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The Influence of Oxygen Gas Flow Rate on Growth of Tin Dioxide Nanostructures (이산화주석 나노구조물의 성장에서 산소가스 유량이 미치는 영향)

  • Kim, Jong-Il;Kim, Ki-Chul
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.10
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    • pp.1-7
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    • 2018
  • Tin dioxide, $SnO_2$, is applied as an anode material in Li-ion batteries and a gas sensing materials, which shows changes in resistance in the presence of gas molecules, such as $H_2$, NO, $NO_2$ etc. Considerable research has been done on the synthesis of $SnO_2$ nanostructures. Nanomaterials exhibit a high surface to volume ratio, which means it has an advantage in sensing gas molecules and improving the specific capacity of Li-ion batteries. In this study, $SnO_2$ nanostructures were grown on a Si substrate using a thermal CVD process with the vapor transport method. The carrier gas was mixed with high purity Ar gas and oxygen gas. The crystalline phase of the as-grown tin oxide nanostructures was affected by the oxygen gas flow rate. The crystallographic property of the as-grown tin oxide nanostructures were investigated by Raman spectroscopy and XRD. The morphology of the as-grown tin oxide nanostructures was confirmed by scanning electron microscopy. As a result, the $SnO_2$ nanostructures were grown directly on Si wafers with moderate thickness and a nanodot surface morphology for a carrier gas mixture ratio of Ar gas 1000 SCCM : $O_2$ gas 10 SCCM.

A Study on the Development of Evaluation Index for the Improvement and Operation of R&D Project Management Process (R&D 프로젝트 관리 프로세스 개선 및 운영을 위한 평가지표 개발 연구)

  • Lee, Seol-Bin
    • The Journal of the Korea Contents Association
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    • v.18 no.9
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    • pp.308-319
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    • 2018
  • This study is intended to develop evaluation indicators for the improvement and operation of R&D project management process. To achieve this, an empirical survey was carried out to small companies specializing in technology-centered R&D. First, 12 evaluation indicators showed that there was a deviation of more than 2 times from the highest score of 60.77 to the lowest score of 30 in integrated management, which the R&D project management process needs to be selectively used for the improvement and operation. Second, the difference in industry showed that the biotech industry was the highest, while the chemical, electrical and electronic industries were the lowest. Third, the difference in the number of employees showed that companies with 50~100 employees were relatively high, while small companies with more than 100 employees were somewhat low. Fourth, the difference in career showed that 5~7-year career was relatively high, while 7~10-year career was somewhat high. Overall, evaluation indicators for the improvement and operation of R&D project management processor showed that integrated management was the most important, followed by communication management, risk management, and time management. This implies that small companies specializing in technology-centered R&D need to concentrate on the importance of efficient integrated management and rapid decision-making and risk management among individual participation subjects.

Effects of Operating Parameters on Phenol Degradation by Pulsed Corona Discharges in Aqueous Solutions (펄스 코로나 방전에 의한 페놀 분해에 미치는 운전변수의 영향)

  • Chung, Jae-Woo;Moon, Ji-Hoon;Park, Eun-Ok
    • Journal of Korean Society of Environmental Engineers
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    • v.32 no.1
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    • pp.79-86
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    • 2010
  • Effects of operating parameters such as applied voltage, solution conductivity, ferrous ion concentration, electrode material on phenol degradation by pulsed corona discharges were investigated in laboratory scale experiments. The increase of applied voltage enhanced the phenol degradation by generating more energetic electrons. The solution conductivity inversely affected phenol removal rate in the tested ranges because the increase of conductivity decreased the electric field strength through the liquid phase. The addition of ferrous sulfate promoted the phenol degradation through the OH radical production by the Fentonlike reactions between ferrous ion and hydrogen peroxide generated by pulsed corona discharges. Catechol and hydroquinone were detected as primary intermediates of phenol degradation and the decrease of pH and the increase of conductivity were observed probably due to the generation of organic acids. Almost all of the initial phenol was disappeared and 29% of total organic corbon (TOC) was removed in the condition of 0.5 mM of ferrous sulfate after approximately 230 kJ of discharge energy transferred to the reactor.

