• Elastomers and Composites
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• v.49 no.3
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• pp.181-190
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• 2014

Melt grafting of itaconic acid (IA) onto an ethylene-propylene-diene terpolymer (EPDM) with various organic peroxide initiators was performed. Finding the optimum mixing conditions and concentration of ingredients is critical for effective grafting and optimum properties of grafted materials. This study focused on the effects of mixing conditions (temperature and time), initiator type/concentration and monomer concentration on the grafting degree and efficiency, melt flow index, and gel content of EPDM-g-IA. The initiator, 2,5-dimethyl-2,5-di(tert-butyl peroxy)-hexane (T-101), appeared to meet for the best grafting degree (1.91%). The grafting degree increased markedly by increasing the amounts of monomer IA and initiator T-101. The grafting degree also increased by increasing mixing temperature and time. The optimum monomer and initiator concentrations and reaction temperature and time were found to be about 5wt%/0.05wt% and $160^{\circ}C$/15min, respectively. It was found that the physical properties of EPDM-g-IA were higher than those of the pristine EPDM.

• Journal of the Korea Concrete Institute
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• v.23 no.1
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• pp.39-48
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• 2011

The present investigation evaluates the flexural behavior of pre-tensioned lightweight concrete beams under two-point symmetrical concentrated loads according to the variation of the partial prestressing ratio and the effective prestress of prestressing strands. The designed compressive strength of the lightweight concrete with a dry density of 1,770 $kg/m^3$ was 35 MPa. The deformed bar with a yield strength of 383 MPa and three-wire mono-strands with tensile strength of 2,040 MPa were used for longitudinal tensile reinforcement and prestressing steel reinforcement, respectively. According to the test results, the flexural capacity of pre-tensioned lightweight concrete beams increased with the increase of the partial prestressing ratio and was marginally influenced by the effective prestress of strands. With the same reinforcing index, the normalized flexural capacity of pre-tensioned lightweight concrete beams was similar to that of pre-tensioned normal-weight concrete beams tested by Harajli and Naaman and Bennett. On the other hand, the displacement ductility ratio of pre-tensioned lightweight concrete beams increased with the decrease of the partial prestressing ratio and with the increase of the effective prestress of strands. The load-displacement relationship of pre-tensioned lightweight concrete beam specimens can be suitably predicted by the developed non-linear two-dimensional analysis procedure. In addition, the flexural cracking moment and flexural capacity of pre-tensioned lightweight concrete beams can be conservatively evaluated using the elasticity theorem and the approach specified in ACI 318-08, respectively.

• Applied Chemistry for Engineering
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• v.25 no.3
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• pp.318-323
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• 2014

In order to analyze the effect of maleic anhydride (MAH) content and styrene monomer (SM)/MAH mole ratio on reactive extrusion of maleic anhydride grafted random polypropylenes (MAH-g-rPP), MAH-g-rPPs were prepared by using a twin screw extruder. MAH contents were 0.5, 1.0, 3.0, and 5.0 phr and SM/initiator mole ratio was 0.0, 1.0, and 2.0. Dicumyl peroxide (DCP) was used as an initiator. The graft degree of MAH was confirmed by the existence of carbonyl group (C = O) stretching peak at $1700cm^{-1}$ from FT-IR spectrum. The degree of graft reaction increased up to 3.0 phr MAH and showed the optimum value at 1.0 SM/MAH mole ratio from the area ratio of C = O and C-H stretching peak. Thermal and crystallization properties of MAH-g-rPP and PP/MAH-g-rPP/pulp composites were investigated by DSC, TGA, XRD, and POM. There was a decrease in non-isothermal crystallization temperature of PP/MAH-g-PP/pulp composites. Based on tensile properties and SEM pictures for the fractured surface of PP/MAH-g-PP/pulp composites, MAH content of 1.0 wt% and SM/MAH mole ratio of 1.0 were the optimum formulation as the compatibilizer. The rheological properties of the composites were measured by dynamic Rheometer to compare the processability of the composites with and without compatibilizer. The power law index showed slightly low value at the composites with compatibilizer.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.30 no.1
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• pp.63-72
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• 2024

