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Effect of Functionalized Binary Silane Coupling Agents by Hydrolysis Reaction Rate on the Adhesion Properties of 2-Layer Flexible Copper Clad Laminate (이성분계 실란 커플링제의 가수분해속도 조절에 의한 2-FCCL의 접착특성 변화 연구)

  • Park, U-Joo;Park, Jin-Young;Kim, Jin-Young;Kim, Yong-Seok;Ryu, Jong-Ho;Won, Jong-Chan
    • Polymer(Korea)
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    • v.35 no.4
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    • pp.302-307
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    • 2011
  • The parameters of silanol formation reaction of organosilane including solvent type, solution concentration, pH and hydrolysis time influence the adhesion property of 2 layer flexible copper clad laminate (FCCL). Especially, the hydrolysis reaction time of silane coupling agent affects the formation of the silanol groups and their self-condensation to generate oilgomeric structure to enhance the surface treatment as an adhesive promoter. In our study, we prepared the binary silane coupling agents to control hydrolysis reaction rate and surface energy after treatment of silane coupling agents for increasing the adhesive property between a copper layer and a polyimide layer. The surface morphology of rolled copper foil, as a function of the contents of the coated binary silane coupling agent, was fully characterized. As fabricated 2-layer FCCL, we observed that adhesive properties were changed by hydrolysis rate and surface energy.

Evaluation on the Appearance and Gluing Characteristics of Pine Laminated Boards according to Overlaying Materials (소나무 집성판의 표면화장 재료별 외관품질 및 접착성 평가)

  • So, Won-Tek
    • Journal of the Korean Wood Science and Technology
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    • v.35 no.1
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    • pp.27-35
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    • 2007
  • This experiment was carried out to investigate the appearance and surface gluing characteristics of laminated boards overlaied with teak sliced veneer, printing paper, wall paper, cotton cloth, and wool cloth, The overlaying sheets were glued on the laminated boards with polyvinyl acetate emulsion adhesives and the species for laminated boards was red pine. The obtained results are summarized as follows; in case of the teak sliced veneer overlaied boards, the appearance quality was very good and showed the first grade of KS standard. but the delamination rate was 44.0% and 895% for cold water or warm water dipping treatments, respectively, so the wet gluing properties were very bed. In the case of the paper or cloth overlaied boards, the appearance quality was same good and showed the first grade of KS standard, but their delamination rate was 10~20% and 39.3~49.0 for cold water or warm water dipping treatments, respectively, so the wet gluing properties were bed, relatively better than sliced veneer overlaied boards. The present work showed that appearance of laminated boards overlaid with several sheets appeared quite positive in terms of secondary gluing qualities of laminated boards, suggesting that sliced veneer, paper, and cloth would be appropriate for the overlaying materials of laminated boards.

Improvement of Interfacial Adhesion of Copper-Epoxy Using Silane Primer (실란 프라이머 도입에 의한 동박-에폭시 계면접착 향상)

  • Jeong, Gyeong-Ho;Lee, Bo-Hyeon;Kim, Seong-Hun
    • Korean Journal of Materials Research
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    • v.9 no.12
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    • pp.1160-1169
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    • 1999
  • In this study, the silane primers were introduced to improve the interface adhesion between copper and epoxy. Especially, the polymer types obtained by solution and emulsifier-free emulsion polymerization of vinyltriethoxysilane and the low molecular weight types of 3-aminopropyltriethoxysilane(3-APTES) and 3-glycidoxypropyltrimethoxysilane(3-GPTMS) were used to improve the adhesion strength between epoxy and copper. Also, the surface of copper was treated by 1,1,1-trichloroethane. According to the results, the interfacial adhesion strength of copper-epoxy increased about 2~5 times with the introduction of silane primer. Also, the optimum treatment time of copper surface was about 10 minutes. Additionally, the adhesion strength as a function of concentration of low molecular weight silane was maximum at about 0.5 vol.% for 3-APTES and about 0.2 vol% for 3-GPTMS.

