• Journal of the Korea Academia-Industrial cooperation Society
• /
• v.17 no.1
• /
• pp.21-27
• /
• 2016

Global warming due to greenhouse gas emissions is considered as a major problem worldwide, and many countries are making great efforts to reduce carbon dioxide emissions. Many technologies in post-combustion, pre-combustion and oxy-fuel combustion $CO_2$ capture have been developed. Among them, a hybrid pre-combustion $CO_2$ capture system of a water gas shift (WGS) reactor and a membrane gas separation unit was investigated. The 2 stage WGS reactor integrated high temperature shift (HTS) with a low temperature shift (LTS) was used to obtain a higher CO conversion rate. A Pd/Cu dense metal membrane was used to separate $H_2$ from $CO_2$ selectively. The performance of the hybrid system in terms of CO conversion and $H_2$ separation was evaluated using a 65% CO, 30 % $H_2$ and 5% $CO_2$ gas mixture for applications to pre-combustion $CO_2$ capture. The experiments were carried out over the range of WGS temperatures ($200-400^{\circ}C$), WGS pressures (0-20bar), Steam/Carbon (S/C) ratios (2.5-5) in a feed gas flow rate of 1 L/min. A very high CO conversion rate of 99.5% was achieved with the HTS-LTS 2 stage water gas shift reactor, and 83% $CO_2$ was concentrated in the retentate using the Pd/Cu membrane.

• Journal of the Korean Society of Propulsion Engineers
• /
• v.13 no.3
• /
• pp.58-63
• /
• 2009

The global restriction on pollutant emissions and the soaring of crude oil price are expected to result in the change of future transportation system. Hydrogen is considered to be the leading candidate as an alternative energy source before other new alternative energy sources emerge. Scientists anticipate that hydrogen fuel gas turbine engine and fuel cell will be the power plant of the aircraft in the near future. To realize the aircraft powered by fuel cell system in the future, the technologies such as fuel cell with higher energy density, compressed gas or liquid storage system of hydrogen fuel, and efficient and lightweight electric motor have to be developed first.

• Prospectives of Industrial Chemistry
• /
• v.24 no.4
• /
• pp.1-21
• /
• 2021

화석연료의 과도한 사용으로 유발된 기후변화 문제를 해결하기 위해 대체에너지의 개발에 대한 관심이 높아지고 있는 가운데 재생가능하며 친환경적인 수소에너지가 실현가능한 궁극적 대안으로 주목받고 있다. 다양한 수소 생산 기술 중 물의 전기분해를 이용한 수전해 기술은 온실가스와 같은 오염물질을 배출하지 않으며 재생에너지와 연계하여 미이용 전력을 대용량 장주기로 저장할 수 있다는 장점이 있다. 수전해 장치는 수소와 산소를 발생하는 전극과 기체의 섞임을 방지하고 이온을 전달하는 분리막으로 구성되며 그 중 분리막은 수전해 장치의 효율과 안정성을 결정짓는 핵심 부품이다. 본 총설에서는 수전해 기술 중 저온 수전해에 해당하는 알칼라인 수전해(alkaline water electrolysis), 고분자전해질막 수전해(polymer electrolyte membrane water electrolysis)와 음이온교환막 수전해(anion exchange membrane water electrolysis)에 사용되는 분리막에 대한 특성을 분석하고 최근 연구 동향에 대해서 다루고자 한다.

