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Sulfonated poly(arylene ether copolymer)-g-sulfonated Polystyrene Membrane Prepared Via E-beam Irradiation and Their Saline Water Electrolysis Application (전자빔조사를 이용한 술폰화 폴리아릴렌 에테르 술폰-g-술폰화 폴리스틸렌 분리막 제조 및 염수전기분해 특성평가)

  • Cha, Woo Ju;Lee, Chang Hyun
    • Membrane Journal
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    • v.26 no.6
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    • pp.458-462
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    • 2016
  • Saline water electrolysis, known as chlor-alkali (CA) membrane process, is an electrochemical process to generate valued chemicals such as chlorine, hydrogen and sodium hydroxide with high purities higher than 99%, using an electrolytic cell composed of cation exchange membrane, anode and cathode. It is necessary to reduce energy consumption per a unit chemical production. This issue can be solved by decreasing intrinsic resistance of the membrane and the electrodes and/or by reducing their interfacial resistance. In this study, the electron radiation grafting of a $Na^+$ ion-selective polymer was conducted onto a hydrocarbon sulfonated ionomer membrane with high chemical resistance. This approach was effective in improving electrochemical efficiency via the synergistic effect of relatively fast $Na^+$ ion conduction and reduced interfacial resistance.

Hazards and Solutions of Loss of the PEN Conductor in TN-C-S System (TN-C-S계통에서 PEN도체의 단선고장의 위험성 및 보호대책)

  • Lee, Bok-Hee;Lee, Kyu-Sun;Ahn, Chang-Hwan;Kim, Han-Su
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.21 no.8
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    • pp.113-120
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    • 2007
  • This paper presents the electric shock hazards and solutions of loss of the combined protective and neutral (PEN) conductor in TN-C-S system. In order to mitigate the touch voltage on exposed-conductive-parts in a break in the PEN conductor, the touch voltages on exposed-conductive-parts in a break in the PEN conductor were experimentally investigated as a function of the ground resistances of the source grounding electrode and customer's additional grounding electrode. As a result, the equipotential bonding is one of important requirements for installations supplied by TN-C-S system. A solution of mitigating the touch voltages on exposed-conductor-parts caused by a loss of the PEN conductor would be the installation of the additional grounding electrode at the customer's service entrance. The ground resistance of additional grounding electrode necessary to limit the touch voltage to a safety voltage of less than 50[V] depends on the load and circuit parameters. In addition, the undervoltage sensing devices oner affordable solutions to detect a loss of the PEN conductor in TN-C-S system.

The Estimation and Application of Optimum Design Variables for Road Tunnel Ventilation System Based on Statistical Analysis (통계적 분석을 이용한 터널 환기시스템 적정설계변수의 산정 및 적용에 관한 연구)

  • 이보영;유용호;김진
    • Tunnel and Underground Space
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    • v.14 no.5
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    • pp.373-380
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    • 2004
  • In this study, the emission rate of pollutant was modified according to the published standards, and the distribution of pollutant concentration was analyzed for each vehicle velocity. This modified emission rate was applied to a model tunnel and it was proved that the required air quantity was reduced to 49%, compared to the PIARC method. From the simulation result, it was proved by using statistics that the most sensitive factor among them is the friction coefficient and it was modified to the value in the range of 0.018 to 0.021. It is also expected that the required air quantity can be decreased form 14.4% to 19.2% according as the coefficient is applied to the domestic model tunnels. In conclusion, it is proposed that the number of jet fans can be reduced and the annual operating cost can be curtailed as well.

