Overall, dataset of IBI, QHEI, and water chemistry showed that river health was a gradual decline at upstream to downstream. So, Dongjin River should be protected from habitat disturbance and chemical pollutions.

학술자료: 구제역의 원인, 숙주역, 전파 및 바이러스 인공감염 및 화학물질(T-1105)투여시험 결과 내역에 대하여

  • Ryu, Il-Seon
    • Journal of the korean veterinary medical association
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    • v.47 no.2
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    • pp.165-176
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    • 2011
  • 구제역은 우제류 동물이 걸리는 급성열성전염병으로, 본 병에 걸린 동물은 발열이나 식욕부진을 지나 병명대로 구강과 혀 점막, 발굽 주위나 유방의 피부에 수포를 형성한다. 이후 이환된 가축은 섭취 장애나 보행장애가 일어나고, 산육능력이나 비유량이 저하됨에 따른 경제동물로서의 가치를 현저하게 떨어지게 한다. 또한 본 병의 전파는 극히 빠르고 동물이나 축산물에 대하여 엄격한 이동제한이나 방역조치가 본 병의 전파나 확대를 막기 위해 실시하기 때문에 본 병에 의해 생기는 경제적 피해는 농가의 지역단위 뿐만 아니라 국가단위에도 미쳐 심각하다. 그 때문에 자유무역을 표방하는 WTO체재하에 있어서도 구제역의 만연방지를 목적으로 한 무역제한은 국제적으로 용인되어져 오고 있고, 세계동물보건기구에 의해 국가나 지역단위의 청정도 구분이 장해져 각국의 법에 반영되어져 있다. 구제역의 병원체로 있는 바이러스는 숙주역이 넓고, 적지 않은 바이러스양에도 감염이 성립, 감염동물체내에서 바이러스가 신속하게 복제, 감염동물로부터 다량의 바이러스가 배설, 접촉전파만이 아닌 공기전파를 일으킨다는 등이 본 병의 전파나 확대에 유리한 복잡한 성성을 가질 경우에 구제역의 방역 및 박멸을 어렵게 하기 때문에 수의학영역에서 가장 경계해야할 전염병의 하나이다. 따라서 본 필자는 최근의 국내 구제역 발생상황속에서 관련자료정리를 하다가 대동물 임상수의사가 알아야 부분과 일본 동물위생연구소 등에서 구제역바이러스 인공감염 및 화학물질(T-1105)투여시험 결과 내역를 정리하여 소개해두고 저 한다.

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Discussion on the application of odor sensor for the estimation of odor unit concentration (악취농도단위 산정을 위한 복합취기센서의 활용 고찰)

  • 김학민;김선태;김덕현;전의찬
    • Proceedings of the Korea Air Pollution Research Association Conference
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    • 2002.04a
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    • pp.209-210
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    • 2002
  • 감각적인 불쾌감을 야기하는 악취물질의 종류는 다양하며, 매우 낮은 농도에서도 감각기관을 자극할 뿐 아니라 물질간 반응이 복잡한 특징을 갖고있어 화학성분분석법과 함께 감각적인 자극수준을 평가하는 관능측정법을 병행하여 악취현상을 종합적으로 평가하게 된다 특히 매립지 등의 환경기초시설이 운영됨에 따라 나타나는 악취현상을 객관적으로 평가하기 위해서는 대기확산모델의 운영이 필요하며, 이를 위한 악취배출량 자료의 구축이 필요하게 된다. (중략)

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Physio-chemical and Mineralogical Characterization of the Tailings in the Guryoung Mining Area (구룡광산 광미층의 심도변화에 따른 물리.화학적 및 광물학적 특성)

  • Moon, Yong-Hee;Kim, Jeong-Yeon;Song, Yun-Goo;Moon, Hi-Soo
    • Economic and Environmental Geology
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    • v.41 no.2
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    • pp.183-199
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    • 2008
  • This study is focused on characterization of the physio-chemical and mineralogical properties, investigation of their vertical changes in the tailing profile of the Guryoung mining area, classification of the profile into distinct zones, and condition conceptual model of physio-chemical conditions and phases-water relationships controlling the element behaviors in the tailings. The upper part of the groundwater is characterized by the high contents of $Fe_2O_3$ and $SO_3$ for whole rock analysis, low pH, and the occurrence of jarosite, schwertmannite and Fe-oxyhydroxide as the secondary mineral phases. The tailing profile can be divided into the covering soil, jarosite zone, Fe-sulfate zone, Fe-oxyhydroxide and gypsum-bearing pyrite zone, calcite-bearing pyrite zone, soil zone, and weathered zone on the based of the geochemical and mineralogical characteristics. The profile can be sampled into the oxidized zone and the carbonate-rich primary zone with the dramatic changes in pH and the secondary mineral phases. The conceptual model proposed for the tailing profile can be summarized that the oxidation of pyrite is the most important reaction controlling the changes in pH, the dissolution of the primary silicates and carbonates, the precipitation of secondary mineral phases, acid-neutralizing, and heavy metal behaviors through the profile.

