• Title/Summary/Keyword: 이산화규소

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Rheological Characteristics of Nitromethane Gel Fuel with Nano/Micro Size of SiO2 Gellant (SiO2계열 젤화제 입자크기에 따른 니트로메탄 젤 추진제의 유변학적 특성 연구)

  • Jang, Jinwu;Kim, Sijin;Han, Seongjoo;Kim, Jinkon;Moon, Heejang
    • Proceedings of the Korean Society of Propulsion Engineers Conference
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    • 2017.05a
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    • pp.456-461
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    • 2017
  • In this study, the rheological properties of nitromethane gel propellants on nano/micron sized gelling agent are investigated. Silicon dioxide is used as the gellant with 5 wt%, 6.5 wt% and 8 wt% concentration, respectively, where the measurements are conducted under steady-state shear flow conditions using a rotational rheometer. The nitromethane/silicon dioxide gel showed non-Newtonian flow behavior for the entire experimental shear rate ranges. The gel fuels with nano-sized gellant had a slightly higher viscosity than the gel fuels with micron-sized one for low shear rate range. Additionally, it was found that Herschel-Bulkley model can hardly describe the rheological behavior of nitromethane gel propellant, but the NM model(by Teipel and Forter-Barth) is better suited to explain the rheological behavior of nitromethane gel propellant.

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Study on the effect of DSSC(Dye Sensitizer Solar Cell) Material on the electrical properties of Mercuric Iodide (염료감응형태양열 물질이 요오드화수은의 전기적 특성에 미치는 영향에 관한 연구)

  • Cho, Gyu-Seok;Park, Ji-koon;Heo, Seung-Wook;Song, Yong-keun;Han, Moo-Jae;Kim, Kum-Bae;Choi, Sang-Hyun
    • Journal of the Korean Society of Radiology
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    • v.11 no.6
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    • pp.525-529
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    • 2017
  • As a photoconductive material with a high X-ray sensitivity, many researches about mercury iodide has been carried out to substitute for amorphous selenium. However, it has many limitations in commercialization because of the high leakage current. In this study, we fabricated $HgI_2$ unit-cells with mixed silicon oxide($SiO_2$) and titanium oxide($TiO_2$) to reduce a high leakage current and we evaluated an electrical properties of the fabricated unit-cells. As a result, we confirmed that both mixtures were effective in reduing the leakage current of the $HgI_2$ and x-ray sensitivity were significantly increased in fabricated $HgI_2-TiO_2$ unit-cell.

Development of Solid Self-nanoemulsifying Drug Delivery Systems of Ticagrelor Using Porous Carriers (다공성의 캐리어를 이용한 티카그렐러 함유 고형의 자가 나노유화 약물전달시스템 개발)

  • Choi, Hyung Joo;Kim, Kyeong Soo
    • Journal of Life Science
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    • v.31 no.5
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    • pp.502-510
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    • 2021
  • The objective of this study was to develop a novel ticagrelor-loaded self-nanoemulsifying drug delivery system with an enhanced solubility and dissolution rate. Numerous oils and surfactants were screened, then medium chain triglyceride (MCT) oil and the surfactants polyoxyethylene sorbitan monooleate (Tween 80) and Labrafil M1944CS were selected for the preparation of the ticagrelor-loaded self-nanoemulsifying drug delivery system. A pseudo-ternary phase diagram was constructed to detect the nanoemulsion region. Of the various formulations tested, the liquid SNEDDS, composed of MCT (oil), Tween 80 (surfactant), and Labrafil M1944CS (cosurfactant) at a weight ratio of 20/70/10 produced the smallest emulsion droplet size (around 20.56±0.70 nm). Then, particle size, polydispersity, and zeta potential were measured using drugs containing liquid SNEDDS. The selected ticagrelor-loaded liquid SNEDDS was spray-dried to convert it into a ticagrelor-loaded solid SNEDDS with a suitable inert carrier, such as silicon dioxide, calcium silicate, or magnesium aluminometasilicate. The solid SNEDDS was characterized by scanning electron microscopy, transmission electron microscopy, and in vitro dissolution studies. SEM, PXRD, and DSC results suggested that amorphous ticagrelor was present in the solid SNEDDS. Also, the solid SNEDDS significantly increased the dissolution rate of ticagrelor. In particular, the emulsion particle size and the polydispersity index of the solid SNEDDS using silicon dioxide (SS1) as a carrier was the smallest among the evaluated solid SNEDDS, and the flowability and compressibility result of the SS1 was the most suitable for the manufacturing of solid dosage forms. Therefore, solid SNEDDS using silicon dioxide (SS1) could be a potential nano-sized drug delivery system for the poorly water-soluble drug ticagrelor.

