대한기계학회논문집B (Transactions of the Korean Society of Mechanical Engineers B)

  • 제38권8호
  • /
  • Pages.695-700
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  • 2014
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  • 1226-4881(pISSN)
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  • 2288-5324(eISSN)
대한기계학회 (The Korean Society of Mechanical Engineers)
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수정된 증발법을 이용하여 제작된 주석 나노입자의 녹는점 강하에 관한 연구

Study on the Melting Point Depression of Tin Nanoparticles Manufactured by Modified Evaporation Method

  • 김현진 (한국항공대학교 항공우주 및 기계공학부) ;
  • 백일권 (한국항공대학교 항공우주 및 기계공학부) ;
  • 김규한 (한국항공대학교 항공우주 및 기계공학부) ;
  • 장석필 (한국항공대학교 항공우주 및 기계공학부)
  • Kim, Hyun Jin (School of Mechanical and Aerospace Engineering, Korea Aerospace Univ.) ;
  • Beak, Il Kwon (School of Mechanical and Aerospace Engineering, Korea Aerospace Univ.) ;
  • Kim, Kyu Han (School of Mechanical and Aerospace Engineering, Korea Aerospace Univ.) ;
  • Jang, Seok Pil (School of Mechanical and Aerospace Engineering, Korea Aerospace Univ.)
  • 투고 : 2014.03.24
  • 심사 : 2014.05.22
  • 발행 : 2014.08.01
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초록

본 논문에서는 수정된 증발법을 이용하여 제작된 주석(Sn) 나노입자의 녹는점 강하 특성에 대한 연구를 진행하였다. 이를 위해 대량생산이 가능한 수정된 증발법을 이용하여 10nm 급 주석 나노입자를 제조하였다. 주석 나노입자 표면의 산화 방지를 위하여 Benzyl Alcohol 을 기본유체로 사용하였으며, 제작된 주석 나노입자의 형상과 입자크기를 알아보기 위하여 투과전자현미경(TEM)을 사용하였다. 제작된 나노입자의 녹는점은 시차주사열량계(DSC)를 통해 측정하였으며, 광전자분광분석기(XPS)를 사용하여 제작된 주석 나노입자의 성분 분석을 진행 하였다. 주석 나노입자의 녹는점은 주석의 녹는점인 $232^{\circ}C$보다 44% 감소한 $129^{\circ}C$로 측정되었다. 녹는점 측정 결과는 Gibbs-Thomson 식 및 Lai 의 식과 비교하였으며, 그 결과 Lai의 식이 실험결과를 잘 예측함을 확인할 수 있었다.

In the present study, the melting temperature depression of Sn nanoparticles manufactured using the modified evaporation method was investigated. For this purpose, a modified evaporation method with mass productivity was developed. Using the manufacturing process, Sn nanoparticles of 10 nm size was manufactured in benzyl alcohol solution to prevent oxidation. To examine the morphology and size distribution of the nanonoparticles, a transmission electron microscope was used. The melting temperature of the Sn nanoparticles was measured using a Differential scanning calorimetry (DSC) which can calculate the endothermic energy during the phase changing process and an X-ray photoelectron spectroscopy (XPS) used for observing the manufactured Sn nanoparticle compound. The melting temperature of the Sn nanoparticles was observed to be $129^{\circ}C$, which is $44^{\circ}C$ lower than that of the bulk material. Finally, the melting temperature was compared with the Gibbs Thomson and Lai's equations, which can predict the melting temperature according to the particle size. Based on the experimental results, the melting temperature of the Sn nanoparticles was found to match well with those recommended by the Lai's equation.

키워드

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