• Title/Summary/Keyword: 정삼투

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The Performance Evaluation of Blended Fertilizers as Draw Solution in Forward Osmosis Desalination (유도용액으로 혼합비료를 사용한 정삼투식 해수담수화에서 혼합비료의 성능평가)

  • Kim, Seung-Geon;Lee, Ho-Won
    • Membrane Journal
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    • v.28 no.1
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    • pp.45-54
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    • 2018
  • This study is to find the optimum draw solution in fertilizer-drawn forward osmosis desalination. Considering osmotic pressure, solubility, and pH, 20 blended fertilizers were screened. Their performance were evaluated in terms of pure water permeate flux, reverse solute flux, and specific reverse solute flux for nitrogen, phosphorus, and potassium. The pure water permeate flux of blended fertilizers including KCl were relatively higher. The reverse solute flux and specific reverse solute flux for nitrogen of blended fertilizers containing ${NO_3}^-$ ion were relatively higher than those of the nitrate ion-free draw solution. Those for phosphorus, and potassium of blended fertilizers including $NH_4H_2PO_4$, and $KNO_3$ were relatively higher than those of the phosphorus-free, and potassium-free draw solution, respectively. The blended fertilizer of $NH_4H_2PO_4$ and KCl contains all of nitrogen, phosphorus and potassium which are essential elements of fertilizer, and has the relatively high water permeation flux and the low reverse solute flux for nitrogen, phosphorus, and potassium. Therefore, it is the most effective draw solution for fertilizer-drawn forward osmosis desalination.

Evaluation of FO membrane performance for each type of pre-treatment from WWTP secondary effluents (하수방류수의 전처리 조건별 FO막의 운전성능평가)

  • Jeong, Junwon;Kim, Jihoon;Kim, Geonyoub;Park, Junyoung;Kim, Hyungsoo;Kim, Hyungsook
    • Journal of Korean Society of Water and Wastewater
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    • v.30 no.2
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    • pp.131-137
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    • 2016
  • The development of alternative water resources has emerged as an effective method for solving drought of water resources due to extreme weather and increase in water consumption. Recently, in Korea, there has been active research on reverse osmosis desalination technology, wastewater reuse using forward osmosis membranes, and the forward osmosis(FO)-reverse osmosis(RO) hybrid process combining these two technologies. In this study, the basic performance of FO membranes manufactured by three domestic and international manufactures such as Microfilter Co., Ltd., Toray Chemical Korea Inc., and Hydration Technologies Inc., were investigated for wastewater reuse. In addition, as an experiment to select feed solution, the selected membranes were operated 48 consecutive hours using three secondary effluents pretreated by the UF membrane with a pore size of $0.1{\mu}m$ and auto strainer with pore sizes of $1{\mu}m$ and $100{\mu}m$ as feed solution. Although there was not much difference in the operating performance. Thus, the treated water using the $100{\mu}m$ auto strainer was selected as feed solution applied to the assessment.

Electrokinetic-Fenton Process for Removal of Phenanthrene (동전기-펜턴 공정을 이용한 phenanthrene 오염토양의 정화)

  • 양지원;박지연;김상준;이유진;기대정
    • Journal of Soil and Groundwater Environment
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    • v.9 no.1
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    • pp.47-53
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    • 2004
  • Feasibility of electrokinetic process combined with Fenton-like reaction was investigated for the removal of phenanthrene from contaminated soil. Transport of hydrogen peroxide by electroosmosis and decomposition of phenanthrene by Fenton-like reaction were observed in a model system. Electrical potential gradient and electroosmotic flow (EOF) at 10 mA were higher than those at 5 mA. High accumulated EOF resulted in high removal efficiency of phenanthrene because the large amount of hydrogen peroxide was transfered through the soil. Removal efficiency of phenanthrene by water washing was 8.5% for 7 days. The highest removal efficiency including phenanthrene decomposition was 95.6% for 14 days. After the operation, soil samples with removal efficiency of 95.6% showed low concentrations of phenanthrene and its intermediates. From this result, it was presumed that phenanthrene was decomposed to small molecules or mineralized to water and carbon dioxide due to continuous supply of hydrogen peroxide by electroosmotic flow.

