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삼중접합 실리콘 박막 태양전지 고효율화를 위한 a-$SiO_x$ 상부전지 특성 연구

  • Lee, JiEun;Jo, Jun Sik;Park, Sang Hyun;Yoon, Kyung Hoon;Song, Jinsoo;Kim, Dong Hwan;Lee, Jeong Chul
    • 한국신재생에너지학회:학술대회논문집
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    • 2010.06a
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    • pp.63.2-63.2
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    • 2010
  • 삼중접합 태양전지에 상부전지로 이용되는 a-SiO:H 태양전지는 PECVD(Plasma Enhanced Chemical Vapour Deposition)을 이용하여 증착하였다. i a-SiO:H는 $CO_2/SiH_4$ 비율을 변화하여 밴드갭을 조절하였다. $CO_2/SiH_4$가 0에서 0.43으로 증가 할수록 밴드갭이 1.74 eV에서 1.94 eV로 증가하는 경향을 보였다. 이는 FTIR에서 나타난 결과인 Si-O-Si 결합의 증가 때문인 것으로 판단한다. 그에 반해서 광 전도도는 감소하는 경향을 보였다.그러나 암전도도와 광전도도의 비율인 광민감도는 $10^5$에서 $10^4$의 값으로 비정질 태양전지에 적용가능한 값을 보였다. 이러한 박막 특성을 가진 i a-SiO:H를 이용하여 비정질 실리콘 태양전지를 제작한 결과 $CO_2/SiH_4$의 비율이 증가함에 따라 태양전지의 $V_{oc}$가 0.8 V에서 0.5 V로 현저하게 감소하였고, $J_{sc}$와 FF 역시 11 $mA/cm^2$에서 4 $mA/cm^2$, 69%에서 50%로 감소하였다. 단위박막 결함을 측정하는 CPM(Constant Photocurrent Method)을 이용하여 i a-SiO:H 내부에 $10^{16}cm^{-3}$ 정도의 내부 결함을 관찰하였고 이는 태양전지의 특성 감소와 관련이 있는 것으로 판단한다.

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Analysis of Lateral Behavior of PSC Bridge Girders under Wind Load During Construction (시공 중 풍하중에 의한 PSC 교량 거더의 횡방향 거동 해석)

  • Lee, Jong-Han;Kim, Kyung Hwan;Cho, Baiksoon
    • Journal of the Korea Concrete Institute
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    • v.27 no.4
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    • pp.377-385
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    • 2015
  • The span-lengthening of PSC I girder has increased the risk of lateral instability of the girder with the increases in the aspect ratio and self-weight of the girder. Recently, collapses of PSC I girder during construction raise the necessity of evaluating the lateral instability of the girder. Thus, the present study evaluated the lateral behavior and instability of PSC I girders under wind load, regarded as one of the main causes of the roll-over collapse during construction. Lateral instability of the girder is mainly dependent on the length of the girder and the stiffness of the support. The analysis results of this study showed the decrease in the critical wind load and the increase in the critical deformation and angle of the girder, leading to the lateral instability of the girder. Finally, this study proposed analytical equations that can predict the critical amount of wind load and lateral deformation of the girder, which would provide quantitative management values to maintain lateral stability of PSC I girder during construction.

Experimental Study for Dynamic Characteristics of Eddy Current Shock Absorber (와전류 충격완충장치의 실험적 동특성 연구)

  • Kwag, Dong-Gi;Hwang, Jai-Hyuk;Bae, Jae-Sung
    • Journal of the Korean Society for Aeronautical & Space Sciences
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    • v.35 no.12
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    • pp.1089-1094
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    • 2007
  • This paper is concerned with a new concept for the damper without neither a coil spring nor fluid. The new damper concept consists of the permanent magnets and the cylinder of the conducting material. The opposite pole magnets produces the repulsive forces and this is substituted for the coil spring. The relative motion between the magnets and conducting cylinder produces eddy currents thus resulting in the electromagnetic force, which turns out to be the damping force and is substituted for a damping fluid. This damper is called the eddy current damper(ECD). The important advantage of the proposed ECD is that it does not require any damping fluid and any external power and is non-contacting and relatively insensitive to temperature. In the present study, the proposed ECD was constructed and the experiments were performed to investigate its dynamic characteristics. The experiments shows that the proposed ECD has the excellent damping ability.

