• Title/Summary/Keyword: 점탄성거동

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Experimental and numerical study on viscoelastic behavior of polymer during hot embossing process (핫엠보싱 공정의 폴리머 점탄성 거동에 대한 연구)

  • Song, N.H.;Son, J.W.;Rhim, S.H.;Oh, S.I.
    • Proceedings of the Korean Society for Technology of Plasticity Conference
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    • 2007.05a
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    • pp.191-194
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    • 2007
  • In hot embossing lithography which has shown to be a good method to fabricate polymeric patterns for IT and bio components, it is very important to determine the proper process conditions of pressure, temperature, and time. It is also a key factor for predicting the optical properties of final product to calculate residual stress distribution after the embossing process. Therefore, to design the optimum process with right conditions, the ability to predict viscoelastic behavior of polymer during and after the hot embossing process is required. The objective of the present investigation is to establish simulation technique based on constitutive modeling of polymer with experiments. To analyze deformation behavior of viscoelastic polymer, the large strain material properties were obtained from quasi-static compression tests at different strain rates and temperatures and also stress relaxation tests were executed. With this viscoelastic material model, finite element simulation of hot embossing was executed and stress distribution is obtained. Proper process pressure is very important to predict the defect and incomplete filling.

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Development and Performance Evaluation of Polymer Micro-actuator using Segmented Polyurethane and Polymer Composite Electrode (세그먼트화 폴리우레탄을 이용한 고분자 마이크로 액츄에이터의 제작 및 고분자 전극의 상태에 따른 구동성능)

  • Jung Young Dae;Park Han Soo;Jo Nam Ju;Jeong Hae Do
    • Journal of the Korean Society for Precision Engineering
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    • v.22 no.2
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    • pp.180-187
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    • 2005
  • This paper is focused on the development of the flexible electrode for disc-type polymer actuators using Segmented Polyurethane(SPU). This paper consists of two parts. The one is about the mechanical property such as elastic modulus. these parameters mainly affect behaviors of polymer actuators and the other is about the electro-chemical property such as the surface resistance of the composite electrode affects the strength of electrostatic force, results in the deformation of polymer actuators. The Young's modulus was measured by UTM. As result, by increasing the modulus of a body of polymer actuators, the maximum displacement of polymer actuators are decreased. The surface resistance of the electrode was measured by 4 point probe system. Compared with the conductive silver grease, the displacement of polymer actuators using carbon black(CB) composite electrodes is comparably small but CB composite electrode should be the practical approach for the improvement of the performance of all-solid actuators, compared with another types of electrode materials.

Oscillatory behavior of microglial cells (미세아교세포의 진동 거동의 연구)

  • Park, Eunyoung;Cho, Youngbin;Ko, Ung Hyun;Park, Jin-Sung;Shin, Jennifer H.
    • Journal of the Korean Society of Visualization
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    • v.19 no.1
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    • pp.74-80
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    • 2021
  • Cells regulate their shapes and motility by sensing the cues from the internal and external microenvironment. Under different circumstances, microglia, the brain resident immune cells, undergo dynamic phenotypic changes, one of which is a remarkable periodic oscillatory migration in vitro. However, very little is known about the kinematic and dynamic perspectives of this oscillatory behavior. In this study, we tracked the changes in cell morphology and nuclear displacement, and visualized the forces using traction force microscopy (TFM). By correlation analyses, we confirmed that the lamellipodia formation preceded the nuclear translocation. Moreover, traction, developed following lamellipodia formation, was found to be localized and fluctuated at two ends of the oscillating cells. Taken together, our results imply that oscillatory microglial cells feature a viscoelastic migration, which will contribute to the field of cell mechanics.

The Effect of Compatibilizer on the Rheological Properties of Polypropylene/Glass-fiber Composites (폴리프로필렌/유리섬유 복합재료의 유변물성에 미치는 상용화제의 영향)

  • Lee Seung-Hwan;Youn Jae-Ryoun
    • Composites Research
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    • v.19 no.3
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    • pp.15-22
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    • 2006
  • In this study, we prepared glass fiber reinforced polypropylene composites using Brabender twin-screw extruder. Compatibilizer, polypropylene-based maleic anhydride (PP-g-MAH), was used to increase the molecular interaction between polypropylene matrix and glass fiber and to enhance melt processability. We also measured the shear and uniaxial elongational behaviors of glass-fiber reinforced composites in the absence or presence of compatibilizer. The effects of compatibilizer and fiber loading on the viscoelastic behaviors were examined. It was fuund that the PP-g-MAH compatibilizer improved the fluidity and increased the molecular bonding of composite melts in shear flow. Transient elongational viscosity was increased with fiber loadings in uniaxial elongational flow However, it was decreased with increasing elongational rates because of microscale shear flow between fibers.

