• Title/Summary/Keyword: 전기화학 센서

Search Result 351, Processing Time 0.025 seconds

Study on Basic Properties of Single Crystalline ZnO Nanowire (단결정 산화아연 나노선의 기초 물성 연구)

  • Ra, H.W.;Khan, R.;Kim, J.T.;Yeo, C.H.;Im, Y.H.
    • Journal of the Korean Vacuum Society
    • /
    • v.18 no.4
    • /
    • pp.259-265
    • /
    • 2009
  • We fabricated the field effect transistor using single crystalline ZnO nanowires synthesized by a conventional thermal evaporation method and investigated their basic properties under the various conditions such as ultraviolet irradiation, reducing gas and electrolyte. The typical carrier concentration and mobility of the single crystalline ZnO nanowire with a diameter of 100 nm and length of 5 um were $1.30{\times}10^{18}cm^{-3}$ and $15.6cm^2V^{-1}s^{-1}$, respectively. The current of ZnO nanowire under ultraviolet irradiation significantly increased about 400 times higher as compared to in the darkness. In addition, the ZnO nanowire showed typical sensing characteristics for $H_2$ and CO due to well-known surface reactions and typical current-voltage characteristics under the 0.1 M NaCl electrolyte.

Fluvial mixing characteristics in large scale confluence between Nam and Nakdong River (남강-낙동강 합류부 대하천 규모 수리학적 혼합특성 연구)

  • Choi, Suin;Kim, Dongsu;Son, Geunsoo;Kim, Youngdo;Lyu, Siwan
    • Proceedings of the Korea Water Resources Association Conference
    • /
    • 2022.05a
    • /
    • pp.264-264
    • /
    • 2022
  • 하천의 합류부는 두 개 이상의 하천이 하나로 합쳐지는 구간으로 서로 다른 특성으로 인해 급격한 흐름의 변화와 수리학적 지형변화가 발생하는 구간이다. 하천의 합류부에서는 유체의 물리화학적인 특성과 흐름 구조의 변화가 발생할 수 있다. 흐름 구조의 변화로 인한 유사 이송으로 세굴과 같은 지형적인 변화가 발생할 수 있다. 합류부의 혼합을 이해하기 위해서는 본류와 지류의 다양한 유입조건에 따른 공간적인 패턴을 분석하는 것이 중요하다. 그러나, 대부분의 합류부 연구들은 실측에 기반한 공간적인 패턴 분석의 어려움으로 인해 실내실험 또는 수치모형에 의존하여 연구가 수행되어, 실측자료에 기반한 공간적인 수체혼합의 분석은 매우 제한적이었다. 따라서, 본 연구에서는 하천 합류부의 혼합 현상을 규명하는 인자로 흐름 방향 유속, 2차류와 수심 등 기본적인 수리학적 인자들 외에 연직, 수평 방향으로 측정한 수질 자료와 드론 영상을 활용하여 합류부의 혼합 특성을 해석하고자 하였다. 수질 자료 중 하천의 혼합을 가장 잘 확인할 수 있는 인자로써 전기전도도와 온도를 활용하였다. SonTek ADCP를 이동식으로 횡단하여 측정해 흐름 방향 유속과 2차류, 수심을 확인하였다. ADCP를 운용함과 동시에 YSI의 수질센서를 활용하여 연직, 수평 방향으로의 전기전도도와 온도의 분포를 확인하였다. 또한, 합류부의 2차원 공간적인 분포를 확인하기 위해 드론 영상을 촬영하였다. ADCP, YSI, 드론의 계측자료는 한국의 낙동강과 남강 합류부에서 측정되었고, 분석 결과 계측장비 간의 경향성이 일치하였다. 또한, 이전에 진행된 해외의 합류부 연구 결과와 유사한 결과가 관측되었으나, 일부 부분에서는 다른 결과를 보였다.

