• Journal of the Korean Society for Marine Environment & Energy
• /
• v.11 no.4
• /
• pp.191-198
• /
• 2008

To design a reliable $CO_2$ marine geological storage system, it is necessary to perform numerical process simulation using thermodynamic equation of state. $CO_2$ capture process from the major point sources such as power plants, transport process from the capture sites to storage sites and storage process to inject $CO_2$ into the deep marine geological structure can be simulate with numerical modeling. The purpose of this paper is to compare and analyse the relevant equations of state including ideal, BWRS, PR, PRBM and SRK equation of state. We also studied the effect of thermodynamic equation of state in designing the compression and transport process. As a results of comparison of numerical calculations, all relevant equation of state excluding ideal equation of state showed similar compression behavior in pure $CO_2$. On the other hand, calculation results of BWRS, PR and PRBM showed totally different behavior in compression and transport process of captured $CO_2$ mixture from the oxy-fuel combustion coal-fired plants. It is recommended to use PR or PRBM in designing of compression and transport process of $CO_2$ mixture containing NO, Ar and $O_2$.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.13 no.3
• /
• pp.187-197
• /
• 2010

Carbon dioxide Capture and Storage(CCS) is regarded as one of the most promising options to response climate change. CCS is a three-stage process consisting of the capture of carbon dioxide($CO_2$), the transport of $CO_2$ to a storage location, and the long term isolation of $CO_2$ from the atmosphere for the purpose of carbon emission mitigation. Up to now, process design for this $CO_2$ marine geological storage has been carried out mainly on pure $CO_2$. Unfortunately the $CO_2$ mixture captured from the power plants and steel making plants contains many impurities such as $N_2$, $O_2$, Ar, $H_2O$, $SO_2$, $H_2S$. A small amount of impurities can change the thermodynamic properties and then significantly affect the compression, purification, transport and injection processes. In order to design a reliable $CO_2$ marine geological storage system, it is necessary to analyze the impact of these impurities on the whole CCS process at initial design stage. The purpose of the present paper is to compare and analyse the relevant physical property models including BWRS, PR, PRBM, RKS and SRK equations of state, and NRTL-RK model which are crucial numerical process simulation tools. To evaluate the predictive accuracy of the equation of the state for $CO_2-SO_2$ mixture, we compared numerical calculation results with reference experimental data. In addition, optimum binary parameter to consider the interaction of $CO_2$ and $SO_2$ molecules was suggested based on the mean absolute percent error. In conclusion, we suggest the most reliable physical property model with optimized binary parameter in designing the $CO_2-SO_2$ mixture marine geological storage process.

• Membrane Journal
• /
• v.30 no.2
• /
• pp.97-110
• /
• 2020

CO₂ capture and storage (CCS) is one of the promising technologies that can mitigate ever-growing emission of anthropogenic carbon dioxide and resultant climate change. Among them, chemical looping combustion (CLC) and calcium looping (CaL) are getting increasing attention recently as the prospective alternatives to the existing amine scrubbing. Both methods use metal oxides in the process and consist of cyclic reactions. Yet, due to their cyclic nature, they both need to resolve sintering-induced cyclic stability deterioration. Moreover, the structure of the metal oxides needs to be optimized to enhance the overall performance of CO₂ capture and storage. Deposition of thin film coating on the metal oxide is another way to get rid of wear and tear during the sintering process. Chemical vapor deposition or atomic layer deposition are the well-known, established methods to form thin film membranes, which will be discussed in this review. Various effective recent developments on structural modification of metal oxide and incorporation of stabilizers for cyclic stability are also discussed.

• Cement Symposium
• /
• s.49
• /
• pp.21-22
• /
• 2022

The purpose of this study is to reduce carbon dioxide emissions in the cement industry and to collect carbon dioxide generated in industrial facilities such as cement factories and thermal power plants, store and utilize it, and convert high-value-added resources. While conventional Ordinary Portland Cement is characterized by hardening through hydration reactions, basic research is underway to develop cement that reacts with carbon dioxide and converts it into carbonate mineralization.

• Journal of the Korean Society for Marine Environment & Energy
• /
• v.15 no.2
• /
• pp.67-75
• /
• 2012

Carbon-dioxide capture and storage (CCS) process is consisted by capturing carbon-dioxide from large point source such as power plant and steel works, transporting and sequestrating captured $CO_2$ in a stable geological structure. During CCS process, it is inevitable of introducing impurities from combustion, capture and purification process into $CO_2$ stream. Impurities such as $SO_2$, $H_2O$, CO, $N_2$, Ar, $O_2$, $H_2$, can influence on process efficiency, capital expenditure, operation expense of CCS process. In this study, experimental apparatus is built to simulate the behavior of $CO_2$ transport under various impurity composition and process pressure condition. With this apparatus, $N_2$ impurity effect on $CO_2$ mixture transportation was experimentally evaluated. The result showed that as $N_2$ ratio increased pressure drop per mass flow and specific volume of $CO_2-N_2$ mixture also increased. In 120 and 100 bar condition the mixture was in single phase supercritical condition, and as $N_2$ ratio increased gradient of specific volume change and pressure drop per mass flow did not change largely compared to low pressure condition. In 70 bar condition the mixture phase changed from single phase liquid to single phase vapor through liquid-vapor two phase region, and it showed that the gradient of specific volume change and pressure drop per mass flow varied in each phase.

