• Title/Summary/Keyword: 유해액체물질

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에칠아세테이트와 톨루엔 가연성액체혼합용액의 폭발하한계

  • 하동명;이수경
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2000.11a
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    • pp.129-134
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    • 2000
  • 가연성가스나 액체는 화학공업의 원료, 중간제품 그리고 완제품으로 화학공정의 광범위한 분야에서 사용되고 있을 뿐만 아니라, 가정에서도 널리 사용되고 있다. 이들 물질의 취급함에 있어 밸브의 조작실수, 배관접합부파손, 저장 및 수송의 부주의로 인해 주위에 공기와 혼합되면 화재 및 폭발이 발생할 수도 있고 유해물질이 유출되는 경우도 있다.(중략)

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Comparison of Liquid-Liquid Extraction and Solid-Phase Extraction Coupled with GC/MS for Determination of Priority Pollutants in Water (액체 추출법과 고체상 추출법에 의한 수질 중 유해물질 농축법 비교)

  • Yook, Keun-Sung;Hong, Sa-Moon;Kim, Jong-Ho
    • Analytical Science and Technology
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    • v.7 no.4
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    • pp.441-453
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    • 1994
  • Two extraction methods, liquid-liquid extraction(LLE) and solid-phase extraction(SPE), coupled with GC/MS were compared as preconcentration procedures for priority pollutants in water. Among the semi-volatile priority pollutants, 11 acid and 44 base/neutral compounds were spiked in reagent water. With LLE, which is a modification of EPA Method 625, the overall mean recovery of the 54 compounds was 91% with a mean relative standard deviation(RSD) of 4.6%. With SPE, the overall mean recovery of the 52 compounds was 53% with a mean RSD of 8.9%. The detection limits of both methods were in the range of $1{\sim}5{\mu}g/l$.

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The Study for Hazardous Material Incidents in Korea

  • Kim, Geun-Young;Il, James E. Moore
    • Journal of the Korean Society of Hazard Mitigation
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    • v.9 no.1
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    • pp.91-97
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    • 2009
  • Hazardous material (HazMat) is the material or substance that poses an unreasonable risk to human safety and health, and to property when transported in gases, solids, and liquids of all sizes. When HazMats are improperly released, they have potential to harm humans, property, or the environment to be considered hazardous, resulting in human-caused disasters. As the Korean economy has advanced, the use of HazMats has increased. And, the total number and the impacts of HazMat incidents have grown up. It increases the risk of HazMat incidents. When many goods of HazMats are transported from supply points to demand places, it is important to know what the types and characteristics of HazMat incidents are in terms of disaster management. The objectives of this research are: (1) to investigate types and characteristics of HazMats that generate HazMat incidents in Korea, and (2) to analyze time-series trends of HazMat incidents in terms of facilities and/or transportation. Statistical analysis methods including frequency analysis or analysis of category data are applied to examine the significance of difference in HazMat incidents.

HNS behavior modelling for atmospheric and oceanic dispersion model (위험유해물질 대기 해양 확산모델을 위한 물질 거동특성 모델링)

  • Lee, Moonjin;Park, Mi-Ok;Jung, Jung-Yeul;Kang, Yong Q.
    • Proceedings of KOSOMES biannual meeting
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    • 2017.11a
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    • pp.157-157
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    • 2017
  • 해상으로 운송되는 위험유해물질(HNS, Hazardous and Noxious Substance)은 6,000여종 이상으로 많은 종류를 포함하고 있으므로, 유출시 대응전략 수립을 위한 HNS 거동 및 위험반경 예측을 결정론적으로 제시하기 어렵다. HNS 거동예측에서는 예측의 신속성과 효율성을 고려하여 차이가 미미한 모든 종류의 HNS 특성을 모두 고려하는 대신에 거동에 크게 영향을 미칠 수 있는 특성들에 초점을 맞쳐 대표적인 거동예측 모델을 개발하여 적용할 필요가 있다. 본 연구에서는 HNS를 기체상, 액체상, 고체상 등 크게 3분류로 구분하고, 각각의 분류별 거동특성 모델링을 연구하였다. 물질 특성별 거동특성은 증기압, 용해도, 밀도 등을 고려하였으며, 각각의 변수에 따른 증발, 혼?, 침강 등의 거동을 모델링하였다. 물질의 거동특성 모델링은 대기 해양 확산모델의 계산에서 대기중 확산, 수중 확산, 해저면 침적 등을 결정하는 과정으로 활용된다.