• Applied Chemistry for Engineering
• /
• v.22 no.5
• /
• pp.532-539
• /
• 2011

The physical and chemical properties of the dried low rank coals (LRCs) before and after the surface treatment using ozone and ammonia were characterized in this study. The contents of moisture, volatiles, fixed carbon and ash consisting of dried LRCs before the surface treatment were about 2.0, 44.8, 44.9 and 8.9%, respectively. Also, it was composed of carbon of 62.66%, hydrogen of 4.33%, nitrogen of 0.94%, oxygen of 27.01% and sulfur of 0.09%. The dried LRCs was surface-treated with the various dry methods using gases such as ozone at room temperature, ammonia at $200^{\circ}C$ and then the dried LRCs before and after the surface treatment were characterized by the various analysis methods such as FT-IR, TGA, proximate and elemental analysis, caloric value, ignition test, adsorption of $H_2O$ and $NH_3-TPD$. As a result, the oxygen content increased and the calorific value, ignition temperature and the contents of carbon and hydrogen relatively decreased because the oxygen-contained functional groups were additionally generated by the surface oxidation with ozone which plays a role as an oxidant. Also, its $H_2O$ adsorption ability got higher because the hydrophilic oxygen-contained functional groups were additionally generated by the surface oxidation with ozone. On the other hand, it was confirmed that the dried LRCs after the surface treatment with $NH_3$ at $200^{\circ}C$ have the decreased oxygen content, but the increased calorific value, ignition temperature and contents of carbon and hydrogen because of the decomposition of oxygen-contained functional groups the on the surface. In addition, the $H_2O$ adsorption ability was lowered bucause the surface of the dried LRCs might be hydrophobicized by the loss of the hydrophilic oxygen-contained functional groups. It was concluded that the various physico-chemical properties of the dried LRCs can be changed by the surface treatment.

• Journal of The Korean Association For Science Education
• /
• v.40 no.3
• /
• pp.237-251
• /
• 2020

Issues on climate change we are facing, such as global warming, are very important as it affects our lives directly. To overcome this, efforts to reduce greenhouse gases emissions (e.g., carbon dioxide) are necessary and these efforts should be based on our integrated understanding of carbon cycle. The purpose of this study is to examine the research trend on carbon cycle education and to suggest the value and direction of carbon cycle education for students who will be citizens of the future. We analyzed 52 carbon cycle education related studies collected from academic research databases (RISS, KCI, ERIC, Google Scholar, and others). As a result, we conclude that resources are still limited and more researches on verification and utilization of developed program, development of accurate and comprehensive tools for students' recognition and level assessment, developing educational model or teacher professional development, providing more appropriate curriculum resources, and the use of various topics or materials for carbon cycle education are necessary. Students' comprehensive understanding of the carbon cycle is important to actively react to the changes in the global environment. Therefore, to support such learning opportunities, resources that can be connected to students' daily experiences to improve students' understanding of carbon cycle and replace misconceptions based on the verification of existing programs should be provided in the classroom as well as the curriculum. In addition, sufficient exemplary cases in carbon cycle education including various materials and topics should be provided through professional development to support teachers teaching strategies with carbon cycle.

• Journal of Korean Society of Environmental Engineers
• /
• v.38 no.12
• /
• pp.641-646
• /
• 2016

Soil organic matter (SOM) is an important soil component releasing nutrients to the plants and reducing risks of soil contamination to the human and ecosystem. Much attention has been recently paid to SOM investigation and management because SOM holds the most of carbon in the earth and sequestrate carbon as a sink tank. The first objective of the study was to investigate SOM of 495 soil samples taken at the Korea Soil Quality Monitoring Network. Soil samples were collected from 16 regions and 8 land use types. The second objective of the study was to find a relationship between the Tyurin method and loss-on-ignition (LOI) method for SOM. The means of SOM by Tyurin and LOI methods were 1.90 and 2.92 % (w/w), respectively. Land uses such as forest, religious area and park where organic matters continuously supply to normally showed higher SOMs than residential and school areas having sandy soils. A regression equation of the relationship between Tyurin and LOI methods was y(Tyurin) = 0.6257x(LOI) + 0.0602 (P-value < 0.001). The coefficient of determination was $R^2=0.749$, relatively linearly related. Although LOI may result in higher SOMs than the Tyurin method, LOI may be a preference for the SOM investigation if various kinds of land uses and many soil samples should be measured.

