• Fire Science and Engineering
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• v.31 no.3
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• pp.97-105
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• 2017

Because asphalt is a solid at normal temperature and is not a hazardous material as stipulated in the Safety Management Act on Hazardous Materials, it is often recognized as having no risk of fire or explosion. On the other hand, it is as dangerous as flammable liquid because it is heated to $170-180^{\circ}C$ and stored in a storage tank. This study analyzed the risk of fire and explosion during the storage and handling of asphalt and the actual conditions of asphalt regulations by fire service organizations. Moreover, this study analyzed the domestic case of explosions in the production process of asphalt concrete (ASCON) and domestic and foreign cases of asphalt storage tank explosions. The analysis suggested that unlike Japan, Korea has no asphalt regulations in fire service organizations. Explosions can occur when ignition is delayed after fuel is sprayed on the dryer drum burner of the aggregates during the production of ASCON. A physical explosion can occur in the storage tank when environmental purification facilities suddenly work strongly to remove air pollutants or bad smells during the heating of asphalt in an asphalt storage tank. In addition, explosions can occur when fires such as welding is performed in the asphalt storage tank.

• Journal of the Korean Institute of Gas
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• v.22 no.4
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• pp.27-31
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• 2018

Classification of explosion hazard areas is very important in terms of cost and safety in the workplace handling flammable materials. This is because the radius of the hazardous area determines whether or not the explosion-proof equipment is installed in the electrical machinery and apparatus. From November 6, 2017, KS C IEC-60079-10-1: 2015 will be issued and applied as a new standard. It is important to understand and apply the difference between the existing standard and the new standard. Leakage coefficients and compression factors were added to the leakage calculation formula, and the formula of evaporation pool leakage, application of leakage ball size, and shape of explosion hazard area were applied. The range of the safety factor K has also been changed. Also, in the radius of the hazardous area, the existing standard applies the number of ventilation to the virtual volume, but the revised standard is calculated by using the leakage characteristic value. In this study, we investigated the differences from existing standards in terms of ventilation and dilution and examined the effect on the radius of the hazard area. Comparisons and analyzes were carried out by applying revised standards to workplaces where existing explosion hazard locations were selected. The results showed that even if the ventilation and dilution were successful, the risk radius was not substantially affected.

• Korean Chemical Engineering Research
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• v.58 no.3
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• pp.356-361
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• 2020

Propylene is widely used in petrochemical manufacturing at over 200 ℃. However, since propylene is a flammable gas with fire and explosion risks, inert nitrogen is injected to prevent them. In this study, experiments were conducted using propylene-nitrogen-oxygen upon pressure changes at 200 ℃. At 21% oxygen, as pressure increased from 0.10 MPa to 0.25 MPa, lower explosion limit (LEL) decreased from 2.2% to 1.9% while upper explosion limit (UEL) increased from 14.8% to 17.6%. In addition, minimum oxygen concentration (MOC) decreased from 10.3% to 10.0%, indicating higher risks with the expanded explosive range as pressure increased. With increase of pressure from 0.10 MPa to 0.25 MPa, explosion pressure increased from 1.84 MPa to 6.04 MPa, and the rate of rise of maximum explosion pressure increased drastically from 90 MPa/s to 298 MPa/s. It is hoped that these results can be used as basic data to prevent accidents in factories using propylene.

• Journal of the Korean Institute of Gas
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• v.23 no.6
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• pp.17-24
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• 2019

The combustion properties of the flammable substance used in industrial fields include lower/upper flash point, lower/upper explosion limit, autoignition temperature(AIT), fire point, and minimum oxygen concentration(MOC) etc.. The accurate assessment of these characteristics should be made for process and worker safety. In this study, tert-amylalcohol(TAA), which is widely used as a solvent for epoxy resins, oxidizers of olefins, fuel oils and biomass, was selected. The reason is that there are few researches on the reliability of combustion characteristics compared to other flammable materials. The flash point of the TAA was measured by Setaflash, Pensky-Martens, Tag, and Cleveland testers. And the AIT of the TAA was measured by ASTM 659E. The lower/upper explosion limits of the TAA was estimated using the measured lower/upper flash points by Setaflash tester. The flash point of the TAA by using Setaflash and Pensky-Martens closed-cup testers were experimented at 19 ℃ and 21 ℃, respectively. The flash points of the TAA by Tag and Cleveland open cup testers were experimented at 28 ℃ and 34 ℃, respectively. The AIT of the TAA was experimented at 437 ℃. The LEL and UEL calculated by using lower and upper flash point of Setaflash were calculated at 1.10 vol% and 11.95 vol%, respectively.