Dental Hygienist's Harmful Factor Exposure and Recognition of Material Safety Data Sheets of Workplace Type (치과위생사의 근무기관 유형별 유해인자 노출과 물질안전보건자료 인식 연구)

  • Kim, Hae-Kyeong;Kim, Ji-Young;Oh, Na-Rae
    • The Journal of the Korea Contents Association
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    • v.18 no.11
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    • pp.540-549
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    • 2018
  • This study was conducted on 238 dental hygienists working in Daegu and Gyeongbuk area. In order to understand the status of harmful transmission of dental materials by type of work, we compared the differences in exposure time and work environment characteristics of hospital types and investigated the difference in the degree of recognition of material safety data. The results of the study were as follows: In case of hospitals, the exposure time of dust generated from chemicals was the longest. Resin filling, contact with disinfectant. 37 workers (29.4%) and 14 workers (12.5%) answered that they perceive the question about whether they are aware of the material safety data sheet (MSDS) for dental materials. There were 18 hospital workers and 6 clinic workers who had experience reading MSDS before using dental materials. The respondents who answered that they provided the material safety data of the dental materials used had a 2.39 times MSDS in hospital workers. Therefore, by recognizing the health hazards of chemical substances in accordance with the characteristics of each type of hospital and continuing to conduct health and safety education, the work environment should be improved by establishing proper recognition of MSDS information. It suggests the necessity of a system that can strengthen the management of chemical information provision and guarantee the strategic approach and workers' right to know.

Status and Implications of Hydrogeochemical Characterization of Deep Groundwater for Deep Geological Disposal of High-Level Radioactive Wastes in Developed Countries (고준위 방사성 폐기물 지질처분을 위한 해외 선진국의 심부 지하수 환경 연구동향 분석 및 시사점 도출)

  • Jaehoon Choi;Soonyoung Yu;SunJu Park;Junghoon Park;Seong-Taek Yun
    • Economic and Environmental Geology
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    • v.55 no.6
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    • pp.737-760
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    • 2022
  • For the geological disposal of high-level radioactive wastes (HLW), an understanding of deep subsurface environment is essential through geological, hydrogeological, geochemical, and geotechnical investigations. Although South Korea plans the geological disposal of HLW, only a few studies have been conducted for characterizing the geochemistry of deep subsurface environment. To guide the hydrogeochemical research for selecting suitable repository sites, this study overviewed the status and trends in hydrogeochemical characterization of deep groundwater for the deep geological disposal of HLW in developed countries. As a result of examining the selection process of geological disposal sites in 8 countries including USA, Canada, Finland, Sweden, France, Japan, Germany, and Switzerland, the following geochemical parameters were needed for the geochemical characterization of deep subsurface environment: major and minor elements and isotopes (e.g., 34S and 18O of SO42-, 13C and 14C of DIC, 2H and 18O of water) of both groundwater and pore water (in aquitard), fracture-filling minerals, organic materials, colloids, and oxidation-reduction indicators (e.g., Eh, Fe2+/Fe3+, H2S/SO42-, NH4+/NO3-). A suitable repository was selected based on the integrated interpretation of these geochemical data from deep subsurface. In South Korea, hydrochemical types and evolutionary patterns of deep groundwater were identified using artificial neural networks (e.g., Self-Organizing Map), and the impact of shallow groundwater mixing was evaluated based on multivariate statistics (e.g., M3 modeling). The relationship between fracture-filling minerals and groundwater chemistry also has been investigated through a reaction-path modeling. However, these previous studies in South Korea had been conducted without some important geochemical data including isotopes, oxidationreduction indicators and DOC, mainly due to the lack of available data. Therefore, a detailed geochemical investigation is required over the country to collect these hydrochemical data to select a geological disposal site based on scientific evidence.