• Title/Summary/Keyword: 임계온도

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Thermal Properties and Fracture Toughness of Bisphenol-Based DGEBA/DGEBS Epoxy Blend System (Bisphenol계 DGEBA/DGEBS 에폭시 블렌드 시스템의 열적 특성 및 파괴인성)

  • 박수진;김범용;이재락;신재섭
    • Polymer(Korea)
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    • v.27 no.1
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    • pp.33-39
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    • 2003
  • In this study, the bisphenol-based DGEBA/GEBS blend systems were studied in cure kinetics, thermal stabilities, and fracture toughness of the casting specimen. The content of DGEBA/DCEBS was varied in 100 : 0, 90 : 10, 80 : 20, 70 : 30, and 60 : 40 wt%. The cure activation energies ($E_a$) of the blend systems were determined by Ozawa's equation. The thermal stabilities, including initial decomposed temperature (IDT), temperatures of maximum rate of degradation ($T_{max}$), and integral procedural decomposition temperature (IPDT) of the cured specimen were investigated by thermogravimetric analysis (TGA). For the mechanical interfacial properties of the specimens, the critical stress intensity factor ($K_{IC}$) test was performed and their fractured surfaces were examined by using a scanning electron microscope (SEM). As a result, $E_a$, IPDT, and $K_{IC}$ show maximum values in the 20 wt% DGEBS content compared with the neat DGEBA resins. This was probably due to the fact that the elevated networks were farmed by the introduction of sulfonyl groups of the DCEBS resin.

ZnSe 박막 성장을 위한 Molecular Beam Epitaxy 성장 조건의 결정

  • Jeong, Myeong-Hun;Park, Seung-Hwan;Kim, Gwang-Hui;Jeong, Mi-Na;Yang, Min;An, Hyeong-Su;Jang, Ji-Ho;Kim, Hong-Seung;Song, Jun-Seok;Yao, Takafumi
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • v.9 no.1
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    • pp.990-994
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    • 2005
  • MBE growth conditions such as growth temperature, flux ration and growth rate for II-VI compound semiconductor growth has been studied. The growth temperature, flux ration and growth rate were tentatively controlled to 290$^{\circ}C$, 2, and 0.6 ${\mu}m$/h, respectively. From AFM result, relatively rough surface (RMS ${\sim}$ 2.9 nm) was observed. It was regarded as an indication of low growth temperature and high growth rate. XRD measurement shows that the film is relaxed, also the series of XRD measurements of different diffraction planes such as (002), (004), (115), (006) diffractions were performed to calculate the dislocation density in the film. The calculated dislocation density was found to be 8.30${\times}10^8$ dis/cm$^2$ which is compatible to the previous results.

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Experimental Assessment of Microwave Sintering Efficiency Based on System Configuration and Dwell Time (시스템 구성 및 유지시간에 따른 마이크로파 소결 효율 평가)

  • Lee, Jangguen;Jin, Hyunwoo;Kim, Young-Jae
    • Journal of the Korean Geotechnical Society
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    • v.40 no.4
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    • pp.81-90
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    • 2024
  • With the discovery of energy resources such as water ice on the Moon's surface, the Moon is attracting attention as an outpost for deep space exploration. As the concept of in situ resource utilization (ISRU) for establishing sustainable deep space exploration outposts gains traction, there is an increasing demand for technology to solidify lunar regolith as an in situ resource. In this study, sintered blocks were manufactured using a hybrid microwave sintering furnace. The effects of system configuration and dwell time on the microwave sintering efficiency were assessed. The results indicated that the composition of the SiC susceptor and its distance from the magnetron influenced the manufacturing of homogeneous sintered blocks. Additionally, varying the dwell time at a sintering temperature of 1,080℃ under optimal conditions revealed that exceeding the threshold dwell time caused the sintered blocks to become heterogeneous, thereby reducing the sintering efficiency.