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Dual-purpose Reagent for Separating Paper with Tape and Developing Fingerprints on the Paper Simultaneously (종이에 부착된 테이프를 박리하는 동시에 지문을 현출하는 이중목적시약(dual-purpose)에 관한 연구)

  • Seo, Youn-Hee;Kim, Yeon-Ji;Shin, Min-Seop;Yu, Je-Seol
    • The Journal of the Korea Contents Association
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    • v.19 no.1
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    • pp.463-471
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    • 2019
  • Tapes are usually used in violent crimes and may contain important evidence. Separating adhesive side should be preceded to collect these evidence. In this study, we researched a novel dual-purpose reagent that can separate the tape without damaging and develop the fingerprints on porous surface when the tape is attached to A4 paper. As a result, the reagent of 1:2 ratio of 1,2-IND stock solution and HFE-7100 can separate without damaging the adhesive surface and develop fingerprints on separated A4 paper.

Bond Strength of Band on Zirconia Crown with Compomer and Resin Cement (지르코니아 기성관에 컴포머와 레진 시멘트로 접착한 교정 밴드의 결합력)

  • Park, Chanhee;Lee, Jonghyung;Lee, Hangil;Kim, Jihun
    • Journal of the korean academy of Pediatric Dentistry
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    • v.46 no.2
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    • pp.127-134
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    • 2019
  • The aim of this study was to evaluate the compomer cement and resin cement as an orthodontic band cement on zirconia crown. A total of 30 specimens were prepared. Preformed stainless steel crowns and zirconia crowns of upper right second primary molar were used. Orthodontic bands were cemented on stainless steel crowns (Group I, n = 10) and zirconia crowns (Group II, n = 10) with compomer cement. The other bands were cemented on zirconia crowns with resin cement (Group III, n = 10). The tensile loads were applied to band to measure the bond strength. The mean of bond strengths of group I, II and III were 0.79 MPa, 1.09 MPa and 1.56 MPa respectively. Bond strength of group II is significantly higher than group I. There was no significant difference between group II and III. Compomer cement and resin cement containing functional monomers showed favorable bond strength of orthodontic bands.

A Study on Fracture Property of Adhesive Interface at Tapered Double Cantilever Beam with Inhomogeneous Composite Material due to Loading Conditions of In-plane and Out-plane (면내 및 면외 하중 조건들에 따른 이종 복합 소재를 가진 경사진 이중외팔보에서의 접착계면의 파괴 특성 연구)

  • Lee, Jung-Ho;Kim, Jae-Won;Cheon, Seong-Sik;Cho, Jae-Ung
    • Composites Research
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    • v.33 no.6
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    • pp.401-407
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    • 2020
  • At the engineering and industrial areas, the lightweight composite material has been substituted with the metals, such as steel at the structural parts. This composite material has been applied by the adhesive bonding method, as well as the joint methods with rivets, welds or bolts and nuts. The study on the strength characteristics of adhesive interface is necessarily required in order to apply the method to composite materials. CFRP specimens as the fiber reinforced plastic composites were manufactured easily and this study was carried out. The static experiments were performed under the loading conditions of in-plane and out-plane shears with the inhomogeneous composite TDCB specimens with CFRP, aluminum (Al6061), and aluminum foam (Al-foam). Through the result of this study, the durability on the inhomogeneous composite structure with adhesive interface was investigated by examining the fracture characteristic and the point in time.

Shear Performance Evaluation of Composite Thermal Insulation with Quasi-Non-Combustible according to Adhesive Type (부착 유형에 따른 준불연 복합단열판 전단성능평가)

  • Choi, Ki-Sun;Oh, Keunyeong;Park, Keum-Sung;Ha, Soo-Kyung
    • Journal of the Korea Institute of Building Construction
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    • v.22 no.5
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    • pp.507-518
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    • 2022
  • The purpose of this research is to obtain experimental data for developing a structural design of an external insulation system by evaluating the shear performance of a composite insulation system according to the adhesive type. The shear performance of the composite insulation system was experimentally evaluated by considering a simultaneous placement method, full and spot/edge coverage using adhesive mortar. As a result of the test, the shear strength of simultaneous placement and full coverage method was almost similar, the spot/edge coverage method was about 80% of them. Also, the simultaneous placement method is considered to be constructively advantageous when applied as an external insulation system to a high-rise building compared to using an adhesive mortar.