A Study on Analysis Method of Asphalt Plug Joint using FEM (유한요소 해석을 통한 Asphalt Plug Joint의 분석 방법에 대한 연구)

  • Moon, Kyoung-Tae;Park, Philip;Park, Sang-Yeol
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.31 no.2D
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    • pp.237-245
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    • 2011
  • Asphalt Plug Joint(APJ) is a new type of expansion joint that it's application are increased in USA as well as several European countries. APJ's' advantages are cheap construction and maintenance costs, and simple construction and securing of excellent flatness. However, APJ's usability is hindered because it showed a problem of premature failure. Research for solving this problem has been progressed, and FEM analysis among existing researches was peformed. However, the behavior of APJ was insufficiently analyzed and the reliability of the analysis was much low, since the material showing complicated behavior was oversimplified, Therefore, a material model was proposed and its effectiveness was confirmed by comparing it with actual behavior in order to improve the reliability of FEM analysis in this paper. ABAQUS program was used for FEM analysis, and an elasto-plastic model and a viscous-plastic model as the material model of APJ were suggested on the base of experiment results of APJ material performed by Bramel et al. The elasto-plastic model was defined by time-independent analysis since it didn't consider time and strain rate, and the viscous-plastic model was defined by time-dependent analysis since it considered. Influence of various elements affecting the behavior of APJ was investigated, and it was confirmed that the time-dependent analysis showed better result closed to actual behavior than the time-independent analysis.

Development of Vibration and Impact Noise Damping Wood-Based Composites -Synthesis of the Polymer Showing a Broad Damping Peak (진동·충격음 흡수성 목질계 복합재료의 개발 -폭 넓은 감쇠곡선을 나타내는 고분자의 합성-)

  • Lee, Hyun-Jong
    • Journal of the Korean Wood Science and Technology
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    • v.27 no.2
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    • pp.15-22
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    • 1999
  • Polymeric meterials that are used for noise and vibration damper in wood/polymer/wood sandwich composites, must have a high loss factor(tan ${\delta}$), and at the same time the storage modulus(E) of $5{\times}10^7$ to $10^9$ dyne/$cm^2$ must withstand over a wide temperature and frequency ranges. In this study, the series of epoxy resinlpolyacrylate interpenetrating polymer networks(IPNs) were synthesized by simultaneous polymerization. Their dynamic tensile properties were measured at 110Hz using Rheovibron instrument. Composite damping factor(tan ${\delta}_c$) and dynamic bending modulus($E_c,\;E_^{\prime\prime}c$) of wood/polymer/wood sandwich composites were measured at 110Hz using a Rheovibron in bending mode of vibration. These dynamic tensile studies indicated that cured epoxy resin/polyacrylates IPNs were semicompatible in the sense that both the shifting of T($E^{\prime\prime}_{max}$) or T(tan ${\delta}_{max}$) and the broadening of glass transition temperature range were observed. Especially, the cured Epikote871/P(n-BMA) IPNs of composition 70/30 to 50/50 showed a relatively high tan a and appropriate E' value over a wide temperature range; consequently the tan a e curves of wood/IPNs/wood sandwich composites was broadened over a wide temperature range.