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The Present State and Future Prospect of the Education for Marine Pollution Prevention Manager in Korea I. Marine Pollution Prevention Manager on Board Ship (해양오염방지관리인 교육의 현황과 전망 I. 선박 오염방지관리인 교육)

  • Kim, Kwang-Soo;Cho, Dong-Oh;Yun, Jong-Hwui;Cho, Hyeon-Seo
    • Proceedings of KOSOMES biannual meeting
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    • 2009.06a
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    • pp.105-111
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    • 2009
  • Marine pollution prevention manager system has been operated for the purpose of preventing marine pollution from ships and marine facilities in Korea. As a new "marine environment management act" replacing an old "marine pollution prevention act" had entered into force from January 20, 2008, the works and business of the education and training courses for marine pollution prevention manager are scheduled to transfer from KIMFT(Korea Institute of Maritime and Fisheries Technology) and FHRDI(Fisheries Human Resource Development Institute) to KOEM(Korea Marine Environment Management Corporation) on January 1, 2011. The present state of the education and training for marine pollution prevention managers on board ships was surveyed and analyzed In order to prospect trainee demands for the education and training and to provide KOEM with basic data for establishing a new system for the education and training. The existing education and training courses of KIMFT for marine pollution prevention manager on board ships are classified into a regular course of 21 classes for 3 days, a reeducation course of 18 classes for 2 days and a NLS course of 17 classes for 2days. The annual numbers of trainees in 2008 were 516 persons for regular course, 1085 persons for reeducation course and 135 persons for NLS course in KIMFT. The trainee demands for the education and training were attempted to be predicted on a basis on annual increase rate of ships. The predicted demands for the education and training are changeable depending on the major factors such shipping market, naval architecture industry, etc.

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Prioritizing Noxious Liquid Substances (NLS) for Preparedness Against Potential Spill Incidents in Korean Coastal Waters (해상 유해액체물질(NLS) 유출사고대비 물질군 선정에 관한 연구)

  • Kim, Young-Ryun;Choi, Jeong-Yun;Son, Min-Ho;Oh, Sangwoo;Lee, Moonjin;Lee, Sangjin
    • Journal of the Korean Society of Marine Environment & Safety
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    • v.22 no.7
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    • pp.846-853
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    • 2016
  • This study prioritizes Noxious Liquid Substances (NLS) transported by sea via a risk-based database containing 596 chemicals to prepare against NLS incidents. There were 158 chemicals transported in Korean waters during 2014 and 2015, which were prioritized, and then chemicals were grouped into four categories (with rankings of 0-3) based on measures for preparedness against incident. In order to establish an effective preparedness system against NLS spill incidents on a national scale, a compiling process for NLS chemicals ranked 2~3 should be carried out and managed together with an initiative for NLS chemicals ranked 0-1. Also, it is advisable to manage NLS chemicals ranked 0-1 after considering the characteristics of NLS specifically transported through a given port since the types and characteristics of NLS chemicals relevant differ depending on the port. In addition, three designated regions are suggested: 1) the southern sector of the East Sea (Ulsan and Busan); 2) the central sector of the South Sea (Gwangyang and Yeosu); and 3) the northern sector of the West Sea (Pyeongtaek, Daesan and Incheon). These regions should be considered special management sectors, with strengthened surveillance and the equipment, materials and chemicals used for pollution response management schemes prepared in advance at NLS spill incident response facilities. In the near future, the risk database should be supplemented with specific information on chronic toxicity and updated on a regular basis. Furthermore, scientific ecotoxicological data for marine organisms should be collated and expanded in a systematic way. A system allowing for the identification Hazardous and Noxious Substances (HNS) should also be established, noting the relevant volumes transported in Korean waters as soon as possible to allow for better management of HNS spill incidents at sea.

