A Study on removal of Geosmin by Ozonation and Photocatalysis and Generation of by-products

오존과 광촉매를 이용한 Geosmin 제거 및 부산물 생성에 관한 연구

  • Kim, Young-Ung (Pusan Water Quality Institute) ;
  • Son, Hee-Jong (Pusan Water Quality Institute) ;
  • Yu, Myung-Ho (Pusan Water Quality Institute) ;
  • Kim, Seong-Yun (Research Laboratory for Nuclear Reactors, Tokyo Institute of Technology) ;
  • Kim, Chul (Department of Envirommental System Engineering, Dongeui Institute of Technology)
  • 김영웅 (부산시 수질연구소) ;
  • 손희종 (부산시 수질연구소) ;
  • 유명호 (부산시 수질연구소) ;
  • 김성윤 (동경공업대학 원자로공학연구소) ;
  • 김철 (동의공업대학 환경시스템공학과)
  • Published : 2000.12.30

Abstract

This study was carried out comparing with ozone oxidation and photocatalytic degradation for removal of geosmin. In the change of pH, Ozonation, UV-Germicidal lamp and Halogen lamp irradiation and Halogen $lamp/TiO_2$ Powder was very slowly changing, but UV-Germicidal $lamp/TiO_2$ Powder was rapidly changed from 7.0 to 7.7 until 300min of irradiation time, and varied a little after. Geosmin degradation ratio was as following, UV-Germicidal $lamp/TiO_2$ $Powder(200mg/L){\geq}O_3$ > UV-Germicidal $lamp/TiO_2$ $Pw(100mg/L)$ > UV-Germicidal lamp > Halogen lamp. The result of investigation of generated by-products were 3-Heptanone, two sort of aldehydes and three sort of alcohols by ozonation. But It was not generated by photocatalytic degradation.

Keywords

References

  1. J.Am.Wat.Wks.Ass. v.80 Optimizing the Removal of Geosmin and 2-MIB by Powdered Activated Carbon Craig,S.L.;Pirbazari,M.;Dale,M.S.;Tanaka,T.;Mcguire,M.J.
  2. Wat.Res. v.30 Biodegradation of a Musty Odor Compounds 2-Methyl-isoborneol and Geosmin Tanaka,a.;Fuchigami,K.
  3. Wat.Res. v.27 Removal of Geosmin and Methylisoborneol from Water by Adsorption on Ultrastable Zeolite-Y Ellis,J.;Korth,W.
  4. Guidelines for Mastering the Properties of Molecular sieve Derouane,E.G.
  5. Wat.Res. v.30 Biodegradation of Powdered Activated Carbon(PAC) Loaded with Aromatic Compounds De Jonge,R.J.;Van Andel,J.G.
  6. Proceedings of a Symposium on Advanced Oxidation Processes Advanced Technology for Destruction of Organic Pollutants by Photocatalysis Hussain,A.E.;Ali,S.A.;Joan,S.;Wendy,S.
  7. Journal of Catalysis v.122 Photocatalytic Degradation of Organic Water Contaminants : Mechanisms involvin Radical Attack Craig,S.T.;David,F.O
  8. J.Phy.Chem. v.83 no.24 Spin Trapping and Electron Spin Resornance of Radical Intermediates in the Photodecomposition of Water at TiO2 Particulate System Calvin,D.J.;Allen,J.B.
  9. Wat.Sci.Tech. v.20 Behavior of Musty Odorous Compounds during the Process of Water Treatment Ashitani,K.;Hishida,Y.;Fujiwara,K.
  10. 부산수질연구소 상수도연구보 제4집 흡착제를 이용한 수중의 미량이취물질 분석법 개발에 관한 연구 손희종;조이규;정철원;배효무;이수애
  11. 대한환경공학회지 v.12 no.2 오존, 과산화수소, UV를 이용한 고급산화처리 공정의 kinetic에 관한 연구(Ⅰ) 강준원
  12. Chem.Rev. v.93 Photochemical Processes for Water Treatment Legrini,O.;Oliveros,E.;Braun,A.M.
  13. Lehrgang Nr.13656/43.127, UV-Strahlung-Erzeugung, Messung und Anwendungen Anlaysenverfahren mit UV-photobiologische UV-Wirkungen, medizinische und kosmetische UV-Behandlung, UV-Entkeimung von Wasser, Luft etc Schulz,J.P.
  14. Journal of AWWA v.82 no.10 Assessing ozonation research needs in water treatment Phlip,C.S.