• Title/Summary/Keyword: 저항 증가

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Study on Electrochemical Performances of PEO-based Composite Electrolyte by Contents of Oxide Solid Electrolyte (산화물계 고체전해질 함량에 따른 PEO 기반 복합전해질 전기화학 성능 연구)

  • Lee, Myeong Ju;Kim, Ju Young;Oh, Jimin;Kim, Ju Mi;Kim, Kwang Man;Lee, Young-Gi;Shin, Dong Ok
    • Journal of the Korean Electrochemical Society
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    • v.21 no.4
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    • pp.80-87
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    • 2018
  • Safety issues in Li-ion battery system have been prime concerns, as demands for power supply device applicable to wearable device, electrical vehicles and energy storage system have increased. To solve safety problems, promising strategy is to replace organic liquid electrolyte with non-flammable solid electrolyte, leading to the development of all-solid-state battery. However, relative low conductivity and high resistance from rigid solid-solid interface hinder a wide application of solid electrolyte. Composite electrolytes composed of organic and inorganic parts could be alternative solution, which in turn bring about the increase of conductivity and conformal contact at physically rough interfaces. In our study, composite electrolytes were prepared by combining poly(ethylene oxide)(PEO) and $Li_7La_3Zr_2O_{12}$ (LLZO). The crystallinity, morphology and electrochemical performances were investigated with the control of LLZO contents from 0 wt% to 50 wt%. From the results, it is concluded that optimum content and uniform dispersion of LLZO in polymer matrix are significant to improve overall conductivity of composite electrolyte.

Evaluation of Ozone Resistance and Anti-Corrosion Performance of Water Treatment Concrete according to Types of Metal Spray Coating (수처리시설용 콘크리트의 금속용사 피막 종류에 따른 내오존성 및 전기화학적 방식 성능 평가)

  • Park, Jin-Ho;Choi, Hyun-Jun;Lee, Han-Seung;Kim, Sang-yeol;Jang, Hyun-O
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.23 no.4
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    • pp.61-68
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    • 2019
  • As the pollution of water resources deteriorates due to industrialization and urbanization, it is difficult to supply clean water through a water treatment method using chlorine. Therefore, the introduction of advanced water treatment facilities using ozone is on the increase. However, epoxy which is used as waterproofing and anticorrosives and stainless steel used in conventional waterproofing and anti-corrosive methods have deteriorated because of the strong oxidizing power of ozone, causing problems such as leaking. Moreover, it even causes the durability degradation of a concrete. Therefore, in this study, metal spraying system was used as the means of constructing a metal panel with excellent ozone resistance and chemical resistance which is an easier method than an existing construction method. Ozone resistance was evaluated in accordance with the type of metal sprayed coatings to develop a finishing method which can prevent the concrete structure of water treatment facilities from deterioration. Furthermore, electrochemical stability in actual sewage treatment plant environment was evaluated. Experimental results showed that Ti has superior ozone resistance after spraying and the electrochemical stability in the sewage treatment plant environment showed that Ti has the highest polarization resistance of $403.83k{\cdot}{\Omega}{\cdot}cm^2$, which ensures high levels of durability.

The Problems and its Improvement of Sea Area Utilization Consultation and Impact Assessment for Projects Related to Marine Environment Restoration (해양환경복원관련 사업에 따른 해역이용협의·영향평가의 문제점 및 개선방안)

  • Yi, Yong Min;Jun, Eun Ju;Lee, Dae In;Kim, Gui Young
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.1
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    • pp.34-44
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    • 2019
  • Marine activities are becoming more diverse and extensive due to recent social developments, exceeding the environmental capacity of the marine ecosystem. The resilience, resistance, and constancy of marine ecosystems are being damaged or degraded. This prevents the ecosystem from functioning properly, leading to a decline in ecosystem services and value. As a means of returning the damaged ecosystem to health, more and more people are interested in restoration. At a time when restoration projects are gradually expanding, various problems that may arise when implementing the Sea Area Utilization Consultation and Impact Assessment for restoration projects need to be checked, in addition to confirming the direction to be pursued. Therefore, in this study terms related to restoration from research papers and reports were summarized, and the status of the Sea Area Utilization Consultation related to restoration projects and the status of the restoration project were reviewed. In addition, problems with Sea Area Utilization Consultations were considered through a case study to ensure the successful execution of restoration projects. Based on this, we intend to present improvement measures for Sea Area Utilization Consultations and Impact Assessments for restoration projects. This will provide effective information for future policies and plans.