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Tuning the rheological properties of colloidal microgel controlled with degree of cross-links (가교도가 제어된 콜로이드 마이크로겔의 유변학적 물성 분석)

  • Han, Sa Ra;Shin, Sung Gyu;Oh, Seung Joo;Cho, Sung Woo;Jung, Naseul;Kang, Bu Kyeung;Jeong, Jae Hyun
    • Journal of the Korean Applied Science and Technology
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    • v.36 no.2
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    • pp.645-655
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    • 2019
  • In this study, colloidal microgel with viscoelasticity were prepared by using dispersion containing physical crosslinking agents and microgels with various strengths depending on the degree of cross-links.As the chemical crosslinking agent PEGDA400 content increased, hydrogels have various physical properties the swelling ratio decreased from $2.0{\times}10^4%$ to $6.0{\times}10^3%$ and increased viscosity by about 60%. The colloidal microgel was prepared with micro hydrogel grinded to $100{\mu}m$ size and the rheological behavior was confirmed with physical cross linking agent. A colloidal microgel having various viscosities was prepared by controlling starch and alginate based on micro-hydrogel containing 0.75% (w/v) of PEGDA400. In conclusion, these results would be highly useful for applying as a product that can give various physical properties to the colloidal suspensions, cosmetics, paint, and food industry.

도공층의 공극 구조와 인쇄후 잉크의 잔류 거동에 관한 연구(II)

  • ;;Douglas W. Bousfield
    • Proceedings of the Korea Technical Association of the Pulp and Paper Industry Conference
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    • 2001.11a
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    • pp.127-127
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    • 2001
  • 종이의 공극은 도공용 원지 또는 인쇄 용지로 사용될 때 도공액과 잉크 조성분의 침 투 거동에 영향을 미침으로써 여러 가지 물리적 성질에 변화를 가져온다. 도공 공정의 경우, 도공액에 포함되어 있는 물과 수용성 고분자 물질의 원지 침투는 도공 작업성과 도공층의 구조에 변화를 가져 올 수 있다. 이러한 변화는 물을 포함한 수용성 물질의 원지 침투가 빨라질 때 도공액의 고형화점 상승에 의한 원지 피복력 저하에 따른 도공 지의 평활성 감소를 가져온다. 또한 높은 전단력이 가해지는 블레이드 도공에서는 도피 직전 도공액의 수분 이탈이 급격하게 일어날 경우 블레이드에서 도공액의 유동성 저하 가 발생됨으로써 여러가지 문제점을 나타낸다고 보고 된 바 있다. 인쇄 공정의 경우에 는 도공층이 잉크의 직접적인 기질(substrate)로 작용되어 잉크 성분의 잔류 및 침투 거동에 영향을 미친다. 즉 지나치게’발달된공극 특성을 지닌 도공층에서는 잉크 안료가 적절한 결합력을 가지고 도공층에 정착되기 전에 잉크 속의 레진과 용제가 도공층의 공극으로 소실됨으로써 인쇄 완료 후 작은 외력에도 잉크 층이 파괴되는 효킹 ( (chalking) 현상이 일어난다. 그러나 과도한 바인더의 적용과 미세한 안료의 사용에 따 라 도공층의 공극이 폐쇄될 경우에는 인쇄 후 잉크의 건조가 늦어져 인쇄 작업성의 저 해 요인으로써 작용한다. 종이의 공극성과 인쇄적성은 주지하는 바와 같이 불가분의 관계에 있으며, 본 연구에 서는 피인쇄체로서 공극성을 달리한 세 종류의 도공지를 제조하고 실험실적으로 제조 된 잉크를 사용하여 각각의 특성에 따른 잉크의 잔류 특성에 대하여 고찰해 보고자 하 였다. 특히 인쇄 전 피인쇄체의 공극 특성에 따른 인쇄 전후의 공극율 변화와 주요 인 쇄 적성간의 관계에 대해 초점을 맞추었다.시아노에틸화한 PYA용액의 점탄성 평가를 위하여 storage modulus와 loss modulus 를 분석하였다. 일반적 유변특성 평가 결과 PYA용액은 shear-thinning, pseudoplastic 한 특성을 나타내어 표면사이즈 공정에서의 적용 가능성을 확인할 수 있었다. 사용하는 통계기법 중의 하나인 주성분회귀분석을 실시하였다. 주성분 분석은 여러 개의 반응변수에 대하여 얻어진 다변량 자료의 다차원적인 변 수들을 축소, 요약하는 차원의 단순화와 더불어 서로 상관되어있는 반응변수들 상호간 의 복잡한 구조를 분석하는 기법이다. 본 발표에서는 공정 자료를 활용하여 인공신경망 과 주성분분석을 통해 공정 트러블의 발생에 영향 하는 인자들을 보다 현실적으로 추 정하고, 그 대책을 모색함으로써 이를 최소화할 수 있는 방안을 소개하고자 한다.금 빛 용사 둥과 같은 표면처리를 할 경우임의 소재 표면에 도금 및 용 사에 용이한 재료를 오버레이용접시킨 후 표면처리를 함으로써 보다 고품질의 표면층을 얻기위한 시도가 이루어지고 있다. 따라서 국내, 외의 오버레이 용접기술의 적용현황 및 대표적인 적용사례, 오버레이 용접기술 및 용접재료의 개발현황 둥을 중심으로 살펴봄으로서 아직 국내에서는 널리 알려지지 않은 본 기 술의 활용을 넓이고자 한다. within minimum time from beginning of the shutdown.및 12.36%, $101{\sim}200$일의 경우 12.78% 및 12.44%, 201일 이상의 경우 13.17% 및 11.30%로 201일 이상의 유기의 경우에만 대조구와 삭제 구간에 유의적인(p<0.05) 차이를 나타내었다.는 담수(淡水)에서 10%o의 해수(海水)로 이주된지 14일(日) 이후에 신장(腎臟)에서 수축된 것으로