  • PDF

Dual Photonic Transduction of Porous Silicon for Sensing Gases (이중의 광학적 변화를 이용한 다공성 실리콘 가스센서 제작)

  • Koh, Young-Dae;Kim, Sung-Jin;Jang, Seung-Hyun;Park, Cheol-Young;Sohn, Hong-Lae
    • Journal of the Korean Vacuum Society
    • /
    • v.16 no.2
    • /
    • pp.99-104
    • /
    • 2007
  • Porous silicon exhibiting dual optical properties, both $Febry-P{\acute{e}}rot$ fringe (optical reflectivity) and photoluminescence had been developed and used as chemical sensors. Porous silicon samples were prepared by an electrochemical etch of p-type silicon wafer (boron-doped, <100> orientation, resistivity ; $1-10{\Omega}cm$). Two different types of porous silicon, fresh porous silicon (Si-H terminated) and oxidized porous silicon (Si-OH terminated)by the thermal oxidation, were prepared. Then the samples were exposed to the vapor of various organics, such as methanol, acetone, hexane, and toluene. Both reflectivity and photoluminescence were simultaneously measured under the exposure of organic vapors for sensing VOC's. These surface-modified samples showed unique respond in both reflectivity and photoluminescence with various organic vapors. While polar molecules exhibit greater quenching photoluminescence, molecules having higher vapor pressure show greater red shift for reflectivity.

I-V Characteristics of a Methanol Sensor for Direct Methanol fUel Cell(DMFC) as a Function of Deposited Platinum(Pt) Thickness (직접 메탄올 연료전지용 메탄올 센서의 백금 두께의 변화에 따른 전류-전압 특성 변화)

  • Yang, Jin-Seok;Kim, Seong-Il;Kim, Chun-Keun;Park, Jung-Ho
    • Journal of the Microelectronics and Packaging Society
    • /
    • v.14 no.1
    • /
    • pp.49-53
    • /
    • 2007
  • The direct methanol fuel cell (DMFC) is a promising power source for portable applications due to many advantages such as simple construction, compact design, high energy density, and relatively high energy-conversion efficiency. In this work, an electrochemical methanol sensor for monitoring the methanol concentration in direct methanol fuel cells was fabricated using a thin composite nafion membrane as the electrolyte. We have analyzed the I-V characteristic of the fabricated methanol sensor as a function of methanol concentration, catalyst electrode and platinum(Pt) thickness. The fabricated sensor was analyzed by I-V measurement with various methanol concentration. When we measured the sensor characteristics with 10nm Pt and at 1V, the current value was $1.30{\times}10^{-6}A,\;1.96{\times}10^{-6}A\;and\;2.80{\times}10^{-6} A$ for three methanol concentration of 1M, 2M and 3M, respectively. When the methanol concentration was fixed at 2M, the current value of the fabricated device with Pt layers of 5, 10 and 15 nm thickness was $3.06{\times}10^{-6}A,\;1.96{\times}10^{-6}A\;and\;1.00{\times}10^{-6}A$, respectively. These results lead us to the conclusion that when the methanol concentration increases, the output current increases and when the catalyst electrode become thinner, the current increase more. It showed that, the thinner the catalyst electrode, the more electrochemistry become activation.

  • PDF

One-component Room Temperature Vulcanizing-Type Silicone Rubber-Based Solid-State Carbonate Ion Selective Electrode (단일 조성 실온 경화형 실리콘러버를 지지체로 사용한 고체상 탄산이온선택성 전극의 개발)

  • Kim, Mi-Kyoung;Yoon, In-Jun;Cho, Sung-Ho;Shin, Hye-Ra;Han, Jong-Ho;Ha, Jeong-Han;Nam, Hak-Hyun;Cha, Geun-Sig
    • Journal of the Korean Chemical Society
    • /
    • v.48 no.3
    • /
    • pp.266-272
    • /
    • 2004
  • We developed a miniaturized solid-state carbonate ion-selective electrode (carbonate ISE) based on one-component room temperature vulcanizing type silicone rubber 730 (730 RTV) without adding plasticizer to the matrix. The optimized carbonate ion selective membrane is prepared with 85.8 wt% of 730 RTV, 11.1 wt% of trifluoroacetyl-p-decylbenzene (TFADB), and 3.1 wt% of tridodecyl-methylammonium chloride (TDMACl). This carbonate ISE exhibited excellent potentiometric properties (i.e., slope: 26.3 mV/dec; selectivity: $logKT^{pot}_{CO_{2},Cl^-}$= -4.00 and $logKT^{pot}_{TCO_{2},Sal^-}$=1.69); and detection limit for $TCO_2:\;4.0{\times}10^{-4}M$). In addition, the early potentiometric properties of the solid-state sensor with optimized membrane composition were not deteriorated for more than 60 days.

