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First-principles Study on the Half-metallicity and Magnetism of the (001) Surfaces of (AlP)1/(CrP)1 Superlattice ((AlP)1/(CrP)1 초격자계에서 (001) 표면의 자성과 반쪽금속성에 대한 제일원리 연구)

  • Bialek, Beata;Lee, Jae Il
    • Journal of the Korean Magnetics Society
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    • v.25 no.6
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    • pp.175-179
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    • 2015
  • The half-metallicity and magnetism of the (001) surfaces of $(AlP)_1/(CrP)_1$ superlattice were investigated by means of FLAPW (Full-potential Liniarized Augmented Plane Wave) method. We considered four types of (001) surface termination, i.e., Al(S)-, Cr(S)-, P(S)Al(S-1)- and P(S)Cr(S-1)-term systems. We found that only Cr(S)-term system maintains the half-metallicity at the surface as only this system has the calculated magnetic moment of integer number of bohr magnetons. The magnetic moment of Cr(S) atom in the system was $3.02{\mu}_B$ which was increased from the bulk value by the effects of band narrowing and increased spin-splitting at the surface. The electronic density of states of the P(S) atom in the P(S)Al(S-1)-term showed very sharp surface states due to the broken $p_z$ bonds at the surface. We found there is still a strong p-d hybridization between the P(S) and Cr(S-1) layers in the P(S)Cr(S-1)-term which causes a considerable increase of magnetic moment of P(S) atom.

Preparation of Cobalt-Substituted Iron Oxide Powder from Organometallic Precursors (Ⅱ) (유기금속 전구체로부터 코발트 치환 산화철 분말 제조 (Ⅱ))

  • Kim, Jeong Su;Gang, Han Cheol;Hong, Yang Gi
    • Journal of the Korean Chemical Society
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    • v.38 no.2
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    • pp.92-100
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    • 1994
  • Ultrafine cobalt-substituted iron oxide particles were prepared by the thermal decomposition and oxidation of the new organometallic precursor, $Co_xFe_{1-x}(N_2H_3COO)_2(N_2H_4)_2$ (x = 0, 0.01, 0.02, 0.03, 0.05, 0.10, 1.00). The organometallic precursors were synthesized by the reaction of Co(II) and Fe(II) ion in a mole ratio of x : 1-x with hydrazinocarboxylic acid, and characterized by quantitative analysis, elemental analysis and infrared spectroscopy. The mechanistic study on the thermal decomposition of the organometallic precursors was performed by TG-DTG and DSC. The cobalt-substituted iron oxide particles were obtained by the heat treatment of the precursors at $350^{\circ}C$ and $450^{\circ}C$ for six hours in air. The prepared iron oxide was found to have two phases such as ${\gamma}-Fe_2O_3$ and a mixture of ${\gamma}-Fe_2O_3\;and\;{\alpha}-Fe_2O_3$ at $350^{\circ}C$ and $450^{\circ}C$ respectively. The particle shape was equiaxial and the particle size was less than 0.05 ${\mu}m.$ The coercivity and squareness of the cobalt substituted iron oxide particles increased with increasing cobalt content. Both coercivity and squareness showed higher values at $450^{\circ}C.$

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A New Species of Cellular Slime Molds from Korea, Dictyostelium flavidum sp. nov. (한국산 세포성 점균의 1 신종)

  • 홍정수
    • Journal of Plant Biology
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    • v.35 no.3
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    • pp.197-203
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    • 1992
  • During the study of the distribution of cellular slime molds in Halla mountain of Korea, a new yellow-pigmented Dictyostelium was isloated. This exibited several distinctive features which differed from the published species, and was designated as a new species, Dictyostelium jlavidum sp. n. Hong et Chang (Type strain HL-1). It was cultivated at $20-22^{\circ}C$ on weak nutrient agar media, 0.1 L-P in association with Escherichia coli. Sorocarps were 4-10 mm or more in length, conspicuously yellow throughout or with sori, typically solitary, unbranched or sparsely and irregularly branched. Sorophores were strongly tapered from bases to tips. Bases were typically well-formed disks in form or conically expanded. Sori were yellow to yellowish in color, and the pigmentation intensified with age. Spores were long and thin elliptical, mostly $4.8-9.6{\times}1.9-3.8\;(ave.\;7.3{\times}2.8)\;\mu\textrm{m}$, L/B index about 2.4-2.8, without polar granules.anules.

