• Journal of the Korean Chemical Society
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• v.39 no.8
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• pp.657-665
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• 1995

The oxidation of various benzyl ethers and benzyl alkyl ethers to benzoates has been studied in two-phase system of $CH_3CO_2Et$ and aqueous NaOCl (6.6 mol eq.). The oxidant N-oxo-4-methoxy-2,2,6,6-tetramethylpiperidium bromide (N-oxoammonium salt) was prepared in situ and recycled by addition of 4-methoxy-2,2,6,6-tetramethylpiperidine-1-oxyl (0.03 mol eq., 4-methoxy-TEMPO), co-catalyst KBr (0.03mol eq.) and second oxidant NaOCl. Thus the catalytic amount of 4-methoxy-TEMPO was used. An adjustment of the pH value of below 8.0 was also required for this reaction with 2.5 hr of reaction time at 0∼5$^{\circ}C$. Under these conditions benzyl ethers were oxidized to benzoates. The selectivity of oxidation of benzyl alkyl ethers is dependent on the acidity of hydrogen and steric effect of alkyl group.

• Microbiology and Biotechnology Letters
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• v.34 no.2
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• pp.129-135
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• 2006

A gene encoding for a putative microsomal epoxide hydrolase (mEH) of a zebrafish, Danio rerio, was cloned and characterized. The putative mEH protein of D. rerio exhibited sequence similarity with mammalian mEH and some other bacterial EHs. A structural model for the putative mEH was constructed using homology modeling based on the crystallographic templates, 1 qo7 and 1 ehy. The catalytic triad consisting of $Asp^{233}$, $Glu^{413}$, and $His^{440}$ was identified, and the characteristic features such as two tyrosine residues and oxyanion hole were found to be highly conserved. Based on bioinformatic analysis together with EH activity assay, the putative protein was annotated as mEH of D. rerio. Enantiopure styrene oxide with enantiopurity of 99%ee and yield of 33.5% was obtained from racemic styrene oxide by the enantioselective hydrolysis activity of recombinant mEH of D. rerio for 45 min.

• 월간 기계설비
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• no.11 s.184
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• pp.57-71
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• 2005

SHOP DWG의 현주소 어디까지 왔는가? 설계에서 제조에 이르는 전 과정을 컴퓨터로 제어하고 관리하는 기술. 캐드(CAD)와 캠(CAM)은 각각 computer-aided design,computer-aided manufacturing의 약칭으로 컴퓨터보조설계와 컴퓨터보조생산을 뜻한다. CAD는 설계도면을 한 장씩 수작업으로 제도하지 않고 설계 데이터베이스의 정보를 CRT(cathode ray tube)에서 화상을 보고 합성하면서 설계하므로 작업을 최적화 할 수 있다. CAD로 설계된 설계도의 내용은 CAM을 통해 NC(수치제어)공작기계에 정확한 작업동작을 지시하게 되며, 작업관리∙가공∙조립∙검사 등의 제조과정을 컴퓨터로 관리하여 작업속도와 제품의 정밀성을 높이게 된다. 최근에는 건축현장의 2D system이 보편화되어 있지만 건축현장의 핵심이라고 할 수 있는 기계설비의 기계실, 또는 조립화 공법 등에는 3차원 CAD∙CAM시스템이 개발되어 입체형상을 화면에 3차원으로 재현할 수 있고, 대상물의 표면적∙부피∙무게∙강도 등의 물리적 성질도 자동 계산하여 최적상태에서 현장의 시공에 적용할 수 있게 되었다. 1960년대 초 미국에서 자동차 모델∙엔진, 항공기 부품 등 의 설계에 수작업의 한계를 느껴 개발되었으며, 한국에서는 70년대 중반에 도입되어 운용되고 있다. 이에 따라 프로그램 회사들은 다양한 방법 등을 SHOP DWG에 적용하여 판매경쟁이 치열하다. (주)우진아이엔에스는 급속한 산업경제의 변화와 무한경쟁시대에 보다 나은 기술개발 투자에도 노력을 기울여, 2000년 11월 용인공장, 생산라인을 천안으로 이전, 확장 하여 배관 및 닥트의 CAD-CAM SYSTEM, P.F.P공법, 기계실3D, 블럭화배관, 닥트자동화 시스템, 설계, 용접공정을 공장화시켰으며, 신 개발품인 S.C.D(SEMI-CON DUCT)를 신설하여 모든 건축물에 맞는 필수적인 제품을 생산함으로써 선택의 폭을 넓히고, 현장 시공능력 효율을 높이고 있다. 이번 호에서는 (주)우진아이엔에스가 95년 설계팀을 발족하여 제로시스템의 3D공법을 공장 및 현장의 SHOP DWG에 적용해왔고 최근에는“서초 프로젝트A”현장에 SHOP DWG의 최대 결집체인 3D활용의 조립화 공법을 적용하여 초고층 오피스텔현장을 시공한 사례를 게재한다. 우진아이엔에스는 30여년의 기술 축척을 바탕으로 최고의 기술력과 풍부한 경험을 통해 아셈무역센타, 타워팰리스1차, 3차 및 목동트라팰리스, 분당트리폴리스, 수원삼성전자 R4, 등 국내굴지의 초고층빌딩 시공을 근거로 초고층의 기본설계를 이해하고 SHOP DWG을 통해서 기계설비공사의 향후 나아갈 지표를 제시하고 있다.

