• 제목/요약/키워드: 오존제거

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저온 공기 표면 플라즈마 특성과 이를 이용한 화학작용제 제독

  • 정희수;서진아;최승기
    • 한국진공학회:학술대회논문집
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    • 한국진공학회 2016년도 제50회 동계 정기학술대회 초록집
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    • pp.195.2-195.2
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    • 2016
  • 대기압 플라즈마는 공기중에서 방전이 가능하고, 이때 생성되는 활성산소종(ROS)과 활성질소종(RNS)을 적절히 이용하면 살균은 물론 제독이 가능하다. 특히 신경작용제나 수포작용제 등의 화학물질은 박테리아 포자, 세균, 바이러스 등의 생물작용제에 비해 더 많은 에너지와 시간이 요구된다. 현재 군이나 의료 시설에서는 과산화수소를 이용한 제독이나 염소계 표백제 성분으로 구성된 수용성 제독제를 이용하지만, 플라즈마의 경우는 단순히 기체를 방전하여 제독에 이용할 수 있으므로 보다 제독 시스템을 간단하게 구성할 수 있다. 하지만 대기압 방전시 방전전압을 낮추기 위해 헬륨과 알곤등의 기체를 공급하여 사용할 경우 부가적인 시스템의 규모가 커져 활용에 제한이 따른다. 따라서 본 연구에서는 대기중에 존재하는 질소, 산소 등을 이온화시키기 위해 10-25kHz의 주파수에서 4.5kV의 8us 펄스전원을 인가하여 공기 플라즈마를 얻고, 열에 의한 분해효과를 제거하기 위해 플라즈마의 기체온도를 20도로 유지시켰다. 플라즈마의 특성은 방출광 분석법을 이용하여 떨림온도를 계산하였고, 질소와 오존의 농도를 동시에 관찰하였다. 분해된 화학작용제는 기체분석기(Gas Chromatography)를 통해 표준 오염농도대비 잔류한 양을 측정함으로써 제독효율을 계산하였다.

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오존과 광촉매를 이용한 Geosmin 제거 및 부산물 생성에 관한 연구 (A Study on removal of Geosmin by Ozonation and Photocatalysis and Generation of by-products)

  • 김영웅;손희종;유명호;김성윤;김철
    • 한국물환경학회지
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    • 제16권4호
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    • pp.445-457
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    • 2000
  • This study was carried out comparing with ozone oxidation and photocatalytic degradation for removal of geosmin. In the change of pH, Ozonation, UV-Germicidal lamp and Halogen lamp irradiation and Halogen $lamp/TiO_2$ Powder was very slowly changing, but UV-Germicidal $lamp/TiO_2$ Powder was rapidly changed from 7.0 to 7.7 until 300min of irradiation time, and varied a little after. Geosmin degradation ratio was as following, UV-Germicidal $lamp/TiO_2$ $Powder(200mg/L){\geq}O_3$ > UV-Germicidal $lamp/TiO_2$ $Pw(100mg/L)$ > UV-Germicidal lamp > Halogen lamp. The result of investigation of generated by-products were 3-Heptanone, two sort of aldehydes and three sort of alcohols by ozonation. But It was not generated by photocatalytic degradation.

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PCR법에 의한 박테리아의 동정 및 오존과 UV에 의한 제거 연구 (Monitoring of Bacteria using PCR Method and Inactivation with Ozone and UV)

  • 오병수;주설;김경숙;강태희;이지영;이혜영;강준원
    • 한국물환경학회지
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    • 제20권2호
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    • pp.170-175
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    • 2004
  • The purpose of this study was to monitor bacteria present in raw water and to investigate the effect of ozone, UV and combined ozone/UV processes for inactivating bacteria. Both polymerase chain reaction (PCR)-fragment length polymorphic analysis (PRA) and PCR-sequence analysis (PSA) were applied for the simultaneous analysis of numerous bacteria species present in each tested water, such as drinking water (DRW), drinking water source (DRWS) and sewage effluent water (SEW). According to the result, the number of detected bacteria species was zero in DRW, 58 in DRWS and 13 in SEW. After treatment of the each process, the ozone/UV process was the most successful for inactivating almost all bacteria. However, it was found that Flavobacterium sp., Pseudomonas sp. and Beta proteobacterium sp. had strong resistant to all tested processes, requiring further detailed study.