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Reflective Bistable Chiral Splay Nematic Liquid Crystal Display (반사형 쌍안정 카이랄 스플레이 네마틱 액정표시소자)

  • Kim, Tae-Hyung;Lee, Joong-Ha;Shen, Zheng-Guo;Jang, Ji-Hyang;Kim, Jeong-Soo;Jhun, Chul-Gyu;Kwon, Soon-Bum;Yoon, Tae-Hoon;Kim, Jae-Chang
    • Korean Journal of Optics and Photonics
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    • v.22 no.1
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    • pp.23-29
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    • 2011
  • Bistable chiral splay nematic liquid crystal display (BCSN LCD) is a memory type liquid crystal display using splay and $-\pi$ twist states as two stable states. When the cell thickness to pitch (d/p) ratio is 0.25, splay and $-\pi$ twist states have permanent memory time. However, when the transition from $-\pi$ twist state to splay state is caused by a fringe field, pixel regions show that the splay state is not perfect, but rather includes a contribution from the $-\pi$ twist state. In this paper, we propose a reflective BCSN LCD using $-\pi$ twist state in which the two stable states do not coexist. The fabricated reflective BCSN LC cell shows a high contrast ratio of over 30:1 and response times of 950 ms and 450 ms in vertical and fringe field switching, respectively. The proposed cell also shows wide viewing angle characteristics of $180^{\circ}$ in left- and right directions.

Antidiabetic Activity of a Chloroform Fraction of Vigna nakashimae in db/db mice (db/db 마우스 동물모델에서 Vigna nakashimae 클로로포름층 분획물의 항당뇨 효능)

  • Nam, Jeong-Su;Ha, Tae Joung;Park, Jae Hong;Jung, Myeong Ho
    • Journal of Life Science
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    • v.23 no.4
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    • pp.578-585
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    • 2013
  • In this study, we evaluated the antidiabetic effect of a chloroform fraction of a methanol extract of Vigna nakashimae (designated VN) and compared it with that of a water fraction. Both fractions were administrated to eight-week old db/db mice for two weeks, after which the plasma glucose, triglyceride, and total cholesterol levels were measured. The chloroform fraction (VN-C) lowered the fasting glucose and blood glycated hemoglobin in the db/db mice more effectively than those of the water fraction (VN-W). VN-C also improved the glucose tolerance and led to a significant decrease in the plasma levels of free fatty acids and triglycerides. VN-C enhanced the phosphorylation of AMP-activated protein kinase (AMPK) and increased the expression of carnitine palmitoyltransferase-1 (CPT-1) in HepG2 and C2C12 cells more significantly than VN-W. Consistent with AMPK activation, VN-C inhibited cAMP/Dex-stimulated expression of gluconeogenic genes and increased glucose uptake in C2C12. Collectively, these results suggest that VN-C has an antidiabetic effect, which is exerted via AMPK activation, and that this effect is stronger than that of VN-W.

Physiological Function of a DNA-Binding Protein from Starved Cells in Combating Diverse External Stresses in Escherichia coli (대장균 세포 내 다양한 외부 스트레스에 대한 DPS 단백질의 생리적 기능)

  • Lee, Joo Hyeong;Cheong, Su Jin;Oh, Hun Taek;Kim, Woe Yeon;Jung, Young Jun
    • Journal of Life Science
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    • v.23 no.4
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    • pp.479-486
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    • 2013
  • The DNA-binding protein from starved cells (DPS), originally identified as a DNA binding protein in Escherichia coli, is known to play an important role in DNA protection. The aim of this study was to evaluate the functional roles of DPS in E. coli against various kinds of external stresses by comparing the properties of wild-type E. coli cells and dps knockout mutant E. coli (${\Delta}dps$) cells. Under various stress conditions, we measured the cell growth of the wild-type E. coli and the dps knockout mutant E. coli (${\Delta}dps$) cells using a UV spectrophotometer. The growth rate of the cells was compared to investigate the functional roles of the DPS protein in E. coli. In comparison to the properties of the wild-type E. coli cells, the dps knockout mutant E. coli (${\Delta}dps$) cells showed highly sensitive phenotypes under various stress conditions, such as heat shock, acidic pH, nutrient deficiency, and different concentrations of reactive oxygen species (ROS), suggesting that DPS plays key roles in E. coli in combating diverse external stresses. The DPS DNA-binding protein in E. coli plays crucial roles in bacterial cell growth and in the protection of the cells from environmental stresses by tightly binding and preserving their DNA molecules.