Transient Characteristics of Fuel Cell Stack at Continuous Current Discharge (일정 전류에서 연료전지의 비정상 특성)

  • Park, Chang Kwon;Jeong, Kwi Seong;Oh, Byeong Soo
    • Transactions of the Korean hydrogen and new energy society
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    • v.14 no.3
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    • pp.195-206
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    • 2003
  • Polymer electrolyte membrane fuel cells(PEMFC) are very interesting power source due to high power density, simple construction and operation at low temperature. But they have problems such as high cost, improvement of performance and effect of temperature. This problems can be approached using mathematical models which are useful tools for analysis and optimization of fuel cell performance and for heat and water management, in this paper, transient model consists of various energy terms associated with fuel cell operation using the mass and energy balance equation. And water transfer in the membrane is composed of back diffusion and electro-osmotic drag. The temperature calculated by transient model approximately agreed with the temperature measured by experiment in constant current condition.

Effect of Twisted Hollow Fiber Membranes in a Module: Computational Fluid Dynamics Simulations on the Pressure and Concentration Profile of the Module in the forward Osmosis (비틀린 중공사막이 모듈에 미치는 영향: 전산 유체역학 시뮬레이션을 통한 정삼투 모듈의 압력과 농도 분포)

  • Kim, Suhun;Lee, Chulmin;Kim, In S.
    • Membrane Journal
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    • v.30 no.1
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    • pp.66-77
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    • 2020
  • The current study focused on the effect of twisting hollow fibers (HFs) in a module during forward osmosis operation mode. Computational fluid dynamics simulation was employed for a straight HF module and twisted modules with five different angles to predict the mass transfer and observe the draw solution profile in terms of concentration and pressure. The simulation results showed that when the membranes were twisted, the concentration was distributed more evenly and the pressure at the module outlet increased gradually as the twisting angle increased. As pressure at the outlet increased, the fluid velocity inside the membrane decreased and the residence time of fluid increased, thereby facilitating mass exchange across the membrane. This is evidenced by a doubling of the ratio of water flux through the membrane in module flux when the HFs were twisted.

Predicting flux of forward osmosis membrane module using deep learning (딥러닝을 이용한 정삼투 막모듈의 플럭스 예측)

  • Kim, Jaeyoon;Jeon, Jongmin;Kim, Noori;Kim, Suhan
    • Journal of Korean Society of Water and Wastewater
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    • v.35 no.1
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    • pp.93-100
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    • 2021
  • Forward osmosis (FO) process is a chemical potential driven process, where highly concentrated draw solution (DS) is used to take water through semi-permeable membrane from feed solution (FS) with lower concentration. Recently, commercial FO membrane modules have been developed so that full-scale FO process can be applied to seawater desalination or water reuse. In order to design a real-scale FO plant, the performance prediction of FO membrane modules installed in the plant is essential. Especially, the flux prediction is the most important task because the amount of diluted draw solution and concentrate solution flowing out of FO modules can be expected from the flux. Through a previous study, a theoretical based FO module model to predict flux was developed. However it needs an intensive numerical calculation work and a fitting process to reflect a complex module geometry. The idea of this work is to introduce deep learning to predict flux of FO membrane modules using 116 experimental data set, which include six input variables (flow rate, pressure, and ion concentration of DS and FS) and one output variable (flux). The procedure of optimizing a deep learning model to minimize prediction error and overfitting problem was developed and tested. The optimized deep learning model (error of 3.87%) was found to predict flux better than the theoretical based FO module model (error of 10.13%) in the data set which were not used in machine learning.

Dewatering of Sewage Sludge by Electrokinetics (동전기를 이용한 슬러지 탈수에 관한 연구)

  • Kim, Ji Tae;Won, Se Yeon;Cho, Won Cheol
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.26 no.6B
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    • pp.661-667
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    • 2006
  • In this study, an experiment of sewage sludge dewatering is carried by using electrokinetic method, and the electrokinetic dewatering efficiency of digested sludge is analyzed. Digested sludge without coagulants is selected and gravitational and pressing dewatering methods are applied in combination with electro-osmotic and electro-osmotic pulse technology. After the test of digested sludge, dewatering test of thickened sludge is carried to evaluate the electrokinetic dewatering feasibility of thickened sludge. Under the condition of constantly applied voltage, however, electrical resistance increases with decreasing of water content so that dewatering rate decreases with time. To reduce such a hindrance caused by constantly applied voltage, electro-osmotic pulse technology which is considered to reduce the difference of water content with height, is applied. For the application of electro-osmotic pulse, the dewatered flow rate and the dewatered volume became more increasing from the middle of the dewatering process than that of continuous voltage. Through the test of thickened sludge, electro-osmotic dewatering combined with gravitational and expression also showed high dewatering rate, which proved the possibility of using electrokinetic dewatering.