Poly (butylene adipate-co-terephthalate) (PBAT) is one of the representative biodegradable polymers with high ductility and processability to replace petroleum-based polymers. Many investigations have been conducted to broaden the applications of PBAT in a variety of industries, including the food packaging, agricultural mulching film, and logistics and distribution fields. Foaming process is widely known technique to generate the cell structure within the polymer matrix, offering the insulation and light weight properties. However, there was no commercially feasible foam product based on biodegradable polymers, especially PBAT, and maintaining a proper melt viscosity of the polymer would be a key parameter for the foaming process. In this study, chemical foaming agent and cross-linking agent were introduced to PBAT, and a compression molding process was applied to prepare a foam sheet. The correlation between cell morphological structures and mechanical and physical properties was evaluated. It was found that PBAT with foam structures effectively reduced the density and thermal conductivity, allowing them to be suitable for applications such as insulation and lightweight packaging or cushion materials.

• Clean Technology
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• v.23 no.4
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• pp.378-387
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• 2017

To obtain epoxy resin with permanently attached flame-retardant groups, phosphorus compound containing di-hydroxyl group [10-(2,5-dihydroxyphenyl)-9,10-dihydro-9-oxa-10-phospha phenanthrene-10-oxide, DOPO-HQ] and silicone compound containing di-hydroxyl group (polydimethylsiloxane, hydroxyl terminated, PDMS) were reacted with uncured epoxy prepolymer (diglycidyl ether of bisphenol A, DGEBA) and then cured using 4,4-diaminodiphenylmethane (DDM) as a crosslinking agent. The properties of the resulting epoxy materials were characterized using Fourier transform infrared (FTIR) spectrometer, differential scanning calorimetry (DSC), thermogravimetric analysis (TGA), limiting oxygen index (LOI) test/vertical burning test (UL 94-V test), tensile properties test and impact test. This study examined the effect of phosphorus/silicone compound contents on the thermal/mechanical properties and flame retardancy of cured epoxy resins containing phosphorus and silicone compounds. It was found that the thermal/mechanical properties of epoxy resins containing phosphorus and silicone components were higher than those of simple epoxy resin. The flame-retardancy (LOI: 29.9 ~ 31.8% and UL 94-V: V-0) of all samples containing phosphorus compound and phosphrous compound/silicone compound was found to be passed the flame-retardant requirements (LOI: > 30%, UL 94-V: V-0) of LOI and vertical burning tests. However, the flame-retardancy (LOI: 21.4% and UL 94-V: no rating) of simple epoxy resin was found to be failed the flame-retardant requirements.

• The Journal of Engineering Geology
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• v.17 no.3
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• pp.393-404
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• 2007

The purpose of this study is to capture the essentials in survey and evaluation scheme which are able to assess the hazard of a rock slope systematically. Statistical analysis are performed on slope instability parameters related to failure of the rock slope. As the slope instability parameters, twelve survey items are considered such as tension crack, surface deformation, deformation of retaining structures, volume of existing failures, angles between strike of discontinuity and strike of cut slope face, angles between dip of discontinuity and dip of cut slope face, discontinuity condition, cut slope angle, rainfall or ground water level, excavation condition, drainage condition, reinforcement. A total of 233 road cut slopes located in Gyeongnam were considered. The stability of the road cut slopes were evaluated by estimating the slope instability index(SII) and corresponding stability rank. 126 rock slopes were selected to analyze statistical relation between SII and slope instability parameters. The multiple regression analysis was applied to derive statistical models which are able to predict the SII and corresponding slope stability rank. Also, its applicability was explored to predict the slope failures using the variables of slope instability parameters. The results obtained in this study clearly show that the methodology given in this paper have strong capabilities to evaluate the failures of the road cut slope effectively.

