• Journal of the Korean Applied Science and Technology
• /
• v.32 no.3
• /
• pp.469-479
• /
• 2015

This study is related to the developing method of a transparent sunscreen cosmetic which has waterproofing property and no white turbidity when applied to skin. The transparent sunscreen is prepared by exploiting refractive index difference between oil-phase and water-phase of water-in-oil(W/O) emulsion. The sunscreen according to this study is prepared as a W/O type emulsion so that it is water-stable and water resistance. Also, the stability of W/O type emulsion is developed by adjusting the content of oil phase part and water phase part. As a result of this studying, the transparent W/O emulsion is prepared by adjusting the refractive index of oil-phase and water-phase within 0.004 and it is found that the stability of the transparent sunscreen is increasing when the water phase part is over 75% (w/w) of the W/O emulsion. Through clinical test of transparent sunscreen, the value of sun protection Factor(SPF) and Protection Factor of UVA(PFA) were determined. SPF and PFA values of transparent sunscreen were indicated $30.99{\pm}1.65$ and $3.01{\pm}0.30$.

• Journal of the Korean Applied Science and Technology
• /
• v.32 no.2
• /
• pp.339-347
• /
• 2015

This study is to evaluate moisturizing effect and durability of UV A/B blocking activity with multiple (W/O/W) emulsion system. Most of the sun protective products come to be hot issue having both high SPF and long-lasting activity as using special products when is going out, mountain climbing and sports. Also, many consumers prefer the products which have the excellent waterproofing activity of sun care cosmetics as well as the non-sticky feeling that carried out the study of the sensorial science and texture preference. Therefore, development of the specific formulation using this multiple (W/O/W) emulsion technology, it has O/W type hydro skin feel having soft and moist texture when it is treated on the skin. Finally, this formulation is instantly changed to W/O type feel after adsorbed into the skin. The purpose of this study is to get high SPF lasting effect having high water resistance tactivity with high functional multiple (W/O/W) emulsion cream. We used major ingredients, UV-B absorbers were selected with ethylhexyl methoxycinnamate, isoamyl-p-methoxycinnamate, ethylhexylsalicylate, and octocrylene, UV-A absorbers were selected with butylmethoxydibenzoylmethane, bis-ethylhexyloxyphenol methoxy phenyltriazine. SPF effect of O/W type cream was 34.1. SPF effect of W/O/W type cream was 40.6 (increased about 19%). Water resistance effect after 4 hours, SPF effect of O/W type cream was 3.6 (quickly drop down). SPF effect of W/O/W type cream having 81.0 % waterproofing effect was 32.7 (decreased about SPF 7.9). Moisturizing effect of O/W cream at first was superior comparing multiple emulsion. But after 3 hours quickly was drop-down. Moisturizing effect of multiple emulsion was high comparing O/W type and other sun block creams after 4 hours was constantly maintaining water-content.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.30 no.1
• /
• pp.117-122
• /
• 2004

Exessive UV radiation causes a lot of problems in our skin. In order to find out the alternative UV absorber that can safely be used in cosmetics, we have screened various natural extracts in terms of their UV absorbing effect. Some natural extracts, which possess antioxidative activities, have also been found to retard the oxidation process in our experiment. Natural compound such as 7-hydroxycymopol, baicalein, etc. could be transformed into adjuvant UV absorber by chemical modification. In cosmetics, its chemical stability against UV radiation, exposure to oxygen and other factors could be improved by using the silicone or W/S type emulsion. The values of MED (minimal erythema dose) were improved to 0.10 ${\pm}$ 0.02∼0.11 ${\pm}$ 0.02 by adding this natural extract into the cosmetic formulations. In conclusion, the results of the present study show that natural extracts could be used as an adjuvant UV absorber, if they are stabilized.