DESIGN AND IMPLEMENTATION OF HITL SIMULATOR COUPLEING COMMUNICATIONS PAYLOAD AND SOFTWARE SPACECRAFT BUS (통신탑재체와 소프트웨어 위성버스체를 통합한 HITL 시뮬레이터의 설계 및 구현)

  • 김인준;최완식
    • Journal of Astronomy and Space Sciences
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    • v.20 no.4
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    • pp.339-350
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    • 2003
  • Engineering qualification model payload for a communications and broadcasting satellite(CBS) was developed by ETRI from May, 2000 to April, 2003. For. the purpose of functional test and verification of the payload, a real-time hardware-in-the-loop(HITL) CBS simulator(CBSSIM) was also developed. We assumed that the spacecraft platform for the CBSSIM is a geostationary communication satellite using momentum bias three-axis stabilization control technique based on Koreasat. The payload hardware is combined with CBSSIM via Power, Command and Telemetry System(PCTS) of Electrical Ground Support Equipment(EGSE). CBSSIM is connected with PCTS by TCP/IP and the payload is combined with PCTS by MIL-STD-1553B protocol and DC harness. This simulator runs under the PC-based simulation environment with Windows 2000 operating system. The satellite commands from the operators are transferred to the payload or bus subsystem models through the real-time process block in the simulator. Design requirements of the CBSSIM are to operate in real-time and generate telemetry. CBSSIM provides various graphic monitoring interfaces and control functions and supports both pre-launch and after-launch of a communication satellite system. In this paper, the HITL simulator system including CBSSIM, communications payload and PCTS as the medium of interface between CBSSIM and communications payload will be described in aspects of the system architecture, spacecraft models, and simulator operation environment.

An Exploration of Career Competency Mobility Map (CCMM) Focusing on Engineering Students in K University (경력역량이동지도(CCMM) 적용사례 연구: K 대학을 중심으로)

  • Park, Jiwon;Woo, Heajung;Noh, Kyungwon;Yi, Yejih;Hwang, Seong-jun;Kim, Woocheol
    • Journal of Practical Engineering Education
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    • v.11 no.2
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    • pp.195-206
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    • 2019
  • Accelerated technological advances and the convergence of information and communication technologies have led to changes of career concepts from one of lifetime employment to that of lifetime career. Given the importance of continuous career development for workers these days, systematic supports for workers' career development at the national level is necessary. Accordingly, a conceptual model of career competency mobility map (CCMM) has been proposed to support the development of workers' career competencies. The purpose of this study is to identify key issues that we should consider for real implementation by applying to each stage of the CCMM conceptual model as a case study. Based on the procedure presented in the conceptual model, the research process which includes collecting user information, conducting self-diagnosis of NCS-based job competencies, deriving necessary training competency, offering the guidance of training programs and job information were conducted. The results of the case study showed our participants' scores of competencies required further development and ranged from 1.83 to 4.52. Sequentially, a personalized information profile was offered for competency development, including training, certificates, and job information. Participants stated that the diagnosis results and profiles were meaningful and helped to explore further career development. Based on the results, implications are suggested.

An Energy-efficient LED Lighting Control Scheme with Provision of User Illumination Requirement (사용자 요구조도 보장 에너지 효율적 LED 조명 제어 기법)