Studies on Adhesion of Fancy Veneer and Formaldehyde Emission of Wood-Based Floorings by Mole Ratios of Urea and Melamine (요소·멜라민 접착제의 수지 조성에 따른 마루판의 천연무늬단판 접착성 및 포름알데히드 방출에 대한 연구)

  • Kang, Eun-Chang;Park, Jong-Young;Park, Heon
    • Journal of the Korean Wood Science and Technology
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    • v.30 no.2
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    • pp.165-171
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    • 2002
  • This study was to investigate the adhesion properties of fancy veneer and base panels and formaldehyde emission of wood-based floorings bonded with urea-melamine formaldehyde adhesives. We focused on stoichiometric mole ratio of reactive functional groups. The urea-melamine formaldehyde adhesives were made at twelve different formaldehyde/urea-melamine mole ratios. The interlaminated shear strength and formaldehyde emission of wood-based floorings bonded with selected adhesive among these adhesives were examined. The results showed that the bonding properties were high and the formaldehyde emission was low as the adhesive consisted of stoichiometric mole ratio of formaldehyde/urea-melamine. Interlaminated shear strengths of HDF(High Density Fiberboard) flooring were over 14 kgf/cm2 at all mole ratios. At the mole ratio of 1.0, HDF flooring showed low value of formaldehyde emission of 953 mg/L. Interlaminated shear strengths of Plywood flooring were high, 14.02 kgf/cm2 at mole ratio of 1.4. At the mole ratio of 1.0, Plywood flooring showed low value of formaldehyde emission of 0.26 mg/L.

A Study on the Manufacture and Physical Properties of Liquid Adhesive for Wood Preservation - Focusing on the Synthesis of Gelatin and Carrageenan - (목재 보존용 액상 접착제의 제조 및 물성 연구 - 젤라틴과 카라기난 합성 중심으로 -)

  • Oh, Seung Jun;Han, Won Sik;Wi, Koang Chul
    • Journal of Conservation Science
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    • v.37 no.6
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    • pp.801-806
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    • 2021
  • In order to improve the usability of glue, a traditional adhesive material, and the gelation process of seaweed extract carrageenan, a liquid adhesive for wood preservation was prepared by mixing the two materials. The prepared wood adhesive was mixed with a 15 wt% aqueous solution of glue, λ-carrageenan, an antibacterial agent, an antifoaming agent, and the maximum adhesive strength of 1.80 Mpa was confirmed. As a result of comparison, the adhesive strength was superior to that of 5 different types of traditional natural adhesive ingredients (aqueous solution) and 1 type of polyvinyl acetate-based adhesive.

Effect of Carbon Filler and Ester Type Binder on the Reactivity and Adhesive Properties with PET Film of Conductive Paste (탄소필러와 에스테르계 바인더가 전도성 페이스트의 반응성 및 PET 필름과의 접착특성에 미치는 영향)

  • Shim, Chang Up;Ku, Hyo Sun;Kim, Youn Cheol
    • Applied Chemistry for Engineering
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    • v.33 no.4
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    • pp.381-385
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    • 2022
  • It is very important to secure the adhesion durability between the base film and the conductive paste for the development of a sensor for detecting hazardous chemicals. In this study, an ester binder was used to improve the adhesive properties which can be a problem when applying the sensor to the cross cut 0B or 1B grade. This problem was found while evaluating the adhesive properties by coating the polyaniline/graphene nano plate (GNP) paste on the polyethylene terephthalate (PET) film. When 10 wt% or more of the ester-based binder was added, the cross cut grade to which the sensor can be applied was 3B or higher. It was confirmed that the excessive addition of the binder may affect the electrical properties of the conductive paste and actually decrease the reactivity to sulfuric acid. To improve the electrical property, a carbon black (CB) content was varied resulting in the optimum electrical property observed at 2 wt% of CB.