오존산화에 의한 정수장의 Microcystin제거 특성에 관한 연구 (A Study on the Removal Characteristics of Microcystin in the Water Treatement Plant by Ozonation)

  • 김민규;권재현;조영하;이진애;권오섭
    • 한국환경보건학회지
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    • 제29권1호
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    • pp.74-83
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    • 2003
  • Microcystin, stable compounds with circular heptapeptides, is presented inside cyanobacterial cell. So far, over 30 types have been known to exist and microcystin-LR, RR among them are the most potent toxin compound. By this reason, a strong oxidant, ozone was used in this study to remove the microcystins produced by cyanobacteria. Removal efficiency of microcystin at M water treatment plant was also evaluated. Microcystin concentration was determined by protein phosphatase inhibition assay. The results showed that dissolved microcystin in raw water detected in the range of 0.011-0.028 ㎍ Microcystin-RR equivalent/l. Above 98% of microcystin was removed through overall treatment system. Therefore, the water treatability of M treatment plant seemed to be excellent. Removal efficiency of microcystin according to unit process varied as characteristics of raw water such as DOC, UV/sub 254/ and turbidity. Removal efficiency of microcystin by ozonation was investigated in laboratory according to contact time and ozone dose. Dissolved microcystin was increased by twice fold according to ozone contact time, but increased by fifth fold according to ozone dose. So, changing of ozone dose more affected microcystin release than changing of ozone contact time. Behavior of microcystin by ozonation was similar to that of DOC, and residual ozone concentration gave influence to removal ratio of microcystin. In conclusion, single ozone treatment wasn't effective on microcystin removal in case of water containing a lot of cells. Therefore, it's more effective to use ozonation process after the removal of cyanobacterial cells in advance.

압력측정용 A/D변환기의 OPAMP 개발 (Development of OPAMP in an A/D Converter for Pressure Measurement)

  • 채용웅
    • 한국전자통신학회논문지
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    • 제5권4호
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    • pp.435-442
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    • 2010
  • 자동차의 와이퍼 브레이드 성능은 자동차 안전성 확보에 크게 기여한다. 유리면에 접착된 먼지나 이물질 등을 제거하는 기능을 확보하기 위해 와이퍼 브레이드는 닦임성, 내구력, 내열 저온 내오존성 내화학성이 높아야 할 뿐만 아니라 소음이 적어야 한다. 이와 같이 와이퍼의 기능 개선을 위해서는 와이퍼의 성능을 평가하고 분석할 수 있는 시스템 장비가 필수적이다. 본 논문에서는 자동차의 와이퍼 누름압을 측정하는 시스템의 개발을 위해 누름압 센서에서 출력되는 신호를 받아 퍼스널 컴퓨터에 전달하는 아날로그 디지털 변환기를 설계하고자 한다. 설계한 ADC는 빠른 동작 속도를 얻으면서 전체 시스템의 면적 및 전력소모를 최적화하는 구조인 파이프라인 ADC이다.

서울과 부산지역 기상의 영향을 제거한 오존농도 추세 (Meteorologically Adjusted Ozone Trends in the Seoul and Susan Metropolitan Areas)

  • 김유근;오인보;황미경
    • 한국대기환경학회지
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    • 제19권5호
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    • pp.561-568
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    • 2003
  • Surface ozone concentrations are highly sensitive to meteorological variability. Therefore, in order to reveal the long-term changes in ozone due to the changes in precursor emissions, we need to remove the effects of meteorological fluctuations on the annual distribution of surface ozone. In this paper, the meteorologically adjusted trends of daily maximum surface ozone concentrations in two major Korean cities (Seoul and Busan) are investigated based on ozone data from 11 (Seoul) and 6 (Busan) sites over the period 1992 ∼ 2000. The original time series consisting of the logarithm of daily maximum ozone concentrations are splitted into long-term, seasonal and short-term component using Kolmogorov-Zurbenko (KZ) filter. Meteorological effects are removed from filtered ozone series using multiple linear regression based on meteorologcial variables. The long-term evolution of ozone forming capability due to changes in precursor emission can be obtained applying the KZ filter to the residuals of the regression. The results indicated that meteorologically adjusted long-term daily maximum ozone concentrations had a significant upward trend (Seoul: + 3.02% yr$^{-1}$ , Busan: + 3.45% yr$^{-1}$ ). These changes of meteorologically adjusted ozone concentrations represent the effects of changing background ozone concentrations as well as the more localized changes in emissions.