  • Kim, Yong-Ho;Lee, Kwon-Hyung;Chang, Kap-Seok;Choi, Yong-Hoon;Kim, Hoon
    • The Journal of Korean Institute of Communications and Information Sciences
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    • v.36 no.11B
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    • pp.1383-1388
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    • 2011
  • Due to many recent activities on enforcement of the intensified environmental regulation such as the policies of curbing the greenhouse gas and the Restriction of Hazardous Substances (RoHS), the usage of Light emitting diode (LED) has been rapidly increased and energy efficient management of LED light system is regarded as an important technology to enhance the energy efficiency. In this paper, we propose an energy-efficient control scheme of LED light, being composed of multiple light sources. The proposed scheme controls the intensity of LED light source to minimize the total intensity while providing the quality of lighting service. The intensity of light is assumed to be proportional to power consumption, thus the objective is to minimize the total power consumption. A linear programming problem is formulated to find the optimal intensity of each light source and procedure to apply the proposed scheme in the real system is suggested. The performance evaluation results elucidate that the proposed scheme achieves over 20% improvement in power consumption of light intensity in comparison with the conventional dimming control scheme.

Microstructure and Electrical Properties of Pb[(Mg,Mn)Nb]O3-Pb(Zr,Ti)O3 Piezoelectric Ceramics

  • Kim, Jin-Ho;Kim, Jong-Hwa;Baik, Seung-Woo
    • Transactions on Electrical and Electronic Materials
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    • v.6 no.5
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    • pp.202-209
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    • 2005
  • Phase evolution, microstructure and the electrical properties such as $k_p$ and $Q_m$ of $Pb(Mg_{1/3}Nb_{2/3})O_3[PMN]-Pb(Mn_{1/3}Nb_{2/3})O3[PM'N]-PbZrO_3[PZ]-PbTiO_3[PT]$ quaternary system were investigated within the compositional ranges $0{\leq}y{\leq}0.125$, y+z=0.125, and $0.39{\leq}x{\leq}0.54$ of the formula $Pb_{0.97}Sr_{0.03}[Mg_{1/3}Nb_{2/3})_y\;(Mn_{1/3}Nb_{2/3})_z\;(Zr_{x}Ti_{1-x})_{1-(y+z)}]O_3$. In the case of increasing Mn/(Mg+Mn) ratio for a fixed Zr/Ti ratio of 47.5/52.5, phase relation remained unchanged but the grain size drastically decreased, and the electrical properties changed as following: both $k_P$ and $Q_m$ reached the peak values at $Mn/(Mg+Mn)\cong0.3l7$ and gradually decreased; $\varepsilon33^T$ showed a monotonic decrease; P-E hysteresis loop gradually changed to asymmetrical one, and $E_i$ increased in correspondence. With increasing Zr/Ti ratio for a fixed Mn/(Mg+Mn) ratio of 0.317, on the contrary, the cell parameter $(\alpha^2c)^{1/3}$ gradually increased, and tetragonal-rhombohedral morphotropic phase boundary appeared in the range of $51/49{\leq}Zr/Ti{\leq}54/46$. the meantime, the grain size substantially increased, and the electrical properties changed as following: $k_P$ and $\varepsilon33^T$ reached peak values at Zr/Ti=51/49 and 48/52, respectively, and then gradually decreased; change of $Q_m$ was adverse to $k_P$; both $E_C\;and\;E_i$ considerably decreased while $P_S$ moderately increased. For the system 0.125(PMN+PM'N)-0.875PZT studied, the composition Mn/(Mg+Mn)=0.3l7 and Zr/Ti=51/49 revealed some promising electrical properties for piezoelectric transformer application such as $k_P=0.58,\;Q_m\cong1000$, and $\varepsilon^T_{33}=970$, as well as dense and fine-grained microstructure.

