• Title/Summary/Keyword: 우레탄 고무

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A Study on the Properties of Ethylene-vinylacetate Emulsion mixed with SBR, Urethane, Epoxy and Acryl Latex (아크릴, 에폭시, 우레탄 및 SBR계 라텍스를 혼합한 에틸렌 비닐아세테이트 에멀젼 수지의 물성에 관한 연구)

  • Park, Young-Sam;Lee, Bok-Yul;Byun, Youn-Seop;Choi, Sang-Goo
    • Elastomers and Composites
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    • v.33 no.5
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    • pp.324-334
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    • 1998
  • SBR, polyurethane, acryl and epoxy latex were seperately mixed with ethylene-vinylacetate emulsion(EVA) in the range of $0{\sim}50%$ (wt.% ). For the mixtures, the various physical properties were examined. The viscosity of mixtures was mainly influenced by compatability with EVA emulsion, was decreased within 20% (wt.% ) of latex content, and showed the similar values over 20% (wt.% ) of latex content. The workable time of cement mixtures was mainly depended on the reactivity with cement. The formation of film could be only within $30{\sim}40$ minutes from mixing cement. The tack-free time of mixtures was influenced by the sorts of resin and the quantity of cement. The slow order of tack-free time was epoxy mixtures>SBR mixtures>urethane mixtures>acryl mixtures. The pencil hardness of mixtures was $4B{\sim}2H$, represented higher value in cement mixtures than in emulsion state.

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The Physical Properties of Ethylene Vinylacetate Emulsion Mixed with SBR, Urethane, Epoxy and Acryl Latex (아크릴, 에폭시, 우레탄 및 SBR계 라텍스를 혼합한 에틸렌 비닐아세테이트계 에멀젼 수지의 물리적 특성)

  • Suh, Won-Dong
    • Elastomers and Composites
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    • v.35 no.3
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    • pp.196-204
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    • 2000
  • SBR, polyurethane, acryl and epoxy latex were separately mixed with ethylene -vinylacetate emulsion(EVA) in the range of $0{\sim}50wt%$. For the mixtures, the various physical properties such as defoamerability, mechanical property, and water resistance were experimentally examined. The excellent defoamer was BYK-021 and the appropriate use of it was 0.3 phr for the total components. The shrinkage of compounds was influenced by the compatability of resins and the formation of voids. The mechanical properties was related to the cohesive force of resin particles, the coagulation of cement particles and the co-bonding of resin particles with cement particles. Mixing latex separately showed better properties then non-mixing in the shrinkage ratio, flexural strength, adhesive strength, and impact strength. The water resistance of composites mixed with cement was worse than that of EVA resin.

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Synthesis of Polyurethane Foam/Organonanoclay/Phosphates Composites and its Characterization (폴리우레탄폼/유기나노점토/포스페이트 복합체의 합성과 그 특성)

  • Park, Kyeong-Kyu;Lee, Sang-Ho
    • Elastomers and Composites
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    • v.46 no.4
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    • pp.343-351
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    • 2011
  • We prepared polyurethane foam/cloisite30B/phosphates composites and characterized their rise time, density, cell morphology, and thermal properties. The composites were synthesized with polyadipatediol-cloisite30B composite (f=2.0), polyether-polyol (f=4.6), polymeric 4,4-diphenyl methane diisocyanate (f=2.5), and D-580 (phenyl polyoxyalkenyl phosphate). As a blowing agent, cyclopentane and distilled water were used at various concentrations of D-580 from 0 to 2.81 wt%. The rise times of PUF/Closite30B/Phosphate composites blown with distilled water were faster than those blown with cyclopentane by 30%. The composites blown with cyclopentane had spherical-shape cells and the cell diameter was decreased with increasing D-580 wt%. While $T_g$ of the composites blown with cyclopentane linearly decreased with increasing the D-580 content, the $T_g$ of the composites blown with distilled water increased with the D-580 content. All PUF/Closite30B/Phosphate composites began to decompose from $250^{\circ}C$. The composites blown with cyclopentane showed the second thermal decomposition at temperatures higher than $500^{\circ}C$. The thermal stability of all composites increased with the D-580 content. The effect of D-580 on the thermal stability of the composites was measured higher at the composites blown with distilled water.