Safety evaluation and approval status of genetically modified foods in Korea (국내 유전자변형식품 안전성 심사 규정 및 승인현황)

  • Kang, Yun-Sook
    • Food Science and Industry
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    • v.52 no.2
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    • pp.130-139
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    • 2019
  • Safety of genetically modified foods (GM foods) in Korea is evaluated according to "Food Sanitation Act" and "Regulation on safety evaluation for GM foods" based on the concept of substantial equivalence. In which cases a person who imports, develops or manufactures GM foods for the purpose of eating imports GM foods for the first time, he/she shall undergo a safety evaluation of the relevant foods, etc. by Ministry of Food and Drug Safety (MFDS). And in which cases ten years have elapsed since GM foods underwent safety evaluation, they shall be re-evaluated for their safety. As of April 2019, a total of 199 events have been approved by MFDS and they are 169 events of GM crops including soybean (29), maize (87), cotton (29), canola (14), sugar beet (1), potato (4), alfalfa (5), 6 events of GM microorganisms (GMM) and 24 events of GM food additives originated from GMM.

Antifouling Effect of an Ultrasonic System Operating at Different Frequencies (주파수 변동에 따른 초음파방오장비의 파울링제거효과)

  • Bae, Jin-Woo;Park, Guan-Sik;Ru, Myung-Lok;Park, Goun-Ha
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.25 no.5
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    • pp.609-616
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    • 2019
  • When the fouling of a vessel occurs, its resistance at sea increases and there is a corresponding increase in fuel consumption. The maintenance cost of the vessel also increases because it is time-consuming to remove the fouling. To solve this problem and minimize environmental contamination of sea-water, there have been recent developments in anti-fouling paints as self-polishing copolymers that not include toxic elements such as tin. When these conventional techniques are applied to vessels, polishing is promoted during the operation whereby friction or vibration with seawater occurs. This leads to enhanced anti-fouling performance. However, when fouling is intensified such as during an anchorage, there is no flow of seawater and polishing is suppressed. This leads to a deterioration of the performance of anti-fouling. To solve these problems, we developed a system that induces vibration in a vessel during anchorage. As such, the deterioration of polishing due to insuf icient flow of seawater is inhibited. The reliability of the ultrasonic antifouling system was evaluated by calculating its repeatability. The removal efficiency of fouling of the proposed system was qualitatively evaluated using test specimens. The test revealed that the value of the coefficient of variation for the reproducibility of the frequency and amplitude was 0.2 % and 4.0 % on average. The degree of fouling of the specimens was the highest at 73.3 g in the No.5 sepcimen. Moreover, efficiency of fouling removal was 93.2 % on average compared to the specimens without the proposed system.

The Effects of Different Membranes on the Performance of Aqueous Organic Redox Flow Battery Using Anthraquinone and TEMPO Redox Couple (안트라퀴논과 템포 활물질 기반 수계 유기 레독스 흐름 전지에서의 멤브레인 효과)

  • Lee, Wonmi;Kwon, Yongchai
    • Korean Chemical Engineering Research
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    • v.57 no.5
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    • pp.695-700
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    • 2019
  • n this study, the evaluation of performance of AORFB using anthraquinone derivative and TEMPO derivative as active materials in neutral supporting electrolyte with various membrane types was performed. Both anthraquinone derivative and TEMPO derivative showed high electron transfer rate (the difference between anodic and cathodic peak potential was 0.068 V) and the cell voltage is 1.17 V. The single cell test of the AORFB using 0.1 M active materials in 1 M KCl solution with using Nafion 212 membrane, which is commercial cation exchange membrane was performed, and the charge efficiency (CE) was 97% and voltage efficiency (VE) was 59%. In addition, the discharge capacity was $0.93Ah{\cdot}L^{-1}$ which is 35% of theoretical capacity ($2.68Ah{\cdot}L^{-1}$) at $4^{th}$ cycle and the capacity loss rate was $0.018Ah{\cdot}L^{-1}/cycle$ during 10 cycles. The single cell tests were performed with using Nafion 117 membrane and SELEMION CSO membrane. However, the results were more not good because of increased resistance because of thicker thickness of membrane and increased cross-over of active materials, respectively.

Evaluation of Chloride Diffusion Characteristics in Concrete with Fly Ash Cured for 2 Years (2년 양생된 Fly Ash 콘크리트의 염화물 확산 특성 평가)

  • Yoon, Yong-Sik;Hwang, Sang-Hyeon;Kwon, Seung-Jun
    • Journal of the Korean Recycled Construction Resources Institute
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    • v.7 no.1
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    • pp.8-15
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    • 2019
  • When RC(Reinforced Concrete) structures are exposed to harsh environment, deterioration phenomenon occurs, and the corrosion in rebar due to chloride intrusion is known as representative deterioration, so called chloride attack. In this paper, chloride resistance performance of 2 years aged concrete is evaluated considering 3 levels of water to binder ratio(0.37, 0.42, and 0.47) and 2 levels of substitution ratio of fly ash(0% and 30%). Accelerated chloride diffusion coefficient tests referred to Tang's method, total passed charge tests referred to ASTM C 1202, and compressive strength tests referred to KS F 2405 are performed. With adaptation of the previous test results and the results from this study, time-dependent chloride diffusion characteristics are analyzed for each concrete. The FA(Fly Ash) concrete has higher chloride resistance performance than OPC(Ordinary Portland Cement) concrete. According to the evaluation standard of ASTM C 1202, the FA concrete has "Moderate" grade after 49 days while OPC concrete does "Moderate" grade after 365 days. As the results of time-parameter for chloride diffusion, OPC concrete and FA concrete show the decreasing behavior of time-parameters with increasing water to binder ratio. Also, FA concrete has 1.57~2.74 times of time-parameter than OPC concrete. That's cause is thought that the time-parameter indicates the gradient of decreasing of diffusion coefficient. FA concrete has higher time-parameters than OPC concrete by pozzolanic reaction of FA.