Fabrication of Label-Free Biochips Based on Localized Surface Plasmon Resonance (LSPR) and Its Application to Biosensors (국소 표면 플라즈몬 공명 (LSPR) 기반 비표지 바이오칩 제작 및 바이오센서로의 응용)

  • Kim, Do-Kyun;Park, Tae-Jung;Lee, Sang-Yup
    • KSBB Journal
    • /
    • v.24 no.1
    • /
    • pp.1-8
    • /
    • 2009
  • In the past decade, we have observed rapid advances in the development of biochips in many fields including medical and environmental monitoring. Biochip experiments involve immobilizing a ligand on a solid substrate surface, and monitoring its interaction with an analyte in a sample solution. Metal nanoparticles can display extinction bands on their surfaces. These charge density oscillations are simply known as the localized surface plasmon resonance (LSPR). The high sensitivity of LSPR has been utilized to design biochips for the label-free detection of biomolecular interactions with various ligands. LSPR-based optical biochips and biosensors are easy to fabricate, and the apparatus cost for the evaluation of optical characteristics is lower than that for the conventional surface plasmon resonance apparatus. Furthermore, the operation procedure has become more convenient as it does not require labeling procedure. In this paper, we review the recent advances in LSPR research and also describe the LSPR-based optical biosensor constructed with a core-shell dielectric nanoparticle biochip for its application to label-free biomolecular detections such as antigen-antibody interaction.

Stand-alone Real-time Healthcare Monitoring Driven by Integration of Both Triboelectric and Electro-magnetic Effects (실시간 헬스케어 모니터링의 독립 구동을 위한 접촉대전 발전과 전자기 발전 원리의 융합)

  • Cho, Sumin;Joung, Yoonsu;Kim, Hyeonsu;Park, Minseok;Lee, Donghan;Kam, Dongik;Jang, Sunmin;Ra, Yoonsang;Cha, Kyoung Je;Kim, Hyung Woo;Seo, Kyoung Duck;Choi, Dongwhi
    • Korean Chemical Engineering Research
    • /
    • v.60 no.1
    • /
    • pp.86-92
    • /
    • 2022
  • Recently, the bio-healthcare market is enlarging worldwide due to various reasons such as the COVID-19 pandemic. Among them, biometric measurement and analysis technology are expected to bring about future technological innovation and socio-economic ripple effect. Existing systems require a large-capacity battery to drive signal processing, wireless transmission part, and an operating system in the process. However, due to the limitation of the battery capacity, it causes a spatio-temporal limitation on the use of the device. This limitation can act as a cause for the disconnection of data required for the user's health care monitoring, so it is one of the major obstacles of the health care device. In this study, we report the concept of a standalone healthcare monitoring module, which is based on both triboelectric effects and electromagnetic effects, by converting biomechanical energy into suitable electric energy. The proposed system can be operated independently without an external power source. In particular, the wireless foot pressure measurement monitoring system, which is rationally designed triboelectric sensor (TES), can recognize the user's walking habits through foot pressure measurement. By applying the triboelectric effects to the contact-separation behavior that occurs during walking, an effective foot pressure sensor was made, the performance of the sensor was verified through an electrical output signal according to the pressure, and its dynamic behavior is measured through a signal processing circuit using a capacitor. In addition, the biomechanical energy dissipated during walking is harvested as electrical energy by using the electromagnetic induction effect to be used as a power source for wireless transmission and signal processing. Therefore, the proposed system has a great potential to reduce the inconvenience of charging caused by limited battery capacity and to overcome the problem of data disconnection.