Numerical Study on Effect of Using Elastic Pads in Flexible Forming Process (가변성형 공정에서 탄성 패드의 영향에 관한 수치적 연구)

  • Heo, Seong-Chan;Seo, Young-Ho;Noh, Hak-Gon;Ku, Tae-Wan;Kang, Beom-Soo
    • Transactions of the Korean Society of Mechanical Engineers A
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    • v.34 no.5
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    • pp.549-556
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    • 2010
  • In general, materials that can be used to form elastic pads, such as urethane and rubber, are often used in flexible forming processes by inserting the pads between a blank and flexible die for smoothing the forming surface that is formed by a reconfigurable die. In this study, the effects of the elastic pad on formability in the flexible forming process for sheet metals are investigated by performing numerical simulations. In the simulation, the hyperelastic material model is used, where the urethane elastic pads serve as elastic cushions. Case studies are carried out for elastic materials with different hardness values and thicknesses. The results are used to evaluate formability by comparing the configuration of the deformed blank and its major cross-sectional profiles. It is verified that the elastic pad used in the flexible forming process for sheet materials should be hard and that its thickness should be chosen appropriately.

Synthesis of UV-Curable PDMS-Modified Urethane Acrylate Oligomer and Physical Properties of the Cured Film (광경화형 PDMS 변성 우레탄 아크릴레이트 올리고머 합성과 경화필름 물성에 관한 연구)

  • Yeo, Jun-Seok;Hwang, Seok-Ho
    • Elastomers and Composites
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    • v.48 no.4
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    • pp.249-255
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    • 2013
  • Hydroxypropyl terminated PDMS was synthesized by the hydrosilylation reaction with allyl alcohol in the presence of Karstedt's catalyst. And them, an one-pot reaction with HDI isocyanurate trimer and hydroxyethyl methacrylate was conducted to give a silicone-modified urethane acrylate oligomer (PUA oligomer) having 9000 g/mol, weight average molecular weight. The synthesized PUA oligomer was characterized by using FT-IR and GPC. The UV-curable coatings were prepared by PUA oligomer blending with a reactive monomer (phenylthioethyl acrylate) under the different mole ratios. It was found that the refractive index of cured film increased when the reactive monomer was added but there was no relationship between the refractive index and amount of reactive monomer. Also, their transmittance for cured films was not change as increasing the content of reactive monomer.

A Research on the Design Techniques for Underwater Acoustic Basin (무향 수조 설계기법 연구)

  • 임용곤;이종무;배상현
    • Journal of the Korea Institute of Information and Communication Engineering
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    • v.5 no.1
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    • pp.212-221
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    • 2001
  • This paper deals with the design techniques for underwater acoustic basin. An underwater acoustic basin is needed for test and calibration of acoustic sensors, acoustic digital communication system, acoustic measurement system, and underwater image data telemetry system. KRISO(Korea Research Institute of Ships and Ocean Engineering) have planned the construction of an underwater acoustic tank from 1999 to 2001 through internal project. We studied about absorbtion characteristics of a porous re-cycled rubber which is selected as a absorption materials and designed absorption plate with wedge shape. The simulation of reflection analysis along the wedge angle for wedged type plate was presented.

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A Research on the Design Techniques for Underwater Acoustic Basin (무향 수조 설계기법 연구)

  • 임용곤;이종무;박종원
    • Proceedings of the Korean Institute of Information and Commucation Sciences Conference
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    • 2000.05a
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    • pp.371-377
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    • 2000
  • This paper deals with the design techniques for underwater acoustic basin. An underwater acoustic basin is needed for test and calibration of acoustic sensors, acoustic digital communication system, acoustic measurement system, and underwater image data telemetry system. KRISO(Korea Research Institute of Ships and Ocean Engineering) have planned the construction of an underwater acoustic tank from 1999 to 2001 through internal project. We studied about absorbtion characteristics of a porous re-cycled rubber which is selected as a absorption materials and designed absorption plate with wedge shape. The simulation of reflection analysis along the wedge angle for wedged type plate was presented.

