• 한국신재생에너지학회:학술대회논문집
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• 2005.06a
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• pp.248-251
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• 2005

Graphite reinforced conductive polymer composites for PEMFC bipolar plates were fabricated by the compression molding technique. Graphite powder was mixed with an phenol resin to impart electrical property in composites. In this study, conductive polymer composites with high filler $loadings(>60wt.\%)$ were manufactured to accomplish high electrical conductivity above 100S/cm. The level of compaction is important because graphite powder increase electrical conductivity of composites by direct physical contact between particles. The optimum molding pressure according to filler was proposed experimentally. Various tests(electrical conductivity, flexural strength, compressive strength, leach test, etc) were carried out to verify the performance of fabricated composites for PEMFC bipolar plates. Fabricated composites have good electrical conductivity and mechanical strength. The results of leach test and contact angle measurement showed similar characteristics compared with commercial bipolar plates.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2005.04a
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• pp.257-260
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• 2005

Graphite reinforced conductive polymer composites were fabricated by the compression molding technique. Graphite powder was mixed with an phenol resin to impart electrical property in composites. The ratio and particle size of graphite powder were varied to investigate electrical conductivity of cured composites. In this study, graphite reinforced conductive polymer composites with high filler loadings(>66wt.%) were manufactured to accomplish high electrical conductivity. With increasing the loading ratio of graphite powder, the electrical conductivity and flexural strength increased. However. above 80wt.% filler loadings, flexural strength decreased due to lack of resin. Regardless of graphite particle size, electrical conductivity wasn’t varied. On the other hand, with decreasing particle size, flexural strength increased due to high specific surface area.

• Proceedings of the Korean Society For Composite Materials Conference
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• 2004.04a
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• pp.147-150
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• 2004

Graphite reinforced conductive polymer composites were fabricated by the compression molding technique. Graphite powder (conductive filler) was mixed with an epoxy resin to impart electrical property in composites. The ratio of graphite powder was varied to investigate electrical property of cured conductive composites. In this study, graphite filled conductive polymer composites with high filler loadings$(>60wt.\%)$ were manufactured to accomplish high electrical conductivity(> 100S/cm). Graphite powder increase electrical conductivity of composites by direct physical contact between particles. While high filler loadings are needed to attain good electrical property, the composites becomes brittle. So the ratio of filler to epoxy was varied to optimize of cured composites. The optimum molding pressure according to filler was proposed experimentally.

• Polymer(Korea)
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• v.38 no.4
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• pp.502-509
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• 2014

Carbon-based nanoplatelets such as graphene oxide (GO) sheets and graphite nanoplatelets (GNPs) are frequently used as conductive nanofillers for polymer nanocomposites. In this study, polystyrene (PS)/GO and PS/GNP nanocomposites were prepared through a latex technology and investigated to compare the effect of nanofillers on rheological and electrical properties of the PS nanocomposites. PS particles were prepared by emulsifier-free emulsion polymerization and GO was synthesized by using the modified Hummers' method from graphite. Hydrophilic GO was dispersed in aqueous PS suspension, but hydrophobic GNPs were dispersed with the help of a surfactant. In comparison with PS/GO nanocomposites, the rheological properties of PS/GNP counterparts were not too high because GNP existed in aggregates of graphene layers. Conducting pathways of PS/GO and PS/GNP nanocomposites were achieved at the electrical percolation threshold of 0.50 and 5.82 wt%, respectively. The reason for enhanced electrical conductivity in PS/GO nanocomposites is that GO was thermally reduced during molding.

• Composites Research
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• v.35 no.6
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• pp.431-438
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• 2022

Efficient heat dissipation in current electronics is crucial to ensure the best performance and lifespan of the devices along with the users' safety. Materials with high thermal conductivity are often used to dissipate the generated heat from the electronics to the surroundings. For this purpose, polymer composites have been attracted much attention as they possess advantages rooted from both polymer matrix and thermally conductive filler. In order to meet the thermal conductivity required by relevant industries, composites with high filler loadings (i.e., >60 vol%) have been fabricated. At such high filler loadings, however, composites lose benefits originated from the polymer matrix. To achieve high thermal conductivity at a relatively low filler loading, therefore, constructing the heat conduction pathway by controlling filler structure within the composites may represent a judicious strategy. To this end, this review introduces several recent approaches to manufacturing heat dissipating materials with high thermal conductivity by manipulating thermally conductive filler structures in polymer composites.