• Journal of the Korean Society of Hazard Mitigation
• /
• v.11 no.2
• /
• pp.179-183
• /
• 2011

In this study, photochemical effects (OH radical formation) in the photoreactor was investigated to analyze UV-C intensity distribution. In addition, The influence radius of the UV-C lamp was measured at various dose of $TiO_2$ (Degussa P-25). The photoreactor used in this study was bath type reactor which is made by acrylic and the UV-C lamp (SANKYO DENKI, wavelength : 254 nm, Diameter : 2.2 cm, Length : 18.5 cm) was used as photo source. The maximum electric power consumption of the UV lamp was 10.5 W. The OH radical formation by UV-C was measured by KI dosimetry methods. From the results, the effective OH radical formation was occurred under the following condition. The reasonable distance of UV-C lamp is within 13 cm and the intensity of UV-C lamp should be more than 0.367 mW/$cm^2$. Moreover, the concentration of catalyst affects on the influence radius of the UV lamp.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.41 no.4
• /
• pp.351-359
• /
• 2015

Acute and chronic ultraviolet (UV) irradiation triggers severe skin photoaging processes, which directly disrupt the normal three-dimensional integrity of skin. UV light stimulates the expression of matrix metalloproteinases (MMPs) which degrade constituents of extracellular matrix (ECM) proteins. These MMPs reduce collagen synthesis and decrease skin elasticity and integrity, resulting in wrinkle formation. In this study, we identified Rosa multiflora hip extract (RME) as an effective anti-photoaging ingredient. First, cell proliferation activity of RME was verified using Hs68 human dermal fibroblast cell line. RME downregulated MMPs expression through the inhibition of activator protein (AP)-1. In addition, type I and IV collagen expressions were increased with RME treatment and UVB-induced inflammatory responses were also reduced after RME treatment. In conclusion, R. multiflora hip extract may effectively improve UVB-induced skin aging and wrinkle formation which may provide as an anti-aging, anti-wrinkle, and anti-inflammation ingredient in cosmetic industry.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.37 no.3
• /
• pp.247-256
• /
• 2011

Existing organic UV protection materials seem to be problematic due to their penetration and irritation to skin. Inorganic UV protection materials are also at issue for safety of their nano-type transformation. Therefore, the recent studies of UV protection materials have been focused not only on the effectiveness but also on their safety. One of the UV protection materials in study which have higher safety is the organic-inorganic conjugation type UV protection material. Previously, we have reported the manufacturing process, physical property and UV protection efficiency of methoxychinnamidoprophy poloysilsesquixan as a new cross-linked polymer type UV protection material. In this study, we have evaluated the effect of the methoxychinnamidoprophy poloysilsesquixan on embryo-fetal development in SD rats. This study is expected to show some definite information related to the effect on pregnancy or embryo-fetal abnormality in case of the clinical exposure of the methoxychinnamidoprophy poloysilsesquixan.

• Journal of the Society of Cosmetic Scientists of Korea
• /
• v.39 no.3
• /
• pp.251-257
• /
• 2013

In this study, ultraviolet protection factor (Sun Protection Factor, SPF) was investigated to provide basic data for subject safety and research of ultraviolet (UV) irradiation test in the future. Trial subjects (395 people) of skin type I, II, and III were evaluated according to skin type standard table. After measuring the skin color using a colorimeter, ITA (Individual Typology Angle) value was calculated. Subjects with 28 and above ITA value were positioned comfortably to be UV irradiated for 60 s and erythema was evaluated 24 hours after application. MED (Minimal Erythema Dose) was investigated where the minimal amount of erythema existed among UVB irradiated area. Statistical analysis was investigated using Statistical Package the Social Sciences program. As a result, the darker skin color results in the higher MED value since the higher skin type number results increased MED value and female has higher MED value than male since female has darker skin type than male. There was no relation between MED difference by ages in all different ages. However, it is hard to draw a conclusion as above since the number of subjects were not sufficient to support statistical significance for MED values by different ages. However, MED values by skin types obtained through this study can be used as a standard when MED value is expected to evaluate efficacy of sunscreen product and as basic data for further safety of clinical researches.

• Proceedings of the Korean Society of Dyers and Finishers Conference
• /
• 2011.03a
• /
• pp.105-105
• /
• 2011

