• Title/Summary/Keyword: 주촉매

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Isolation of Acinetobacter calcoaceticus BP-2 Capable of Degradation of Bisphenol A (Bisphenol A 분해균주 Acinetobacter calcoaceticus BP-2의 분리 및 bisphenol A 분해 특성)

  • Kwon, Gi-Seok;Kim, Dong-Geol;Lee, Jung-Bok;Shin, Kee-Sun;Kum, Eun-Joo;Sohn, Ho-Yong
    • Journal of Life Science
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    • v.16 no.7 s.80
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    • pp.1158-1163
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    • 2006
  • Bisphenol A (BPA), 2,2-bis(4-hydroxyphenyl) propane, has been widely used as a monomer for production of epoxy resins and polycarbonate plastics, and final products of BPA include adhesives, protective coatings, paints, optical lens, building materials, compact disks and other electrical parts. Since BPA is a toxic chemical to elicit acute cell cytotoxicity and chronic endocrine disrupting activity, the degradation of BPA has been focused during last decades. To overcome the problem of photo-, and chemical-degradation of BPA, in this study, a bacterium that is able to biodegrade BPA, was isolated. The bacterium, isolated froln the soil of plastic factory, was identified as Acinetobacter calcoaceticus (strain BP-2) based on physiological and 16S rDNA sequencing analysis. A. calcoaceticus BP-2 was able to grow in the presence of $1140{\mu}g\;ml^{-1}$ BPA. Biodegradation experiments showed that BP-2 mineralized BPA via 4-hydroxybenzoic acid and 4-hydroxyacetophenone, and average degradation rate was $53.3{\mu}g\;ml^{-1}\;day^{-1}$ under optimal conditions (pH 7 and $30^{\circ}C$). In high density resting cell $(3.5g-dcw.1^{-1})$ experiments, the maximal degradation rate was increased to $89.7{\mu}g\;ml^{-1}\;h^{-1}$. Our results suggest that BP-2 has high potential as a catalyst for practical BPA bioremediation.

Detection of Carbonic Anhydrase in the Gills of Rainbow Trout (Oncorhynchus mykiss) (무지개 송어 rainbow trout, Oncorhynchus mykiss의 아가미에서의 carbonic anhydrase의 존재)

  • Kim, Soo Cheol;Choi, Kap Seong;Kim, Jung Woo;Choi, Myeong Rak;Han, Kyeong Ho;Lee, Won Kyo;Kho, Kang Hee
    • Journal of Life Science
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    • v.23 no.12
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    • pp.1557-1561
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    • 2013
  • Carbonic anhydrase isozymes are a widespread, zinc-containing metalloenzyme family. The enzyme catalyzes the reversible inter-conversion of $CO_2$ and $HCO_3$. This reaction is the main role played by CA enzymes in physiological conditions. This enzyme has been found in virtually all organisms, and at least 16 isozymes have been isolated in mammals. Unlike mammals, there is little information available regarding CA isozymes in the tissues of non-mammalian groups, such as fish. Carbonic anhydrase is very important in the osmotic and acid-base regulation in fish. It is well-known that the gills of fish play the most important role in acid-base relevant ion transfer, the transfer of $H^+$ and/or $HCO_3^-$, for the maintenance of systemic pH. Rainbow trout, Oncorhynchus mykiss, is the most important freshwater fish species in the aquaculture industry of Korea, with annual production increasing each year. In addition, environmental toxicology research has shown that rainbow trout is known to be the species that is most susceptible to environmental toxins. Consequently, carbonic anhydrase was detected in rainbow trout, Oncorhynchus mykiss. The isolated protein showed the specific band with a molecular weight of 30 kDa and pI of 7.0, and it was identified as being carbonic anhydrase. The immunohistochemical result demonstrated that the carbonic anhydrase was located in the epithelial cells of the gills.

