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Origin and Reservoir Types of Abiotic Native Hydrogen in Continental Lithosphere (대륙 암석권에서 무기 자연 수소의 성인과 부존 형태)

  • Kim, Hyeong Soo
    • Korean Journal of Mineralogy and Petrology
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    • v.35 no.3
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    • pp.313-331
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    • 2022
  • Natural or native abiotic molecular hydrogen (H2) is a major component in natural gas, however yet its importance in the global energy sector's usage as clean and renewable energy is underestimated. Here we review the occurrence and geological settings of native hydrogen to demonstrate the much widesprease H2 occurrence in nature by comparison with previous estimations. Three main types of source rocks have been identified: (1) ultramafic rocks; (2) cratons comprising iron (Fe2+)-rich rocks; and (3) uranium-rich rocks. The rocks are closely associated with Precambrian crystalline basement and serpentinized ultramafic rocks from ophiolite and peridotite either at mid-ocean ridges or within continental margin(Zgonnik, 2020). Inorganic geological processes producing H2 in the source rocks include (a) the reduction of water during the oxidation of Fe2+ in minerals (e.g., olivine), (b) water splitting due to radioactive decay, (c) degassing of magma at low pressure, and (d) the reaction of water with surface radicals during mechanical breaking (e.g., fault) of silicate rocks. Native hydrogen are found as a free gas (51%), fluid inclusions in various rock types (29%), and dissolved gas in underground water (20%) (Zgonnik, 2020). Although research on H2 has not yet been carried out in Korea, the potential H2 reservoirs in the Gyeongsang Basin are highly probable based on geological and geochemical characteristics including occurrence of ultramafic rocks, inter-bedded basaltic layers and iron-copper deposits within thick sedimentary basin and igneous activities at an active continental margin during the Permian-Paleogene. The native hydrogen is expected to be clean and renewable energy source in the near future. Therefore it is clear that the origin and exploration of the native hydrogen, not yet been revealed by an integrated studies of rock-fluid interaction studies, are a field of special interest, regardless of the presence of economic native hydrogen reservoirs in Korea.

Nondestructive Examination of PHWR Pressure Tube Using Eddy Current Technique (와전류검사 기술을 적용한 가압중수로 원전 압력관 비파괴검사)

  • Lee, Hee-Jong;Choi, Sung-Nam;Cho, Chan-Hee;Yoo, Hyun-Joo;Moon, Gyoon-Young
    • Journal of the Korean Society for Nondestructive Testing
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    • v.34 no.3
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    • pp.254-259
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    • 2014
  • A pressurized heavy water reactor (PHWR) core has 380 fuel channels contained and supported by a horizontal cylindrical vessel known as the calandria, whereas a pressurized water reactor (PWR) has only a single reactor vessel. The pressure tube, which is a pressure-retaining component, has a 103.4 mm inside diameter ${\times}$ 4.19 mm wall thickness, and is 6.36 m long, made of a zirconium alloy (Zr-2.5 wt% Nb). This provides support for the fuel while transporting the $D_2O$ heat-transfer fluid. The simple tubular geometry invites highly automated inspection, and good approach for all inspection. Similar to all nuclear heat-transfer pressure boundaries, the PHWR pressure tube requires a rigorous, periodic inspection to assess the reactor integrity in accordance with the Korea Nuclear Safety Committee law. Volumetric-based nondestructive evaluation (NDE) techniques utilizing ultrasonic and eddy current testing have been adopted for use in the periodic inspection of the fuel channel. The eddy current testing, as a supplemental NDE method to ultrasonic testing, is used to confirm the flaws primarily detected through ultrasonic testing, however, eddy current testing offers a significant advantage in that its ability to detect surface flaws is superior to that of ultrasonic testing. In this paper, effectiveness of flaw detection and the depth sizing capability by eddy current testing for the inside surface of a pressure tube, will be introduced. As a result of this examination, the ET technique is found to be useful only as a detection technique for defects because it can detect fine defects on the surface with high resolution. However, the ET technique is not recommended for use as a depth sizing method because it has a large degree of error for depth sizing.

