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Studies on the Kinetics for the Formation Reaction $Ti_3AI$ by SHS (Self-propagating High-temperatuer Synthesis) Method (자체반응열 고온합성법에 의한 $Ti_3AI$ 생상반응의 동력학적 연구)

  • 전광식
    • Journal of the Korean Ceramic Society
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    • v.35 no.6
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    • pp.569-574
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    • 1998
  • The thickness of flame zone reaction rate and apparent activation energy in the formation reaction of $Ti_3AI$ intermetallic compound were investigated using SHS method which sustains the reaction spontaneously and utilizes the heat generated by thye exothermic reaction itself. In this reaction the thickness of flame zone was 1.4 mm and the reaction rate was $0.4g/\textrm{cm}^2{\cdot}sec$. Also the apparent activation energy calculated using from the experimental data obtained by controlling the realtive green density was 40kJ/mol.

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Shock Waveform Synthesis for Shock Response Spectrum Test by Using Wavelets (충격반응 스펙트럼 시험에서 웨이브레트를 이용한 충격파형 합성)

  • 윤을재
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 1998.04a
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    • pp.25-25
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    • 1998
  • 진동시험기를 사용한 충격시험은 자유 낙하식 충격시험기를 이용하는 것 보다 여러 가지 장점이 있으며, 충격반응 스펙트럼 시험의 요구가 점점 증가하고 있다. 진동시험기를 이용하여 충격반응 스펙트럼 시험을 실시하는데 진동시험기에서 허용하는 최대 힘, 속도, 변위에 의하여 제약을 받게 된다. 충격반응 스펙트럼을 만족하는 충격파형은 무수히 많으나 최대 가속도, 속도, 변위 등이 작으면 작을수록 그 충격파형의 품질이 우수하다고 말할 수 있다. 충격 지속시간이 짧고 충격가속도의 최대치가 큰 충격파형을 인가할 수 없지만, 충격 지속시간이 보다 길고 충격가속도의 최대치가 작은 파형이 동일한 충격반응 스펙트럼 규격을 만족할 수 있다. 진동시험기를 사용하여 충격반응 스펙트럼 시험을 수행하기 위한 충격파형이 웨이브레트를 이용하여 시험규격의 충격반응 스펙트럼을 만족하도록 합성된다. 웨이브레트의 매개변수는 주파수, 반파의 개수, 지연시간, 극성이다. 각 웨이브레트의 진폭은 시험규격의 충격반응 스펙트럼을 만족하도록·반복적으로 조절된다. 이렇게 합성된 충격파형은 진동시험기를 사용한 충격반응 스펙트럼 시험의 참조 가속도 파형으로 간주된다.

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Controlled Reproductive Cycle of Rockfish (Sebastes inermis) by Water Temperature and Photoperiod (수온과 광주기에 의한 볼락(Sebastes inermis)의 번식주기 조절)

  • KO Chang Soon;CHANG Young Jin;LIM Han Kyu;KIM Jong-Hyun;CHO Kee Chae
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.31 no.5
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    • pp.713-720
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    • 1998
  • Experiments on the control of rockfish, Sebastes inermis reproduction were performed by artificially changed water temperature (WT) and photoperiod (PP). The experiments were divided into three conditions; artificial changes of both WT and PP delayed two months against their natural variations (Exp.I), natural WT and PP replaced with artificial light (Exp.II) and natural WT and PP (Exp.III) from September to April (220 days). Initial gonadosomatic index (GSI) in female groups of experiments was 0.2. Female GSI of responded group in Exp.I began to increase from December and reached the highest value in February with 15.0, while the un-responded group kept the lower value during the experimental period. Female GSI of Exp.II and Exp.III reached the highest values in January with 13.0 and 14.7, respectively. Male GSI of Exp,I reached the maximum in October, and that of Exp.II and III reached the maximum in November and then rapidly decreased. Among the experimental groups, male GSI did not show the different tendency. Monthly changes of hepatosomatic index in both sexes showed the reciprocal tendency with those of GSI. The control of WT and PP did not affect on the changes of HSI and condition factor of rockfish. From the histological observations, maturation of ovary was delayed by the changes of WT and PP, but that of testis was not influenced. Judging from the above results, the maturation and parturition of female rockfish could be delayed one or two months by artificial changes of WT and PP.