국내 해양레저산업 중 세일요트산업은 현재 초기시장을 형성하고 있으나, 현재 정부의 해양레저 활성화 정책과 해양레저 인구 또한 관련 협회, 클럽 등의 중심으로 급속한 증가세를 이루고 있다. 이에 요트수요 증대에 따라 요트 관련 부품 소재의 경우에도 향후 그 수요가 대폭 증가할 것으로 예상되어지고 있으며, 그 중 요트용 돛(Sail)의 경우에는 전량 해외 수입에 의존하고 있어 제품개발을 통해 국산화함으로써 해외 제품의 수입대체가 요구되고 있다. 본 연구는 해외의 산업용 폴리에스터 원사로 제조된 요트세일 제품의 특성 및 성능 분석 결과와 국산 고강력 폴리에스터 소재로 제조된 요트 세일 개발 제품의 물성 및 성능을 비교 분석하고자 한다. 세일 제품 개발을 위해 해외 요트용 세일 제품을 분석한 결과, 소재는 고상중합형태의 폴리에스터 산업용 원사를 사용하여 직물자체의 고강도 및 저신도 특성발현을 위한 고밀도 제직을 실시한 것으로 분석 되었으며, 가공에서는 해양에서 사용하는 세일 직물의 특성 상 일광 및 자외선에 대한 내구성을 높이고, 황변을 방지할 수 있도록 하기 위해 직물표면에 멜라민계 수지를 이용한 함침방식의 특수코팅을 실시한 것으로 분석되었다. 이러한 해외 요트용 세일 제품의 분석결과를 바탕으로 국산 고강력 폴리에스터 고밀도 직물에 자외선 및 일광에 대한 내구성이 우수한 무황변 타입의 폴리에스터계 수지를 사용하여 단면 코팅으로 양면코팅 가공효과를 부여하는 나이프 방식의 특수코팅, 에이징 처리를 통해 세일을 제조하였다. 본 연구에서는 제조된 세일 직물 제품에 대해, 물리적 특성을 분석하기 위해 인장 강신도, 무게, 두께 및 주사전자현미경 관찰 등의 테스트를 실시하였으며, 세일 성능 분석을 위해 공기투과도, 일광견뢰도 자외선 조사 후 강도변화, 황변 Test 등의 테스트를 실시하여, 해외 선진 제품과 개발제품의 물성 및 성능에 대해 고찰하였다.

• Korean Chemical Engineering Research
• /
• v.47 no.6
• /
• pp.669-675
• /
• 2009

A study has been made on the preparation of liquid resin of non-solvent and non-discoloration type for replacement of the soft PVC at room temperature. A new synthetic process was developed by structure-control design of polyurethane synthesis using pre-polymer and polyols as curing agent. The optimum recipe was made according to macro-glycols, molecular weight and reaction conditions, and the final products indicated that the mechanical properties such as tensile strength, tear strength and flexibility was very excellent than PVC products. Also, viscosity, hardness and color operations of the final products can be controlled by this system. And yellowing property by UV and NOx gas was improved from the various additive experiment.

• Journal of the Korean Applied Science and Technology
• /
• v.37 no.6
• /
• pp.1517-1527
• /
• 2020

This study is about the UV protection effect and water resistance of a multiple emulsion (W/O/W) sunblock cream applied with emotional engineering and reports an actual industrial case. Multiple emulsion system of sunblock cream has the characteristics of changing to a W/O type that is soft and moist when applied, and has excellent water resistance after absorption. Multiple emulsion cream is a highly functional sunblock cream that has both moisture and water resistance. It is a stable milky white cream with a viscosity of 36,000 cps. The organic sunscreen used for the sunscreen was ethylhexylmethoxycinnamate and bisethylhexyloxyphenolmethoxyphenyltriazine. Hexagonal zinc oxide and titanium dioxide that block both UVB and UVA were used. As a result of measuring the UV protection effect by the in-vitro method, the UV protection effect (SPF) is 78.9 for multiple emulsion cream, 76.7 for W/O cream, and 71.3 for O/W cream. It was found that the blocking effect was different. This obtained the highest effect value in the multiple emulsion. As a clinical (in-vivo) result of the UV protection effect, the SPF value representing the UV protection effect of the sunblock cream developed with a multiple emulsion system was 85.7, and the PA-value that blocks the UVA area was 26.5, and ++++. It was found that it has a corresponding high blocking effect. As a result of the water resistance test, the W/O/W formulation had a high waterproofing resistance of 93.8% even after 4 hours, W/O had 75.4%, and O/W had a low water resistance of 25.3%. In the results of the HUT test, it was found in the order of multiple emulsion sun block cream > hydrophilic cream > lipophilic cream. Based on the research results of this multiple emulsion, it is expected to be highly active as a sunblock cream dedicated to outdoor activities by improving the feeling of use, UV protection index, and water resistance. Therefore, in this study, a multiple emulsion system of sunblock cream is developed and has a characteristic that changes to a W/O type that has a soft and moist feeling when applied, and has excellent water resistance after absorption.