Building Wind Corridor Network Using Roughness Length (거칠기길이를 이용한 바람통로 네트워크 구축)

  • An, Seung Man;Lee, Kyoo-Seock;Yi, Chaeyeon
    • Journal of the Korean Institute of Landscape Architecture
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    • v.43 no.3
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    • pp.101-113
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    • 2015
  • The purpose of this study is increasing ventilation network usability for urban green space planning by enhancing its practicality and detail. A ventilation network feature extraction technique using roughness length($z_0$) was proposed. Continuously surfaced DZoMs generated from $z_0$(cadastral unit) using three interpolations(IDW, Spline, and Kriging) were compared to choose the most suitable interpolation method. Ventilation network features were extracted using the most suitable interpolation technique and studied with land cover and land surface temperature by spatial overlay comparison. Results show Kriging is most suitable for DZoM and feature extraction in comparison with IDW and Spline. Kriging based features are well fit to the land surface temperature(Landsat-7 ETM+) on summer and winter nights. Noteworthy is that the produced ventilation network appears to mitigate urban heat loads at night. The practical use of proposed ventilation network features are highly expected for urban green space planning, though strict validation and enhancement should follow. (1) $z_0$ enhancement, (2) additional ventilation network interpretation and editing, (3) linking disconnected ventilation network features, and (4) associated dataset enhancement with data integrity should technically preceded to enhance the applicability of a ventilation network for green space planning. The study domain will be expanded to the Seoul metropolitan area to apply the proposed ventilation network to green space planning practice.

Flow Characteristics According to Velocity Conditions of Cylinder Boundary Under Low Reynolds Number (저 레이놀즈 수에서 실린더 경계 유속조건에 따른 흐름 특성)

  • Song, Chang Geun;Seo, Il Won;Kim, Tae Won
    • KSCE Journal of Civil and Environmental Engineering Research
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    • v.33 no.6
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    • pp.2267-2275
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    • 2013
  • Existing conventional model for analysis of shallow water flow just assumed the internal boundary condition as free-slip, which resulted in the wrong prediction about the velocity, vorticity, water level, shear stress distribution, and time variation of drag and lift force around a structure. In this study, a finite element model that can predict flow characteristics around the structure accurately was developed and internal boundary conditions were generalized as partial slip condition using slip length concept. Laminar flow characteristics behind circular cylinder were analyzed by varying the internal boundary conditions. The simulation results of (1) time variations of longitudinal and transverse velocities, and vorticity; (2) wake length; (3) vortex shedding phenomena by slip length; (4) and mass conservation showed that the vortex shedding had never observed and laminar flow like creeping motion was occurred under free-slip condition. Assignment of partial slip condition changed the velocity distribution on the cylinder surface and influenced the magnitude of the shear stress and the occurrence of vorticity so that the period of vortex shedding was reduced compared with the case of no slip condition. The maximum mass conservation error occurred in the case of no slip condition, which had the value of 0.73%, and there was 0.21 % reduction in the maximum mass conservation error by changing the internal boundary condition from no slip to partial slip condition.

Numerical Study on Rayleigh-Taylor Instability Using a Multiphase Moving Particle Simulation Method (다상유동형 입자법을 이용한 Rayleigh-Taylor 불안정성의 수치해석)

  • Kim, Kyung Sung;Koo, Bonguk;Kim, Moo-Hyun;Park, Jong-Chun;Choi, Han-Suk;Cho, Yong-Jin
    • Journal of the Korean Society for Marine Environment & Energy
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    • v.20 no.1
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    • pp.37-44
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    • 2017
  • Complexity of multiphase flows due to existence of more than two interface including free-surface in one system, cannot be simulated easily. Since more than two fluids affect to flows and disturb interface, non-linearities such as instabilities can be appeared. Among several instabilities on multiphase flows, one of representative is Rayleigh-taylor instability. In order to examine in importance of density disparity, several cases with numerous Atwood number are set. Moreover, investigation of influence on initial disturbance were also considered. Moving particle simulation (MPS) method, which was employed in this paper, was not widely used for multiphase problem. In this study, by adding new particle interaction models such as self-buoyance correction, surface tension, and boundary condition at interface models, MPS were developed having more strength of physics and robust. By applying newly developed multiphase MPS, considered cases are performed and compared each other. Additionally, though existence of disagreement of magnitude of rising velocity between theoretical values from linear potential theory and that of numerical simulation, agreement of tendency can be proved of similarity of result. the discordance of magnitude can be explained due to non-linear effects on numerical simulation which was not considered in theoretical result.