• Journal of the Korean Electrochemical Society
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• v.16 no.4
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• pp.198-203
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• 2013

Copolymer consisted of MMA and tBMA was synthesized by radical polymerization and poly(MMA-co-MA) was prepared by selective hydrolysis of tert-butyl group. The obtained polymer was coupled with epoxy functionalized PEO of various molecular weight to synthesize poly(MMA-co-PEGMA) with different side chain length. The AC-impedance measurement shows $1.88{\times}10^{-6}Scm^{-1}$ of room temperature ionic conductivity from 48mol% of MMA while $5.11{\times}10^{-8}Scm^{-1}$ was observed in 82mol% sample. In addition, there was an effect of PEGMA molecular weight on ionic conductivity possibly due to the steric hindrance in grafting-onto coupling reaction. Finally, the polymer electrolytes shows electrochemical stability up to 6V at room temperature.

• Journal of Korean Association for Spatial Structures
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• v.12 no.1
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• pp.59-68
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• 2012

The space frame structure is one of the large span structural system consisting of longitudinal and latitudinal members. The members are connected in three dimension. A space frame structure has high stiffness with a structure resisting external forces in steric conformation. According to many structural conditions, structural stability problems in the space frame are determined and considered very important. This study seeks to understand the space frame collapse mechanism using the 2-free nodes truss model in order to examine static structural instability characteristics of the latticed dome. According to geometrical shape, the star dome, parallel lamella dome and three way grid dome were selected as models. The models were examined for characteristics of instability under STEP Excitations behavior according to rise-span ratio(${\mu}$) and shape imperfection.

• Journal of Korean Association for Spatial Structures
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• v.12 no.2
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• pp.109-118
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• 2012

Few paper deal with the dynamic bucking under the load with periodic characteristics, and the behavior under periodic excitation is expected the different behavior against STEP excitation. A space frame structure has high stiffness with a structure resisting external forces in steric conformation. According to many structural conditions, structural stability problems in the space frame are determined and considered very important. This study seeks to understand the space frame collapse mechanism using the 2-free nodes truss model in order to examine static structural instability characteristics of the latticed dome. According to geometrical shape, the star dome, parallel lamella dome and three way grid dome were selected as models. The models were examined for characteristics of instability behavior according to rise-span ratio(${\mu}$) and shape imperfection.

• The Journal of the Korea Contents Association
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• v.22 no.6
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• pp.78-91
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• 2022

The importance of emotional intelligence education in the development of children's augmented reality education content is overlooked. Therefore, in-depth research is needed to develop children's emotional intelligence. This study was conducted through theoretical consideration and case analysis. The proposal of this paper is that the augmented reality type for children aged 2 to 7 is suitable for indoor activities with marking recognition technology. To promote an understanding of emotions, a large screen is selected, and emoticon dolls or emoticon books are recommended for learning content. Children aged 7 to 11 are suitable for indoor activities of non-marker recognition technology, and can induce emotional control and emotional recognition through active manipulation. For the learning content, "3D art teaching content" and "Online Classic Musical" are recommended. Children after the age of 11 are suitable for non-marker recognition technology outdoor activities and improve each element of emotional intelligence through interaction with nature and society. For the learning content, 'Forest Play Activity through Art' and 'EQ Theater Play' are recommended. Through this paper, we intend to promote the development of children's augmented reality emotional intelligence education.

