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Research for refining processes to produce high-purity polycrystalline silicon from domestic quartzite mine (국내 규석광으로부터 고순도 실리콘 제조를 위한 정련 공정에 관한 연구)

  • Moon, Byung Moon;Kim, Gangjune;Koo, Hyun Jin;Park, Dong Ho;Yu, Tae U
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.11a
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    • pp.48-48
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    • 2011
  • 2010년 약 19.5 GWp 의 규모로 성장한 태양광 시장의 주요 소재는 실리콘을 이용한 태양전지이며, 고성능 및 고효율 태양전지 시장이 급성장 하였다. 이러한 고품질 태양전지에 사용되는 주요 원료인 9N 급 폴리실리콘은 2008년 4월 $265/kg 까지 상승하였으나, 점차 하향안정세에 있으며, 급속한 가격 경쟁을 통해 당분간 장기공급가가 50$/kg 이하로 하락할 것으로 전망된다. 이러한 실리콘 제조기술 중 가장 많이 사용되는 기술은 Trichloro-silane (TCS) 또는 Mono-silane (MS)를 사용하는 기상법인 일명 Siemens 공정이다. 이러한 기상법의 경우 12N 이상의 초고품질 실리콘 제조가 가능하나, 대규모의 설비투자(1억원/폴리실리콘 1톤)와 높은 에너지(120 kWh/kg)가 요구된다. 이에 최근 기상법이 아닌 야금학적인 정련법에 대한 기술이 개발되고 있으며, 이는 금속 실리콘을 슬래그 처리, 편석 분리, 응고 급랭, 전자빔, 플라즈마 등을 이용하여 정련하는 공정을 말한다. 야금학적 정련법은 순도 면에서 기상법에 비하여 낮은 단점이 있음에도 불구하고, 여러 장점들로 인해 활발히 연구되며 점차 실용화 되고 있는 매우 유용한 기술이다. 야금학적 정련법의 주요 장점은 기상법에 비해 약 25% 정도의 설비 투자비로 가능하고, 금속 실리콘을 직접 사용하며, 에너지 payback이 짧다. 또한, 산 및 염화실렌을 사용하지 않으므로 환경 문제를 적게 야기하고, 생산설비의 확장성도 매우 높다. 본 연구에서는 국내 규석광을 이용하여 일련의 정련 공정을 거쳐 고순도SG(Solar Grade)급 실리콘을 제조하고자 하였다. 실리콘 용융 환원로를 개발하고 순도를 높이기 위해 슬래그정련법을 이용하였으며, 생산된 3N 급의 금속 실리콘을 비기상법정련 방식인 일방향 응고와 플라즈마 정련 및 전자기유도 용해법을 이용하여 고순도의 실리콘을 제조하였다. 본 연구에서는 상업생산을 개시한 외국의 E사와 비교하여 산침출공정을 거치지 않으므로 실리콘회수율 및 환경부하 절감의 장점을 갖고 있으며 최종 순도 실리콘 6N 이상, 보론 함유량 0.2 ppm 이하를 달성하였으며, 기존 기상법 대비 약 20%의 전력 감소와 약 13%의 금속실리콘 원료 절감 효과가 있었다. 저가/고순도 SG급실리콘의 제조기술 개발은 향후 세계 태양광 시장에 대한 경쟁력을 확보하고, 시장 점유율 상승에 기여할 수 있으며, 산업 확대를 통한 주변 산업으로의 파급 효과가 매우 클 것으로 예상된다.

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Effects of Light Quality and Lighting Type Using an LED Chamber System on Chrysanthemum Growth and Development Cultured In Vitro (LED Chamber System을 이용한 광질 및 광조사 방법 제어가 국화 배양소식물체의 생장에 미치는 영향)