Fabrication and Electromechanical Behaviors of a SWNT/PANi Composite Film Actuator (탄소나노튜브/도전성폴리머 복합재 엑츄에이터의 제조 및 특성실험)

  • Zhang, Shuai;Kim, Cheol
    • Composites Research
    • /
    • v.19 no.5
    • /
    • pp.7-11
    • /
    • 2006
  • The improved SWNTs/PANi composite actuator films applicable to an artificial muscle were fabricated successfully using a new process of manufacture that consists of 90% pure single-walled carbon nanotubes (SWNT) and chemical polymerization. PANi is electrically conducting polyaniline polymer. The conductivities of the composite SWNTs/PANi film-type actuators and the pure PANi films fabricated were measured as 56.15 S/cm and 17.38 S/cm, respectively, by the 4-prove method. The conductivity of the composite actuator is 3.2 times higher than the pure PANi film. The fabricated composite actuator showed higher conductivity than any other similar ones. The quality of samples was investigated by an electron scanning microscope (SEM). To measure the actuating strains, a specially designed beam balance apparatus was developed and strains of the composite actuators was measured by a laser displacement sensor subjected to electric currents. During the operation, the sample was soaked in the $NaNO_3$ solution and the sine-wave voltage in the range of $+1V{\sim}-1V$ was applied. The length of the composite actuator changed from $l_0=12.690$ mm to $l_1=12.733$ so that the change of length was l=0.043 mm and the strain was 0.34 %. This is a very high strain for this kind of a composite actuator. Other result reported by Tahhan showed 0.23 % strain, so that the present result is improved by 48%.

Design and Implementation of Healthcare System Based on Non-Contact Biosignal Measurement (비접촉 생체신호 측정 기반 헬스케어 시스템 설계 및 구현)

  • Hong, Seong-Pyo
    • The Journal of the Korea institute of electronic communication sciences
    • /
    • v.15 no.1
    • /
    • pp.185-190
    • /
    • 2020
  • The rapid aging is increasing as the shortage of medical facilities and the resulting of decline in the quality of public health. In order to ease the burden of rising medical expenses, advanced medical institutions are expanding their remote medical care to lower the cost of services. U-healthcare detects the changes in physical and chemical phenomena occurring in the human body and converts them into electrical signals that can be processed and feeds back to the results through analytical and visualization processes to select only the desired information from the measured signals. The service is provided through a process of providing an alarm to a user. However, traditional biometric methods of attaching sensors directly to the body can be annoying and rejected in daily life. Therefore, there is a need for a method of continuously measuring biometric information without causing inconvenience to daily life. In this paper, we propose an IR-UWB-based non-contact and non-responsive respiratory measurement system that can continuously monitor biological information without any inconveniences to daily life.

A Study for The X-ray Image Acquisition Experiment Using by Gas Electron Multipliers (기체전자증폭기를 이용한 X-선 영상획득실험에 관한 연구)

  • 강상묵;한상효;조효성;남상희
    • Journal of Biomedical Engineering Research
    • /
    • v.24 no.2
    • /
    • pp.83-89
    • /
    • 2003
  • The gas electron multiplier placed in the drift volume of conventional gas detectors, is a conceptually simple device for producing a large gas gain by concentrating the drift electric field over a very short distance to the point that electron avalanching occurs(〉 10$^4$ V/cm), greatly increasing the number of drifting electrons. This device consists of a thin insulating foil of several tens of urn in thickness. covered on each side with a thin metal layer(Cu), with tiny holes, usually 100 ${\mu}{\textrm}{m}$ or less in diameter. and with a spacing of 100-200 ${\mu}{\textrm}{m}$ through the entire foil. perforated by using chemical etching or high-powered laser beam technique In this study, we have investigated its operating properties with various experimental conditions, and demonstrated the possibility of using this device as a digital X-ray imaging sensor, by acquiring X-ray images based on the scintillation properties of the gas electron multiplier with standard CCD camera.