A Study on virtual character from the viewpoint of E-branding (E-branding관점에서 본 감정이입 가상 캐릭터의 연구)

  • 이지희
    • Archives of design research
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    • v.17 no.3
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    • pp.81-90
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    • 2004
  • The reason of the appearance of Internet is regarded as a milestone since we have shared information globally in a mutual way. The important thing on this point is what contents we choose for ourselves. The Internet could be meaningless unless we use it in a certain way, which ultimately means that the Internet has to deliver something valuable to us humans. Therefore, we have looked at how we can deliver and share humanity and emotion through the Internet, also how we can instill vital power into our real life, through the Internet. Fortunately, the current study must essentially be ongoing due to its nature with perhaps a multidisciplinary team brainstorming ideas. The reason for that is that not only could we find new business models for companies, but also find out new ways to appease the human mind in the modern age. In addition, as consumers needs become more specialized and diversified, companies are expected to face up to fierce competition with the help of innovative ideas. The ever-intensifying competition requires companies to cultivate new strategic tools in order to have new, powerful and sustainable comparative advantages. The goal of this research will be to explore ways of finding a new approach. Specifically, this research is about how to use the EVC(empathetic virtual character), which, this researcher believes, can deliver emotional benefits so as to make e-branding successful. According to reports, it has been proven that this new concept including the EVC can result in tremendous success. So the goal of this research is to explore the current situation and to anticipate the future concerning virtual characters.

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Preparation of PMSQ/TiO2 Composite Fine Powder by Sol-Gel Process (Sol-Gel Process를 이용한 PMSQ/TiO2 복합 미립자의 합성)

  • Lee, Dong Hyun;Koo, Sangman
    • Applied Chemistry for Engineering
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    • v.9 no.5
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    • pp.634-638
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    • 1998
  • Monodisperse, spherical $PMSQ/TiO_2$ composite fine powders were prepared by modified sol-gel process where 300 nm $TiO_2$ fine powders were used as seed particles for hetero-condensation with hydrolyzed MTMS (Methyltrimethoxysilane). The reaction was carried out under $N_2$ atmosphere at ambient temperature using $NH_3$ as a catalyst. Methanol was used as a solvent. Powder was obtained by the filtration of the solution with a glass filter and washing with acetone. The stirring rate, reaction temperature, $[H_2O]/[MTMS]$ and $[MTMS]/[TiO_2]$ ratio were varied to investigate shapes and sizes of particles. Monodisperse particles of $1-2{\mu}m$ diameter were obtained with [MTMS]=0.2 M, $[NH_3]=0.6M$, $[H_2O]/[MTMS]=100$, $[MTMS]/[TiO_2]=10-50$ at ambient temperature with mild stirring condition. These composite particles had a contact angle of almost 180 degree contact angle with water, which proves their excellent hydrophobicity. The study of UV absorption spectra showed that they have UV protecting effect.

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Numerical Study on Performance of PEMFC with Block and Sub-channel of Cathode Flow Field (캐소드 유로에서 블록과 서브 채널의 고분자전해질 연료전지의 성능에 관한 전산해석 연구)

  • Jo, Seonghun;Kim, Junbom
    • Applied Chemistry for Engineering
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    • v.32 no.6
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    • pp.613-620
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    • 2021
  • A flow channel shape of PEMFC has an influence on the internal flow uniformity. If the reactant distribution in a flow path is not uniform during operation, both catalyst deactivation and mechanical damage of membrane could occur resulting in decreasing the membrane electrode assembly (MEA) durability. Numerous studies concerning flow design have been conducted to make smooth supply and uniform distribution of reactants in fuel cells. The baffle of flow path could improve fuel cell performance through the forced convection effect. A sub-channel, as an additional air flow path, could increase the reactant concentration and reduce the mass transfer loss via a smooth water discharge. In this study, computational fluid dynamics (CFD) was used to analyze the effect of blocks and sub-channels on the current density and oxygen concentration of the fuel cell. As a result, the limit current density and oxygen concentration at a rear block increased when using blocks and sub-channels in a flow channel. In particular, the current density increased significantly when the sub-channel was placed between two blocks. Also, the sub-channel position was optimized by analyzing the oxygen concentration, and the oxygen concentration was recovered at a rear block in the fuel cell.