• The Korean Journal of Pesticide Science
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• v.6 no.3
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• pp.209-217
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• 2002

Two different QSAR methods, the comparative molecular similarity indices analyses (CoMSIA) and hologram quantitative structure activity relationship (HQSAR) are studied for the fungicidal activities ($pI_{50}$) of 2-N-benzyl-5-phenoxy-3-isothiazolone derivatives against sensitive (SPC: 95CC7105) and resisitive (RPC: 95CC7303) phytophthora blight fungus (Phytaphthora capsici). According to the findings from these QSAR investigation, the cross-validation value, $q^2$ and Pearson correlation coefficient, $r^2$ in the two methods were CoMSIA: RPC; $q^2=0.675,\;r^2=0.942$, SPC; $q^2=0.350,\;r^2=0.876$ and HQSAR: RPC; $q^2=0.519,\;r^2=0.869$, SPC; $q^2=0.483,\;r^2=0.990$, respectively. Therefore, the two models of comparative statistical significance were obtained. From the CoMSIA contour maps, the important factors for selective fungicidal activity against RPC are to be expected that the lower hydrophobic and not bulkiness substituent as hydrogen bonding acceptor have to introduce to meta and para-position (C1-C6) on the phenoxy moiety. And the results of prediction suggest that HQSAR method showed higher fungicidal activity than CoMSIA method.

• Applied Biological Chemistry
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• v.47 no.4
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• pp.414-421
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• 2004

3D QSAR studies for protox inhibition activities against root and shoot of the rice plant (Orysa sativa L.) and barnyardgrass (Echinochloa crus-galli) by a series of new 1-(5-methyl-3-phenylisoxazolin-5-yl)methoxy-2-chloro-4-fluorobenzene derivatives were conducted based on the results (Sung, N. D. et al.'s, (2004) J. Korean Soc. Appl. Biol. Chem. 47(3), 351-356) using comparative molecular similarity indices analysis (CoMSIA) methodology. Four CoMSIA models, without hydrogen bond donor field for the protox inhibition activities against root and shoot of the two plants, were derived from the combination of several fields using steric field, hydrophobic field, hydrogen bond acceptor field, LUMO molecular orbital field, dipole moment (DM) and molar refractivity (MR) as additional descriptors. The predictabilities and fitness of CoMSIA models for protox inhibition activities against barnyard-grass were higher than that of rice plant. The statistical results of these models showed the best predictability of the protox inhibition activities against barnyard-grass based on the cross-validated value $r^2\;_{cv}\;(q^2=0.635{\sim}0.924)$, non cross-validated, conventional coefficient $r^2\;_{ncv.}$ value $(r^2=0.928{\sim}0.977)$ and PRESS value $(0.255{\sim}0.273)$. The protox inhibition activities exhibited a strong correlation with the steric $(5.4{\sim}15.7%)$ and hydrophobic $(68.0{\sim}84.3%)$ factors of the molecules. Particularly, the CoMSIA models indicated that the groups of increasing steric bulk at ortho-position on the C-phenyl ring will enhance the protox inhibition activities against barnyard-grass and subsequently increase the selectivity.

• Korean Chemical Engineering Research
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• v.51 no.3
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• pp.394-402
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• 2013

The new complex catalysts were synthesized by the reaction of titanium compounds (titanium chloride or titanium butoxide) and diamines in this work, and they showed very high catalytic activities for the cyclododecatriene (CDT) synthesis from 1,3-butadiene through trimerization. CDT synthetic reaction was performed in an autoclave reactor, and the effects of reaction temperature, type of catalyst, catalyst amount added into the system, the mole ratio of Al/Ti and immobilization method were investigated on the yield of product CDT. The titanium complex catalyst combined to diamine with 1:1 ratio showed high selectivity to CDT more than 90%. The ratio of TTT-CDT/TTC-CDT isomers in the product revealed as different values, depending on the type of diamine combined to titanium and Ti/diamine ratios. Those homogeneous complexes could be used as a heterogenized catalyst after anchoring on the supports, and the immobilized titanium catalyst retained the catalytic activities for several times in the recycled reactions without leaching. The carbon support containing titanium has exhibited superior activity to the silica support. Especially, when the titanium complex was anchored on the support which was fabricated by the hydrolysis of tripropylaminosilane itself, the resulting titanium catalyst showed the highest BD conversion and CDT selectivity.