냉음극 변압기 플라즈마와 TEOS 소스를 이용한 $SiO_2$ 박막 증착

  • Lee, Je-Won;No, Gang-Hyeon;Song, Hyo-Seop;Kim, Seong-Ik;Lee, Eun-Ji;Lee, Se-Hui;Jo, Gwan-Sik
    • Proceedings of the Korean Vacuum Society Conference
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    • 2012.08a
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    • pp.164-164
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    • 2012
  • 저진공 (>100 mTorr)에서 냉음극 변압기 전원 소스를 이용하여 플라즈마를 발생시키는 시스템을 개발하였다. 또한 이 장치를 이용하여 Tetraethylorthosilicate (TEOS)를 기화시켜 이산화규소 ($SiO_2$) 박막 증착 기술을 연구하였다. 공정 압력은 400~1,000 mT이었다. 증착된 박막의 박막 두께, 굴절률 등의 측정을 실시하였다. 결과를 요약하면, 플라즈마 공정 압력이 증가함에 따라 박막 증착 속도는 약 200~300 A/min이었다. 또한 전압이 1,100에서 2,100 V로 증가함에 따라 산화막의 증착 속도는 약 300에서 40 nm/min으로 증가하였다. TEOS만을 사용하였을 때 굴절률은 약 1.5~1.6정도였다. 그러나 TEOS에 산소를 추가하면 자연 산화막의 굴절률인 1.46을 쉽게 얻을 수 있었다. 초기 연구 결과를 정리하면 냉음극 변압기 플라즈마 장치는 향후 실용적인 산화막 플라즈마 증착 연구 장치로 사용될 수 있을 것으로 생각된다.

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Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Styrene Core-Shell Polymer(II) (이산화규소/스티렌 코어-셀 합성에서 음이온 계면활성제의 영향(II))

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.1
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    • pp.74-79
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    • 2009
  • The inorganic-organic composite particles with core-shell structure were polymerized by using styrene and potassium persulfate (KPS) as a shell monomer and an initiator, respectively. We studied the effect of surfactants on the core-shell structure of silicone dioxide/styrene composite particles polymerized in the presence of sodium dodecyl sulfate(SDS), polyoxyethylene alkylether sulfate (EU-S133D), and at none surfactant condition. We found that $SiO_2$ core / polystyrene(PS) shell structure was formed when polymerization of styrene was conducted on the surface of $SiO_2$ particles, and the concentration SDS and EU-Sl33D was $8.34{\times}10^{-2}mole/L$. The core-shell structure was confirmed by measuring the thermal decomposition of the polymer composite using thermogravimetric analyzer (TGA), and the morphology of the composite particles was characterized by transmission electron microscope (TEM).

Growth of $SiO_2$ nanowire by VS method. (기상증착방법에 의한 이산화규소 나노와이어의 성장)

  • 노대호;김재수;변동진;진정근;김나리;양재웅
    • Proceedings of the Materials Research Society of Korea Conference
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    • 2003.11a
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    • pp.115-115
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    • 2003
  • Silica nanostructures have been attached considerable attention because of theirs potential application in mesoscopic research and the potential use of large surface area structure of catalysts. SiO2 nannowire and nanorods was synthesized various methods including thermal evaporation, chemical vapor deposition (CVD), and laser ablation methods. In this experiments, SiO2 nanowire were grown using thermal evaporation method followed by VS (Vapor-Solid) growth mechanisms. Grown SiO2 nanowires were amorphous phases because of its low growth temperatures. Grown nanowires diameters were about 20-40nm at all growth conditions, but its microstructres were different by that used substrate because of it's oxygen contents.