• KOREAN JOURNAL OF PACKAGING SCIENCE & TECHNOLOGY
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• v.24 no.1
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• pp.1-11
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• 2018

In this study, pro-oxidant($d2w^{(R)}$) and rPP/ZnO nanocomposite flexible films for food packaging were prepared, and their mechanical and antimicrobial properties were investigated. As a result, the carbonyl index and hydroxyl index increased with exposured time to heat and UV rays. Surface analysis showed that the addition of zinc oxide improved the dispersibility and compatibility of the polymer, so that the surface of the composite film was smooth and the zinc oxide particles were smaller than the compared film. And it kept the physical properties by heat and UV ray blocking effect, and it worked to reduce decomposition. In the antimicrobial activity test, the microbial reduction rate was 3 logs or more at the use concentration of zinc oxide. The tensile strength was increased and the elongation was decreased. Oxidative degradability of multi-layered film in UV exposured for 72 hours, the molecular weight of the film decreased by 75.6%, 1,294 g/mol Mn and 5,920 g/mol Mw. In the safety analysis of food packaging materials, we obtained that are in standard of polypropylene, a food contact material of domestic law.

• Journal of Conservation Science
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• v.31 no.3
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• pp.267-278
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• 2015

In this study, the elastomer cover, a new contact material, was developed to establish the customized ultrasonic measurement considering surface irregularities of stone cultural heritages. The cover exhibits high elastic force and wear resistance because it has tensile strength of 17MPa and elongation of 625%. In addition, as a result of comparative experiments for the seven types according to transducers and contact materials including the elastomer cover, rock surface irregularities significantly affect attenuation of ultrasonic velocity. The phenomenon was more noticeable in the chiseling finish and indirect transmission measurement rather than the dabbed finish and direct transmission measurement. However, the Type F using the exponential transducer and elastomer cover showed stable P-wave velocity and high amplitude regardless of the surface irregularities. This because the elastomer cover sufficiently sticks to surface irregularities and removes pores between a transducer and a rock specimen. Therefore, the Type F should be used for the ultrasonic measurement of stone cultural heritages with surface irregularities.

• Elastomers and Composites
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• v.43 no.4
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• pp.241-252
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• 2008

ZnAl-LDH(layered double hydroxide) modified with oleic acid(SO-ZnAl LDH) was synthesized and added to the flame retardant ABS compounds containing brominated epoxy resin(BER) and antimony trioxide(${Sb_2}{O_3}$). Flame retardant ABS compounds were manufactured by using a twin-screw co-rotating extruder and subsequently injection molded into several specimen for flame retardancy and mechanical properties. The XRD patterns of ABS nanocomposites showed no peaks. The thermal stability of ABS nanocomposites was enhanced by the addition of SO-ZnAl LDH as shown in TGA results. However, these nanocomposites showed no rating in the UL 94 vertical test at 1.6 mm thickness. Only ABS nanocomposites with additional BER more than 1.5 wt% showed UL 94 V0 rating. Notched Izod impact strength, tensile modulus, and elongation at break of flame retardant ABS nanocomposites increased with the proportion of So-ZnAl LDH whereas their melt index decreased.

• Journal of the Korean Geotechnical Society
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• v.20 no.5
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• pp.79-86
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• 2004

Interfacial properties between rock mass and shotcrete play a significant role in the transmission of loads from the ground to shotcrete. These properties have a major effect on the behaviours of rock mass and shotcrete. They, however, have merely been considered in most of numerical analyses, and little care has been taken in identifying them. This paper aimed to identify interfacial properties including cohesion, tension, friction angle, shear stiffness, and normal stiffness, through direct shear tests as well as interface normal compression tests for shotcrete/rock cores obtained from a tunnel sidewall. Mechanical properties such as compressive strength and elastic modulus were also measured to compare them with the time-dependent variation of interfacial properties. Based on the experiments, interfacial properties between rock and shotcrete showed a significant time-dependent variation similar to those of its mechanical properties. In addition, the time-dependent behaviours of interfacial properties could be well regressed through exponential and logarithmic functions of time.