Radio-sensitivity of Human Colorectal Cancer Cell is Regulated by Potassium Cyanate (Potassium cyanate에 의해 조절되는 사람 대장암 세포의 방사선 감수성 변화)

  • Yang, Eun Ju;Chang, Jeong Hyun
    • Journal of the Korean Society of Radiology
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    • v.13 no.1
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    • pp.125-132
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    • 2019
  • Potassium cyanate (KCN) is an inorganic reagent and can induce the post-translation carbamylation of proteins. The carbamylated reaction in the body is involved in cell death in various diseases. According the results in our previous study, KCN enhances the radiosensitivity of human colorectal cancer cell line, HCT 116 cells. However, it was not enough to confirm the mechanism that KCN works in these cells. To determinated the mechanisms of KCN in the cells with increased radiosensitivity, HCT 116 cells were treated KCN with low-dose gamma-radiation. And then, we examined alteration of the cell cycle, cell proliferation, cytokine level and the activation of cell signaling protein. As a result, cell cycle arrest and cell death were induced by the activation of caspase-3 and PARP in the irradiated cells with KCN treatment. These changes of the irradiated cell with KCN treatment were induced by the release of $TNF-{\alpha}$ via $NF-{\kappa}B$ activation. In conclusions, enhanced radio-sensitivity mediated by KCN induced cell death and it occurs by $NF-{\kappa}B$-dependent $TNF-{\alpha}$ production.

A Study on the Thermal Flow Analysis for Heat Performance Improvement of a Wireless Power Charger (열 유동해석을 통한 무선충전기 발열 성능 향상에 관한 연구)

  • Kim, Pyeong-Jun;Park, Dong-Kyou
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.20 no.7
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    • pp.310-316
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    • 2019
  • In automotive application, customers are demanding high efficiency and various functions for convenience. The demand for these automotive applications is steadily increasing. In this study, it has been studied the analysis of heat flow to improve the PCB(printed circuit board) heating performance of WPC (wireless power charger) recently developed for convenience. The charging performance of the wireless charger has been reduced due to power dissipation and thermal resistance of PCB. Therefore, it has been proposed optimal PCB design, layout and position of electronic parts through the simulation of heat flow analysis and PCB design was analyzed and decided at each design stage. Then, the experimental test is performed to verify the consistency of the analysis results under actual environmental conditions. In this paper, The PCB modeling and heat flow simulation in transient response were performed using HyperLynx Thermal and FloTHERM. In addition, the measurement was performed using infrared thermal imaging camera and used to verify the analysis results. In the final comparison, the error between analysis and experiment was found to be less than 10 % and the heating performance of PCB was also improved.

Pilot Study of Single Session Song-Based Music Therapy for Decreasing ICU Caregiver Anxiety (중환자 보호자의 불안 감소를 위한 단회기 노래중심 음악치료 적용 예비연구)

  • Jung, Yu Sun;Na, Sungwon
    • Journal of Music and Human Behavior
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    • v.16 no.1
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    • pp.25-46
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    • 2019
  • This pilot study involved a single session of song-based music therapy to relieve the anxiety of intensive care unit (ICU) caregivers. Six caregivers of ICU patients participated in the intervention session individually. During the initial stage of the intervention, the participants' current emotional states were identified. Then they listened to familiar songs and playing a tone chime, which was intended to help them relax their body and reduce their psychological resistance. During singing experiences as an essential part of the intervention, the participants discussed the lyrics of songs in an attempt to find the meaning related to them. Also, they sang the songs with a live accompaniment in which their emotional states were reflected with changes in musical elements (e.g., tempo, dynamics, rhythm, or chords). In the final stage, they identified personal application to their everyday lives. To analyze the results, the State-Trait Anxiety Inventory (STAI) and a visual analog scale on emotional states were completed by participants before and after the session, and participants' verbal responses during the session were also recorded. According to the results, STAI anxiety scores significantly declined following the session. Also, they showed significant increases in positive emotions and significant decreases in negative emotions. This suggests that short-term music therapy can be an effective intervention for relieving the psychological distress of ICU caregivers.