• Title/Summary/Keyword: 일산화 질소

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Synthesis of 8-Cycloalkoxychrysin Analogs and their Inhibitory Activity Against NO Production (고리형 알콕시기를 함유한 크리신 유도체의 합성 및 일산화질소 생성 억제작용)

  • Kim, Sung-Soo;Park, Haeil
    • YAKHAK HOEJI
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    • v.59 no.1
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    • pp.12-16
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    • 2015
  • Several 8-cycloalkoxychrysin analogs were synthesized from 6-benzyloxy-5,8-dihydroxyflavone and cycloalkanols in 2 steps and we evaluated their inhibitory activities against NO production from LPS-induced RAW 264.7 cells. Among tested analogs, two analogs with cyclopentyl substructure (796 and 798) showed strong inhibitory activity against NO production.

Combustion Flame Diagnostics Using Laser-Induced Fluorescence (레이저 유도 형광법에 의한 연소화염 진단기법 연구)

  • Kim, T.K.
    • Transactions of the Korean Society of Automotive Engineers
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    • v.3 no.5
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    • pp.24-29
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    • 1995
  • A laser system and signal aquisition system to use a laser-induced fluorescence technique were arranged to measure NO concentration. To identify the NO fluorescence signal, verification of the fluorescence was performed through use of comparison of the signals taken both in a undoped and doped calibration flames. Finally, the spatial NO number densities in partially premixed flames were found as a function of fuel-tube equivalence ratio(${\phi}_c$) and overall equivalence ratio(${\phi}_o$).

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Effect of Electrode Process Variables in case of Decomposition of $NO_x$ by SPCP (연면방전에 의한 질소산화물의 분해시 전극 공정변수에 대한 영향)

  • 안형환;강현춘
    • Proceedings of the Safety Management and Science Conference
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    • 1999.11a
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    • pp.543-563
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    • 1999
  • For hazardous air pollutants(HAP) such as NO and $NO_2$ decomposition efficiency, power consumption, and applied voltage were investigated by SPCP(surface induced discharge plasma chemical processing) reactor to obtain optimum process variables and maximum decomposition efficiencies. Decomposition efficiency of HAP with various electric frequencies(5~50 kHz), flow rates(100~1,000 mL/min) initial concentrations(100~1,000 ppm), electrode materials(W, Cu, Al), electrode thickness(1, 2, 3 mm) and number of electrode windings(7, 9, 11) were measured. Experimental results showed that for the frequency of 10 kHz, the highest decomposition efficiency of 94.3% for NO and 84.7% for $NO_2$ were observed at the poser consumptions of 19.8 and 29W respectively and that decomposition efficiency decreased with increasing frequency above 20 kHz. Decomposition efficiency was increased with increasing residence times and with decreasing initial concentration of pollutants. Decomposition efficiency was increased with increasing thickness of discharge electrode and the highest decomposition efficiency was obtained for the electrode diameter of 3mm in this experiment. As the electrode material, decomposition efficiency was in order : tungsten(W), copper(Cu), aluminum(Al).

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Performance of CO adsorption on Transition metal impregnated zeolite molecular seive (전이금속 담지 제올라이트 분자체 이용한 CO 흡착특성)

  • Lee, Joo-Bo;Jung, Eui-Min;Kim, Dae-Kyung;Peng, MeiMei;Jang, Hyun-Tae;Cha, Wang-Seog
    • Proceedings of the KAIS Fall Conference
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    • 2012.05a
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    • pp.33-35
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    • 2012
  • 본 연구에서는 전이금속 Cu, Mn이 함침된 제올라이트를 사용하여 일산화탄소의 흡착능을 연구하였다. 금속 복합 산화물촉매 제조는 Cu, Mn을 서로 다른 비율로 물리 혼합하여 지지체에 담지하였다. 제올라이트 분자체는 상용 13X를 사용하였다. 함침방법은 과잉용액 함침법을 사용하였고, 건조 후 소성 하여 산화물 형태로 담지하였다. 합성된 개질 흡착제의 표면특성 분석은 $N_2$흡착 및 탈착곡선을 통한 질소흡착 특성 분석으로 기공크기, 기공분포, 비표면적을 구하였으며, FT-IR, X-선 회절분석, 전자주사현미경, $NH_3$-TPD/TPR 으로 특성을 분석하였다. 흡착 실험은 고정층 반응기에서 수행하였으며, 내경 4 mm 석영관에 흡착제를 충진하고 흡착파과곡선을 Gas Chromatograph로 측정하여 Cu-Mn 제올라이트 촉매의 일산화탄소 흡착 성능을 연구하였다. Cu-Mn 함량 비율과 흡착조업조건에 따른 흡착능을 측정하여 최적 흡착조건을 구하였다.

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The influence of significant design factor on CO and NOx emission in gas cooktop burner (가스 쿡탑 버너에서 디자인 형상이 배기배출물에 미치는 영향)

  • Jeong, Yong-Ki;Kim, Yoong-Soo;Yang, Dae-Bong;Kim, Yang-Ho;Ryu, Jong-Wan;Wie, Jae-Hyug;Lim, Jae-Beom;Seok, Jun-Ho;Chang, Yoong-June;Jeon, Chung-Hwan
    • Proceedings of the KSME Conference
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    • 2008.11b
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    • pp.2192-2197
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    • 2008
  • An experimental study was performed to investigate the effects of configuration of burner and air excess ratio on CO & NOx emission characteristics of the cooktop burners which are used extensively. In this study, the combustion characteristics were investigated with the variation of design factor of cooktop burners. The results showed that as the thermal input increases, flammable region go narrower. With the increase of loading height from the cap to grate, the CO emission decrease owing to the reduction of quenching by flame impingement on the load. Additionally, the CO emission increase with angle of main slot, however the NO emission is almost unaffected.