Melt Grafting of EPDM and Itaconic Acid: Effect of Reaction Conditions and Initiator Type/Concentration (Ethylene-propylene-diene terpolymer (EPDM)와 itaconic acid의 melt grafting: 반응조건과 개시제 종류 및 농도의 영향)

  • Kim, Ki-Jae;Bae, Jong-Woo;Kim, Jung-Soo;Lee, Jin-Hyok;Kim, Gu-Ni;Oh, Sang-Taek;Kim, Wonho
    • Elastomers and Composites
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    • v.49 no.3
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    • pp.181-190
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    • 2014
  • Melt grafting of itaconic acid (IA) onto an ethylene-propylene-diene terpolymer (EPDM) with various organic peroxide initiators was performed. Finding the optimum mixing conditions and concentration of ingredients is critical for effective grafting and optimum properties of grafted materials. This study focused on the effects of mixing conditions (temperature and time), initiator type/concentration and monomer concentration on the grafting degree and efficiency, melt flow index, and gel content of EPDM-g-IA. The initiator, 2,5-dimethyl-2,5-di(tert-butyl peroxy)-hexane (T-101), appeared to meet for the best grafting degree (1.91%). The grafting degree increased markedly by increasing the amounts of monomer IA and initiator T-101. The grafting degree also increased by increasing mixing temperature and time. The optimum monomer and initiator concentrations and reaction temperature and time were found to be about 5wt%/0.05wt% and $160^{\circ}C$/15min, respectively. It was found that the physical properties of EPDM-g-IA were higher than those of the pristine EPDM.

Evaluation of the efficiency of the Vac-lock type belly board in Pelvic cancer Radiation Treatment (골반부 방사선치료 시 자체 제작한 Vac-lock type belly board에 대한 유용성 평가)

  • Kim, YoungYeun;Bang, Seungjae;Jung, Ilsun;Kim, Jungsu;Kim, YoungKon
    • The Journal of Korean Society for Radiation Therapy
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    • v.26 no.1
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    • pp.37-42
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    • 2014
  • Purpose : At the time of the pelvis cancer radiation treatment using the belly board, set-up error is large because of a prone position. In order to improve the reproducibility, we made Vac-lock type belly board. In this study, we attempt to validate its utility. Materials and Methods : We compared belly board and Vac-lock type belly board through the OBI. OBI was performed three times with entire course of treatment and the setup errors in the direction of X axis, Y axis, Z axis were recorded and calculated the distance from the isocenter. Results : X axis, Y axis, Z axis setup errors with existing belly board were 0.32 cm, 0.41 cm, 0.29 cm. The setup errors with the vac-lock type belly board were 0.12 cm, 0.19 cm, 0.17 cm. Further, errors of 0~0.29 cm were increased from 48% to 83% when using VLT belly board. Error of 0.5 cm or more was reduced from 21% to 2%. Conclusion : Vac-lock type belly board is able to maintain the efficacy of existing and create to match the characteristics of the patient. Therefore We think that vac-lock type belly board is very useful in pelvic cancer patients.

THE GROWTH OF FOOD ORGANISMS FOR THE MASS PRODUCTION OF MOLLUSCAN SEEDLINGS 1. Phaeodactylum, Platymonas and Chlorella (패류 종묘의 대 생산시에 필요한 먹이 생물의 배양에 관한 연구 1. Phaeodactylum, Platymonas 및 Chlorella)

  • Yoo Sung Kyoo
    • Korean Journal of Fisheries and Aquatic Sciences
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    • v.3 no.1
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    • pp.1-6
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    • 1970
  • A series of experiments have been made on the mass culture of Phaeodactylum tricornutum, Platymonas sp. and Chlorella sp. in the laboratory. The shortest lag phase was found In the culture of Ph. tricornutum followed by Platymonas sp. and Chlorella sp. As compared to the aeration culture, the stagnant culture, in general, showed long duration of the lag phase, short period of the exponential phase and extremely small daily increment. The relative growth constants of Ph. tricornutum, Chlorella sp. and Platymonas sp. were $0.302{\pm}0.028$, $0.226{\pm}0.013$, and $0.151{\pm}0.008$, respectively The maximum daily increment of the three species and then daily ages are as follows: Ph. tricornutum Maximum daily increment : 47.5, Daily age : 10, Platymonas sp. Maximum daily increment : 5.6, Daily age : 14, Chlorella sp. Maximum daily increment : 21.1, Daily age : 14 Comparing the packed cell volume with a certain number of cells, the largest value was found in the population of Ph. tricornutum followed by Platymenas sp. and Chlorella sp. A straight line relationship exists between the two values, and the magnitude of the relationship coincides well with the size of the cells. The culture of Ph. tricornutum was proved satisfactory for feeding the larvae of bivalves at about 12 days after innoculation and both of Platymenas sp. and Chlorella sp. were about 16 days respectively.