• Journal of the Korean earth science society
• /
• v.35 no.4
• /
• pp.249-258
• /
• 2014

Despite the greenhouse gases like carbon dioxide have steadily increased in atmosphere, the overall trend of the global average surface air temperature has stalled during the last decade (2002-present). This phenomenon is often called hiatus or warming pause, which is challenging the prevailing view that anthropogenic forcing causes warming environment. Our study characterized the hiatus by analyzing the HadGEM2-AO (95 yrs) simulation data based on RCP8.5 scenario. The PC2 time series from the EOF of the zonal mean vertical ocean temperature has been defined as the index that represents the warming pause. The relationship between the hiatus, ENSO and the changes in climate system are identified by utilizing the newly defined PC2. Since the La Nina index (defined as the negative of NINO3 index) leads PC2 by about 11 months, it may be possible that the La Nina causes the warming to be interrupted. We also show that the cooling of the climate system closed tied to the heat penetration into the deep ocean, indicating the weakening the warming rate is due to the oceanic heat uptake. Finally, the global warming hiatus is characterized by the anomalous warming in Arctic region as well as the intensification of the trade wind in the equatorial Pacific.

• Journal of Korean Society for Atmospheric Environment
• /
• v.23 no.2
• /
• pp.225-241
• /
• 2007

A closed flux chamber system was used for measuring major greenhouse gas (GHG) emission from tideland and/or wetland soils in estuarine area at Saemankum, Kunsan in southwestern Korea during from months of February to June 2006. Hourly averaged GHG soil emissions were measured two to three times a day during the ebb tide hours only. Site soils were analyzed for soil parameters (temperature, pH, total organic contents, N and C contents in soil) in the laboratory. Soil GHG fluxes were calculated based on the GHG concentration rate of change measured inside a closed chamber The analysis of GHG was conducted by using a Gas Chromatography (equipped with ECD/FID) at laboratory. Changes of daily, monthly GHGs' fluxes were examined. The relationships between the GHG emissions and soil chemical contents were also scrutinized with respect to gas production and consumption mechanism in the soil. Soil pH was pH $7.47{\pm}0.49$ in average over the experimental period. Organic matter contents in sample soil was $6.64{\pm}4.98\;g/kg$, and it shows relatively lower contents than those in agricultural soils in Kunsan area. Resulting from the soil chemistry data, soil nitrogen contents seem to affect GHG emission from the tidal land surface. The tidal soil was found to be either source or sink for the major GHG during the experimental periods. The annual average of $CH_{4}\;and\;CO_{2}$ fluxes were $0.13{\pm}0.86\;mg\;m^{-2}h^{-1}\;and\;5.83{\pm}138.73\;mg\;m^{-2}h^{-1}$, respectively, which will be as a source of these gases. However, $N_{2}O$ emission showed in negative flux, and the value was $-0.02{\pm}0.66\;mg\;m^{-2}h^{-1}$, and it implies tidal land surface act as a sink of $N_{2}O$. Over the experimental period, the absolute values of gas fluxes increased with soil temperature in general. Averages of the ambient gas concentration were $86.8{\pm}6.\;ppm$ in $CO_{2},\;1.63{\pm}0.34\;ppm\;in\;CH_{4},\;and\;0.59{\pm}0.15\;ppm\;in\;N_{2}O$, respectively. Generally, under the presence of gas emission from agricultural soils, decrease of gas emission will be observed as increase in ambient gas concentration. We, however, could not found significant correlation between the ambient concentrations and their emissions over the experimental period. There was no GHG compensation points existed in tide flat soil.