가시광 투과율 향상을 위한 2차원적 벌집구조를 갖는 이산화 바나듐(VO2) 박막 제작

  • Kim, Dong In;Yu, Jung-Hoon;Nam, Sang-Hun;Seo, Hyeon Jin;Hwang, Ki-Hwan;Kim, Jee Yun;Joo, Yong Tae;Boo, Jin-Hyo
    • Proceedings of the Korean Vacuum Society Conference
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    • 2015.08a
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    • pp.256-256
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    • 2015
  • 이산화 바나듐 ($VO_2$)은 340 K 임계온도를 기점으로 금속-절연체 상전이를 통해 전기적, 광학적 특성이 가역적으로 변하는 물질로 잘 알려져 있다. 그러나 낮은 가시광 투과율과 비선호적인 색상(황갈색)으로 인해 열변색 스마트 창호응용과 관련하여 해결해야 할 문제로 남아있다. 본 연구에서는 상기 문제를 해결하고자 고분자 나노 구 템플릿을 응용하여 2차원의 벌집구조를 갖는 $VO_2$ 박막을 졸 겔 방법을 통해 제작하였으며 가시광 투과율 향상을 유도하였다. 나노 구의 지름과 코팅조건에 따라 구조변화를 유도하였으며 FE-SEM과 AFM을 통해 박막의 구조적 변화를 측정하였다. 결과로부터 나노 구의 역상모양을 갖는 박막이 형성 되었으며 직경에 따라 패턴 간격이 확연하게 변화되었음을 확인 하였다. 나노 구가 위치하고 있던 자리로부터 빈 공간형성을 유도할 수 있었으며 이는 가시광 투과율향상에 직접적 영향을 주었다. 또한 상기 패턴화된 $VO_2$ 박막은 광학 스위칭 효율을 유지하면서 주기적 패턴으로부터 시각적으로 광결정유도를 통한 미적 시너지를 보였며 본 연구로부터 $VO_2$기반 스마트 창호 응용에 많은 기여가 기대된다.

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Superconducting Properties and Tunneling Spectroscopy of Bi2Sr2Ca(Cu1-xNix)2O8+δ Film by LPE Method (LPE법으로 성장시킨 Bi2Sr2Ca(Cu1-xNix)2O8+δ 막(film)의 초전도특성 및 터널링 분광)

  • 이민수
    • Journal of the Korean Ceramic Society
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    • v.40 no.5
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    • pp.455-459
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    • 2003
  • Tunneling spectra of B $i_2$S $r_2$Ca(C $u_{1-x}$ N $i_{x}$ )$_2$ $O_{8+}$$\delta$/ film by LPE method have been measured using break junctions. The energy gap 2$\Delta$ and 2$\Delta$/ $k_{B}$ $T_{c}$ $^{zero}$ increased with increase of ft. We obtained the energy gap Parameter 2$\Delta$(4.2 K) = 54.4~64 meV, and corresponding1y $\Delta$/ $k_{B}$ $T_{c}$ $^{zero}$=7.36~10.14, larger than the BCS value. The lattice constant c and critical temperature $T_{c}$ $^{zero}$ decrease with increase of $\chi$$_{L}$.

Finite Element Based Multi-Scale Ductile Failure Simulation of Full-Scale Pipes with a Circumferential Crack in a Low Carbon Steel (유한요소기반 다중스케일 연성파손모사 기법을 이용한 원주방향 균열이 존재하는 탄소강 실배관의 파손예측 및 검증)

  • Han, Jae-Jun;Bae, Kyung-Dong;Kim, Yun-Jae;Kim, Jong-Hyun;Kim, Nak-Hyun
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.38 no.7
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    • pp.727-734
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    • 2014
  • This paper describes multi-scale based ductile fracture simulation using finite element (FE) damage analysis. The maximum and crack initiation loads of cracked components were predicted using proposed virtual testing method. To apply the local approach criteria for ductile fracture, stress-modified fracture strain model was adopted as the damage criteria with modified calibration technique that only requires tensile and fracture toughness test data. Element-size-dependent critical damage model is also introduced to apply the proposed ductile fracture simulation to large-scale components. The results of the simulation were compared with those of the tests on SA333 Gr. 6 full-scale pipes at $288^{\circ}C$, performed by the Battelle Memorial Institute.