  • Heo, Jeong-Wook;Lee, Yong-Beom;Chang, Yu-Seob;Lee, Jeong-Taek;Lee, Deog-Bae
    • Korean Journal of Environmental Agriculture
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    • v.29 no.4
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    • pp.374-380
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    • 2010
  • This experiment was carried out to investigate the effect of light qualities and lighting types provided by LED Chamber System which designed by Rural Development Administration on growth and development of Chrysanthemum (Dendranthema grandiflorum L., cv. 'Cheonsu') plantlet cultured in vitro. The explants of single-node cuttings were exposed to monochromic or mixture radiation of blue, red, or green under continuous and intermittent lighting for 42 days. The intermittent lighting of 20 sec. on and off per minute significantly stimulated shoot elongation with lower number of internodes compared with continuous lighting treatments. However, continuous blue, red, or green light gave greater dry weight comparing the intermittent lighting, and the lowest weight was recorded at the continuous fluorescent lamp. Otherwise, the plantlet growth in dry weight or leaf area was inhibited by the green light controlled at 50 times intermittence but internode elongation was significantly increased. These results showed that the plantlets were successfully grown under the LED Chamber System controlled with different light qualities and lighting types. Quantitative growth of the plantlets was improved under the shorter photoperiod with a intermittent lighting cycle compared with continuous lighting using fluorescent lamps. It is concluded that the growth and development of in vitro plantlets such as single-node cuttings can be achieved by the controlling of light quality or lighting type during the photoperiod per day with a lower electric cost compared with conventional continuous lighting system.

A Comparative Analysis on the Economic Effects Between New and Renewable- and Thermal- Power Generation in Korea (한국 신재생에너지발전과 화력발전의 경제적 파급효과 비교분석)

  • Kang, Ji Eun;Lee, Jung Ho;Park, Jung Gu
    • Journal of Energy Engineering
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    • v.26 no.3
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    • pp.51-63
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    • 2017
  • Paris Agreement on Climate Change(2015) requires to reduce the greenhouse gas emission. One of the responses to the requirement is to change the proportion of power generation, which is summarized to the decrease in thermal power and the increase in new and renewable power. This article conducts a comparative analysis on the economic effects between thermal- and new and renewable- power generations, using the Input-Output Table from The Bank of Korea. The results of this analysis show that the new and renewable power generation has got the larger effects in production-inducing, value-added-inducing, employment-inducing, and supply-shortage scopes, while the smaller effect in price-pervasive scope than the thermal power generation. According to these results, the complex consideration should be taken into when the changes in power generation mix are tried. Especially, the political efforts to reduce the supply-shortage effect of new and renewable power and the price-pervasive effect of thermal power will be important.

Column-aware Transaction Management Scheme for Column-Oriented Databases (컬럼-지향 데이터베이스를 위한 컬럼-인지 트랜잭션 관리 기법)

  • Byun, Si-Woo
    • Journal of Internet Computing and Services
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    • v.15 no.4
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    • pp.125-133
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    • 2014
  • The column-oriented database storage is a very advanced model for large-volume data analysis systems because of its superior I/O performance. Traditional data storages exploit row-oriented storage where the attributes of a record are placed contiguously in hard disk for fast write operations. However, for search-mostly datawarehouse systems, column-oriented storage has become a more proper model because of its superior read performance. Recently, solid state drive using MLC flash memory is largely recognized as the preferred storage media for high-speed data analysis systems. The features of non-volatility, low power consumption, and fast access time for read operations are sufficient grounds to support flash memory as major storage components of modern database servers. However, we need to improve traditional transaction management scheme due to the relatively slow characteristics of column compression and flash operation as compared to RAM memory. In this research, we propose a new scheme called Column-aware Multi-Version Locking (CaMVL) scheme for efficient transaction processing. CaMVL improves transaction performance by using compression lock and multi version reads for efficiently handling slow flash write/erase operation in lock management process. We also propose a simulation model to show the performance of CaMVL. Based on the results of the performance evaluation, we conclude that CaMVL scheme outperforms the traditional scheme.