• Composites Research
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• v.29 no.6
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• pp.401-407
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• 2016

IPMC is composed of thin ion conductive polymer film sandwiched between metallic electrodes plated on both surfaces. Ionic Polymer-Metal Composite (IPMC) generates voltages when bent by mechanical stimuli. IPMC has a potential for the variety of energy harvesting applications due to its soft and hydrophilic characteristics. However, the large-scale implementation is necessary to increase the output power. In this paper, the scale-up of surface area effect on voltage generation characteristics of IPMC was investigated using IPMC samples with different surface areas. Also, a circuit model simulating both the output voltage and its offset variations was designed for estimating the voltages from IPMC samples. The proposed model simulated the output voltages with offsets well corresponding to various frequencies of input bending motion. However, some samples showed that the increase of error between real and simulated voltages with time due to the nonlinear characteristic of offset variations.

• Polymer(Korea)
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• v.36 no.3
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• pp.364-371
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• 2012

Polystyrene/single-walled carbon nanotube (PS/SWCNT) nanocomposites were prepared by latex technology and the effect of surfactant (SDS) on nanotube dispersion, rheological and electrical properties was investigated. The nanocomposites were prepared through freeze-drying after mixing PS particles and aqueous SWCNT/SDS suspension. As the SDS content increased, the storage modulus and complex viscosity of the nanocomposites were increased due to enhanced dispersion of nanotubes, but if the content excessively increased, the modulus and viscosity began to decrease due to low molecular weight of SDS. The electrical conductivity sharply increased with the addition of SDS, and then did not show significant changes. This result is speculated to be the competition between the increased dispersion of nanotubes and the deterioration of electrical conductivity by SDS adsorption. An optimal ratio of SDS to SWCNT for improving electrical conductivity and end-use properties was 2. With this ratio, the electrical percolation threshold of SWCNT was less than 1 wt%.

• Polymer(Korea)
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• v.27 no.3
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• pp.265-270
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• 2003

In spite of high ionic conductivity, the polymer gels have poor mechanical properties and high reactivity with lithium metal anode. To solve these problems, the dry solid systems and polymer composites have been intensively studied, due to their good mechanical, thermal, chemical, and electrochemical stability. The objectives of this experiment were to improve ionic conductivity and mechanical properties of the solid polymer electrolytes based on PEO-LiClO$_4$. To obtain higher ionic conductivity and better mechanical properties, ceramic or rubber phase was added in the PEO-LiClO$_4$(8:1) matrix. The results showed that ionic conductivity and mechanical properties were improved. The ionic conductivity of the samples was as high as 10$\^$-5/ S cm$\^$-1/. This value is similar to the best ionic conductivity ever reported in the solid drying system. To obtain better results, we used PEO with various molecular weights (600∼8000) and changed the salt contents. By using DSC, we found that the addition of salt reduced the crystallinity of PEO. The mobility of polymer dependence on salt contents was examined by FT-IR.

• Applied Chemistry for Engineering
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• v.33 no.2
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• pp.210-215
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• 2022

Two types of lignin materials with a different surface ionic character were used and polypyrrole layer was introduced on the lignin surface to obtain polypyrrole@lignin and polypyrrole@lignosulfonate composites using a simple chemical oxidation polymerization, reported in a previous article. Polypyrrole was effectively prepared regardless of the lignin type and the resulting composites were investigated using scanning electron microscope (SEM), cyclic voltammetry (CV), and impedance analysis. SEM and CV results showed that the obtained composites retained stable electrochemical properties after introduction of polypyrrole on the lignin surface. Impedance analyses showed that the surface properties of composites were dependent on lignin characteristics. In addition, the composites were embedded in agarose, an gelifying agent, to obtain conductive gels. It was found that the conductive gels possessed an electrical conductivity and also retained stable electrochemical properties, which indicated that the conductive gels might be useful for some applications.

• Composites Research
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• v.35 no.3
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• pp.175-181
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• 2022

Due to the increasing number of wireless communication devices in mmWave frequency bands, there is a high demand for electromagnetic interference (EMI) shielding and heat dissipating materials to avoid device malfunctions. This paper proposes an EMI shielding composite film with a high heat dissipation characteristic. To achieve this, a conductive grid is integrated with a polymer-based composite layer including magnetic and heat dissipating filler materials. A high shielding effectiveness (>40 dB), low reflection shielding effectiveness (<3 dB), high thermal conductivity (>10 W/m·K), thin thickness (<500 ㎛) are simultaneously achieved with a tailored design of composite layer compositions and grid geometries in 5G communication band of 26.5 GHz.