Ignition of Solid Propellants at Subatmospheric Pressures (대기압 이하에서 고체 추진제의 점화 특성 향상 연구)

  • Kim In-Chul;Ryoo Baek-Neung;Jung Jung-Yong
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2006.05a
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    • pp.383-386
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    • 2006
  • Several HTPB/AP and HTPB/AP/HMX propellants were investigated experimentally for ignition characteristics in subatmospheric pressure. The threshold ignition pressure was 4psia for HTPB/AP composite propellant. The partial replacement of AP in HTPB/AP composite propellant by $5\sim15%$ of HMX, HNIW showed improvements in the threshold pressure was below 0.4psia. This appears to be due to the exothermic dissociation characteristics of HMX and HNIW at lower temperature $(\sim220^{\circ}C)$ than that of AP. The ignition substance B/KNO3 was coated thinly on the propellant surface for better ignition effect. As a result, ignition delay time of 15% was improved. NC is applied to $B/KNO_3$ ignition substance as a secondary binder and $NC-B/KNO-3$ suspension solution is coated to the propellant surface.

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Thermal-Structure Interaction Parallel Fire Analysis for Steel-Concrete Composite Structures under Bridge Exposed to Fire Loading (화재에 노출된 교량하부 강합성 구조물에 대한 열-구조 연성 병렬화재해석)

  • Yun, Sung-Hwan;Gil, Heungbae;Lee, Ilkeun;Kim, Wooseok;Park, Taehyo
    • Journal of the Computational Structural Engineering Institute of Korea
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    • v.26 no.4
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    • pp.283-292
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    • 2013
  • The objective of this research is to evaluate of global and local damage for steel-concrete composite structures under highway bridge exposed to fire loading. To enhance the accuracy and efficiency of the numerical analysis, the proposed transient nonlinear thermal structure interaction(TSI) parallel fire analysis method is implemented in ANSYS. To validate the TSI parallel fire analysis method, a comparison is made with the standard fire test results. The proposed TSI parallel fire analysis method is applied to fire damage analysis and performance evaluation for Buchen highway bridge. The result of analysis, temperature of low flange and web are exceed the critical temperature. The deflection and deformation state show good agreement with the fire accident of buchen highway bridge.

Analyzing Mortality Rate and Social Costs of Climate Vulnerable Groups caused by Heat Waves in Korea (폭염 발생에 따른 취약계층의 사망률 변화와 사회적 비용 추정: 7대 광역시의 65세 이상 고령층을 중심으로)

  • Shin, Dong-Hee;Lee, Na-Young;Cho, Yongsung
    • Journal of Environmental Policy
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    • v.14 no.1
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    • pp.3-32
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    • 2015
  • The critical temperature and the rate of increase in excess death caused by heat waves in the age group of 65 years and older are derived. The value of statistical life method was used to quantify economic damages, and the willingness to pay after 71 years of age for 10 years was measured based on the dichotomous choice contingent valuation method survey. The result shows about KRW 481,110,000 is required annually to reduce the possibility of death by climate change to 1/1000.

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Gas Permeation Characteristics of PTMSP/PMMH Dendrimer Composite Membranes (PTMSP/PMMH Dendrimer 복합막의 기체투과특성)

  • Lee, Hyun-Kyung;Jung, Won-Sook
    • Membrane Journal
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    • v.18 no.3
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    • pp.226-233
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    • 2008
  • PTMSP/PMMH dendrimer composite membranes were made by dispersing $0{\sim}20$ wt% (based on polymer content) PMMH dendrimer nanoparticles in the PTMSP casting solution. The effect of PMMH dendrimer on gas permeability characteristics of the composite membranes was investigated. The permeabilities of $H_2,\;N_2,\;CO_2$, and $CH_4$ decreased as the PMMH dendrimer content within PTMSP increased. The permeabilities of different gases except hydrogen in PTMSP/PMMH dendrimer membranes follow the order: $N_2\;<\;CH_4\;<\;CO_2$ which are consistent with the order of critical temperature ($N_2\;<\;CH_4\;<\;CO_2$). The selectivities of gases for $N_2$ increased as the PMMH dendrimer content within PTMSP increased. The $CO_2/N_2$ selectivity increased from 5.6 up to 16.9.