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A Study on the Toxicity of Closing material of building with chamber (Smoke density chamber를 적용한 건축물 마감재의 연소가스 독성 평가)

  • Lee, In-Ku;Cho, Nam-Wook;Lee, Bong-Jae;Rie, Dong-Ho
    • Proceedings of the Korea Institute of Fire Science and Engineering Conference
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    • 2011.04a
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    • pp.248-251
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    • 2011
  • 연소가스분석을 통한 건축물 마감재료의 연소독성평가를 위해 독성지수 계산법(NES 713)을 활용하여 독성평가를 수행하였다. 가연성 건축재료(우레탄, 고무바닥재)를 대상으로 독성가스를 측정하기 위해 ISO19702에서 규정하는 FT-IR(퓨리에변환적외선분광분석기)을 이용하였으며, 화재 모델은 ISO5659의 Smoke Density Chamber를 사용하였다. 독성지수를 산정하기 위해 Cf(사람이 30분간 노출시에 사망할 수 있는 가스의 농도)를 기준으로 하였다. 본 연구를 통해 연소가스 독성지수 연구의 기초연구자료로 활용하고자 한다.

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Effect of Coupling Agent, Methylene Diisocyanate, in the Blending of Poly(methyl methacrylate)-Modified Starch and Styrene-Butadiene Rubber (폴리(메틸 메타크릴레이트)-개질된 전분과 스티렌-부타디엔 고무의 혼합에서 커플링제 메틸렌 디이소시아네이트의 효과)

  • Li, Mei-Chun;Cho, Ur Ryong
    • Elastomers and Composites
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    • v.49 no.2
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    • pp.117-126
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    • 2014
  • Methylene diisocyanate (MDI) was investigated as a novel interfacial modifier to enhance the performances of poly(methyl methacrylate)-modified starch/styrene-butadiene rubber (PMMA-modified starch/SBR) composites. Owing to the formation urethane linkage on one side and ${\pi}-{\pi}$ adhesion on the other side, MDI acted as an intermediated linkage role in the PMMA-modified starch/SBR interfaces, which was evidenced by the morphological, mechanical, dynamic mechanical and thermal decomposition studies. As a result, the presence of MDI significantly improved the mechanical properties and thermal stability of PMMA-modified starch/SBR composites. In addition, the effect of starch concentration on the various performances of the resulted MDI/PMMA-modified starch/SBR composites, such as morphology, vulcanization characteristics, mechanical properties, toluene swelling behavior, and thermal stability were investigated and discussed in detail. The obtained MDI/PMMA-modified starch/SBR composites exhibited superior mechanical properties to carbon black/SBR (CB/SBR) composites, demonstrating the potential use of the renewable starch as a substitute for CB in the rubber compounds.

Study on Type of Different Polyols for Physical Properties of Polyurethane Foam Under Sea Water (해수에서 폴리올 종류가 폴리우레탄 폼의 물성에 미치는 영향)

  • Kim, Sang-Bum
    • Elastomers and Composites
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    • v.46 no.2
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    • pp.158-163
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    • 2011
  • Rigid polyurethane foam (PUF) was synthesized with different contents of aliphatic polyester polyol, aromatic polyester polyol and aliphatic polyether polyol to know change of properties under sea water. UTM(universal testing machine), DSC(differential scanning calorimetry), hardness meter and FT-IR(Fourier transform spectroscopy) were used to study the PUF`s physical properties under sea water. Compressive strength and hardness of PUF decreased with increasing the content of aromatic polyester polyol under sea water as aging. According to the results of IR spectral analysis, reduction of urethane and urea peak was found and allophanate and biuret peak increased. Although glass transition temperature of PUF increased, mechanical properties of PUF decreased under sea water, because PUF gets brittle when crosslink density increase.