• Geophysics and Geophysical Exploration
• /
• v.24 no.3
• /
• pp.78-88
• /
• 2021

Owing to the abnormal weather conditions due to global warming, carbon capture and storage (CCS) technology has attracted global attention as a countermeasure to reduce CO₂ emissions. In the Pohang CCS demonstration project in South Korea, 100 tons of CO₂ were successfully injected into the subsurface CO₂ storage in early 2017. However, after the 2017 Pohang earthquake, the Pohang CCS demonstration project was suspended due to an increase in social concerns about the safety of the CCS project. In this study, to reconfirm the structural suitability of the CO₂ storage site in the Pohang Basin, we employed seismic imaging based on reverse-time migration (RTM) to analyze small-scale ocean-bottom seismic data, which have not been utilized in previous studies. Compared with seismic images using marine streamer data, the continuity of subsurface layers in the RTM image using the ocean-bottom seismic data is improved. Based on the obtained subsurface image, we discuss the structural suitability of the Pohang CO₂ storage site.

• Korean Chemical Engineering Research
• /
• v.50 no.6
• /
• pp.1008-1014
• /
• 2012

The amount of domestic carbon dioxide emissions is more than 600 million tons/year. The emitted $CO_2$ should be captured and stored, however, suitable storage sites have not been found yet. A lot of researches on the conversion of captured carbon dioxide to useful carbon source have been conducted. The purpose of this study is to convert stable carbon dioxide to useful resources using less energy. For this purpose reducing gas and metallic oxide (activator) are required. Hydrogen was used as reducing gas and cobalt ferrite was used as activator. Considering that activator has different physical properties depending on synthesis methods, activator was prepared by hydrothermal synthesis and solid method. Decomposition characteristics of carbon dioxide were investigated using synthesized powders. Temperature programmed reduction/oxidation (TPR/TPO) and thermogravimetric analyzer (TGA) device were used to observe the decomposition characteristics of carbon dioxide. Activator prepared by solid method with 5 and 10 wt% CoO content showed an excellent performance. In TGA experiments with samples prepared by the solid method, reduction by hydrogen was 29.0 wt% and oxidation by $CO_2$ was highest in 27.5 wt%. 95% of adsorbed $CO_2$ was decomposed with excellent oxidation-reduction behaviors.

• Proceedings of the Korea Committee for Ocean Resources and Engineering Conference
• /
• 2006.11a
• /
• pp.265-268
• /
• 2006

The preliminary design of a deep-sea injection system for carbon dioxide ocean sequestration is performed. Common functional requirements for a deep-sea injection system of mid-depth type and lake type are determined, Liquid transport system, liquid storage system and liquid injection system are conceptually determined for the functional requirements. For liquid injection system, the control of flow rate and temperature of liquid $CO_2$ in the injection pipe is needed in the view of internal flow. The function of depressing VIV(Vortex Induced Vibration) is also required in the view of dynamic stability of the injection pipe. A case study is performed for $CO_2$ sequestration capacity of 10 million tons per year. In this study, the total number of injection ships, the flow rate of liquid $CO_2$ and the configuration of a injection pipe are designed. The static structural analysis of the injection pipe is also performed. Finally the preliminary design of a deep-sea injection system is proposed.

• Transactions of the Korean hydrogen and new energy society
• /
• v.30 no.4
• /
• pp.347-355
• /
• 2019

As a solution to the growing concern on the global warming, researches are being actively carried out to apply carbon dioxide capture and storage technology to power generation systems. In this study, the integrated gasification combined cycle (IGCC) adopting oxy-combustion carbon capture was modeled and the effect of replacing the conventional air separation unit (ASU) with the ion transport membrane (ITM) on the net system efficiency was analyzed. The ITM-based system was predicted to consume less net auxiliary power owing to an additional nitrogen expander. Even with a regular pressure ratio which is 21, the ITM-based system would provide a higher net efficiency than the optimized ASU-based system which should be designed with a very high pressure ratio around 90. The optimal net efficiency of the ITM-based system is more than 3% higher than that of the ASU-based system. The influence of the operating pressure and temperature of the ITM on system efficiency was predicted to be marginal.

• Economic and Environmental Geology
• /
• v.53 no.4
• /
• pp.491-504
• /
• 2020

Given the continued climate change and global warming, various technologies for greenhouse gas reduction were discussed worldwide as all 195 countries participated in the Paris Agreement on the reduction of greenhouse gases. The agreement was adopted at the 21st Conference of Parties to the UNFCCC (COP21), which was held in Paris, France, in December 2015, and it revealed that reducing CO₂ is the most efficient method of greenhouse gas reduction. Accordingly, carbon capture/utilization/storage (CCUS) technology has been noted as a means of making practical contributions to CO₂ reduction, and research and development (R&D) activities in many countries are active in the field of CCUS technology. Therefore, this study aims to provide a basis for CCUS R&D and strategic support measures by analyzing patent trends in technologies related to CCUS. The patent analysis collected a total of 10,137 patents in the United States, Korea, Japan, Europe, and China; the number of patents in the United States was the highest according to patent analysis by country. According to an analysis by technology, capture-related technology was high at 60%, but given the recent increase in technology related to utilization, technology demonstration, R&D, and policy support should be continued.