• Title/Summary/Keyword: 정극성

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Optimum Condition for Non-Aqueous Dispersion Polymerization of Environmentally-friendly Acrylic Resin (비수계 분산중합에 의한 환경친화적 아크릴 수지 합성의 최적화 연구)

  • Oh, Dae Geun;Lee, Kyung Hoon;Kim, Wan Tae;Min, Byung Hoon;Chung, Dae-won;Lee, Jong Doo;Kim, Jeong Ho
    • Applied Chemistry for Engineering
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    • v.19 no.4
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    • pp.370-375
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    • 2008
  • Optimum synthesis conditions were investigated for the non-aqueous dispersion (NAD) polymerization of environmentally-friendly acrylic resin. The optimum amount of stabilizer was observed to be 20 wt% to prevent flocculation of the synthesized polymer particles. The optimum ratio of aliphatic solvents to aromatic solvents turned out to be 80 to 20 in order to obtain a stabilized NAD resins. The viscosity of NAD resins was affected not only by the reaction time but also by the amount of initiator and the impeller rpm. Also, the particle size and the size distribution were influenced by the amount of stabilizers and initiators. Since the stability of NAD resin was devastated by the increase in particle size when all the monomers were fed at the beginning of polymerization, the monomers need to be put into the reactor step by step throughout the entire polymerization process.

Nitrite-scavenging and Antimutagenic Effects of Various Solvent Extract from Different Parts of Loquat (Eriobotrya japonica, Lindl.) (비파 부위별 용매추출물의 아질산염 소거 및 항돌연변이 효과)

  • 심기환;배영일;정창호
    • Food Science and Preservation
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    • v.9 no.1
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    • pp.92-96
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    • 2002
  • The nitrite-scavenging and antimutagenic effects of various solvent extracts from different parts of the loquat. were investigated to develope as source of functional food. The nitrite-scavenging and antimutagenic effects of fractions obtained from methanol extract were most highest in ethyl acetate fraction. Ethyl acetate fraction showed better results in the nitrite scavenging activity of 80% in leaf, 81% in seedless fruit, 73% in peel and 63% in seed. The antimutagenic effect showed strong ethyl acetate fraction of 53.1%, 48.3% in leaf and seedless fruit. The antimutagenic effect increased with increasing concentration of ethyl acetate fraction against mutagenicity induced by direct mutagen of IQ in Salmonella typhimurium TA 100. Addition of 2.5 mg and 5 mg of ethyl acetate fraction showed inhibitory effect of 65.5%, 71.2% in leaf and 63.4%, 69.2% in seedless fruit, respectively.

Surface Modification of Low Density Polyethylene and Adhesion Characteristics of Low Density Polyethylene/Aluminum Laminate (저밀도 폴리에틸렌의 표면개질과 이를 이용한 저밀도 폴리에틸렌/알루미늄 라미네이트의 접착특성)

  • Jung, B.Y.;Ryu, S.H.
    • Elastomers and Composites
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    • v.36 no.3
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    • pp.195-200
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    • 2001
  • Ultraviolet photografting of acrylic acid onto low density polyethylene was characterized using XPS and contact angle measurement. Effects of surface modification at LDPE and aluminum on LDPE/Al laminate were also investigated. Contact angle decreased significantly at initial state arid tends to level off with increasing UV irradiation time. The improvement of hydrophilicity was due to the presence of acrylic acid on LDPE surface. Graft of acrylic acid onto LDPE was also identified from O1s/C1s ratios in XPS spectrum. Adhesion strength of LDPE-g-AAc/Al laminate showed about 30 times higher than LDPE/A1 system and it could be attributed to the increase of polarity of LDPE surface. Chemical treatment of Al surface using sulfuric acid/sodium dichromate also increased the adhesion strength of LDPE/Al laminate. Adhesion strength of LDPE/Al laminate decreased significantly under acetic acid.

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Screening of electron donating ability, antibacterial activity and nitrite scavenging effect of some herbal extracts (Herb추출물의 전자공여능, 항균활성 및 아질산염 소거능 검색)

  • 정해정;노경림
    • Korean journal of food and cookery science
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    • v.16 no.4
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    • pp.372-377
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    • 2000
  • Six kinds of herbs(applemint, geranium, lemonbalm, rosemary, sage and thyme) were extracted with water and 95% methanol, and the electron donating ability, antibacterial activity and nitrite scavenging effect were examined. The electron donating ability of herbs ranged from 60.7 to 92.2% and the highest value was observed in geranium, followed by sage and lemonbalm. Antibacterial activity of methanol extracts was much stronger than that of water extracts and gram positive bacteria were more sensitive than gram negative bacteria. Rosemary and geranium exhibited excellent antimicrobial activities against a wide range of bacteria. Nitrite scavenging activity, which was measured at various pH conditions(1.2, 3.0, 3.6, 4.2), was the highest in all herbs at pH 1.2 and the lowest at pH 4.2, suggesting that it is pH dependent. Methanol fraction also provided higher nitrite scavenging effect than the water fraction.