Behaviors of Impulse Ground Impedances Associated with the Current Injection Point in a Ground Rod (봉상 접지전극에시 전류유입위치에 따른 임펄스 접지임피던스의 특성)

  • Lee, Bok-Hee;Jeong, Dong-Cheol;Lee, Su-Bong
    • Journal of the Korean Institute of Illuminating and Electrical Installation Engineers
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    • v.19 no.1
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    • pp.94-100
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    • 2005
  • This paper presents the behaviors of transient and effective impulse impedances of a long ground rod associated with the current injection points. The laboratory test for the time domain performance of actual-sized model ground rod subjected to a lightning stroke current has been carried out The transient ground impedances of long ground rods under impulse currents were higher than the ground resistance. Both of the ground resistance and the effective impulse ground impedance decrease with increasing the length of the ground rods. Also, the effective impulse ground impedances are significantly increased in fast rise time ranges. The reduction of the ground resistance is decisive to improve the impulse impedance characteristics of grounding systems. When the test current is injected at the bottom of ground rod, the oscillating pulses with high frequency are included on the wave front of ground rod potential and the effective impulse impedances are higher than any other cases.

Strength and Crack Resistance Properties of Fiber Reinforced Concrete Mixed with Recycled PET Fiber (재생 PET 섬유가 혼입된 섬유 보강 콘크리트의 강도 및 균열저항 특성)

  • Kim, Sung-Bae;Kim, Hyun-Young;Yi, Na-Hyun;Kim, Jang-Ho Jay
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.14 no.1
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    • pp.102-108
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    • 2010
  • The main objective of this study was to evaluate the effect of recycled PET (RPET) fiber made from waste PET bottles to examine application on concrete member. To evaluate the reinforcement effect of RPET fiber in concrete member, experimental tests were performed, such as mechanical property tests (compressive strength, modulus of elasticity and splitting tensile strength) and drying shrinkage test. In mechanical property tests, compressive strength and modulus of elasticity in concrete mixed with RPET fiber gradually decreased, but splitting tensile strength gradually increased as volume fraction of fiber increased. In drying shrinkage test, free drying shrinkage increased. In restrained case, in contrast, crack occurrence was delayed because of tensile resistance increase by RPET fiber. The comparison of RPET and PP fiber added concrete specimen's properties showed that two materials had similar properties. In conclusion, RPET fiber is an alternative material of PP fiber, even finer for its excellence in eco-friendliness due to the recycling of waste PET bottles and its possible contribution to the pollution declination.

Suppressed Sheet Resistance of Ag Nanostructure Films by O2 Plasma Treatment (O2 플라즈마 처리를 통한 Ag 나노구조체 필름의 면저항 저감)

  • Kim, Wonkyung;Roh, Jong Wook
    • Journal of the Microelectronics and Packaging Society
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    • v.26 no.3
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    • pp.37-41
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    • 2019
  • Sheet resistance reduction in the Ag nanowire (NW) coated films is accomplished with slight improvement of optical properties for the application of transparent conducting electrodes by using $O_2$ plasma treatment. The sheet resistance was optimized after 30 seconds $O_2$ plasma treatment, showing the 27 % of maximum decrease of sheet resistance. It is found that the $O_2$ plasma treatment get rid of the residual organic materials at the junction of Ag NWs. However, the Ag NWs may be also snapped by the excessive $O_2$ plasma treatment can showing the collapses of Ag NWs networks. Furthermore, the optical properties such as optical transmittance and haze were monotonically improved with the $O_2$ plasma treatment time until 90 seconds.

Material Properties of 3D Printed Mortars Produced with Synthetic Fibers and Biopolymers (합성섬유 및 바이오 폴리머를 혼입한 3D 프린팅 모르타르의 재료특성)

  • Hyo-Jung Kim;Byung-Jae Lee;Yun-Yong Kim
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.27 no.4
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    • pp.78-85
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    • 2023
  • In this study, synthetic fibers were applied to reduce shrinkage cracks that may occur in mortar produced by 3D printer. We used a biopolymer in powder form made from cactus stem (CS) as an admixture. The material properties of 3D printed mortar were experimentally evaluated. Replacing methylcellulose(MC) with 10% CS increases compressive strength by 9.84-23.92% regardless of the casting method. In addition, regardless of the casting method, shrinkage change, freeze-thaw resistance, and crack resistance are more effective than Plain. Incorporation of CS increases the polysaccharide macromolecular structure and improves durability. Mortars reinforced with synthetic fibers do not affect compressive strength and freeze-thaw. It is also effective for shrink deformation and crack resistance. Incorporating CS and fibers from 3D-printed mortar was found to be effective for durability and crack resistance.