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Influence of Crystal Orientation on Corrosion Resistance of Al-Mg films on steel substrate prepared by PVD method (PVD법에 의해 강판상에 제작한 Al-Mg 코팅막의 내식성에 미치는 결정배향성의 영향)

  • Hwang, Seong-Hwa;Park, Jae-Hyeok;Jeong, Jae-In;Yang, Ji-Hun;Yun, Yong-Seop;Lee, Myeong-Hun
    • Proceedings of the Korean Institute of Surface Engineering Conference
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    • 2016.11a
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    • pp.110-110
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    • 2016
  • 금속재료 중 철강은 기계적 성질이 우수하고 대량생산에 의한 뛰어난 경제성을 가지기 때문에 다양한 산업 분야에서 널리 사용되고 있다. 그러나 스테인리스강 등과 같은 일부 특수한 용도의 강을 제외하고는 부식 환경에 취약하기 때문에 그 용도에 따라 표면처리를 함으로서 내식특성을 부여하고 있다. 일반적으로 이러한 철강재료에 대한 부식문제를 해결하기 위한 방법으로는 습식프로세스 중 아연(Zn)도금이 사용되는데, 아연은 그 자체가 보유하고 있는 차폐(barrier)효과는 물론 상대적으로 이온화 경향이 크기 때문에 철에 대하여 전자를 공급하는 희생양극적(Sacrificial anode)역할을 하여 철을 방식하는 원리를 가지고 있다. 하지만 최근에 이르러 기존의 도금 프로세스 처리된 제품의 사용 및 적용분야가 확대되고 가혹해 짐에 따라서 내식성 향상을 위한 새로운 재료 및 신기술 개발이 요구되고 있는 실정이다. 본 연구에서는 친환경 프로세스 방법인 PVD법 중 하나인 스퍼터링(Sputtering)을 이용하여 0.8mm 두께의 냉연강판 (cold rolled steel) 상에 Al에 대한 Mg 함량을 10~30wt.%로 하여 약 $5{\mu}m$ 두께의 막을 제작하였다. 이때 20wt.% 막의 경우 공정압력조건을 증가시켜 증착 막의 결정배향성을 변화시켰다. 뿐만 아니라 제작된 막들에 대해서 $400^{\circ}C$온도에서 10분간 열처리함으로서 코팅막의 성분변화에 따른 영향을 살펴보기 위해 시편을 추가 제작하였다. 이와 같이 제작된 막들에 대한 형성메커니즘과 내식성의 상관관계 해명을 위해 막의 조성분포, 표면 및 단면의 모폴로지 관찰 및 결정구조 등 재료특성분석과 더불어 염수분무(Salt spray test), 침지시험 그리고 양극분극 시험 등을 통해 내식성 평가를 진행하였다. 이상의 종합적인 결과를 살펴보면 제작된 Al-Mg 막은 마그네슘 함량비 및 열처리 조건에 따라 조성분포와 막의 모폴로지 및 결정배향성이 변화한다는 것을 알 수 있었는데, 마그네슘 함량이 증가하고 열처리한 막의 내식성이 가장 양호한 것으로 나타났다. 이것은 Al-Mg 성분이 표면을 중심으로 균일 분산-분포하며, Al에 대한 Mg의 고용으로 인해 안정적으로 형성된 부식생성물과 금속화합물의 단계적 반응 효과에 의해 차폐효과와 희생양극적 특성이 동시에 향상되었기 때문으로 생각된다. 한편 공정 압력을 증가시켜 형성한 막은 결정학적 구조에서 보다 높은 표면 에너지와 증가한 격자 정수에 의해 Mg이 부식환경에서 빠르게 반응하여 안정적 피막을 형성하기 때문에 내식성이 향상된 것으로 보여 진다. 이상의 연구를 통해서 고내식성을 Al-Mg막의 유효성 확인하였으며, 설계에 대한 기초적인 응용지침을 제시할 수 있을 것으로 사료된다.

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