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Combined Effects of Sustained Load and Temperature on Pull-off Strength and Creep Response between CFRP Sheet and Concrete Using Digital Image Processing (디지털 이미지 분석을 통한 지속 하중과 온도의 복합 환경이 CFRP 쉬트와 콘크리트의 부착강도 및 크리프 거동에 미치는 영향 분석)

  • Jeong, Yo-Seok;Lee, Jae-Ha;Kim, Woo-Seok
    • Journal of the Korea Concrete Institute
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    • v.28 no.5
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    • pp.535-544
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    • 2016
  • This paper aims at examining the effects of sustained load and elevated temperature on the time-dependent deformation of a carbon fiber reinforced polymer (CFRP) sheets bonded to concrete as well as the pull-off strength of single-lap shear specimens after the sustained loading period using digital images. Elevated temperature during the sustained loading period resulted in increased slip of the CFRP composites, whereas increased curing time of the polymer resin prior to the sustained loading period resulted in reduced slip. Pull-off tests conducted after sustained loading period showed that the presence of sustained load resulted in increased pull-off strength and interfacial fracture energy. This beneficial effect decreased with increased creep duration. Based on analysis of digital images, results on strain distributions and fracture surfaces indicated that stress relaxation of the epoxy occurred in the 30 mm closest to the loaded end of the CFRP composites during sustained loading, which increased the pull-off strength provided the failure locus remained mostly in the concrete. For longer sustained loading duration, the failure mode of concrete-CFRP bond region can change from a cohesive failure in the concrete to an interfacial failure along the concrete/epoxy interface, which diminished part of the strength increase due to the stress relaxation of the adhesive.

Synthesis and Curing Behavior of UV-curable Polycarbonate-based Polyurethane Methacrylate : Effect of Polyol Molecular Weight, Contents of Photoinitiator and Monomers on the Flexibility and Properties (자외선 경화형 폴리카보네이트계 폴리우레탄 메타아크릴레이트의 합성과 경화거동 : 폴리올 분자량, 광개시제 및 모노머 함량이 유연성과 물성에 미치는 영향)

  • Park, Eun-Suk;Hwang, Hyeon-Deuk;Park, Cho-Hee;Lee, Yong-Hee;Moon, Je-Ik;Kim, Hyun-Joong
    • Journal of Adhesion and Interface
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    • v.12 no.2
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    • pp.47-55
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    • 2011
  • UV-curable coatings have been used in various industries due to their advantages such as high mechanical property, good solvent resistance, fast curing process and low volatile organic compounds. However, a lack of flexibility of UV-cured films is a weak point for the pre-coated system of roll-to-roll process. In this study, UV-curable polycarbonate-based methacrylates were synthesized with polycarbonate diol, isophorone diisocyanate and 2-hydroxyethylmethacrylate to improve flexibility of the UC-cured films. The effects of polyol molecular weight, content of photoinitiator and monomers on the UV-curing behavior, flexibility and properties were investigated. The UV-curing behavior was measured by a photo-DSC, the pendulum hardness, tensile strength, viscoelastic properties were also evaluated.