• Title/Summary/Keyword: 완충 시간

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Determination of Thioglycolic acid in the presence of Copper(II) by Adsorptive Stripping Voltammetry (흡착 벗김 전압전류법에 의한 구리이온(II) 존재하에서 티오글리콜산의 정량)

  • Hong, Mi-Jeong;Kwon, Young-Sun
    • Analytical Science and Technology
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    • v.8 no.1
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    • pp.25-32
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    • 1995
  • Determination method of trace thioglycolate has been studied by adsorptive stripping voltammetry. Copper(II)-thioglycolate complex is adsorbed at the hanging mercury drop electrode and stripped during cathodic scan. Electrolyte was used pH 6.5 phosphate and pH 9.5 borate buffer solutions. Optimal conditions were a copper(II) concentration $1{\times}10^{-4}M$, an adsorption accumulation potential -0.2V, an adsorption accumulation time 60 sec and a scan rate 20mV/sec. A detection limit of $1{\times}10^{-9}M$ thioglycolate was obtained. The method was applied to the determination of thioglycolate in cold wave fluids and depilating creams.

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Task Scheduling Technique for Online Bandwidth Smoothing (온라인 대역폭 평활화를 위한 태스크 스테줄링 기법)

  • Kim, Jae-Wook;Ha, Rhan;Cha, Ho-Jung
    • Proceedings of the Korean Information Science Society Conference
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    • 2000.04a
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    • pp.148-150
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    • 2000
  • 자원 예약을 보장하지 못하는 네트워크 상에서 실시간 멀티미디어 응용의 만족스러운 서비스를 위해서는 효과적인 종단 시스템의 운영이 필요하다. 이러한 운영 기술 중 버퍼를 이용한 응용 프로그램 수준의 대역폭 평활화 기술과 태스크 스케줄링 기법은 핵심적인 부분을 차지한다. 기존에 제안된 온라인 대역폭 평활화 기법은 동적 슬라이딩 윈도우와 공적 버퍼를 이용하여 네트워크에 적응할 뿐만 아니라 요구 대역폭 평활화를 통해 지터를 흡수, 완충시킴으로써 더 나은 서비스 품질을 보장한다. 그러나 응용 프로그램 수준에서 동작하기 때문에 프로그램의 수행 품질보장을 위한 시간 대역을 보장하지 못할 뿐만 아니라 지터의 발생 가능성이 높다. 본 연구에서는 효과적인 버퍼 관리를 통해 서비스 품질의 손실을 최소화하는 적응성 있는 온라인 대역폭 평활화 기법이 안정적으로 동작하기 위한 최적화된 태스크 스케줄링 기법을 제안한다. 먼저 태스크 스케줄링 기법은 멀티미디어 데이터의 생산과 소비를 적시에 보장할 수 있도록 하여 지터의 발생을 최소화하고, 만일 네트워크 지터가 발생하더라도 응용 프로그램 수준의 버퍼 관리를 통해 완충시킴으로서 서비스 품질의 손실을 최소화한다. 모의 실험에서는 제안된 기법이 온라인 대역폭 평활화 기법을 효과적으로 지원함을 보인다.

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Growth Kinetics and Electronic Properties of Passive Film of Nickel in Borate Buffer Solution (Borate 완충용액에서 니켈 산화피막의 생성 과정과 전기적 성질)

  • Kim, Younkyoo
    • Journal of the Korean Chemical Society
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    • v.58 no.1
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    • pp.9-16
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    • 2014
  • In a borate buffer solution, the growth kinetics and the electronic properties of passive film on nickel were investigated, using the potentiodynamic method, chronoamperometry, and single- or multi-frequency electrochemical impedance spectroscopy. The oxide film formed during the passivation process of nickel has showed the electronic properties of p-type semiconductor, which follow from the Mott-Schottky equation. It was found out that the passive film ($Ni(OH)_2$) of Ni formed in the low electrode potential changes to NiO and NiO(OH) while the electrode potential increases.

Drop and Damping Characteristics of the CEDM for the Integral Reactor (일체형원자로 제어봉구동장치의 낙하 및 완충특성)

  • Choi, M.H.;Kim, J.H.;Huh, H.;Yu, J.Y.
    • Transactions of the Korean Society for Noise and Vibration Engineering
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    • v.20 no.7
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    • pp.658-664
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    • 2010
  • A control element drive mechanism(CEDM) is a reactor regulating system, which inserts, withdraws or maintains a control rod containing a neutron absorbing material within a reactor core to control the reactivity of the core. The ball-screw type CEDM for the integral reactor has a spring-damper system to reduce the impact force due to the scram of the CEDM. This paper describes the experimental results to obtain the drop and damping characteristics of the CEDM. The drop tests are performed by using a drop test rig and a facility. A drop time and a displacement after an impact are measured using a LVDT. The influences of the rod weight, the drop height and the flow area of hydraulic damper on the drop and damping behavior are also estimated on the basis of test results. The drop time of the control element is within 4.5s to meet the design requirement, and the maximum displacement is measured as 15.6 mm. It is also found that the damping system using a spring-hydraulic damper plays a good damper role in the CEDM.