Development and Application of Slime Meter for Evaluation of Slime Thickness in Borehole (굴착공 내 슬라임 두께 평가를 위한 슬라임미터의 개발 및 적용)

  • Hong, Won-Taek;Woo, Gyuseong;Lee, Jong-Sub;Song, Myung Jun;Lim, Daesung;Park, Min-Chul
    • Journal of the Korean Geotechnical Society
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    • v.34 no.10
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    • pp.29-38
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    • 2018
  • The slime formed at the bottom of the borehole causes the excessive displacement and loss of the bearing capacity of the drilled shaft. In this study, the slime meter is developed for the evaluation of the slime based on the electrical properties of the fluid and the slime in the borehole. The slime meter is composed of a probe instrumented with electrodes and temperature sensor and a frame with rotary encoder, so that the slime meter profiles the electrical resistivity compensated with temperature effect along the depth. For the application of the slime meter, three field tests are conducted at a borehole with a diameter of 3 m and a depth of 46.9 m with different testing time and locations. For all the tests, the experimental results show that while electrical resistivities are constantly measured in the fluid, the electrical resistivities sharply increase at the surface of the slime. Therefore, the slime thicknesses are estimated by the differences in the depths of the slime surface and the ground excavation. The experimental results obtained at the same testing point with different testing time show that the estimated thickness of the slime increases by the elapsed time. Also, the estimated slime at the side of the borehole is thicker than that at the center of the borehole. As the slime meter estimates the slime in the borehole by measuring the electrical resistivity with simple equipment, the slime meter may be effectively used for the evaluation of the slime formed at the bottom of the borehole.

Removal of Phenanthrene by Electrokinetic-Fenton Process in a 2-dimensional Soil System (동전기-펜턴 공정을 이용한 2차원 토양 정화장치에서의 phenanthrene 제거)

  • Park Ji-Yeon;Kim Sang-Joon;Lee You-Jin;Yang Ji-Won
    • Journal of Soil and Groundwater Environment
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    • v.10 no.5
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    • pp.11-17
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    • 2005
  • Characteristics of phenanthrene removal in the Electrokinetic (EK)-Fenton process were investigated in a 2-dimensional test cell in a viewpoint of the effect of gravity and electrosmotic flow (EOF). When the constant voltage of 100 V was applied to this system, the current decreased from 1,000 to 290 mA after 28 days, because soil resistance increased due to the exhaustion of ions in soil by electroosmosis and electromigration. Accumulated EOF in two cathode reservoirs was 10.3 L and the EOF rate was kept constant for 28 days. At the end of operation, the concentration of phenanthrene was observed to be very low near the anode and increased in the cathode region because hydrogen peroxide was supplied from anode to cathode region following the direction of EOP. Additionally, the concentration of phenanthrene decreased at the bottom of the test cell because the electrolyte solution containing hydrogen peroxide was largely transported toward the bottom due to a low capillary action in the soil with high porosity. Average removal efficiency of phenanthrene by EK-Fenton process was 81.4% for 28 days. In-situ EK-Fenton process would overcome the limitations of conventional remediation technologies and effectively remediate the contaminated sites.