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Regulation of Phorbol 12-Myristate 13-Acetate in the Gravitropic Response and Ethylene Production in Primary Roots of Maize (옥수수 뿌리에서 굴중성 반응과 에틸렌 생성에 미치는 Phorbol 12-myristate 13-acetate 조절 작용)

  • Jeong, Yun-Ho;Kim, Jong-Sik;Lee, Kon-Joo;Kim, Soon-Young
    • Journal of Life Science
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    • v.22 no.1
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    • pp.87-91
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    • 2012
  • Phorbol 12-myristate 13-acetate (PMA), a known tumor-promoting phorbol ester, activates the signal transduction enzyme protein kinase C (PKC) in animal cells. We investigated the effect of PMA on the regulation of gravitropism via ethylene production in primary roots of maize. PMA stimulated root growth and the gravitropic response in a concentration-dependent manner at $10^{-6}$ M and $10^{-4}$ M over 8 hrs. These effects were prevented by treatment with staurosporine (STA), a potent inhibitor of PKC. These results support the possibility that the gravitropic response might be regulated through protein kinases that are involved in the signal transduction system. Ethylene is known to play a role in the regulation of root growth and gravitropism. Ethylene production was increased by about 26% and 37% of the control rate in response to $10^{-6}$ M and $10^{-4}$ M PMA, respectively. PMA also stimulated the activity of ACC synthase (ACS), which converts the S-adenosyl-L-methionine (AdoMet) to 1-aminocyclopropane-1-carboxylic acid (ACC) in the ethylene production pathway. These effects on ethylene production were also prevented by STA treatment. These results suggest that the root gravitropic response in maize is regulated through protein kinases via ethylene production.

EVALUATION OF PEDIATRIC DENIAL PATIENTS' BEHAVIOR AFTER USING AUDIO-VISUAL AIDS (시청각 기구를 이용한 소아환자의 행동조절에 관한 연구)

  • Yeom, Soon-Joon;Park, Ki-Tae
    • Journal of the korean academy of Pediatric Dentistry
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    • v.29 no.2
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    • pp.189-195
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    • 2002
  • In the area of pediatric dentistry, several behavior modification techniques have been attempted to relieve young patients' dental fear. The use of audio-visual(AV) aids is one of them and is increasing. In this study, several patients' reactions to dental treatment have been investigated after using AV aids, including patients' sleep, movement, crying and overall behavior. The effectiveness of AV aids have also been investigated through patients' age, previous dental experience and daily exposure to TV or video. Thirty healthy children with Frankl behavior rating (+) or (-) were included in this study. The average age of the children was $52.9{\pm}12.7$ months and no statistical difference was found between the two groups. Thirty patients were equally divided into two groups. Group I(control) received dental treatment with the conventional tell-show-do while group II(AV) with tell-show-do and AV aids. All patients received only restorative dental treatment and received no extraction. Houpt behavior rating scale was used to evaluate patients' behavior during the dental treatment. As a result, there was no significant difference between the two groups in movement and crying. However, more patients in the AV group fell asleep during the dental treatment compared to the control group. Within the AV group, patients with previous dental experience, older age and frequent exposure to AV materials showed better overall behavior during the dental treatment as audio-visual aids were used for behavior management.

