• Title/Summary/Keyword: 종이 열화

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종이의 유전 특성 향상을 위한 표면 사이즈제의 열적 안정성 및 유동현상 평가

  • 이학래;서만석
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.11a
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    • pp.53-53
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    • 2001
  • 종이의 전기적 성질 가운데 유전율은 전기장에 대한 종이의 물리화학적인 반응으로 일반적으로 종이의 밀도와 종이를 구성하는 성분의 쌍극자 모멘트에 비례하며 온도에 따라서도 변화한다. 일반적으로 온도가 상승하면 열에너지를 얻게된 쌍극자가 전기장에 배열됨으로써 유전율이 상승하지만 온도가 유리전이점 이상으로 높아질 경우에는 열적 교란에 의해서 분극능력이 감소하게 되어 유전완화 현상이 나타난다. 전기절연지로 사 용될 종이의 절연특성을 이해하기 위해서는 사용환경에 따른 유전적 특성 및 tan 0에 관한 연구가 필요하며 필름형성능력이 우수한 polyvinyl a1cohoHPV A)와 acrylonitrile을 이용하여 시아노에틸화한 PYA의 표면처리에 의해 종이의 유전적 특성이 향상되었음을 기존의 연구를 통하여 확인할 수 있었다. 본 연구에서는 전기절연지가 사용되는 환경조건에서 PYA를 기본물질로하는 유전필름 의 열적 안정성을 평가하였으며, 아울러 표면사이징 공정에서의 적용성 검토를 위하여 용액의 유동특성을 분석하였다. 유전특성 향상을 위해서는 표면 사이즈제의 유도체화 과정에서 쌍극자 모벤트의 밀도 증가를 통한 유전율 향상이 요청되며 이와 동시에 네트원 구조를 통하여 전기장에 대 한 물리적 특성이 유지되어야 한다. 본 연구에서는 W AXD( wide angle x-ray diffraction)를 이용하여 시아노에틸화 반응 과 고온에서의 열화에 의한 필름의 결정화도를 평가하였으며 온도 상승에 따른 흡열 피크의 변화를 통하여 온도 변화에 따른 PYA 분자구조의 변화와 유리전이온도의 추이 를 분석하였다. 또 열화과정에서 수반되는 필름의 중량감소율을 평가함으로써 열안정성 을 평가하였다. 그 결과 시아노에틸화한 PYA가 안정된 분자구조를 유지하고 있음을 확인할 수 있었다. 시아노에틸화한 PYA용액의 점탄성 평가를 위하여 storage modulus와 loss modulus 를 분석하였다. 일반적 유변특성 평가 결과 PYA용액은 shear-thinning, pseudoplastic 한 특성을 나타내어 표면사이즈 공정에서의 적용 가능성을 확인할 수 있었다.

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Effect of Additives on Paper Aging (종이 첨가제가 종이의 노화에 미치는 영향)

  • 윤병호;이명구;최경화
    • Journal of Korea Foresty Energy
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    • v.21 no.2
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    • pp.25-33
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    • 2002
  • One of the critical problems to preserve books and documents in libraries and archives is the deterioration. Some of previous results showed that the major cause of paper deterioration was the acid-catalyzed hydrolysis of the cellulose in paper fibres and aging rate of acidic paper was faster than that of alkaline paper. Therefore, It is necessary to remove the acid in the paper for reducing the rate of paper deterioration. It has been reported to extend the useful life of acidic paper by three to five times. Recently, It has been recognized the need for an effective method of deacidifying large quantities of books and document. However, in the previous many reports little attention was paid to the effect of paper additives. In this paper, We carried out experiment about the effect of additives on paper aging and the effect of deacidification by the gaseous ethanolamines (monoehtanolamine, diethanolamine, triehtanolamine). In result, it was found that the strength of aging was in the order of the alum+rosin>alum >AKD> control and the rate of deacidification was in the order of the monoethanolamine>diethanolamine>triethanolamine. The treatment with the gaseous ethanolamines caused decreasing of brightness and dropping of fold endurances. However, deacidification by combination treatment of the various gaseous ehtnaolamines prevented from decreasing of brightness and dropping of folding endurances.

