• Journal of the Korean Chemical Society
• /
• v.24 no.4
• /
• pp.269-279
• /
• 1980

A method for calulation of the magnetic moments for both octahedral and distorted octahedral $[V(III)A_3B_3]$ type complexes, all with $t^2_2$ configuration, has been developed [A and B = O, Cl, N, F or Br]. The calculated magnetic moments by this method are in reasonable agreements with the experimental values. The calculated magnetic moments for distorted octahedral $[V(III)A_3B_3]$/TEX> type complexes decrease as the extent of tetragonal distortion increases.The effects of k (orbital reduction faction factor), $\xi'$/TEX> and temperature on the magnetic moments are also investigated.A new method for calculation of the contribution of $^3T_1$ molecular orbitals to the dipole moment and polarizability has also developed. The calculated contribution of $^3T_1$ molecular orbitals falls in the reasonable range of values.

• Journal of the Korean Institute of Telematics and Electronics A
• /
• v.32A no.2
• /
• pp.66-72
• /
• 1995

Using the Si/SiGe layer grown by solid source molecular beam epitaxy(SSMBE) on the LOCOS-patterned wafers, an emitter-base self-aligned hterojunction biplar transistor(HBT) with the polysilicon-emitter and the silicon germanium(SiGe) base has been fabricated. Trech isolation process, planarization process using a chemical-mechanical poliching, and the selectively implanted collector(SIC) process were performed. A titanium disilicide (TiSi$_{2}$), as a base electrode, was used to reduce an extrinsic base resistance. To prevent the strain relaxation of the SiGe epitaxial layer, low temperature (820${^\circ}C$) annealing process was applied for the emitter-base junction formation and the dopant activation in the arsenic-implanted polysilicon. For the self-aligned Si/SiGe HBT of 0.9${\times}3.8{\mu}m^{2}$ emitter size, a cut-off requency (f$_{T}$) of 17GHz, a maximum oscillation frequency (f$_{max}$) of 10GHz, a current gian (h$_{FE}$) of 140, and an emitter-collector breakdown voltage (BV$_{CEO}$) of 3.2V have been typically achieved.

• Korean Journal of Optics and Photonics
• /
• v.6 no.4
• /
• pp.352-358
• /
• 1995

Measurements of the Faraday rotation and magnetization of terbium-doped Hoya FR5 glass and cerium-doped Hoya FR4 glass have been made as a function of temperature T in the range 4.2 K -10 K and of magnetic field H of up to 80 kG at the $Ar^+$ laser wavelength of 514.5nm. The saturations of magnetization and Faraday rotation above H/T> $5kG.K^{-1}$ can be analyzed by the quantum theory of paramagnetism. Calculated parameters show that the large Verdet constant of $Ce^{3+}$ glass is due to the effective $4f\rightarrow5d$ electric dipole transition effect and that of $Tb^{3+}$ glass is due to the magnetization effect.effect.

• Proceedings of the Korean Institute of Intelligent Systems Conference
• /
• 2005.11a
• /
• pp.185-188
• /
• 2005

본 논문에서 신경망을 이용한 자계기반 자율주행 시스템의 조향 제어기 설계를 제안한다. 자율주행시스템에서 가장 중요한 핵심요소는 자계토로상의 센서의 현재위치를 파악하고 주행하는 것이다. 먼저 자계도로상의 현재위치를 파악하기 위한 방법으로, 첫 번째 자기쌍극자 모델식이 센서에서 측정된 자계와 일치함을 보였다. 두 번째 Peak Mapping법을 이용하여 외란으로 작용하는 지자계 성분을 제거할 수 있음을 입증하였다. 세 번째로 신경망을 이용하여 높이성분($B_{z}$)가 변하더라도 정확한 거리가 계측됨을 확인하였다. 따라서 신경망을 이용하면 소량의 메모리를 사용할 수 있으므로 실제 시스템에서 경제적인 효과를 볼 수 있고, 정확한 거리를 계측하므로 경로를 이탈하지 않고 자율주행이 가능한 시스템을 설계하였다.

• Economic and Environmental Geology
• /
• v.47 no.4
• /
• pp.395-404
• /
• 2014

We conducted the geophysical survey of possible hydrothermal vent sites at 2009, in the Lau Basin, the south western Pacific and analyzed the magnetic characteristics of TA19-1 and TA19-2 seamounts. TA19-1 is a cone-shaped seamount with a caldera summit. TA19-2 seamount is bigger and shows more complicated topography than TA19-1 seamount. TA19-2 has a large caldera, a summit in the west side of the caldera and several crests. Simple dipole anomalies with a high over the north and a low over the south occur in TA19-1 seamount. High magnetic anomalies are located in the northern flank and the summit of TA19-2 seamount and low anomalies around the summit and the caldera. The results of bathymetry and magnetic data suggest that TA19-2 seamount might have more complicated magmatic process than TA19-1. Low magnetization zones are located over the summit, the calderas and the caldera rims. The magnetization lows indicate that submarine hydrothermal vents, along faults and fracture zones, could have caused an alteration of magnetic minerals. The magnetization highs over the summit and the calderas might have been related with later magmatisms like volcanic sills, intrusions.