반도체 검출기의 절연 최적화를 위한 다층 절연막 평가

  • Park, Jeong-Eun;Myeong, Ju-Yeon;Kim, Dae-Guk;Kim, Jin-Seon;Sin, Jeong-Uk;Gang, Sang-Sik;Nam, Sang-Hui
    • Proceedings of the Korean Vacuum Society Conference
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    • 2014.02a
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    • pp.372-372
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    • 2014
  • 반도체 검출기는 입사되는 X선 에너지에 의하여 이온화되어 발생하는 전자 전공쌍을 수집함으로 방사선 정보를 확인하는 선량계로써 많은 연구와 활용이 이루어지고 있다. 하지만, X선 에너지에 의하여 반도체 검출기에서 발생하는 전기적 신호량이 높지 않기 때문에 누설 전류의 저감이 필수적이다. 누설 전류를 저감시키기 위한 방안으로 반도체 층과 전극 층의 Schottky Contact 구조의 설계, Insulating Layer의 사용, 높은 비저항의 반도체 물질 연구 등이 이루어지고 있다. 하지만, 기존에 누설 전류 저감을 위하여 Insulating Layer를 전극층과 반도체 층 사이에 형성하는 연구에 있어서 Insulating Layer와 반도체 층의 계면 사이에서 발생하는 Charge Trapping으로 인하여 생성되는 신호의 Reproducibility 저하, 동영상 적용의 제한 등의 문제점을 겪어왔다. 이에 본 논문에서는 누설 전류를 저감시킴과 동시에 Charge Trapping의 최소화를 이루기 위하여 Insulating Layer의 두께 최적화 연구를 수행하였다. 본 연구에서 사용한 Insulating Layer는 검출기 표면에 입사하는 X선 정보 손실을 최소화 시키는 동시에 누설 전류와 Charge Trapping을 최소화 시키는 방법으로써 CVD방법으로 검출기 표면에 균일하게 Insulating Layer를 코팅하였다. Insulating 물질은 Parylene을 사용하였으며, 그 중 온도, 습도 등 외부환경에 영향을 적게 받는 type C를 사용하였다. 증착에 사용한 장비의 진공도는 Torr로 설정하여 증착되는 Parylene의 두께가 약 $0.3{\mu}m$가 되게 하였으며, 실험에는 반도체 물질 PbO를 사용하였다. Parylene의 절연 특성은 Dark Current와 Sensitivity를 측정한 SNR을 이용하여 Parylene코팅이 되지 않은 동일 반도체 검출기와의 신호를 비교하였으며 또한 Parylene를 다층 제작한 검출기의 수집 신호량을 비교하였다. 제작한 검출기의 X선 조사 시의 수집 전하량 측정 결과, 100 kVp, 100mA, 0.03s의 X선 조건에서 $1V/{\mu}m$의 기준 시, Parylene를 코팅하지 않은 PbO 검출기의 Dark current는 0.0501 nA/cm2, Sensitivity는 0.6422 nC/mR-cm2, SNR은 12.184이었으며, Parylene단층의 두께인 $0.3{\mu}m$로 증착된 시편의 Dark current는 0.04097 nA/cm2, Sensitivity는 0.53732 nC/mR-cm2으로 Dark current가 감소되고 sensitivity도 감소하였지만 SNR은 13.1150으로 높아진 것을 확인할 수 있었다. Perylene이 $0.6{\mu}m$로 증착된 시편의 경우, Dark Current는 0.04064 nA/cm2, Sensitivity는 0.31473 nC/mR-cm2, SNR은 7.7443으로써 Insulating Layer가 없는 시편보다 SNR이 약 40% 낮아진 것을 확인할 수 있었다. Parylene이 $0.9{\mu}m$로 증착된 시편의 경우 Dark current는 0.0378 nA/cm2, Sensitivity 0.0461 nC/mR-cm2로 Insulating Layer가 없는 시편에 비해 SNR은 약 1/12배 감소한 1.2196이었고, Parylene이 $1.2{\mu}m$로 증착된 시편의 SNR은 1.1252로서 더 감소하였다. 따라서 Parylene을 다층 코팅한 검출기일수록 절연 효과의 영향이 커짐으로써 SNR 비교 시 수집되는 신호량이 줄어드는 것을 확인하였다. 반도체 검출기의 누설 전류를 저감시킴과 동시에 신호 수집율에 영향을 최소화시키기 위하여 Insulating Layer의 두께를 적절하게 설정하여 적용하면 Insulating Layer가 없는 검출기에 비해 누설전류를 최소한으로 줄일 수 있고 신호 검출효율이 감소하는 것을 방지할 수 있을 것이라 사료된다.