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NO Gas Sensing of ACFs Treated by E-beam Irradiation in H2O2 Solution (과산화수소 용액에 담지 된 활성탄소섬유의 전자선 조사에 따른 일산화질소 가스 감응)

  • LEE, SANGMIN;PARK, MI-SEON;JUNG, MIN-JUNG;LEE, YOUNG-SEAK
    • Transactions of the Korean hydrogen and new energy society
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    • v.27 no.3
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    • pp.298-305
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    • 2016
  • In this study, we treated pitch-based activated carbon fibers (ACFs) in hydrogen peroxide using electron beam (E-beam) irradiation to improve nitrogen monoxide (NO) sensing ability as an electrode material of gas sensor. The specific surface area of ACFs treated by E-beam irradiation with 400 kGy increased from $885m^2/g$ (pristine) to $1160m^2/g$ without any changes in structural property and functional group. The increase in specific surface area of the E-beam irradiated ACFs enhanced NO gas sensing properties such as response time and sensitivity. When the ACFs irradiated with 400 kGy, response time was remarkably reduced from 360 s to 210 s and sensitivity was increased by 4.5%, compared to the pristine ACFs. These results demonstrate convincingly that surface modification of ACFs using E-beam in hydrogen peroxide solution can enhance textural properties of ACFs and NO gas sensing ability of gas sensor at room temperature.

Effect of Nitric Oxide Pretreatment on Quality of MA Packaged Peaches (일산화질소(NO) 전처리가 MA포장 복숭아의 저장성에 미치는 영향)

  • Chung, Hun-Sik;Kim, Jong-Kuk;Kang, Woo-Won;Youn, Kwang-Sup;Lee, Ju-Baek;Choi, Jong-Uck
    • Korean Journal of Food Science and Technology
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    • v.34 no.6
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    • pp.1018-1022
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    • 2002
  • Effect of nitric oxide (NO) treatment on physiology and quality characteristics of peaches (Prunus persica L. Batsch) was determined. Peaches were treated for 4 hr with NO (0, 10, 100 ppm) gas under oxygen-free atmosphere at $10^{\circ}C$, packaged with 0.05-mm LDPE film, and stored at $10^{\circ}C$ for 15 days. Treatment with 100 ppm NO reduced the ethylene production and the loss of flesh firmness in peaches, but did not affect soluble solids, titratable acidity, and surface color. Oxygen-free atmosphere induced the reduction of respiration rate and ethylene production. Modified atmosphere packaging retarded the loss of flesh firmness and surface greenness, but decreased soluble solids and titratable acidity regardless of NO treatment.

The Study on the Physiological Activities of Beta vulgaris such as Antioxidant and Anti-inflammatory in RAW 264.7 cells (RAW 264.7 세포에서 레드비트의 항산화 및 항염증 등의 생리활성 연구)

  • Ji, Joong-Gu
    • Journal of the Korean Applied Science and Technology
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    • v.38 no.1
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    • pp.309-317
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    • 2021
  • This study was designed to examine the cell cytotoxic, anti-inflammatory, and antioxidant activity for raw material of Beta vulagaris tea. Antioxidative ability was evaluated by bioassays using DPPH and ABTS radical scavenging activity. Cell viability was assessed by MTT assay using RAW 264.7 cells, and investigated production levels of reactive oxide speies, and inflammatory meditors(i.e., nitric oxide, tumor necrosis factor-α, and interleukin-6) in LPS-induced RAW 264.7 cells. As a results, DPPH and ABTS raidcal scavenging activity were increased in a dose-dependent manner, and confirmed no cytotoxicity in all concentration. Also, it was significantly decreased level of ROS, NO, IL-6, and TNF-a in LPS-induced RAW 264.7 cells. Therefore these results suggest Beta vulagaris has considerable potential as a raw material of leached tea with safe anti-oxidative and anti-inflammatory effects.

Combustion Gas-emission of Medium Density Fibreboard (MDF) Treated with Alkylenediaminialkyl-bis-phosphonic Acids and Bis-(dimethylaminomethyl) Phosphinic Acid (알킬렌디아미노알킬-비스-포스폰산과 비스-디메틸아미노메틸 포스핀산으로 처리된 중질섬유판의 연소가스 발생)

  • Park, Myung-Ho;Chung, Yeong-Jin
    • Applied Chemistry for Engineering
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    • v.28 no.1
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    • pp.112-117
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    • 2017
  • This study demonstrated the emission of combustion gases of medium density fibreboard (MDF)s coated with piperazinomethyl-bis-phosphonic acid (PIPEABP), methylpiperazinomethyl-bis-phosphonic acid (MPIPEABP), N,N-dimethylethylenediaminomethyl-bis-phosphonic acid (MDEDAP), or bis-(dimethylaminomethyl) phosphinic acid (DMDAP). Each MDFs were coated in three times with a brush with 15 wt% aqueous solution of the phosphorus-nitrogen acid additives. After the specimens were dried at room temperature, the emission of combustion gases was tested using a cone calorimeter (ISO 5660-1, 2). The peak smoke production rate ($SPR_{peak}$) of the specimens coated with phosphorus-nitrogen acids was 18.5 to 41.5%, which is lower than that of using the virgin plate. However, the production of peak carbon monoxide ($CO_{peak}$) was 6.7 to 24.2% higher than that of using the virgin plate. Also, the peak carbon dioxide ($CO_{2peak}$) was 4.2 to 24.4% lower than that of using virgin plate. While the peak oxygen depletion rate was much higher than the level of 15%, which can be fatal to humans and the resulting risk could thus be eliminated. Overall, the combustibility of coated specimens was partially suppressed, but showed a negative effect on the reduction of carbon monoxide.