Transport and Distribution of Calcium Salt in Tofu Manufacturing Process -Part I. Conductometric Measurement of Calcium Salt in Tofu and Drained Solution- (두부제조공정(製造工程)중 Calcium 염(鹽)의 행동(行動)과 분포(分布) -제1보(第一報). 전기전도도법(電氣傳導度法)에 의한 두부 및 순물의 Calcium 농도 측정방법(測定方法)-)

  • Yim, Sang-Bin;Lee, Choon-Ki;Chun, Jae-Kum
    • Applied Biological Chemistry
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    • v.28 no.1
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    • pp.8-12
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    • 1985
  • For measuring calcium content during the manufacturing process of Tofu, conductometric electrodes were made with the copper plate, and the results were compared with chemical analysis methods. Three types of plate material (I, II, III) for electrode were tested to apply for measuring $CaCl_2$ content in solution, drained solution from Tofu and in agar-agar gel ana Tofu. Empirical linear correlation equations between conductivity (Y, mho) and calcium content (C, Mole $\bar{C}$, mg% wet basis) were obtained for the quick estimation of calcium content during Tofu processings. Equations with plate II type electrode were Y=0.6364C+0.0775 for drained solution with r=0.99, and $Y=7.1503{\times}10^{-5}\bar{C}-2.9895{\times}10^{-3}$ for Tofu with r=0.91,respectively.

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Groundwater Flow Characterization in the Vicinity of the Underground Caverns by Groundwater Level Changes (지하수위 변화에 따른 지하공동 주변의 지하수 유동특성 해석)

  • 강재기;양형식;김경수;김천수
    • Tunnel and Underground Space
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    • v.13 no.6
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    • pp.465-475
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    • 2003
  • Groundwater inflow into the caverns constructed in fractured rock mass was simulated by numerical modeling, NAPSAC (DFN, discrete fracture network model) and NAMMU (CPM, continuous porous media model), a finite-element software package for groundwater flow in 3D fractured media developed by AEA Technology, UK. The input parameters for modeling were determined on surface fracture survey, core logging and single hole hydraulic test data. In order to predict the groundwater inflow more accurately, the anisotropic hydraulic conductivity was considered. The anisotropic hydraulic conductivities were calculated from the fracture network properties. With a minor adjustment during model calibration, the numerical modeling is able to reproduce reasonably groundwater inflows into cavern and the travel length and times to the ground surface along the flow paths in the normal, dry and rainy seasons.

Measurement of thermal conductivity of fluid by unsteady hot wire method (非定常 熱線法 에 의한 流體 의 熱傳達率 測定)

  • 고상근;양상식;노승탁
    • Transactions of the Korean Society of Mechanical Engineers
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    • v.8 no.2
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    • pp.154-161
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    • 1984
  • A modified technique of the transient hot wire method to measure the thermal conductivity of fluid has been described in this paper. The thermal conductivity of fluid can be obtained by acquiring wire temperature as a function of time. Multiplication of the inverse slope of the temperature versus logarithm of time by an instrumental constant gives the thermal conductivity. The constant voltage was applied to Wheatstone bridge circuit. The wire temperature can be measured as a function of time precisely with the aid of the data acquisition system composed of a microprocessor and an analog-digital converter. The thermal conductivity of the electrically conducting fluid has been measured with the insulated hot wire coated by electrically non-conducting material. The effect of the coated insulation layer on the thermal conductivity has been examined, in which it is confirmed that the thermal conductivity of electrically conducting liquid can be determined by the transient coated hot wire method. Thermal conductivities of methanol, carbontetrachrolide, Freon-22 and glycerin have been measured at room temperature in the pressure from 0.1MPa to 35.1MPa. The experiment has been performed to compare the data from the bare and the coated wires, and the results are satisfactory.

A Study on the Hydration and Strength of Accelerated Curing Concrete (가열양생(加熱養生) 콘크리트의 수화(水和) 및 강도(强度)에 관한 연구(研究))

  • Shin, Hyun Mook;Jeon, Chan Ki;Nam, In
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.7 no.3
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    • pp.203-212
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    • 1987
  • The hydration and strength of concrete are affected by curing conditions, especially curing temperature. In this paper, the hydration temperature of heated curing concrete specimen are measured by thermo-couples instead of conduction calorimeter, and strengths of concrete are tested. The results of this study show that the compressive strengths of concrete are especially dependent on the curing temperature. And the strength results of concrete agree approximately with the results of approach to the hydration process of cement concrete.

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The studies on synthesis of aluminum oxide and boron oxide co-doped zinc oxide(AZOB) powder by spray pyrolysis (분무열분해법(Spray Pyrolysis)에 의한 알루미늄 산화물과 보론 산화물이 함께 도핑된 산화아연(AZOB: $Al_2O_3$ and $B_2O_3$ Co-doped Zinc Oxide)의 분말 제조에 대한 연구)

  • Kim, Sang Hern
    • Journal of the Korean Applied Science and Technology
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    • v.31 no.4
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    • pp.731-739
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    • 2014
  • Aluminum and boron co-doped zinc-oxide(AZOB) powders as transparent conducting oxide(TCO) were prepared by spray pyrolysis at $900^{\circ}C$. The micron-sized AZOB particles were prepared by spray pyrolysis from aqueous precursor solutions for aluminium, boron, and zinc. The micron-sized AZOB particle after the spray pyrloysis underwent post-heat treatment at $700^{\circ}C$ for 2 hours and it was changed fully to nano-sized AZOB particle by ball milling for 24 hours. The size of primary AZOB particle by Debye-Scherrer Equation and surface resistance of AZOB pellet were measured.