A study on the electrochemical reduction of carbon dioxide (전기화학환원에 의한 이산화탄소의 수소화 반응연구)

  • Sim, Kyu-Sung;Kim, Jong-Won;Kim, Yeon-Soon;Myeong, Kwang-Sik
    • Transactions of the Korean hydrogen and new energy society
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    • v.9 no.1
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    • pp.8-15
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    • 1998
  • The catalytic hydrogenation of carbon dioxide has been studied for the fixation of carbon dioxide to mitigate global warming problems, but it needed hydrogen, which the price is still high. Recently, the electrochemical reduction of carbon dioxide has been drawn attractions because carbon dioxide could be converted to the valuable chemicals such as methane, ethane and alcohols electrochemically in the electrolyte solution using a catalytic electrode. This system is simple because the water electrolysis and hydrogenation take place at the same time using the surplus electricity at midnight. In this work, a continuous electrochemical reduction system was fabricated, which was composed of the reduction electrode (copper or perovskite type, $2{\times}2cm^2$), reference electrode(platinum, $2{\times}6cm^2$), standard electrode(Ag/AgCl), and potassium bicarbonate electrolyte solution saturated with carbon dioxide. The quality and quantity of the products and reduction current were analyzed, according to the electrolyte concentration and electrode type.

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A Study on the Performance of an 100 kW Class Tidal Current Turbine (100 kW급 조류발전용 터빈의 성능에 관한 연구)

  • Kim, Bu-Gi;Yang, Chang-Jo;Choi, Min-Seon
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.18 no.2
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    • pp.145-152
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    • 2012
  • As the problems of global warming are brought up recently, many skillful solutions for developing new renewable energy are suggested. One of the most remarkable things is ocean energy. Korea has abundant ocean energy resources owing to geographical characteristics surrounded by sea on three sides, thus the technology of commercialization about tidal current power, wave power is demanded. Especially, Tidal energy conversion system is a means of maintaining environment naturally. Tidal current generation is a form to produce electricity by installing rotors, generators to convert a horizontal flow generated by tidal current into rotating movement. According to rotor direction, a tidal current turbine is largely distinguished between horizontal and vertical axis shape. Power capacity depends on the section size crossing a rotor and tidal current speed. We therefore investigated three dimensional flow analysis and performance evaluation using commercial ANSYS-CFX code for an 100 kW class horizontal axis turbine for low water level. Then We also studied three dimensional flow characteristics of a rotating rotor and blade surface streamlines around a rotor. As a result, We found that torque increased with TSR, the maximum torque occurred at TSR 3.77 and torque decreased even though TSR increased. Moreover we could get power coefficient 0.38 at designed flow velocity.

Development of a New Commercial Grain Cooler (곡물냉각기의 개발)

  • 김동철;김의웅;금동혁;한종규
    • Food Science and Preservation
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    • v.11 no.2
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    • pp.250-256
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    • 2004
  • The objectives of this study were to develop a new commercial grain cooler suited to domestic weather and post-harvesting conditions for paddy, and to evaluate the performance. A prototype grain cooler capable of cooling paddy of 200 tons within 24 hours was developed. The grain cooler was designed to control the refrigeration capacity from 0 to 100% by controlling the capacity of compressor with unloading solenoid valve and by changing the flow rates of hot refrigerant gas flowing into reheater and evaporator from compressor. And a controller with one chip microprocessor was developed to control temperature and relative humidity of cooling air. The maximum cooling capacity of the grain cooler was 35,284㎉/hr at condensing/evaporating pressure of 16.5/3.6 kgf/$\textrm{cm}^2$. Maximum flow rate of cooling air was 120 ㎥/min at static pressure of 279 mmAq. The total maximum required power was 22.8㎾, and total required energy was saved from 26.7 to 33.3% of maximum power depending on operating conditions. The coefficient of performance of refrigeration devices and total coefficient of performance of the grain cooler were 4.71 and 1.8, respectively.

Global Trend of CO2 Capture Technology Development (이산화탄소 포집기술 국외 기술개발 동향)