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Study on the Different Characteristic of Chemical and Electronic Properties (SiOC 박막의 화학적 특성과 전기적인 특성에 대한 차이점에 관한 연구)

  • Oh, Teresa
    • Journal of the Korean Vacuum Society
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    • v.18 no.1
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    • pp.49-53
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    • 2009
  • The chemical properties of SiOC film was studied for inter-layer insulator. SiOC film was formed with non polarity due to the appropriate union by the alkyl and hydroxyl group. An amorphous structure of non polarity can induce the low dielectric constant materials. The chemical properties of thin film can define the bonding structure owing to the ionic variation, and the analysis of chemical properties was researched by the carbon content using the FTIR spectra, and induced the film with non polarity. The electrical properties is the electron flow, and is always not the same as the chemical properties. The electrical properties of SiOC film with various flow rate ratios was analyzed and researched the correlation between the chemical properties. SiOC film showed the increasing of the leakage current after annealing process, and abruptly increased the carbon content at some samples. But the sample with increasing the carbon content decreased the leakage current. It means that the chemical properties is not the same as the electrical properties, and the carbon is related with the variation of the bonding structure, and does not contribute the current flow.

Anticariogenic Effects and Inhibition of Glucosyltransferase Activity of Chrysanthemun indicum L. Extracts (감국(Chrysanthemun indicum L.) 추출물의 항충치효과와 Glucosyltransferase 저해활성 탐색)

  • Kim, Seon-Jae;Park, Yun-Mi;Jung, Soon-Teck
    • Journal of the Korean Society of Food Culture
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    • v.20 no.3
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    • pp.341-345
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    • 2005
  • The anticariogenic effects and inhibition of glucosyltransferase activity of Chrysanthemun indicum L. extracts were investigated against 5 strains of microorganisms. The ethanol extracts of Chrysanthemun indicum L. showed the growth inhibition effects on the Streptococcus mutans and oral bacteria. The inhibition rate of glucosyltransferase activity of Chrysanthemun indicum L. extracts showed 78.4 to 92.3% range. The extracts were analysed by using solvent fractionation, silica gel adsorption chromatography, Sephadex LH-20 column chromatography, TLC, HPLC techniques. Three components whose molecular weights ranged from 200 to 400 were confirmed to have the anticariogenic activity.

Ultrasonic Effect on the Extraction of Ash-free coal from Low Rank Coal (저등급 석탄으로부터 초청정석탄의 추출과 초음파의 영향)

  • Lee, Sihyun;Kim, Sangdo;Jeong, Soonkwan;Rhim, Youngjun;Kim, Daehun;Woo, Kwangjae
    • Korean Chemical Engineering Research
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    • v.46 no.3
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    • pp.555-560
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    • 2008
  • Extraction was performed to prepare ash-free coal from low rank coal under the temperature of $200-430^{\circ}C$ and initial pressure of 0.1MPa. Three kinds of coal samples with different rank were used and N-methyl-2-pyrrolidinone(NMP, polar), 1-methyl naphthalene(I-MN, non-polar), Light Cycle Oil(LCO, non-polar) were used as solvents. Results showed that higher extraction yield could be obtained with NMP than with 1-MN and LCO, but the ash concentration shows minimun in the case of 1-MN. Three operation modes were compared, that is, idle, agitation and ultrasonic extraction mode. From the results, it was found that the extraction yield and ash concentration were 70.09% and 1.03% under the agitation mode, 80.7% and 0.76% under the ultrasonic operation mode respectively in the case of NMP used at the temperature of $350^{\circ}C$. Similar results were obtained with 1-MN. Effect of ultrasonic on the extraction was estimated as 15-20% increase in the yields and 26% reduction in the ash concentration.