BTX의 폭발특성에 관한 연구

  • 김종복;오규형;이성은;류창하
    • Proceedings of the Korean Institute of Industrial Safety Conference
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    • 2000.11a
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    • pp.140-145
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    • 2000
  • BTX는 석유화학곧업에서 생산되는 방향족탄화수소 화합물의 주요 생산품목인 Benzene, Toluene, Xylene을 일컫는 말로서 석유화학공정에서 간단히 줄여서 쓰는 용어이다. 벤젠, 톨루엔, 크실렌 등은 페인트 희석제로 쓰이는 유기용매의 주성분들이며, 인체에 중독성을 나타내는 유해물질이기도 하며 소방법상에서는 인화성액체인 4류 위험물로 취급하고 있다.(중략)

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A Study on the Physical and Chemical Characteristics and Hazards Buthanethiol (Buthanethiol의 물리화학적 특성과 유해성 연구)

  • Kim, Hyeon-Yeong
    • Journal of the Korean Institute of Gas
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    • v.17 no.4
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    • pp.9-17
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    • 2013
  • Butanethiol is known as a typical odorant with hydrogen sulfide, methyl mercaptan, methyl sulfide, but on the physical and chemical properties and biological hazard assessment, including inhalation toxicity data are very scarce. Butanethiol as a colorless transparent liquid, and has physic-chemical characteristics with flash point as $-23^{\circ}C$ and strong fire risk, boiling point $84-85^{\circ}C$, vapor pressure 80.71 mmHg ($25^{\circ}C$), freezing point $-140.14^{\circ}C$. From whole body exposure with SD rats, the $LC_{50}$ is above 2,500 ppm (9.22mg/L), and then it is classified as the acute toxic chemical (inhalation) category 4 according to the governmental notification No. 2012-14.

Study on the Gas-Liquid Mixing System by Using Ejector (이젝터를 사용하는 기-액 혼합시스템에 관한 연구)

  • Jin, Zhen-Hua;Kim, Pil-Hwan;Park, Gi-Tae;Chung, Han-Shik;Jeong, Hyo-Min
    • Journal of Power System Engineering
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    • v.12 no.3
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    • pp.5-11
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    • 2008
  • 산업공정에서 널리 사용하는 반응기는 성질이 상이한 물질을 혼합하는 시스템으로서 본 연구에서는 이젝터(ejector)에 의한 반응기의 개발을 수행하였다. 액체-가스 이젝터는 구동유체에 의하여 기체가 흡입되면서 각종 유해가스를 제거하는 목적 또는 기체와 액체의 혼합 등 목적으로 사용된다. 본 실험에서 액체구동 가스혼합반응기의 실험 장치를 구축하고 이젝터 내부의 유동패턴과 기체용해도 자료를 도출하며 고효율 이젝터 설계를 위한 진공도 측정과 디퓨저 각도가 다른 이젝터의 실험 및 수치해석을 수행하였다. 이젝터의 성능은 흡입 측에서의 진공압력으로 평가되며 이 진공압력은 이젝터의 노즐 설계 및 유동조건에 의하여 결정되므로 이에 대한 기본적인 특성 도출이 선결되어야 한다. 순환유체의 유량이 70LPM, 80LPM 90LPM조건에서 두 가지 디퓨저에 대하여 비교실험을 수행하였다. 실험적 연구와 수치해석연구를 통하여 혼합성능과 이젝터의 내부유동특성에 대하여 고찰한 결과 디퓨저의 각도가 5.0도일 때 진공도가 더욱 높으며 구동액체의 유량이 작을 때는 진공도차이가 크지만 유량이 증가함에 따라 진공도 차이가 감소된다. 구동액체의 유량이 증가할수록 용존산소농도는 증가하며 디퓨저의 각도가 5.0도일 때는 용존산소 농도가 더 높게 나타나는 것을 확인할 수 있었다.

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