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A Development of concrete Pavement Material with Low Shrinkage and Reflection, High Strength and Performance (저수축 저반사 고강도 고내구성 콘크리트 포장재료 개발)

  • Kim, Hyo-Sung;Nam, Jeong-Hee;Eum, Ju-Yong;Cho, Yoon-Ho
    • International Journal of Highway Engineering
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    • v.11 no.1
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    • pp.13-24
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    • 2009
  • This study developed a high strength and performance concrete pavement material with low shrinkage and reflection of sunlight. Based on the literature review, a new mix-design of applying flash ash to improve the strength and performance of the concrete as well as to reduce the dry shrinkage is suggested. In addition, adding black pigment to reduce the reflection and technique of applying OAG (Optimized Aggregate Gradation) is also included. The result of the laboratory experiment indicates that the brightness and the reflection, which depends on the ratio of black pigment addition, did not deviate from the normal range. When OAG is considered for the mix-design, the strength and performance of the concrete improved greatly. In addition, the mix-design using fly ash reduced the dry shrinkage of concrete and improved the resistance to the permeation of chloride ion. Furthermore, the mix-design, which uses fly ash (25% replacement) and black pigment (3% addition) with the application of OAG, is found to be the most effective mix to reduce the shrinkage and reflection as well as improving the strength and performance of the concrete. The result of an economic analysis indicates that the initial construction cost of this proposed mix is more expensive than that of normal concrete pavement material. However, it can be more economic in the long run because the normal concrete pavement material is likely to cost more due to higher probability of maintenance and repair and higher social cost due to traffic accident, etc.

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Stiffness Reduction Effect of Vertically Divided Reinforced Concrete Shear Walls Under Cyclic Loading (반복하중을 받는 수직분할된 철근콘크리트 전단벽의 강성저감효과)

  • Hwangbo, Dong-Sun;Son, Dong-Hee;Bae, Baek-Il;Choi, Chang-Sik
    • Journal of the Korea institute for structural maintenance and inspection
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    • v.26 no.3
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    • pp.103-110
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    • 2022
  • The purpose of this study is to experimentally evaluate the stiffness and strength reduction according to the reinforcing bar details of the vertically divided reinforced concrete shear walls. To confirm the effect of reducing strength and stiffness according to vertical division, four real-scale specimens were fabricated and repeated lateral loading tests were performed. As a result of the experiment, it was confirmed that the strength and stiffness were decreased according to the vertical division. In particular, as the stiffness reduction rate is greater than the strength reduction rate, it is expected that safety against extreme strength can be secured when the load is redistributed according to vertical division. As a result of checking the crack pattern, a diagonal crack occurred in the wall subjected to compression control among the divided walls. It was confirmed that two neutral axes occurred after division, and the reversed strain distribution appeared in the upper part, showing the double curvature pattern. In future studies, it is necessary to evaluate the stiffness reduction rate considering the effective height of the wall, to evaluate additional variables such as wall aspect ratio, and to conduct analytical studies on various walls using finite element analysis.