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Solar Module Glass Coating Technology for Improvement of the transmittance (태양광 모듈용 Glass의 투과율 향상을 위한 Coating 기술 개발)

  • Jung, Jin-Su;Jung, In-Sung;Lee, Bum-Su;Jang, Jin-Ho;Ban, Seong-Tae;Kim, Jong-Il
    • 한국신재생에너지학회:학술대회논문집
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    • 2011.05a
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    • pp.120.1-120.1
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    • 2011
  • Increase the efficiency of PV modules for high-efficiency solar cells, light transmittance improvements, increasing the module, and much more research and development. Dual we light transmittance for photovoltaic module materials in low iron tempered glass in SiO2 using liquid AR implementation, light transmittance to solar modules to increase the efficiency of research.

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The Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Acrylate Core-Shell Polymer (이산화규소/아크릴계 유기물의 코어-셀 합성에서 음이온 계면활성제의 영향)

  • Kim, Duck-Sool;Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.26 no.2
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    • pp.199-204
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    • 2009
  • Silicone dioxide absorbed polyoxyethylene alkylether sulfate (EU-S133D) surfactant was prepared. Core-shell polymers of inorganic/organic pair, which have both core and shell component, were synthesized by sequential emulsion polymerization using Acrylate as a shell monomer and potassium persulfate (KPS) as an initiator. We found that when Acrylate core prepared by adding 2.0 wt% EU-S133D, silicone dioxide/Acrylate core-shell polymerization was carried out on the surface of silicone dioxide particle without forming the new silicone dioxide particle during acrylate shell polymerization in the inorganic/organic core-shell polymer preparation. The structure of core-shell polymer were investigated by measuring to the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of latex by scanning electron microscope(SEM).

The Electrical and Optical Characteristics of Silica Sand by Terahertz Electromagnetic Pulses (테라헤르츠 전자기 펄스를 이용한 이산화규소의 전기적 광학적 특성)

  • 전태인
    • Journal of the Korean Institute of Electrical and Electronic Material Engineers
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    • v.14 no.3
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    • pp.202-206
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    • 2001
  • Using THz time-domain spectroscopy (THz-TDS), the power absorption, the index of refraction, and the real conductivity of silica sand are measured from 0.1[Thz] to 0.5[Thz] frequency range. It is impossible to measure the characterization of the silica sand by simple electrical measurements using mechanical contacts, e.g., Hall effect or four-point probe measurements. However, the THz-TDS technique can measure not only electrical but also optical characterization of he sample. Also this technique can measure frequency dependent results. Especially, the real conductivity was increased according to THz frequency. This is unusual material compare with metal and semiconductor materials; the measured real conductivity are not followed by the simple Drude theory.

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Effect of Anionic Surfactants in Synthesizing Silicone Dioxide/Styrene Core-Shell Polymer (이산화규소/스티렌의 코어-셀 합성에서 음이온 계면활성제의 영향)

  • Park, Keun-Ho
    • Journal of the Korean Applied Science and Technology
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    • v.25 no.3
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    • pp.404-409
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    • 2008
  • The core-shell composite particles of inorganic/organic were polymerized by using styrene(St) as a shell monomer and potassium persulfate (KPS) as an initiator. We studied the effect of core-shell structure of silicone dioxide/styrene in the presence of an anionic surfactant sodium lauryl sulfate (SLS) and polyoxyethylene alky lether sulfate (EU-S133D). We found that when $SiO_2$ core/PSt shell polymerization was prepared on the surface $SiO_2$ particle, to minimize the coagulation during the shell polymerization, the optimum conditions were at concentration of $2.56{\times}10^{-2}mole/L$ SLS. The structure of core-shell polymer was confirmed by measuring the thermal decomposition of polymer composite using thermogravimetric analyzer and morphology of core-shell polymer particles by transmission electron microscope (TEM).