Determination of L-Asparagine Using Proteus mirabilis Bacterial Electrode (Proteus mirabilis 박테리아 전극을 이용한 L-Asparagine의 정량)

  • Ihn Gwon-Shik;Moo-Jeong Sohn
    • Journal of the Korean Chemical Society
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    • v.32 no.5
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    • pp.422-427
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    • 1988
  • The bio-electrode for L-asparagine, excellent in the reproducibility of responsibility, has been constructed by immobilizing the bacterium Proteus mirabilis on an ammonia gas sensor. This electrode was investigated for the effects of pH, temperature, buffer solution, bacterial amounts and interferences, and stability with the lapse of time. The response of the bacterial electrode was linear in the range of $9.0{\times}10^{-5}$$1.0{\times}10^{-2}M$ L-asparagine with a slope of 58.9mV/decade in pH 7.8, 0.05M phosphate buffer solution at $30^{\circ}C$. The bacterial amounts used for this electrode was 3 mg and response time was 7∼9 min. Therefore, this assembly can be used for the determination of L-asparagine.

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Particle Size Effects in Buffer System using Calcium Carbonate Bead Immobilized with Alginate for the Cultivation of Bifidobacterium (Alginate에 고정화된 Calcium Carbonate를 이용한 Buffer System에서 비드 크기에 따른 Bifidobacterium의 배양에 대한 효과)

  • Lee, Ki-Yong;Heo, Tae-Ryeon
    • Korean Journal of Food Science and Technology
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    • v.30 no.2
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    • pp.425-433
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    • 1998
  • The characteristics of the reaction of calcium carbonate $(CaCO_3)$ immobilized with alginate as buffer system for the high concentration cultivation of bifidobacteria in fermenter are described by the mathematical model, and tested for the reusing possibility of the used $CaCO_3$ beads. When$CaCO_3$ beads with the various diameters were reacted in 0.1 M of the mixed organic acids (0.6 M of acetic acid and 0.4 M lactic acid) and in fermenter inoculated Bifidobacterium longum ATCC 15707, the change of bead diameters can be calculated with the amount of the decreased $CaCO_3$ from the surface of bead using the mathematical model. These values was similar to the directly measured bead diameter by a micrometer. Therefore, it was considered that the mathematical model could be used for explaining the reaction charateristics of the $CaCO_3$ bead reacted with the organic acids. When Bifidobacterium longum was incubated at $37^{\circ}C$ for 20 hours in fermenter with $CaCO_3$ beads, the buffering effect of $CaCO_3$, the reduce rate of the bead diameter, and the growth rate of Bifidobacterium longum were higher at the smaller beads than beads with the larger diameters. Also, when Bifidobacterium longum was incubated in fermenter with the mixed beads which were added new beads to the recovered beads in order to equalize with the total surface area of initial beads, the buffering effect of $CaCO_3$ bead and the growth rate of Bifidobacterium longum were very corresponded with the results of the fermentation using the only initial beads. Therfore, it is expected that the used beads can be reused by adding the initial beads.

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IN VITRO STUDY OF CARIOGENIC POTENTIAL OF INFANT FORMULAS (이유식의 우식유발능에 관한 생체외 연구)

  • Park, Deuk-Hee;Lee, Kwang-Hee;Kim, Dae-Eop
    • Journal of the korean academy of Pediatric Dentistry
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    • v.27 no.1
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    • pp.32-39
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    • 2000
  • The purpose of this study was to assess the cariogenic potential of five infant formulas in vitro. as compared with 10% sucrose solution and whole bovine milk. Buffering capacities were determined by the amount of 0.1 N lactic acid consumed to titrate the 50ml specimen solutions to pH 4.0. The pH of the specimen solution inoculated by Streptococcus mutans was measured by pH meter and the surface microhardness of primary tooth enamel immersed in the specimen solution was measured by the microhardness tester, before and after 48 hours incubation. Also, the solubility of calcium from synthetic hydroxyapatite was evaluated by atomic absorption spectrophotometer The buffering capacity of infant formulas was higher than that of sucrose solution and lower than that of milk, and there were significant differences among infant formulas(P<0.01). The average pH of infant formulas after 48 hours incubation was lower than that of sucrose solution and milk, and there was significant difference between infant formulas and milk(P<0.05). There were no signifiant differences among oops in the microhardness change of primary tooth enamel and in the amount of dissolved calcium ion from synthetic hydroxyapatite after incubation with Streptococcus mutans. In conclusion, infant formulas seemed to fulfill the basic requirments to cause dental caries in primary teeth, and there were significant differences of cariogenic potential among infant formulas. Cooperative efforts of dentistry and manufacturers to reduce the cariogenic potential of infant formulas would be necessary to prevent the early childhood caries in children.