A Study on the Uniform Mixing of Ammonia-Air with the Change of Ammonia Supply Device Shape in a De-NOx System (탈질설비에서 암모니아 혼합기의 형상에 따른 암모니아-공기 균일 혼합에 관한 연구)

  • Ha, Ji Soo
    • Journal of the Korean Institute of Gas
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    • v.23 no.3
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    • pp.20-26
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    • 2019
  • Selective catalytic reduction(SCR) method is widely used among various methods for reducing nitrogen oxides in combustion devices of coal power plant. In the present study, the computational fluid dynamic analysis was accomplished to derive the optimal shape of ammonia-dilution air mixing device in a ammonia injection grid. The distribution characteristics of flow and $NH_3$ concentration had been elucidated for the reference shape of ammonia mixing device(Case 1). In the mixing device of Case 1, it could be seen that $NH_3$ distribution was shifted to the wall opposite to the inlet of the ammonia injection pipe. For the improvement of $NH_3$ distribution, the case(Case 2) with closing one upper injection hole and 4 side injection holes, the case(Case 3) with installing horizontal plate at the upper of ammonia injection pipe, the case(Case 4) with installing horizontal plate and horizontal arc plate at he upper of ammonia injection pipe were investigated by analyzing flow and $NH_3$ concentration distributions. From the present study, it was found that the % RMS of $NH_3$ for Case 4 was 4.92%, which was the smallest value among four cases, and the range of $R_{NH3}$ also has the optimally uniform distribution, -10.82~8.34%.

Optimal Design of a Coil for Improved Heating Efficiency of Electric Induction Boiler (전기유도보일러의 발열효율개선을 위한 권선최적설계)

  • Kim, Youn-Hyun;Kim, Sol
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.3
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    • pp.476-482
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    • 2019
  • Regulatory protocols such as the Convention on Climate Change and the regulation of greenhouse gas emissions act as catalysts for the development of high-efficiency energy equipment and the efficient use of energy. Among the fields where energy consumption is high, the electric heating equipment is not efficient. The electric boiler mainly uses a method of circulating water by contacting the heater. When the existing electric boiler is used, the water minerals are contacted with the high-temperature heater to be carbonized and adsorbed, thereby promoting the corrosion of the heater and lowering the efficiency of the heater. For this reason, an electric induction boiler, which has high energy efficiency and is applied to an induction heating system that can uniformly heat the object to be heated rather than conduction or convection heating, is in the limelight. This method induces a boiler pipe And it is recognized as an alternative that can solve the problem that occurs when heating is performed by direct heating. Despite the fact that research on induction heating has been conducted for a relatively long period of time, there have been few studies on the electrothermal technology using induction heating. Therefore, in this paper, to improve the heat efficiency of electric induction boiler, the influence of the cross sectional area, number of windings and winding layers is analyzed by finite element method through parametric study method. The method of finding the design point which maximizes the total loss is proposed by the alternating winding design method which can maximize the heat generation by analyzing copper and iron losses.

Feasibility Study on Technology Status Level and Location Conditions of Urban Mining Industry in Abandoned Mine Area (도시광산 산업의 현황수준 및 폐광지역 입지여건 타당성 연구)

