• Proceedings of the KIEE Conference
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• 2001.07b
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• pp.1300-1302
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• 2001

For developing a 100 kW MCFC power generation system. Several design parameters for a fuel cell stack and system analysis results by Cycle Tempo, a processing computer soft ware, were described. Approximately 170 cells are required to generate 100 kW at a current density of $125mA/cm^2$ with $6000cm^2$ cells. An overall heat balance was calculated to predict exit temperature. The 100 kW power is expected only under pressurized operation condition at 3 atm. Recycle of cathode gas by more than 50% is recommended to run the stack at $125mA/cm^2$ and 3 atm. Manifolds should be designed based on gas flow rates for the suggested operating condition. The fuel cell power generation system was designed conceptually with several choices of utilization of anode exhaust gas. Also system efficiency was calculated at various type of system and operation conditions.

• 한국전기화학회:학술대회논문집
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• 2001.06a
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• pp.98-103
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• 2001

• Transactions of the Korean Society of Mechanical Engineers B
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• v.33 no.3
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• pp.149-155
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• 2009

In this work a numerical study to find the characteristics of the internal flow and mixing process has been conducted in a static mixer used in the system of catalytic combustor of the fuel cell power plant. After introducing the model description and final governing equations the present numerical approach is applied to the analysis of static mixer, which may have one or more helical elements inside the circular tube by changing such various parameters as incoming mass flow rates and the number of helical elements. The results show that although the static mixer is efficient in mixing fuel and air, more optimization processes are required to achieve the appropriate mixing characteristics in front of the honeycomb type catalytic combustor used in the MCFC power plant

• Proceedings of the KIEE Conference
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• 1996.07c
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• pp.1407-1408
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• 1996

The development of MCFC is going to the second stage of development and recent studies have been focusing on long-term durability of cell component. Systematic investigation on corrosion behavior of Fe-based alloys has been done in (62+38) mol % (Li+K) $CO_3$ melt at 923K by using steady-state polarization and electrochemical impedance spectroscopy method. It was found that the corrosion current t of these Fe-based alloys decreased with increasing Cr, Al content.

• Proceedings of the KSME Conference
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• 2000.04b
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• pp.264-269
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• 2000

As a part of the ongoing effort towards commercial application of high-temperature fuel cell power generation systems, we have recently built a pilot-scale molten carbonate fuel cell power plant and tested it. The stack test system is composed of diverse peripheral units such as reformer, pre-heater, water purifier, electrical loader, gas supplier, and recycling systems. The stack itself was made of 40cells of $6000cm^2$ area each. The stack showed an output higher than 25kW power and a reliable performance at atmospheric operation. A pressurized performance was also tested, and it turned out the cell performance increased though a few cells have shown a symptom of gas crossover. The pressurized operation characteristics could be analyzed with numerical computation results of a stack model.

• Proceedings of the KIPE Conference
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• 2010.07a
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• pp.200-201
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• 2010

본 논문에서는 동특성이 매우 느린 용융탄산염 연료전지 (Molten Carbonate Fuel Cell, MCFC) 스택이 계통 사고 시 추가적인 UPS (Uninterruptible Power Supply) 없이 비상부하로 전력 공급이 가능하고, 사고 제거 후 즉시 정격전력 발전하여 계통으로 주입할 수 있는 비상부하 추종형 백업 시스템을 제안한다. 제안된 MCFC 발전 시스템용 비상부하 추종형 백업 시스템은 3상 인버터로 구성된 PCS (Power Conditioning System) 출력단에 3상 PWM 컨버터를 연결한 구조이고, 비상부하 추종 및 부하량 조절이 가능한 추가적인 제어 알고리즘으로 PWM 컨버터를 제어한다. 제안된 비상부하 추종형 백업 시스템의 회로와 제어 알고리즘의 타당성을 컴퓨터 시뮬레이션을 통하여 검증한다.

• Journal of the Korean institute of surface engineering
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• v.28 no.4
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• pp.243-254
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• 1995

The fabrication process of Cu-base anode for replacing Ni-base anode of molten carbonate fuel cell was investigated. Electrochemical performance and thermal stability of Cu-base anode were also investigated. Green sheet was prepared by mixing Cu and Ni powder with 1.5wt% methylcellulose and 100wt% water. The pore-size distribution of the Cu-base anode sintered at $800^{\circ}C$ for 30min showed almost uniform pore-size ranging from 4 to 20$\mu\textrm{m}$ and it was considered suitable for MCFC anode. Cu-Ni anode containing between 35 to 50wt% Ni exhibited current density of 111mA/$\textrm{cm}^2$ at 100mV overpotential and it was almost the some value for pure Ni anode. The sintering resistance of Cu-Ni increased with an increase of Ni addition. It was considered that the increase of sintering resistance was due to the decrease of diffusion rate of Cu and Ni with increasing the addition of Ni in Cu-Ni alloy.

• Applied Chemistry for Engineering
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• v.3 no.4
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• pp.535-546
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• 1992

The molten carbonate fuel cell(MCFC) has been under Intensive development for the last decade as a second generation fuel cell. The advantages of the MCFC over the phophoric acid fuel cell are higher efficiency, its ability to accept CO and $H_2$ as a fuel, lower material costs, and high operating temperature making internal reforming possible. These features, along with low atmospheric emissions, will open up a significant market as an attractive means of developing highly efficient power plant. This article reviews a status of the MCFC research and development, a principle of the MCFC, and cell and stack technology including the status of electrodes, matrices and electrolytes. Several technical difficulties which must be resolved to be commercialized art mainly focused.

• Journal of the Korean institute of surface engineering
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• v.27 no.3
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• pp.166-175
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• 1994

The effect of Co addition on the electrochemical performance and structural stability of porous Ni anode for molten carbonate fuel cell(MCFC) was evaluated by the anodic polarization and the sintering test in the simulated MCFC anode condition ($650^{\circ}C$, 80% $H_2$+20%$CO_2$). The anode current density ranged from 110mA/$cm^2$ to 144mA/$cm^2$ was obtained at +100mV overpotential by additions of Co up to 10 wt.%. The sintering resistance of Ni-Co anodes was higher than that of the pure Ni anode. The increase of sintering resistance seemed to be to the lower diffusion coefficient of Co than that of Ni.

• Proceedings of the KIEE Conference
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• 1994.07a
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• pp.94-96
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• 1994

To develop the 2kw class MCFC stack, preliminarly 3 cell and 10 cell stack having a $100cm^2$ effective electrode area were fabricated and tested. These stacks showed 30 W and 100 W of output respectively and average cell voltage of 0.734V at $150mA/cm^2$. The stack performance decreased with the increase of fuel utilization rate. In durability test of 10 cell stack, the performance was sharply decreased at the rate of 180mV/1000Hr during 720hours operation time.