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THE EFFECTS OF CHEMORADIATION THERAPY FOR NEUROBLASTOMA ON DENTAL CARIES ACTIVITY (신경모세포종의 화학 및 방사선요법이 치아우식활성도에 미치는 영향)

  • Lee, Ji-Hyun;Park, Ki-Tae;Sung, Ki-Woong;Kim, Ji-Yeon
    • Journal of the korean academy of Pediatric Dentistry
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    • v.37 no.3
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    • pp.352-358
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    • 2010
  • Chemotherapy or radiotherapy used for the treatment of pediatric cancer may have many adverse effects on the oral cavity. Oral mucositis, reduced salivary flow, oral infection, hypodontia, microdontia, arrested root development, and enamel hypoplasia are common oral complications. The aim of this study is to evaluate the effects of cancer therapy on dental caries activities. The children who had been treated for neuroblastoma in the department of pediatrics, Samsung Medical Center, were included and healthy children served as controls. The salivary flow rate, salivary buffering capacity, and Streptococcus mutans counts of both groups were evaluated using Dentocult$^{(R)}$ SM and Dentobuff$^{(R)}$ Strip. The dental caries activity related to the age at the start of treatment and the time elapsed since treatment completion were also evaluated. As a result, neuroblastoma patients had significantly lower salivary flow rate than the controls, while there were no significant differences between two groups as for salivary buffering capacity and Streptococcus mutans counts. The dental caries activities related to the age at the start of treatment and the time elapsed since treatment completion were not significantly different.

Enhancement of Cultivation Efficiency of Bifidobacterium longum Using Calcium Carbonate Buffer System (Calcium Carbonate Buffer System을 이용한 Bifidobacterium longum의 배양 효율 증대에 관한 연구)

  • Lee, Ki-Yong;Hwang, In-Bum;Heo, Tae-Ryeon
    • Korean Journal of Food Science and Technology
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    • v.29 no.1
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    • pp.126-132
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    • 1997
  • Calcium carbonate ($CaCO_3$) immobilized with alginate was studied as buffer system to enhance the cultivation efficiency of Bifidobacterium longum (ATCC 15707) which is inhibited at low pH. To test the bufferring effect of the immobilized $CaCO_3$ beads, pH value in each modified trypticase-proteose peptone-yeast (TPY) broth which is adjusted to pH 4.0 with acetic acid, lactic acid and complex solution of acetic and lactic acid, 3:2 (M:M) was tested by concentration of $CaCO_3$ bead and reaction time. The bufferring effect of $CaCO_3$ bead became higher with increasing the amount of $CaCO_3$ bead in the acidic solution. The growth rate of bifidobacteria and bufferring effect were examined in relation to the amount of $CaCO_3$ bead and concentration of glucose in the modified TPY media. The growth rate of bifidobacteria and bufferring effect were increased with increasing the amount of $CaCO_3$ bead and concentration of glucose. Also, the exponential time of bifidobacteria became longer with increasing the amount of $CaCO_3$ bead and concentration of glucose in the modified TPY media. When we observed the growth rate of bifidobacteria by the method of pH-controlled culture and $CaCO_3$ buffer system, the $CaCO_3$ buffer system was more effective than that of pH-controlled culture. Therefore, this $CaCO_3$ buffer system may be useful as a method to enhance of the cultivation efficiency of bifidobacteria.

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A Sensitivity Analysis of Design Parameters of an Underground Radioactive Waste Repository Using a Backpropagation Neural Network (Backpropagation 인공신경망을 이용한 지하 방사성폐기물 처분장 설계 인자의 민감도 분석)

  • Kwon, S.;Cho, W.J.
    • Tunnel and Underground Space
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    • v.19 no.3
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    • pp.203-212
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    • 2009
  • The prediction of near field behavior around an underground high-level radioactive waste repository is important for the repository design as well as the safety assessment. In this study, a sensitivity analysis for seven parameters consisted of design parameters and material properties was carried out using a three-dimensional finite difference code. From the sensitivity analysis, it was found that the effects of borehole spacing, tunnel spacing, cooling time and rock thermal conductivity were more significant than the other parameters. For getting a statistical distribution of buffer and rock temperatures around the repository, an artificial neural network, backpropagation, was applied. The reliability of the trained neural network was tested with the cases with randomly chosen input parameters. When the parameter variation is within ${\pm}10%$, the prediction from the network was found to be reliable with about a 1% error. It was possible to calculate the temperature distribution for many cases quickly with the trained neural network. The buffer and rock temperatures showed a normal distribution with means of $98^{\circ}C$ and $83.9^{\circ}C$ standard deviations of $3.82^{\circ}C$ and $3.67^{\circ}C$, respectively. Using the neural network, it was also possible to estimate the required change in design parameters for reducing the buffer and rock temperatures for $1^{\circ}C$.