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Improvement method for viscosity measurement of high viscosity paper and fabric cultural heritages (고점도 지류 및 섬유 문화재의 점도 측정 개선 방법 연구)

  • Kim, Young-Hee;Hong, Jin-Young;Jo, Chang-Wook;Kim, Soo Ji;Lee, Jeung-Min;Seo, Min Seok;Choi, Kyoung Hwa
    • 보존과학연구
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    • s.34
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    • pp.20-29
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    • 2013
  • Paper, textile and wood materials are mainly consisted of cellulose. Cellulose is high molecule and make up the strong crystalline structure by hydrogen bonds. In particular, the polymerization degree of cellulose are closely related to the strength of fiber, and the permanence. the useful life of fiber, also depends on the degradation of this substance. The viscosity of cellulose is considered to be an important indicator of fiber damage in high molecule polymers. The viscosity measurements with CED solution is used to measure the molecular weight and the degree of polymerization of cellulose. Cellulose viscosity of wood fibers is measured with TAPPI standard method T230. However, TAPPI standard method T230 is difficult to completely dissolving the cellulose of high molecular weight and large degree of polymerization, such as Korea traditional papers and fabrics made with mulberry, ramie, cotton fibers. In this study, The high viscosity of hanji and fabric was measured with TAPPI standard method T254. T254 method is that the cellulose specimen with the proper amount of weaker (0.167M CED) solution, and completely dissolved with the stronger (1.0M CED) solution. It was found that cellulose with high degree of polymerization was dissolved more easily in general CED method.

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Aging Behavior of Beeswaxed Hanji(II) - Acidic and Alkaline Aging of Beeswaxed Hanji - (밀랍지의 열화 거동 (제2보) - 산 및 알칼리에 의한 밀랍지의 열화 -)

  • Kim, Kang-Jae;Lee, Min-Hyung;Eom, Tae-Jin
    • Journal of Korea Technical Association of The Pulp and Paper Industry
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    • v.43 no.3
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    • pp.66-72
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    • 2011
  • The annals of Joseon Dynasty is one of UNESCO's Memory of the World Register. For the safety preservation of the waxed annals of Joseon Dynasty, the acidic and alkaline aging mechanism of beeswax and beeswaxed Hanji has been investigated. The weight loss of beeswaxed Hanji by the acidic aging was higher than those of alkaline beeswax. The acid value and relative intensity of carbonyl groups in beeswax were slowly increased with aging time. The strength of dewaxed Hanji was decreased with aging time. The significant changes of crystallinity of dewaxed Hanji by acidic and alkaline aging were not observed.

Study on Poisonous Gas Emission Characteristic of Taxidermied Specimen for Conservation Environment (박제 표본의 보존환경에 따른 유해가스 방출 특성 연구)

  • Lee, Hee Jung;Kang, Dai Ill
    • Journal of Conservation Science
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    • v.29 no.4
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    • pp.389-394
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    • 2013
  • Taxidermied specimen is the art of preparing, stuffing, and mounting the skins of animals (all vertebrate species of animals including mammals, birds, reptiles, and fishes) for display or for other sources of study. But, as these studies are weighted toward ecologic study, related studies on management and conservation environment are short. Also, the analysis of poisonous gas has not yet been studied. Therefore, this study will be suggested proper preservation methods through the analysis of deterioration on taxidermied specimen by poisonous gas. As a result, 4 types of major chemicals were detected in UV deterioration test, 7 types in RH and formaldehyde deterioration test. As a result of SPME, Naphthalene to be used as antiseptic were detected in all of the test conditions. Acetic acid that is VOCs were detected for factor. Moreover as the higher humidity it was, the concentration of chemicals were decreased.

Growth Monitoring of Potato Transplants Using Thermography (열화상을 이용한 감자묘의 생장 감시)

  • 이상헌;김용현;김진국;최유화;이명규
    • Proceedings of the Korean Society for Bio-Environment Control Conference
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    • 2002.11a
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    • pp.320-325
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    • 2002
  • 우리나라의 씨감자 생산체계는 기본종, 기본식물, 원원종, 원종, 보급종 등 5단계의 증식체계를 거쳐 씨감자를 생산농가에 보급하고 있으나 보급률은 25% 정도 밖에 안되는 실정이다. 또한 씨감자 증식과정에서 토양중 괴경이나 지상부 경엽이 병해충에 쉽게 노출되기 때문에 병해충의 감염을 완전히 차단하는 것은 불가능하다. 따라서 현재의 증식단계를 줄여야 씨감자의 품질이 향상될 것이므로 이것을 실현하기 위해서는 상위단계 씨감자의 생산력을 획기적으로 증대시킬수 있는 기술이 전제되어야 한다(구, 2002). (중략)

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