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Electro-Catalytic Hydrogenation and the Electrode Reaction Mechanism of the Carbon-6-Bromo groups of 6,6-Dibromopenicillanic acid 1,1-Dioxide (6,6-Dibromopenicillanic acid 1,1-Dioxide 분자내 탄소 6-위치 브롬기의 전극촉매 수소화반응과 전극반응기구)

  • Il Kwang Kim;Young Haeng Lee;Chai Ho Lee
    • Journal of the Korean Chemical Society
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    • v.35 no.2
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    • pp.165-171
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    • 1991
  • The electrochemical reduction of carbon-6-dibromo groups on 6,6-dibromo penicillanic acid 1,1-oxide(DBPA) was investigated by direct current, differential pulse polarography, cyclic voltammetry and controlled potential coulometry. The irreversible two electrons transfer on the reductive debromination of each bromo group proceeded by EC,EC mechanism at the two electrode reduction steps(-0.48, -1.62 volts). The 6-bromo-PA and 6,6-dihydro-PA was synthesized by controlled potential electrolysis. Upon the basis of results on the products analysis and interpretation of polarograms obtained at various pH, electrochemical reaction mechanism was suggested.

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Effects of Monovalent Cations on the βReaction Kinetics of Tryptophan Synthase (트립토판 합성효소의 β반응속도에 미치는 일가양이온의 영향)

  • Kim, Il;Shin, Hye-Ja;Im, Woon-Ki;Kim, Han-Do
    • Journal of Life Science
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    • v.14 no.1
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    • pp.17-20
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    • 2004
  • Effects of monovalent cations were examined on the fast $\beta$reaction of $\alpha$D56N and $\alpha$D56G mutant tryptophan synthase. Reaction rates for the production and degradation of intermediates in the reaction were changed in the presence of cathons. The mutant proteins showed different reaction rates from those of wild-type protein, and additional changes occurred in the presence of cations. The results showed that monovalent cations and $\alpha$D56 are important in allosteric properties of this protein.

Preparation of Needle-like $\alpha$-Iron Oxide Using a Crystal Growth Controller. (결정 성장 조절제를 이용한 침상형 $\alpha$산화철의 제조)

  • Byeon, Tae-Bong;Son, Jin-Geun
    • Korean Journal of Materials Research
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    • v.6 no.8
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    • pp.768-778
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    • 1996
  • Iron oxide (hematite, $\alpha$-${Fe}_{2}{O}_{3}$) particles were prepared directly from aqueous solution using a crystal growth controller. Paticles properties and reaction mechanisum of products as a function of basicity, formation process and mechanism of needle-lkie hematite were investigated. hexagonal hermatite particles were formed in teh range below pH 9.0, ellipsoidal or rectangular hematite particles in the range of pH 10.75-11.75 respectively. In the range above pH 12.50, acicular $\alpha$-FeOOH was formed. Basicity of product solution produced in the range of pH 10.7511.75 was increased slightly as compared with basicity of reastants due to hydroxly ion(OH-) formed by dissociation crystal growth controller. Citric acid which is acted as a crystal growth controller was adsorbed in the form of itrate anion(R-COO-) on the ferric hydroxide and exerted important role on the formation to the needle-like $\alpha$-${Fe}_{2}{O}_{3}$ particles in this reaction system.

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Reactions of Trimethylbenzenes over Mordenite Catalysts (모더나이트 촉매상에서 트리메틸벤젠의 반응)

  • Byoung Joon Ahn;Hak Ze Chon
    • Journal of the Korean Chemical Society
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    • v.25 no.3
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    • pp.166-171
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    • 1981
  • The reactions of trimethylbenzenes were investigated over dealuminated, cation-exchanged mordenite catalysts. Higher reaction temperature favored the formation of disproportionation products. In the reaction of 1,2,4-trimethylbenzene, the formation of 1,3,5-trimethylbenzene and the disproportionation products decreased sharply with reaction time. The product distribution, especially the distribution of trimethylbenzenes, suggests that the effective pore diameter of Ba-exchanged dealuminated mordenite catalysts lies somewhere between 8.1 and 8.6${\AA}$.

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