• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.04a
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• pp.150-153
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• 1997

Langmuir-Blodgett(LB) technique is one of the ways of fabricating organic ultra-thin films. It is well known that It has the advantage to control the alignment and orientation of the molecules in the films. Metallo-phthalocyanines(MPcs) are sensitive to electron affinitive toxic gaseous molecules, such as NO$_2$, NO, SO$_2$. MPcs are thermal, optical, mechanical, chemical stable. Therefore, it is interesting to prepare phthalocyanine LB films containing copper as a chemical sensor for NO$_2$ and SO$_2$ gas and test their sensitivity to these toxic gases. In this study, thin films of Octa-dodecylosy copper-phthalocyanine were prepared by LB technique. $\pi$-A isotherm, transfer ratio, UV-VIS. spectroscopy of these films were investigated. Also current-voltage(I-V) characteristics of these was auto investigated.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.705-708
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• 2001

The effect of grinding on the synthesis of LaAO$_3$ceramics was investigated. The mixture ground by plantary ball mill showed 70nm particle size (wet ball mill or unground=0.5 $\mu$m). Monophase LaAlO$_3$powders were formed when ground samples were heated at 100$0^{\circ}C$, however unground samples required temperatures above 130$0^{\circ}C$. Density of the ground samples sintered at 140$0^{\circ}C$ showed 98.3% of theoretical density (unground=93.5% at 150$0^{\circ}C$). Dielectric constant of the ground samples($\varepsilon$r=22.4) showed higher values than that of the unground samples($\varepsilon$r=20.32). Temperature coefficient of capacitance($\tau$$_{c}$) and dielectric loss (tan$\delta$) of the ground samples were similar to those of unground samples.s.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2001.07a
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• pp.870-873
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• 2001

The electron drift mobilitity of poly(4,4'-cyclohexylidenediphenyl carbonate)(PC-Z) doped with 3,5-dimethyl-3',5'-di-t-butylstilbenequinone(MBSQ) was measured by the time-of-flight technique. Energy gap of the polymer doped with 25wt% of MBSQ was 3.1 eV. The electron drift mobility was 2.98${\times}$10$\^$-6/$\textrm{cm}^2$/V$.$s at 293K. The electric field and temperature dependences of the electron drift mobility were discussed with Poole-Frenkel and Arrhenius formulations. The activation energy(E$\_$0/), Poole-Frenkel coefficient(${\beta}$) and effective temperature(T$\_$eff/) of the mobility are 0.815 eV, 1.73${\times}$10$\_$-4/ eV$.$cm$\^$1/2//V$\_$1/2/ and 6.43${\times}$10$^2$K, respectively.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.04a
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• pp.249-252
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• 1997

Electroluminescence(EL) devices based on organic thin layers have attracted lot of interests because of their possible application as large-area display-emitting display. One of the problems of such devices is lifetime of the cell, where the degradation of the cell is partially due to the crystalliyzation of organic layers. In large part, this problem can be solved by using a multilayer device structure prepared by vapor deposition technique. In this study, blue light-emitting multilayer organic electroluminescence devices were fabricated vsing Poly (9-vinylcarbaEole) (PVK) and 2- (4-tert-butylphenyl)-5-(4$^{#}$-bis-phenyl) 1,3,4-oxadiazole (PBO) as hole trasport and electron transport material, respectively, where trim(8-hyd roxyquinolinate) aluminum (Al $q_3$) was used as a luminescenct material. A cell structure of glass sub- strate/indume-tin-oxide(ITO)/PCK/Al $q_3$/PBD/Mg:In was employed. Blue emission peak at 510nm was observed with this cell structure.e.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 1997.04a
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• pp.146-149
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• 1997

It is well known that the metallo-phthalocyanines(MPcs) are sensitive to toxic gaseous molecules, such as NO$_2$, NO, SO$_2$. MPcs are thermally, optica1ly, mechanically and chemically stable. Therefore, it is interesting to prepare phthalocyanine LB films containing tin as a chemical sensor for NO$_2$ and SO$_2$ gas and test their sensitivity to these toxic gases. Frist, in this study, ultra thin films of Octa-dodecyloxy tin-phthalocyanine were prepared on various substrates by LB technique. Langmuir-Blodgett(LB) technique is one of the ways of fabricating organic thin films. It has the advantage to control the alignment and orientation of the molecules in the films. $\pi$-A isotherm and transfer ratio of tin-phthalocyanine derivative. UV-VIS. spectroscopy were investigated. Also intrinsic current-voltage(1-V) characteristics of these films was investigated.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.760-763
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• 2002

Nanoparticle size of Titanium dioxide thin films was prepared by novel method. Particle size and surface structure of $TiO_2$ thin films were investigated by atomic force microscopy(AFM), scanning electron microscopy(SEM). All thin films process were prepared at room temperature. Particle size was reduced from 100 to 30nm with increasing amount of $Ti[OCH(CH_3)_2]_4$ observed by AFM images. All thin films were irradiated for 5 minutes by white light. Increasing the annealing temperature, particles size was increased. In the $TiO_2$(40%) thin films was annealed at $300^{\circ}C$ for 30minutes, the particle size was about 10nm.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.752-755
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• 2002

Since Metallo-Porphyrin (MP) is very interesting compound due to its unique electronic and redox properties and it is also chemically and thermally stable, MP has been studied for potential memory and switching devices. In this study, thin films of 5,10,15,20 - Tetrakis - Octadecyloxymethylphenyl - Porphyrin - Zn(II) (Zn-TPP) were prepared by the Langmuir-Blodgett (LB) method and characterized by using UV/vis absorption spectroscopy and cyclic voltammetry. It was found that the proper transfer surface pressure for film deposition was 25 mN/m and the limiting area per molecule was $135{\AA}^2$/molecule. The current-voltage (I-V) characteristics of these films were investigated.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.756-759
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• 2002

Nanoparticles of titanium dioxide$(TiO_2)$ were prepared by photochemical synthesis. Surface structure, morphology and particle size of $TiO_2$ thin films were investigated by UV-VIS spectrophotometer, scanning electron microscopy(SEM) and transmission electron microscopy(TEM). All process was prepared at room temperature. The absorption peak of the films was showed at 360nm and $TiO_2$ nanopaticle size was observed at about 20~30nm. Electron diffraction ring patterns of $TiO_2$ nanoparticles and crystallographic spacing were observed by TEM. As a result, crystallographic spacing was about 3.6A in HR-TEM micrographs.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.618-620
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• 2002

The sintering and dielectric characteristics of $(1-x)Al_2O_3-xLa_2O_3$ ceramics (x=0.2, 0.4, 0.5, 0.6, 0.8, 1.0) were investigated. The sample of x=0.6 composition showed a largest density$(6.5g/cm^3)$ in the all samples and its grain were very uniform. The dielectric constant of the samples linearly increased from 9 to 17 up to x=0.6 with a increasing of x. The temperature coefficient of resonance frequency for the samples showed a positive value at x=0.2 and a negative value at x>0.4.

• Proceedings of the Korean Institute of Electrical and Electronic Material Engineers Conference
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• 2002.07b
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• pp.621-624
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• 2002

Lanthanum nickel oxide$(LaNiO_3)$ powders have been prepared via a mechanochemical processing without any additional heat treatment. When a mixed lanthanum and nickel oxide was mechanically activated for 6 hours with 450 rpm, a stable and single phase perovskite powder was successfully synthesized and its crystallite size of about 90 nm is calculated by using the Scherrer equation.