• Journal of the Korean Society of Safety
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• v.34 no.4
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• pp.22-31
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• 2019

The flammable liquid conductivity is an important factor in determining the generation of electrostatic in fire and explosion hazardous areas, so it is necessary to study the physical properties of flammable liquids. In particular, the relevant liquid conductivity in the process of handling flammable liquids in relation to the risk assessment and risk control in fire and explosion hazard areas, such as chemical plants, is classified as a main evaluation item according to the IEC standard, and it is necessary to have flammable liquid conductivity measuring devices and related data are required depending on the handling conditions of the material, such as temperature and mixing ratio for preventing the fire and explosion related to electrostatic. In addition, IEC 60079-32-2 [Explosive Atmospheres-Part 32-2 (Electrostatic hazards-Tests)] refers to the measuring device standard and the conductivity of a single substance. It was concluded that there is no measurement data according to the handling conditions such as mixing ratio of flammable liquid and temperature together with the use and measurement examples. We have developed the measurement reliability by improving the structure, material and measurement method of measuring device by referring to the IEC standard. We have developed a measurement device that is developed and manufactured by itself. The test results of flammable liquid conductivity measurement and the data of the NFPA 77 (Recommended Practice on Static Electricity) Annex B Table B.2 Static Electric Characteristic of Liquids were compared and verified by conducting the conductivity measurement of the flammable liquid handled in the fire and explosion hazardous place by using Measuring / Data Acquisition / Processing / PC Communication. It will contribute to the prevention of static electricity related disaster by taking preliminary measures for fire and explosion prevention by providing technical guidance for static electricity risk assessment and risk control through flammable liquid conductivity measurement experiment. In addition, based on the experimental results, it is possible to create a big data base by constructing electrostatic physical characteristic data of flammable liquids by process and material. Also, it is analyzed that it will contribute to the foundation composition for adding the specific information of conductivity of flammable liquid to the physical and chemical characteristics of MSDS.

• The Journal of the Convergence on Culture Technology
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• v.7 no.3
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• pp.553-564
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• 2021

This study analyzed the the risk of halogen lamp for pigsty heating and its fire prevention. Halogen lamps are used for keeping warm in pen because of their excellent economy and convenience. However, there is a high risk of fire due to poor safety management and exposure to animal movements. In fact, after exploring old pigsty and cattle shed, it was easy to confirm that they were exposed to fire risks. We noted this point and studied the possibility of fire by experiment due to combustible contact with halogen lamp and carelessness in use. The experiment was conducted under conditions similar to the actual use environment. After installing halogen lamps to the height used in actual pen, the temperature change was observed with infrared camera with straw, sawdust and rice husks on the floor. And assuming abnormal conditions, the experiment was also conducted under conditions the lamp dropped on the floor or combustible material came into contact with the glass tube inside the lamp. If halogen lamps were used in normal condition, there was no risk of fire. However, in abnormal use environments, smoke comes out or even ignited. Even if it is convenient for use or highly utilized, high risk of fire will require setting up fire prevention measures or regulation of use. Through in-depth fire investigation and research, we should promote the risk of fire and make efforts to prevent fire to minimize human life and property damage.