  • Baek, Jeom-In
    • KEPCO Journal on Electric Power and Energy
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    • v.2 no.2
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    • pp.143-165
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    • 2016
  • The amount of greenhouse gas emission reduction based on INDCs (Intended Nationally Determined Contributions) submitted to UN by each party is not sufficient to achieve the Paris Agreement's aim to "hold the increase in the global average temperature to well below $2^{\circ}C$ above pre-industrial levels and to pursue efforts to limit the temperature increase to $1.5^{\circ}C$" which was determined in the $21^{st}$ Conference of the Parties to the UNFCCC (COP 21). Accordingly, the emission reduction target of each party will be revised for the $2^{\circ}C$ goal. Among the several options to reduce the carbon emission, CCS (Carbon Capture and Storage) is a key option to curb $CO_2$ emissions from large emission sources such as fossil-based power plants, cement plants, and steel production plants. A large scale CCS demonstration projects utilizing $1^{st}$ generation $CO_2$ capture technologies are under way around the world. It is anticipated, however, that the deployment of those $1^{st}$ generation $CO_2$ capture technologies in great numbers without government support will be difficult due to the high capture cost and considerable increase of cost of electricity. To reduce the carbon capture cost, $2^{nd}$ and $3^{rd}$ generation technologies are under development in a pilot or a bench scale. In this paper, current status of large scale CCS demonstration projects and the $2^{nd}$ and $3^{rd}$ generation capture technologies are summarized. Novel capture technologies on wet scrubbing, dry sorbent, and oxygen combustion are explained in detail for all capture areas: post-combustion capture, pre-combustion capture, and new combustion technologies.

Electricity Generation and Microbial Community Structure Variation Depending on Separator Types and Cathode Characteristics in Air-cathode MFC (공기환원전극 미생물연료전지에서 분리막 종류 및 환원전극 특성에 따른 전기발생 및 미생물 군집구조 변화)

  • Yu, Jae-Cheul;Lee, Chang-Yeol;Kim, Sun-Ah;Cho, Hae-In;Cho, Sun-Ja;Lee, Tae-Ho
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.2
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    • pp.113-120
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    • 2010
  • Air-cathode microbial fuel cell consisted of 4 unit cells were operated under batch condition and electricity generation and microbial community structure variation were investigated, depending on separator types and cathode characteristics: A) PEM(Proton Exchange Membrane)-30% Wet proofing Carbon Cloth(WC), B) AEM(Anion Exchange Membrane-WC, C) CEM(Cation Exchange Membrane)-WC, D) PEM-No Wet proofing Carbon Cloth(NC). Maximum power densities of PEM-WC, AEM-WC and CEM-WC were 510.9, 522.1 and 504.8 $mW/m^2$, respectively. But PEM-NC showed relatively lower maximum power density of 218.3 $mW/m^2$. And PEM-WC, AEM-WC and CEM-WC showed similar internal resistances(20.0-28.2 ${\Omega}$). PCRDGGE, PCA and diversity indices showed that uncultured bacteria which reported in previous MFC studies were detected in suspended growth bacteria and attached growth bacteria would be affected not by separator type but by cathode characteristic. Thus, cathode characteristic can be one of the critical factors for power generation in air-cathode MFC using PEM, AEM, and CEM as separator.

A Design of Pipelined Adaptive Decision-Feedback Equalized using Delayed LMS and Redundant Binary Complex Filter Structure (Delayed LMS와 Redundant Binary 복소수 필터구조를 이용한 파이프라인 적응 결정귀환 등화기 설계)

  • An, Byung-Gyu;Lee, Jong-Nam;Shin, Kyung-Wook
    • Journal of the Institute of Electronics Engineers of Korea SD
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    • v.37 no.12
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    • pp.60-69
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    • 2000
  • This paper describes a single-chip full-custom implementation of pipelined adaptive decision-feedback equalizer(PADFE) using a 0.25-${\mu}m$ CMOS technology for wide-band wireless digital communication systems. To enhance the throughput rate of ADFE, two pipeline stages are inserted into the critical path of the ADFE by using delayed least-mean-square(DLMS) algorithm. Redundant binary (RB) arithmetic is applied to all the data processing of the PADFE including filter taps and coefficient update blocks. When compared with conventional methods based on two's complement arithmetic, the proposed approach reduces arithmetic complexity, as well as results in a very simple complex-valued filter structure, thus suitable for VLSI implementation. The design parameters including pipeline stage, filter tap, coefficient and internal bit-width, and equalization performance such as bit error rate (BER) and convergence speed are analyzed by algorithm-level simulation using COSSAP. The single-chip PADFE contains about 205,000 transistors on an area of about $1.96\times1.35-mm^2$. Simulation results show that it can safely operate with 200-MHz clock frequency at 2.5-V supply, and its estimated power dissipation is about 890-mW. Test results show that the fabricated chip works functionally well.

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