  • Ko, Ilwon;Park, Joo-Hyun;Park, Jae-Hyun;Yang, In-Jae;Lee, Seung-Ae;Kim, Dae-Yeop;Kim, Su-Ro
    • Journal of the Korean Society of Mineral and Energy Resources Engineers
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    • v.55 no.6
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    • pp.553-563
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    • 2018
  • In this study, the location conditions and optimal technologies required for creating urban municipalities that can utilize the space in an abandoned mine area, where there is no infrastructure related to recycling wastes and valuable metals, are investigated. The urban mining industry deals with mineral resources through the processing of high value-added industrial by-products and wastes, and it is a useful linkage industry for the development of mineral resources and prevention of mining hazards. Urban mining technologies targeted at the abandoned mine area constitute screening, extraction, and smelting for recycling waste products. By analyzing the technologies available, an industrial network can be developed for recycling waste batteries and catalysts, which are promising raw materials. It is also important to establish an appropriate location for related industries that can generate value-added resources, rather than the resource supply and demand conditions seen in general urban mines. In order to overcome the accessibility and infrastructure limitations, the economic foundation of the abandoned mine area should consider the linkage of raw material supply, key technologies for recycling useful mineral resources that are derived from urban mines, spatial and site conditions, and industrial characteristics.

Effects of Draw Ratio and Additive CaCO3 Content on Properties of High-Performance PE Monofilament (연신비와 첨가제 CaCO3가 PE 모노필라멘트의 물성에 미치는 영향)

  • Park, Eun-Jeong;Kim, Il-Jin;Lee, Dong-Jin;Kim, Jung-Soo;Lee, Young-Hee
    • Fashion & Textile Research Journal
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    • v.23 no.2
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    • pp.290-296
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    • 2021
  • The effect of draw ratio (8, 10, 12, 14 times) and additive CaCO3 content (0, 0.5, 1.0, 1.5, 2.0, and 3.0 wt%) on the properties of high-performance PE monofilament was investigated in this study. As the draw ratio increased (8-14 times), the melting enthalpy (ΔHf), crystallinity, specific gravity, and tensile strength increased significantly. However, the draw ratio had little effect on the melting temperature (Tm) and crystallization temperature (Tc). The seawater fastness (stain and fade) of the hydrophobic PE monofilament prepared in this study showed an excellent grade of 4-5 in all draw ratios. To investigate the effect of the additive CaCO3 content on the properties of high-performance PE monofilament, the draw ratio was fixed at 14 times. It was found that the tensile strength of the PE monofilament sample containing 0.5 wt% of CaCO3 was much greater compared to the sample without CaCO3, but the elongation of the sample containing 0.5 wt% of CaCO3 was much less than the sample with 0 wt% CaCO3. However, in the case of the sample containing more than 0.5 wt% CaCO3, the tensile strength slightly decreased and the elongation slightly increased as the CaCO3 content increased. The seawater fastness (stain and fade) of the hydrophobic PE monofilament showed excellent grades of 4-5, regardless of the amount of additives. From the above results, it was found that the maximum draw ratio of 14 times with an additive of 0.5 wt% CaCO3 are the optimal conditions for manufacturing high-performance marine fusion materials with various fineness (denier) with high strength and low elongation.

Effect of Size and Morphology of Silica Abrasives on Oxide Removal Rate for Chemical Mechanical Polishing (기계화학적 연마용 실리카 연마재의 형상과 크기가 산화막 연마율에 미치는 영향)

  • Lee, Jinho;Lim, Hyung Mi;Huh, Su-Hyun;Jeong, Jeong-Hwan;Kim, Dae Sung;Lee, Seung-Ho
    • Applied Chemistry for Engineering
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    • v.22 no.6
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    • pp.631-635
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    • 2011
  • Spherical and non-spherical silica particles prepared by the direct oxidation were studied for the effect of the particle size and shape of these particles on oxide CMP removal rate. Spherical silica particles, which have 10~100 nm in size, were prepared by the direct oxidation process from silicon in the presence of alkali catalyst. The 10 nm silica particles were aggregated by addition of an acid, an alcohol, or a silane as an aggregation inducer between the particles. Two or more aggregated silica particles were used as a seed to grow non spherical silica particles in the direct oxidation process of silicon in the presence of alkali catalyst. The oxide removal rate of spherical silica particles increased with increasing an average particle size for spherical silica abrasives in the oxide CMP. It further increased non-spherical particles, compared with the spherical particles in the similar average particle size.