• Korean Chemical Engineering Research
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• v.61 no.1
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• pp.62-67
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• 2023

Due to the prolonged impact of COVID-19, the demand for Information Technology (IT) products is increasing, and their production facilities are expanded. Consequently, the use of harmful and dangerous chemicals are increased, the risk of fire(s) and explosion(s) is also elevated. In order to mitigate these risks, the government sets standards, such as KS C IEC 60079-10-1, and manages explosion-prone hazardous facilities where flammable substances are manufactured, used, and handled. However, using the standards of KS, it is difficult to predict the actual possibility of an explosion in a facility, because ventilation (an important factor) is not considered when setting up a hazardous work environment. In this study, the SEMI S6, Tracer Gas Test was applied to the chemical vapor deposition (CVD) facility, a major part of the display industry, to evaluate ventilation performance and to confirm the possibility of creating a less explosive environment. Based on the results, it was confirmed that the ventilation performance in the assumed scenarios met the standards stipulated in SEMI S6, along with supporting the possibility of creating a less explosive working condition. Therefore, it is recommended to use the prediction tool using engineering techniques, as well as KS standards, in such hazardous environments to prevent accidents and/or reduce economic burden following accidents.

• Journal of the Korean Institute of Gas
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• v.27 no.2
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• pp.79-85
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• 2023

Recently, in the semiconductor process, large companies are seeking process changes from memory semiconductors to the foundry due to the increase in demand due to the 4th industry. industry is expanding. The characteristics of special gases and precursors, which are raw materials used to produce these semiconductor chips, are toxic, pyrophoric, inflammable, and corrosive. These semiconductor raw materials are operated in a closed system and do not leak to the outside during normal times, but when leaked, they spread to the inside of the gas box, and when proper ventilation is not provided inside the gas box, they spread to the outside, causing fires, explosions, or toxic substances. It can lead to major accidents such as leakage. Recently, there have been cases of accidents in which hazardous materials leaked from the closed system of the semi conductor process and spread to the inside and outside of the gas box. . In this study, we propose preventive measures based on the case of an accident in which raw material leaked from the VCR fitting, which is the connection part of the semiconductor raw material transfer pipe, and spread to the outside of the gas box.

• Membrane Journal
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• v.33 no.3
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• pp.94-109
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• 2023

1,3-Dioxolane is an exciting material that has attracted widespread interest in the chemical, paint, and pharmaceutical industries as a solvent, electrolyte, and reagent because 1,3-dioxolane is not toxic, carcinogenic, explosive, auto-flammable, and multifunctional, and due to their excellent miscibility in most organic and aqueous solvent conditions. Recently, this material has received increasing attention as a CO₂-selective polymer precursor to separating CO₂ from flue gas and natural gas mixtures. Poly(1,3-dioxolane) (PDXL) possesses higher ether oxygen content than polyethylene oxide (PEO), which demonstrates superior membrane CO₂/N₂ separation properties owing to their polar ether oxygen groups exhibiting strong affinity toward CO₂. Thus, PDXL-based membranes displayed an outstanding CO₂ solubility selectivity over non-polar (N₂, H₂, and CH₄) gases. However, the polar groups of PDXL, like PEO, promote chain packing efficiency and cause polymer crystallization, thereby reducing its gas permeability, which should be improved. In this short review, we discuss the recent advancement and limitations of PDXL membranes in gas separation applications. To conclude, we provide future perspectives for inhibiting the limits of 1,3-dioxolane-based polymers in the CO₂ separation process.

• Journal of the Korean Institute of Gas
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• v.28 no.1
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• pp.73-84
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• 2024

In this study, a quantitative risk impact assessment is performed using an ALOHA program to identify the risks when applying ammonia as fuel for combined cycle power plants as one of the solutions of climate change. The worst and the alternative accident scenarios are established for the Sejong combined cycle power plant and the effective ranges are calculated in terms of flammability, thermal radiation, overpressure and toxicity. The analysis results show that the toxic risk is the most critical and the effective distance is highly proportional to the mixing ratio of natural gas and ammonia by showing the Pearson's correlation coefficient over 98% as 0.991, 0.987 and 0.989 for the Level Of Concern(LOC)-1, LOC-2 and LOC-3, respectively. In addition, the coefficients of linearity for LOC-1, LOC-2 and LOC-3 are calculated to 133, 70 and 29, respectively so it can be confirmed that the effective distance increases as the criterion decreases.