오존수를 이용한 프로시미돈의 제거 (Removal of Procymidone by Ozonated Water)

  • 최성우;박신영
    • 한국환경과학회지
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    • 제16권12호
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    • pp.1425-1430
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    • 2007
  • This study was conducted to investigate the effect of ozonated water and ozonated water+hydrogen peroxide treatment of residual procymidone in perilla leaf containing 20 mg/L procymidone. Samples was treated with ozonated water containing 1.0, 2.0 and 3.0 mg $O_3/L$ ozone and hydrogen peroxide water containing 1.0, 2.0 and 3.0 mg $H_2O_2/L$ hydrogen peroxide in pH 5, 7 and 9, respectively, at $15^{\circ}C$. Procymidone removal rate was 26.5% in 7 days at $15^{\circ}C$ and optimum condition of procymidone removal was the case of treating with ozonated water containing 2.0 mg $O_3/L$ and pH 9. As the result procymidone removal rate was about 96.5%. In this case of adding hydrogen peroxide, optimum condition of procymidone removal was $1:0.5{\sim}1(O_3:H_2O_2)$. However, procymidone was nearly removed with the treatment of hydrogen peroxide water only.

고효율 오존장치를 이용한 NOM 제거 및 Bromate 생성 특성 (Investigation on Bromate Formation and Removal of NOM during Ozonation in Super Ozone Mass Transfer Reactor)

  • 송기주;최일환;백경희;이상태
    • 한국물환경학회지
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    • 제22권6호
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    • pp.1137-1143
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    • 2006
  • In this study we investigated the removal characteristics of NOM and bromate formation characteristics in SOMT reactor. The system was recently developed as a novel ozone reactor and installed in SJ pilot plant. DOC values were decreased within 3% after treatment of 0.5~2.0 mg/L ozone dosage in SOMT reactor while the $UV_{254}$ value was 69% decreased at 2.0 mg/L ozone dosage. The composition of NOM was analysed by LC-OCD (Organic Cabon Detector) after ozone treatment in SOMT reactor to elucidate the variation of NOM character. Polysaccharide (more than 20,000 g/mol) fraction of NOM was decomposed while building blocks (350~500 g/mol) and neutral (less than 350 g/mol) fraction increased. Spiked bromide reacted with 0.5~2.0 mg/L ozone dosage in the SOMT reactor. The bromate formation was proportional to the ozone dosage ($R^2=0.978$) but not proportional to reaction time. The maximum concentration of formated bromate was not exceeded to 10% of spiked bromide concentration.

오존과 생물활성탄에 의한 합성세제 제거 특성 연구 (Removal characteristics of surfactant by ozone and biological activated carbon)

  • 구숙현;권진형;이재인;임진경;김동윤
    • 상하수도학회지
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    • 제14권1호
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    • pp.99-107
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    • 2000
  • In this article, the removal of surfactant by ozone and BAC was studied. Batch and pilot tests were carried out for these studies. In batch tests, efficiency of ozone oxidation process was evaluated for LAS(Linear Alkylbenzen Sulfonate) and SLS(Sodium Lauryl Sulfate) removal. Under oxidant conditions, the removal of LAS was more effective than that of SLS. The removal of surfactant was more enhanced with increasing pH in oxidant systems. Pilot tests are carried out with BAC single process and ozone oxidation/BAC combined process. The removal of LAS was more effective in ozone oxidation/BAC combined process than BAC single process about 10-20%. In the case of SLS, the efficiency of BAC single process was similar to that of ozone oxidation BAC combined process. According to temperature, the removal efficiency of SLS changed from 70% to 95% and initial concentration of surfactant had no effects on removal efficiency of SLC under applied temperature above $15^{\circ}C$.

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오존을 이용한 유기물 및 세균의 제거 특성에 관한 연구 (A Study on the Removal Characteristics of Organic matter and Bacteria with the Use of Ozone)

  • 이관영;박상현
    • 한국산업융합학회 논문집
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    • 제10권1호
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    • pp.15-20
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    • 2007
  • The aim of this study is to measure the removal characteristics of organic matter and bacteria with the use of ozone to reduce the problems caused by bacteria and organic matter which appear in sea-water is summer season. When the total input of ozone was $1.4mg/{\ell}O_3$, the removal rate of bacteria and E-coli from sea-water proved to be 100%. With the same input of ozone, on the other hand, the removal rate of COD turned to be relatively low, 50%, which was to the fact that sea-water consists of salt matter which is a kind of COD matter. This result supports the idea that we can keep using ozone steadily in the future to remove organic matters and bacteria from sea-water because ozone destructs relatively less salt matter in sea-water. Also, the treatment effect rate of SS, turbidity and organic matters such as $NH_3$-N, $NO_3$-N etc, was very high. As a result, we assume that the treatment of organic matter in sea-water with ozone is very effective

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