Effect of Rapid Thermal Annealing on the Properties of Nitrogen-doped $In_2O_3$ Thin Films

  • Tak, Seong-Geon;Kim, Jun-Yeong;O, Seok-Hyeon;Jeong, Min-Jae;Kim, Chun-Su;Jo, Sin-Ho
    • Proceedings of the Korean Vacuum Society Conference
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    • 2011.08a
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    • pp.243-244
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    • 2011
  • 최근에 산화물 반도체를 평판 디스플레이와 태양 전지의 투명 전극으로 응용하기 위해 많은 연구가 진행중에 있다. 특히, $In_2O_3$ 박막은 투명 전도 산화막으로써 3.7 eV의 직접 전이 밴드갭 에너지를 갖고 가시광 영역에서 높은 투과도를 갖는 반도체이어서 다양한 영역에서 응용 가능하다. 본 연구는 낮은 비저항과 높은 투과율을 갖는 최적의 투명 전도막을 성장시키기 위하여 라디오파 반응성 마그네트론 스퍼터링 방법을 사용하여 질소 도핑된 $In_2O_3$ 박막을 유리 기판 상부에 증착하였고, 후열처리로 온도 400, 450, 500, 550$^{\circ}C$에서 급속 열처리를 수행하여, 증착된 박막의 구조, 표면, 광학, 전기적 특성을 조사하였다. 증착된 박막은 XRD를 사용하여 구조적 특성을 조사한 결과, $2{\theta}=30.2^{\circ}$와 43.95$^{\circ}$에서 상대적으로 강한 피크가 관측되었다(Fig. 1). 전자는 (222)면에서 회절된 피크이며, 후자는 (100)면에서 발생한 회절 피크이다. 열처리 온도가 0$^{\circ}C$에서 500$^{\circ}C$로 증가함에 따라 (222) 면의 회절 신호의 세기는 상대적으로 증가하였고, 550$^{\circ}C$에서 급격하게 감소하였다. 박막의 광학적 특성은 자외선-가시광선 분광기를 사용하여 광학 흡수율과 투과율을 측정하였다(Fig. 2). 열처리를 하지 않은 박막의 경우에, 파장 200~1,100 nm 범위에서 측정된 평균투과율은 76%이었다. 광학 흡수 계수와 광자 에너지의 관계를 나타내는 포물선 관계식을 기초로 하여 광학 밴드갭 에너지를 계산하였다. 박막의 전기적 특성의 경우에, Hall 효과를 측정하여 전하 운반자 농도, 홀 이동도, 전기 비저항을 조사한 결과, 전기적 특성은 열처리 온도에 상당한 의존성을 나타냄을 알 수 있었고, 열처리 온도 500$^{\circ}C$에서 박막의 비저항값은 $4.0{\times}10^{-3}{\Omega}cm$이었다.

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Preparation and Characterizations of Sulfonated Graphene Oxide (sGO)/Nafion Composite Membranes for Polymer Electrolyte Fuel Cells (고분자 전해질막 연료전지(PEMFCs)용 Sulfonated Graphene Oxide (sGO)/Nafion 복합막의 제조 및 특성분석)

  • Shin, Mun-Sik;Kang, Moon-Sung;Park, Jin-Soo
    • Membrane Journal
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    • v.27 no.1
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    • pp.53-59
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    • 2017
  • In this study, the composite membranes prepared by sulfonated graphene oxide (sGO) and Nafion were developed as proton exchange membranes (PEMs) for polymer electrolyte membrane fuel cells (PEMFCs). The sGO/Nafion composite membranes were prepared by mixing Nafion solution with the sGO dispersed in a binary solvent system to improve dispersity of sGO. The composite membranes were investigated in terms of ionic conductivity, ion exchange capacity (IEC), FT-IR, TGA and SEM, etc. As a result, the binary solvent system, i.e., ortho-dichlorobenzene (ODB) and N,N-dimethylacetamide (DMAc), were used to obtain high dispersion of sGO particles in Nafion solution, and the ionic conductivity of the sGO/Nafion composite membrane showed $0.06Scm^{-1}$ similar to other research results at lower water uptake, 11 wt%.