• Journal of the Korean earth science society
• /
• v.24 no.4
• /
• pp.361-368
• /
• 2003

We have investigated the electric resistivity structure of the fault zone located in the Hongseong area where a big earthquake with M 5.0 occurred in 1978. Usually, Electric and Electromagnetic methods are broadly operated in the field of engineering works since these methods are effective to understand the distribution of geological weak zones - fault or fracture zones. We have conducted the dipole-dipole array resistivity method and MT(magnetotelluric) method and interpreted the resistivity distribution of the fault zone with the aid of various inversion methods. An MT survey was performed at 18 points along a 2.9 km survey line perpendicular to the fault line and a magnetic dipole source was used to enhance the S/N ratio in the high frequency. A Electric dipole-dipole array resistivity survey with the dipole length of 50 meters was carried out perpendicular to the fault. In view of two survey results, the fault marks the boundary between two opposite resistivity structures, especially the low resistivity zone is exhibited deeply through the prospective fault line. The result that the low resistivity zone is located at the center of the fault zone corresponds with the fact that the fault zone of the Hongseong area is active. We expect these results to provide basic information about the physical properties of fault zones in Korea.

• Journal of the Korean Chemical Society
• /
• v.39 no.5
• /
• pp.356-363
• /
• 1995

The chemical behavior of the transition metal (Nb4+ and Mo4+) complexes with organoligand (dichloro-bis(η-cyclopentadienyl) has been investigated by the UV/vis-spectrophotometric, magnetic, and electrochemical method. The two or three energy absorption bands are observed by the spectra of these complexes. The magnitude of crystal field splitting energy, the spin pairing energy and bond strength was obtained from the spectra of the complexes. These are found to be delocalization, low-spin state, and strong bonding strength. The magnetic dipolemoment are found to be paramagnetic and diamagnetic complexes. The redox reaction processes of complexes were investigated by cyclic voltammetry in aprotic media. As a result the redox reaction proceses of Nb-C complex was couple-single reaction with diffusion and reaction current one electron process, and also Mo-C complex was couple-single reaction with reaction current of one electron process.

• Journal of the Korean Chemical Society
• /
• v.55 no.4
• /
• pp.603-611
• /
• 2011

Ethoxylacetyl oxime ligands [HL, (1) and $H_2L^1$, (3)] react with copper(II) acetate monohydrate yield octahedral and square planar complexes, respectively. The complexes have been postulated due to elemental analyses, IR, UVVis. spectra, magnetic susceptibility, conductivity and ESR spectra. Molar conductance of the complexes in DMF indicates a non-ionic character. The ESR spectra of [$(L)_2Cu(H_2O)_2$], (2) complex at room temperature and 77K are characteristic of an axial symmetry ($d_{x2-y2}$) with covalent bond character and have a large line width typical of dipolar interactions. However, [$(L^1)Cu$], (4) complex in the solid state showed spectra of marked broadening and loss of hyperfine splitting confirming spinexchange interactions between the copper(II) sites. The spectrum of the doped copper(II) complex at room temperature showed super-hyperfine splitting from coordinated nitrogen atoms and it has an axial type ($d_{x2-y2}$) with covalent bond character and an essentially square-planar arrangement around the copper(II) ion. The spectrum of [$(L^1)Cu$], (4) in frozen methanol at 77K was characteristic of the triplet state of a dimer species and the distance found between the two copper(II) centers was calculated and is equal to 4.8 ${\AA}$.

• Geophysics and Geophysical Exploration
• /
• v.5 no.4
• /
• pp.280-290
• /
• 2002

Three-dimensional (3-D) electromagnetic (EM) modeling algorithm has been developed using finite element method (FEM) to acquire more efficient interpretation techniques of EM data. When FEM based on nodal elements is applied to EM problem, spurious solutions, so called 'vector parasite', are occurred due to the discontinuity of normal electric fields and may lead the completely erroneous results. Among the methods curing the spurious problem, this study adopts vector element of which basis function has the amplitude and direction. To reduce computational cost and required core memory, complex bi-conjugate gradient (CBCG) method is applied to solving complex symmetric matrix of FEM and point Jacobi method is used to accelerate convergence rate. To verify the developed 3-D EM modeling algorithm, its electric and magnetic field for a layered-earth model are compared with those of layered-earth solution. As we expected, the vector based FEM developed in this study does not cause ny vector parasite problem, while conventional nodal based FEM causes lots of errors due to the discontinuity of field variables. For testing the applicability to high frequencies 100 MHz is used as an operating frequency for the layer structure. Modeled fields calculated from developed code are also well matched with the layered-earth ones for a model with dielectric anomaly as well as conductive anomaly. In a vertical electric dipole source case, however, the discontinuity of field variables causes the conventional nodal based FEM to include a lot of errors due to the vector parasite. Even for the case, the vector based FEM gave almost the same results as the layered-earth solution. The magnetic fields induced by a dielectric anomaly at high frequencies show unique behaviors different from those by a conductive anomaly. Since our 3-D EM modeling code can reflect the effect from a dielectric anomaly as well as a conductive anomaly, it may be a groundwork not only to apply high frequency EM method to the field survey but also to analyze the fold data obtained by high frequency EM method.

• Geophysics and Geophysical Exploration
• /
• v.2 no.3
• /
• pp.142-148
• /
• 1999

Three-dimensional electromagnetic modeling algorithm in homogeneous half-space was developed using the extended Born approximation to an electric field integral equation. To examine the performance of the extended Born approximation algorithm, the results were compared with those of the full integral equation results. For a crosshole source-receiver configuration, the agreement between the integral equation and the extended Born approximation was remarkable when the source frequency is lower than 20 kHz and conductivity contrast lower than 1:10. Beyond this conductivity contrast, the simulated results by the extended Born approximation exhibit a difference with respect to those by the integral equation. Therefore, the limit of accuracy lies below contrast of 1:10 in the extended Born approximation. Since for the source frequency range from 20 kHz to 100 kHz, however, the difference is relatively small, the extended Born approximation could be used for a reasonable 3-D EM modeling algorithm.