Performance evaluation of forward osmosis (FO) hollow fiber module with various operating conditions (중공사막 모듈을 이용한 정삼투 공정에서의 운영조건 변화에 따른 성능평가)

  • Kim, Bongchul
    • Journal of Korean Society of Water and Wastewater
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    • v.32 no.4
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    • pp.357-361
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    • 2018
  • Forward osmosis (FO) process has been attracting attention for its potential applications such as industrial wastewater treatment, wastewater reclamation and seawater desalination. Particularly, in terms of fouling reversibility and operating energy consumption, the FO process is assumed to be preferable to the reverse osmosis (RO) process. Despite these advantages, there is a difficulty in the empirical step due to the lack of separation and recovery techniques of the draw solution. Therefore, rather than using FO alone, recent developments of the FO process have adapted a hybrid system without draw solution separation/recovery systems, such as the FO-RO osmotic dilution system. In this study, we investigated the performance of the hollow fiber FO module according to various operating conditions. The change of permeate flow rate according to the flow rates of the draw and feed solutions in the process operation is a factor that increases the permeate flow rate, one of the performance factors in the positive osmosis process. Our results reveal that flow rates of draw and feed solutions affect the membrane performance, such as the water flux and the reverse solute flux. Moreover, use of hydraulic pressure on the feed side was shown to yield slightly higher flux than the case without applied pressure. Thus, optimizing the operating conditions is important in the hollow fiber FO system.

Forward Osmosis Membrane to Treat Effluent from Anaerobic Fluidized Bed Bioreactor for Wastewater Reuse Applications (하수재이용을 위한 혐기성 유동상 생물반응기 처리수의 정삼투 여과막의 적용)

  • Kwon, Dae-eun;Kim, Jeonghwan
    • Membrane Journal
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    • v.28 no.3
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    • pp.196-204
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    • 2018
  • The anaerobic fluidized bed bioreactor (AFBR) treating synthetic wastewater to simulate domestic sewage was operated under GAC fluidization to provide high surface area for biofilm formation. Although the AFBR achieves excellent COD removal efficiency due to biological activities, concerns are still made with nutrient such as nitrogen remaining in the effluent produced by AFBR. In this study, forward osmosis membrane was applied to treat the effluent produced by AFBR to investigate removal efficiency of total nitrogen (TN) with respect to the draw solution (DS) such as NaCl and glucose. Permeability of FO membrane increased with increasing DS concentration. About 55% of TN removal efficiency was observed with the FO membrane using 1 M of NaCl of draw solution, but almost complete TN removal efficiency was achieved with 1 M of glucose of draw solution. During 24 h of filtration, there was no permeate flux decline with the FO membrane regardless of draw solution applied.

Relationship between Drought-Tolerance and Physiological Parameters in Korean Barley Genotypes (보리 품종의 한발저항성과 생리적 지표와의 상관)

  • 이변우;부금동;백남천;김정곤
    • KOREAN JOURNAL OF CROP SCIENCE
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    • v.48 no.6
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    • pp.516-526
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    • 2003
  • Thirty-six barley varieties including Korean modern and local varieties were tested for drought-tolerance in the field of plastic rain shelter, Drought treatment was initiated at initial tillering stage (March 27, 2002) by withholding irrigation and lasted until harvest. Soil water potential maintained at around -0.05㎫ in the control plot and varied from -0.05㎫ (at the initial stage of drought treatment) to -0.29㎫ in the drought treatment plot. At forty days after drought treatment, relative water content (RWC), osmotic potential (OP), osmotic adjustment (OA), and $^{13}\textrm{C}$ discrimination ($\Delta$) were measured and then plants were sampled for leaf area index (LAI) and dry weight (DW). Barley was harvested at maturity for determining DW, grain yield, 1000 grains weight and number of spikelet. The tested varieties revealed wide spectrum of drought tolerance. Dongbori-1, Chalbori, Changyeongjaerae, Samdobori and Weolseong 87-31 showed strong drought-tolerance while Songhagbori and Suwonmaeg360 showed weak drought-tolerance. The drought injury indexes (drought/control ratio) of DW and yield revealed significant positive correlation with leaf RWC in drought treatment plot and $\Delta$ in the control plot, but obvious negative correlation with leaf OP and OA under drought condition. In addition, all the drought indexes of OP, $\Delta$ and RWC showed obvious positive correlation with the drought injury indexes of DW, 1000 grain weight and yield. Thus, OP and RWC under drought condition and $\Delta$ under well-watered condition would be used as the evaluation criteria for drought- tolerance of barley genotypes. However, further investigation is needed for the relationship between $\Delta$ and drought-tolerance as the other reports were not consistent with our result.