• Journal of Korean Society for Atmospheric Environment
• /
• v.29 no.2
• /
• pp.171-185
• /
• 2013

Wetland has been known as a major biogenic source of $CH_4$ in globe. In a global scale, the amounts of 55~150 Tg $CH_4$ are released into the atmosphere annually from wetlands; and it accounts for about 21% of total $CH_4$ annual global emission. From August 2010 to August 2011, measurements of major greenhouse gas ($CO_2$, $CH_4$, $N_2O$) emissions were conducted from a freshwater wetland at Kunsan ($35^{\circ}56^{\prime}38.94^{\prime\prime}N$, $126^{\circ}43^{\prime}16.62^{\prime\prime}E$), Korea by using floating closed static chamber method. Flux measurements for these gases from western coastal tidal flat at Seocheon ($36^{\circ}07^{\prime}13.85^{\prime\prime}N$, $126^{\circ}35^{\prime}43.18^{\prime\prime}E$), Korea were managed from July 2011 to February 2012 by using closed static chamber method. The average gas fluxes and ranges from freshwater wetland experiment were $0.155{\pm}0.29\;mg\;m^{-2}\;hr^{-1}$ (-0.054~0.942 $mg\;m^{-2}\;hr^{-1}$) for $CH_4$, $17.30{\pm}73.27\;mg\;m^{-2}\;hr^{-1}$ (-52.44~261.66 $mg\;m^{-2}\;hr^{-1}$) for $CO_2$, and $0.004{\pm}0.01\;mg\;m^{-2}\;hr^{-1}$ (-0.02~0.07 $mg\;m^{-2}\;hr^{-1}$) for $N_2O$, respectively. Monthly base flux measurement results revealed that $CH_4$ fluxes during summer months in high water temperature were significantly high, and at least order of one higher than those during other months. The average fluxes and ranges of these greenhouse gases from tidal flat during the experimental period were $0.002{\pm}0.08\;mg\;m^{-2}\;hr^{-1}$ (-0.16~0.22 $mg\;m^{-2}\;hr^{-1}$) for $CH_4$, $-31.18{\pm}75.33\;mg\;m^{-2}\;hr^{-1}$ (-298.87~101.93 $mg\;m^{-2}\;hr^{-1}$) for $CO_2$, and $0.001{\pm}0.01\;mg\;m^{-2}\;hr^{-1}$ (-0.017~0.03 $mg\;m^{-2}\;hr^{-1}$) for $N_2O$, respectively. Comparing the results of gas emissions from tidal flat to those from freshwater wetland, we found significantly lower emissions from tidal flat based on the experiment. Physicochemical parameters of water and soil at these experimental plots were also sampled and analyzed for understanding their correlation with these gas emissions.

• Journal of the Korean Geographical Society
• /
• v.43 no.1
• /
• pp.1-19
• /
• 2008

This study intends to clarify the characteristics and causes of current changes in wintertime precipitation in Korea and to predict the future directions based on surface observational $(1973/04\sim2006/07)$ and modeled (GFDL 2.1) climate data. Analyses of surface observation data demonstrate that without changes in the total amount of precipitation, snowfall in winter (November-April) has reduced by 4.3cm/decade over the $1973\sim2007$ period. Moreover, the frequency and intensity of snowfall have decreased; the duration of snow season has shortened; and the snow-to-rain day ratio (STDR) has decreased. These patterns indicate that the type of wintertime precipitation has changed from snow to rain in recent decades. The snow-to-rain change in winter is associated with the increases of air temperature (AT) over South Korea. Analyses of synoptic charts reveal that the warming pattern is associated with the formation of a positive pressure anomaly core over northeast Asia by a hemispheric positive winter Arctic Oscillation (AO) mode. Moreover, the differentiated warming of AT versus sea surface temperature (SST) under the high pressure anomaly core reduces the air-sea temperature gradient, and subsequently it increases the atmospheric stability above oceans, which is associated with less formation of snow cloud. Comparisons of modeled data between torrent $(1981\sim2000)$ and future $(2081\sim2100)$ periods suggest that the intensified warming with larger anthropogenic greenhouse gas emission in the $21^{st}$ century will amplify the magnitude of these changes. More reduction of snow impossible days as well as more abbreviation of snow seasons is predicted in the $21^{st}$ century.