Study on the Melting Point Depression of Tin Nanoparticles Manufactured by Modified Evaporation Method (수정된 증발법을 이용하여 제작된 주석 나노입자의 녹는점 강하에 관한 연구)

  • Kim, Hyun Jin;Beak, Il Kwon;Kim, Kyu Han;Jang, Seok Pil
    • Transactions of the Korean Society of Mechanical Engineers B
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    • v.38 no.8
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    • pp.695-700
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    • 2014
  • In the present study, the melting temperature depression of Sn nanoparticles manufactured using the modified evaporation method was investigated. For this purpose, a modified evaporation method with mass productivity was developed. Using the manufacturing process, Sn nanoparticles of 10 nm size was manufactured in benzyl alcohol solution to prevent oxidation. To examine the morphology and size distribution of the nanonoparticles, a transmission electron microscope was used. The melting temperature of the Sn nanoparticles was measured using a Differential scanning calorimetry (DSC) which can calculate the endothermic energy during the phase changing process and an X-ray photoelectron spectroscopy (XPS) used for observing the manufactured Sn nanoparticle compound. The melting temperature of the Sn nanoparticles was observed to be $129^{\circ}C$, which is $44^{\circ}C$ lower than that of the bulk material. Finally, the melting temperature was compared with the Gibbs Thomson and Lai's equations, which can predict the melting temperature according to the particle size. Based on the experimental results, the melting temperature of the Sn nanoparticles was found to match well with those recommended by the Lai's equation.

Analysis of the Middle School Students' Conceptions about Buoyancy (중학생들의 부력에 대한 개념 분석)

  • Kim, Yi-Young;Kim, Jina
    • Journal of Science Education
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    • v.36 no.2
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    • pp.369-380
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    • 2012
  • The purpose of this study was to investigate middle students' conceptions of buoyancy. The questionnaires composed of 9 items which asked the reasons for situations with buoyancy; recognized of buoyancy, the facts affecting buoyancy(bottom of the Area of the object, the shape of the object, the depth of the object in the water, amount of water, the degree of the object submerged in the water, volume of the object, weigh of the object), the relationship between the amount of replaced fluid and buoyancy. The subjects were 140 students from the Busan Area who answered questionnaires composed of 9 items which asked the reasons for situations with buoyancy. Among the 140, 132 students were selected who answered all of question in the test. The students' answer types were follow: 1. Related to the shape of the submerged object, students answered that buoynacy depended on the bottom dimensions or the surface area of the object. 2. Students confused press, water press and buoyancy, who answered buoyancy was great when the water press was great. 3. Students answered that the weight and the size of the buoyancy of the object was same in the water. 4. Students answered, gravity was smaller in the water. Students recognized the existence of buoyancy but the reason of the answer depend on their experience. Also students answered using the words that water pressure, pressure, force instead of buoyancy. Students didn't understand the factors affecting the buoyancy. Many students responded that buoyancy was changed depend on weight of object, sinking depth, shape and others. It was considered that these responses didn't understand the cause of buoyancy.

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Structural Analysis of a Suction Pad for a Removable Bike Carrier using Computational and Experimental Methods (탈착식 자전거 캐리어용 흡착 패드의 실험 및 전산적 방법을 활용한 구조해석)

  • Suh, Yeong Sung;Lim, Geun Won
    • Journal of the Korea Academia-Industrial cooperation Society
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    • v.17 no.3
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    • pp.622-628
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    • 2016
  • As the suction pad-supporting bike carrier attached to a car may be subject to an excessive dynamic load due to random vibrations and centrifugal forces during driving, its structural safety is of great concern. To examine this, the finite-element method with a fluid-structure interaction should be used because the pressure on the pad bottom is changed in real time according to the fluctuations of the force or the moment applied on the pad. This method, however, has high computing costs in terms of modeling efforts and software expense. Moreover, the accuracy of computation is not easily guaranteed. Therefore, a new method combining the experiment and computation is proposed in this paper: the bottom pressure and contact area of the pad under varying loads was measured in real time and the acquired data are then used in the nonlinear elastic finite-element calculations. The computational and experimental results obtained with the product under development showed that the safety margin of the pad under the axial loading is relatively sufficient, whereas with an excessive rotational loading, the pad is vulnerable to separation or a local surface damage; hence, the safety margin may not be secured. The predicted contact behavior under the variation of the magnitude and type of the loading were in good agreement with the one from the experiment. The proposed analysis method in this study could be used in the design of similar vacuum pad systems.