Analysis of Inter-Species Association and Covariation in a Natural Deciduous Forest (천연활엽수림(天然闊葉樹林)에서의 수종간(樹種間) 상관관계(相關關係)와 공변이관계(共變異關係)의 분석(分析))

  • Kim, Ji Hong;Kuen, Kee Hyun
    • Journal of Korean Society of Forest Science
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    • v.80 no.4
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    • pp.360-368
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    • 1991
  • Utilizing chi-square test statistics, inter-species association and covariation were analyzed for the 37 woody plant species in a deciduous forest dominated by Quercus mongolica and Q. variabilis. within 50 temporarily established $20m{\times}20m$ square quadrats, the association for each pair of species was presented based on the presence-absence parameters. Acer palmatum had significant positive association with Acer mono and Kalopanax pictus, but negative association with Pinus densiflora. Other positively associated species pairs were Prunus sargentii-Macckia amurensis, Quercus serrata-Kalopanax pictus, Symplocos chinensis var. pilosa-Euonymus oxyphyllus, and Ulmus davidiana var. japonica-Lindera obtusiloba. The covariation far each pair of species was evaluated based on the quantitative measures, density and basal area. Overall results showed that the association and covariation values among species generally agreed with each other. Because covariation was calculated by density and basal area of the tallied species in the sample plots, the number of species pairs of covariation tended to be greater than those of association. Especially, Pinus densiflora, considered to be pioneer species in the successional stage, had negative covariation with most of climax species. These ecological information could be applied to silvicultural practices, such as ecosystem classification, establishment of mixed hardwood forest, and tending operations for marking crop trees and desirable species.

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Design of a Novel Instrumentation Amplifier using Current-conveyor(CCII) (전류-컨베이어(CCII)를 사용한 새로운 계측 증폭기 설계)

  • CHA, Hyeong-Woo;Jeong, Tae-Yun
    • Journal of the Institute of Electronics and Information Engineers
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    • v.50 no.12
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    • pp.80-87
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    • 2013
  • A novel instrumentation amplifier(IA) using positive polarity current-conveyor(CCII+) for electronic measurement systems with low cost, wideband, and gain control with wide range is designed. The IA consists of two CCII+, three resistor, and an operational amplifier(op-amp). The principal of the operating is that the difference of two input voltages applied into two CCII+ used voltage and current follower converts into same currents, and then these current drive resistor of (+) terminal and feedback resistor of op-amp to obtain output voltage. To verify operating principal of the IA, we designed the CCII+ and used commercial op-amp LF356. Simulation results show that voltage follower used CCII+ has offset voltage of 0.21mV at linear range of ${\pm}$4V. The IA had wide gain range from -20dB to 60dB by variation of only one resistor and -3dB frequency for the gain of 60dB was 400kHz. The IA also has merits without matching of external resistor and controllable offset voltage using the other resistor. The power dissipation of the IA is 130mW at supply voltage of ${\pm}$5V.

Antioxidation Activities of Organic Solvent Fractions Obtained from Seaweed, Hizikia fusiformis (톳(Hizikia fusiformis)에서부터 분리된 유기용매 분획물의 항산화활성)

  • Kim, Min-Jeong;Lee, Hye-Hyeon;Seo, Min-Jeong;Kang, Byoung-Won;Park, Jeong Uck;Jeong, Yong Kee
    • Journal of Life Science
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    • v.23 no.3
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    • pp.361-367
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    • 2013
  • Hizikia fusiformis has been widely used in Oriental herbal medicine and health food. To identify antioxidation properties that contain natural bioactive substances, we investigated the distribution of active compounds existing in batches of organic solvent fractionation. A dried form of H. fusiformis was subjected to sequential fractionation using n-hexane, ethyl acetate, n-BuOH, and aqueous n-BuOH. The results showed that among the four isolated fractions, the n-BuOH fraction showed the highest antioxidation activities. The n-BuOH fraction was applied to reserve-phase silica gel column chromatography, which produced three fractions: BA, BB, and BC. Among these fractions, BB showed the highest antioxidation activities, which increased in a concentration-dependent manner. At a concentration of 1.0 mg/ml n-BuOH fraction, the activities of DPPH (1,1-diphenyl-2-picrylhydrazyl) radical scavenging and reducing power were approximately $45{\pm}0.14%$ and $1.34{\pm}0.23$, respectively. In addition, the activities of ${\beta}$-carotene-linoleic acid, hydrogen peroxide scavenging, and ABTS (2,2'-azino-bis(3-ethylbenzothiazoline-6-sulphonic acid)) radical scavenging were $76{\pm}0.12%$, $82{\pm}0.06%$, and $65{\pm}0.17%$, respectively. These findings suggest that the BB fraction contains potent antioxidation properties and that it could be used in the production of natural and functional foods.