A Design Method of Three-phase IPMSM and Clamping Force Control of EMB for High-speed Train (고속철도차량의 EMB 적용을 위한 3상 IPMSM의 설계 및 제동압부력 제어)

  • Baek, Seung-Koo;Oh, Hyuck-Keun;Kwak, Min-ho;Kim, Seog-Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.19 no.4
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    • pp.578-585
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    • 2018
  • This paper proposes a design method for a 3-phase interior permanent magnet synchronous motor (IPMSM) and clamping force control method for an electro-mechanical brake (EMB) using co-simulation for a high-speed train (HST). A traditional pneumatic brake system needs much space for the compressor, brake reservoir, and air pipe. However, an EMB system uses up to 50% less space due to the use of a motor and electric wires for controlling the brake caliper. In addition, it can reduce the latency time for brake control because of the fast response and precise control. A train that has many brakes is advantageous for safety because of the control by sharing the braking force. In this paper, a driving method for a cam-shaft-type EMB is modeled. It is different from the ball-screw-type brakes that are widely used in automobiles. In addition, a co-simulation method is proposed using JMAG and Matlab/Simulink. The IPMSM was designed and analyzed with the JMAG tool, and the control system was simulated using Matlab/Simulink. The effectiveness of the co-simulation results of the mechanical clamping force and braking force was verified by comparison with the clamping force specifications of a HEMU-430X HST.

Preparation of Polymethylene-bridged Half-Titanocenes and Investigation of Their Styrene Polymerization Properties (폴리메틸렌 다리를 가진 Dinuclear Half-Titanocene 합성과 이에 의한 스티렌 중합 연구)

  • 태원태;김상현;노석균;김태학;이동호
    • Polymer(Korea)
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    • v.24 no.2
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    • pp.159-167
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    • 2000
  • The polymethylene-bridged dinuclear half-titanocenes [(CH$_2$)$_{n}$(C$_{5}$ H$_4$)$_2$][TiCl$_3$]$_2$ (n=5(10), 7(11), 9(12)) have been synthesized by treating the distannylated derivatives of the ligands with two equivalents of TiCl$_4$ in toluene. All complexes are characterized by IR, $^1$H NMR, $^{13}$ C NMR and mass spectrometry. In order to examine the catalytic properties of the dinuclear complexes styrene polymerization has been conducted in the presence of MMAO. From the polymerization experiments it was found that ( i ) all the prepared complexes 10-12 produced syndiotactic polystyrenes, ( ii ) the complex 12 holding the longest bridging ligand exhibited the highest activity but produced a polymer having the smallest molecular weight among the polymethylene-bridged dinuclear half-titanocenes. This behavior was attributed to the influence of electron-donating caused by the polymethylene bridge between two active centers as well as the effect of steric congestion around metal center caused by the proximal distance between two active sites.s.

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Anatomy of Quercus variabilis Charcoal Manufactured at Various Temperatures (제조 온도에 따른 굴참나무 목탄의 해부학적 특성)

  • Kim, Nam-Hun;Hwang, Won-Joong;Kwon, Sung-Min;Kwon, Goo-Joong;Lee, Seong-Jae
    • Journal of the Korean Wood Science and Technology
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    • v.34 no.4
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    • pp.1-8
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    • 2006
  • Anatomy of Quercus variabilis charcoal was investigated by scanning electron microscopy. Charcoal was prepared in an electric furnace under nitrogen gas atmosphere at $400^{\circ}C$, $600^{\circ}C$, $800^{\circ}C$, and $1000^{\circ}C$ for 10 min. The structure of charcoal was significantly affected by charring temperature. In cross section, charcoal prepared at $400^{\circ}C$ exhibited a smooth clean surface. As the charring temperature increased, the surface became more rough and increasingly disrupted. The cell walls appeared homogeneous and glass-like. Ray parenchyma cells showed very little separation from each other in radial section at $400^{\circ}C$. At $600^{\circ}C$ and above there is an apparent disintegration of the middle lamella, resulting in a separation of the ray cells. The $2{\sim}4{\mu}m$ wart-like protuberances were observed on the surfaces of the parenchyma cells. These structures were seen in charcoal prepared at all temperatures. Distinctive features can be seen in multiseriate rays as large crack and split. Rhomboidal crystals in crystalliferous cells had a smooth surface at $400^{\circ}C$ and $600^{\circ}C$, but the crystals had a sponge like appearance at $800^{\circ}C$ and $1000^{\circ}C$.